REV IEW TE ST-3

PAPER CODE : A
Class : XIII (XYZ)
Time : 3 hour Max. Marks : 216
INSTRUCTIONS

1. The question paper contains 72 questions and 20 pages. Each question carry 3 marks and all of them are
compulsory. There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.
Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.

2. Indicate the correct answer for each question by filling appropriate bubble in your OMR sheet.

3. Use only HB pencil for darkening the bubble.

4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

5. The answer of the questions must be marked by shading the circles against the question by dark HB pencil only.

6. The answer(s) of the questions must be marked by shading the circles against the question by dark HB
pencil only.
For example if only 'B' choice is correct then, the correct method for filling the bubble is
A B C D

the wrong method for filling the bubble are

(i) A B C D

(ii) A B C D

(iii) A B C D

The answer of the questions in wrong or any other manner will be treated as wrong.

USEFUL DATA
Atomic weights: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4,
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, R = 109637 cm–1
 Select the correct alternative. (Only one is correct) [72×3 = 216]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.111 Number of rectangles with sides parallel to the coordinate axes whose vertices are all of the form (a, b)
with a and b integers such that 0  a, b  n, is (n  N)
n 2 (n  1) 2 (n  1) 2 n 2 (n  1) 2
(A) (B) (C) (D) n2
4 4 4

1
Q.212 Number of roots of the function f (x) = – 3x + sin x is
( x  1) 3
(A) 0 (B) 1 (C) 2 (D) more than 2

Q.313 If p (x) = ax2 + bx + c leaves a remainder of 4 when divided by x, a remainder of 3 when divided by
x + 1, and a remainder of 1 when divided by x – 1 then p(2) is
(A) 3 (B) 6 (C) – 3 (D) – 6

Q.414 Let f (x) be a function that has a continuous derivative on [a, b], f (a) and f (b) have opposite signs, and
f ' (x)  0 for all numbers x between a and b, (a < x < b). Number of solutions does the equation
f (x) = 0 have (a < x < b).
(A) 1 (B) 0 (C) 2 (D) cannot be determined

Q.515 Which of the following definite integral has a positive value?

2 3 
3 0 0 2
(A)  sin(3x  )dx (B) 2sin(3x  )dx (C)  sin(3x  )dx
3 
(D)  sin(3x  )dx
0 0
3 2

ROUGH WORK
Q.616 Let set A consists of 5 elements and set B consists of 3 elements. Number of functions that can be
defined from A to B which are neither injective nor surjective, is
(A) 99 (B) 93 (C) 123 (D) none

Q.717 A circle with center A and radius 7 is tangent to the sides of an angle of
60°. A larger circle with center B is tangent to the sides of the angle and
to the first circle. The radius of the larger circle is
(A) 30 3 (B) 21
(C) 20 3 (D) 30
   
Q.818 The value of the scalar p  q · r  s  can be expressed in the determinant form as
       
q · r q ·s p · r p ·s p · r q ·s p·
r p·s
(A)     (B)     (C)     (D) q · r q ·s
p · r p ·s q ·s q · r q · r p ·s

 x 1 
Q.919 If Lim x ·ln 0 1 x  = – 5, where , ,  are finite real numbers then
x 
1 0 1x
(A)  = 2,  = 1,   R (B)  = 2,  = 2,  = 5
(C)   R,  = 1,   R (D)   R,  = 1,  = 5

Q.1020 If f (x, y) = sin–1( | x | + | y | ), then the area of the domain of f, is

(A) 2 (B) 2 2 (C) 4 (D) 1
Q.1121 A, B and C are distinct positive integers, less than or equal to 10. The arithmetic mean of A and B is 9.
The geometric mean of A and C is 6 2 . The harmonic mean of B and C is
9 8 7 8
(A) 9 (B) 8 (C) 2 (D) 2
19 9 19 17
ROUGH WORK
Q.1222 If x is real and 4y2 + 4xy + x + 6 = 0, then the complete set of values of x for which y is real, is
(A) x  2 or x  3 (B) x  – 2 or x  3
(C) – 3  x  2 (D) x  – 3 or x  2

Q.1323 I alternatively toss a fair coin and throw a fair die until I, either toss a head or throw a 2. If I toss the coin
first, the probability that I throw a 2 before I toss a head, is
(A) 1/7 (B) 7/12 (C) 5/12 (D) 5/7

Q.1424 Let A, B, C, D be (not necessarily square) real matrices such that

AT = BCD; BT = CDA; CT = DAB and DT = ABC
for the matrix S = ABCD, consider the two statements.
I S3 = S
II S2 = S 4
(A) II is true but not I (B) I is true but not II
(C) both I and II are true (D) both I and II are false.

Q.151 The area of the region of the plane bounded above by the graph of x2 + y2 + 6x + 8 = 0 and below by
the graph of y = | x + 3 |, is
 2 
(A) (B) (C) (D) 
4 4 2

Q.162 Consider straight line ax + by = c where a, b, c  R+ and a, b, c are distinct. This line meets the
coordinate axes at P and Q respectively. If area of OPQ, 'O' being origin does not depend upon a, b
and c, then
(A) a, b, c are in G.P. (B) a, c, b are in G.P. (C) a, b, c are in A.P. (D) a, c, b are in A.P.

ROUGH WORK
Q.173 If x and y are real numbers and x2 + y2 = 1, then the maximum value of (x + y)2 is
(A) 3 (B) 2 (C) 3/2 (D) 5

dx
Q.184 The value of the definite integral  (1  x a )(1  x 2 ) (a > 0) is
0

 
(A) (B) (C)  (D) some function of a.
4 2
a b c
cos  cos cos
Q.195 Let a, b, c are non zero constant number then Lim r r r equals
r  b c
sin sin
r r
a 2  b2  c2 c2  a 2  b2 b2  c2  a 2
(A) (B) (C) (D) independent of a, b and c
2bc 2bc 2bc

Q.206 A curve y = f (x) such that f ''(x) = 4x at each point (x, y) on it and crosses the x-axis at (–2, 0) at an
angle of 45°. The value of f (1), is
55 35
(A) – 5 (B) – 15 (C) – (D) –
3 3
sin x cos x tan x cot x
Q.217 The minimum value of the function f (x) = + + +
1  cos 2 x 1  sin 2 x sec 2 x  1 cosec2 x  1
as x varies over all numbers in the largest possible domain of f (x) is
(A) 4 (B) – 2 (C) 0 (D) 2

ROUGH WORK
Q.228 A non zero polynomial with real coefficients has the property that f (x) = f ' (x) · f ''(x). The leading
coefficient of f (x) is
1 1 1 1
(A) (B) (C) (D)
6 9 12 18
1
n
tan 1 (nx ) n 2 ·C n equals
Q.239 Let Cn = 1 1
sin (nx )
dx then Lim
n 

n 1

1
(A) 1 (B) 0 (C) – 1 (D)
2

Q.2410 Let z1, z2, z3 be complex numbers such that z1 + z2 + z3 = 0 and | z1 | = | z2 | = | z3 | = 1 then
z12  z 22  z 32 , is
(A) greater than zero (B) equal to 3 (C) equal to zero (D) equal to 1

ROUGH WORK
Q.2535 Select correct code about complex [Cr(NO2)(NH3)5][ZnCl4]
(I) IUPAC name of the compound is Pentaammine nitrito-N chromium (III) tetra chlorozincate (II)
(II) It shows geometrical isomerism
(III) It shows linkage isomerism
(IV) It shows co-ordination isomerism
(A) III, IV (B) I, III & IV (C) II, III & IV (D) I, II, III & IV
Q.2636 Which statement about the following equilibrium is/are true?
  

Ph3C–H + Me O K l Ph 3 C K + MeOH
(I) The reaction favours the product formation.
(II) Ph3CK is the dominant anionic species in this reaction.
(III) Methanol is the weaker acid in this reaction.
(IV) The reaction favours the reactant formation.
(A) I & II (B) I, II & III (C) IV only (D) III & IV
Q.2737 Select correct statement(s):
(A) Acidic strength of HBr > HCl but reverse is true for their reducing property
(B) Basic strength of PH3 > AsH3 but reverse is true for their Bond angle
(C) Dipole moment of CH3Cl > CH3F but reverse is true for their HCH ^ bond angle

(D) K a1 of fumaric acid is higher than maleic acid but reverse is true for their K a
2

Q.2838 Which one of following carbonyl compound when treated with dilute acid forms the more stable
carbocation?
O O
|| ||
(A) CH 3  C  CH 3 (B) (C) (D) C6 H 5  C  C 6 H 5

ROUGH WORK
Q.2939 Select the correct code regarding total number of space isomers for the following compounds:
(I) [Ma 3b 2c]n  (II) [M (AB)3 ]n  (III) [Ma 2 b 2c 2 ]n 
(I) (II) (III)
(A) 4 4 6
(B) 4 3 5
(C) 3 3 5
(D) 3 4 6

Q.3040 Correct order of heat of combustion is:

(p) 1,3-Pentadiene (q) 1,3-Butadiene
(r) 2,3-Dimethyl-1, 3-butadiene (s) Propadiene
(A) s > q > p > r (B) s > r > q > p (C) r > p > q > s (D) s > r > p > q

Q.3141 Which of the angle is most influenced by the presence of lone pair in SF4.
(A) Equatorial angle (B) axial angle
(C) Angle between axial and equatorial (D) None

Q.3242 The most stable resonating structure of following compound is

(A) (B)

(C) (D)

ROUGH WORK
Q.3343 How many geometrical isomers are possible for [Pd2+ (NH2–CH(CH3)– CO 2 )2]o
(A) 2 (B) 3 (C) 4 (D) 6

Q.3444 Write correct order of reactivity of following halogen derivatives.

(I) (II) CH2=CH–Cl (III) Et3C–Cl (IV) PhCH2Cl (V) Ph3C–Cl

(A) I > V > IV > III > II (B) V > IV > I > III > II
(C) V > I > IV > III> II (D) I > V > III > IV > II

Q.3545 Choose the correct option regarding the following complex compound which follows (F) and does not
follow (NF) the sidgwick EAN rule:
(I) [(Ph3P)2PdCl2PdCl2] (II) [NiBrCl(en)]
(III) Na4[Fe(CN)5NOS] (IV) Cr(CO)3(NO)2
(I) (II) (III) (IV)
(A) NF NF NF NF
(B) F F NF F
(C) NF NF F F
(D) NF NF F NF

Q.3646 Correct order of basicity is:

(I) (II) (III) (IV)

(A) I > II > III > IV (B) II > I > III > IV (C) II > III > I > IV (D) II > III > IV > I

ROUGH WORK
Q.3747 Total number of isomers of [Co(acac)2BrCl]r are
(A) 4 (B) 3 (C) 6 (D) 2

Q.3848 Correct order of nucleophilicity of following anions in polar protic solvent is:
       
(A) CH 3 > NH 2 > OH > F (B) CH 3 < NH 2 < OH < F
   
(C) CH 3 = NH 2 = OH  = F  (D) CH 3 > F > OH > NH 2

Q.3925 If decomposition reaction X (g)  Y (g) + Z (g) follows first order kinetics then the graph of rate of
formation (R) of Y against time t will be

(A) (B) (C) (D)

Q.4026 Which one of following represents different molecules?

(A) and (B) and

(C) and (D) and

Q.4127 Which of the following is an oxidizing agent?

(A) Mn(CO)5 (B) Fe(CO)5 (C) Mn2(CO)10 (D) Fe2(CO)9

ROUGH WORK
Q.4228 The equilibrium constant for the ionization of R–NH2(g) in water as
R–NH 2(g) + H2O(l) l R–NH3+(aq) + OH–(aq)
–6
is 8 × 10 at 25°C. Find the pH of a solution at equilibrium with pressure of R–NH2(g) is 0.5 bar.
[Take log 2.82 = 0.45]
(A)  12.3 (B)  11.3 (C)  11.45 (D) None

Q.4329 Which statement(s) is/are true about the relation between the following compounds?

(a) (b) (c)

(I) a and b are tautomers (II) b and c are resonating structures

(III) a and c are resonating structures (IV) a and c are tautomers
(A) I & III (B) II & IV (C) I, II & III (D) I & IV

Q.4430 Select correct statement about given square planar complex.

(A) It has no geometrical isomer.

(B) It is optically active because it does not have plane of symmetry.
(C) It is optically inactive because square planar complexes have plane of symmetry.
(D) It is optically active because it has symmetric carbon.

ROUGH WORK
Q.4531 XeF2 (g) + H2(g)  2HF(g) + Xe(g) H° = – 430 kJ
using the following bond energies : H–H = 435 kJ/mol
H–F = 565 kJ/mol
Calculate the average bond energy of Xe–F in XeF2.
(A) 267 kJ/mol (B) 562.5 kJ/mol (C) 132.5 kJ/mol (D) None

Q.4632 Arrange the following carbocations in the increasing order of their stability.

(I) (II) (III)

(A) I > II > III (B) I > II = III (C) I > III > II (D) III > I > II

Q.4733 The total possible co-ordination isomers for the following compounds respectively are
[Co(en)3] [Cr(C2O4)3]
[Cu(NH3)4] [CuCl4]
[Ni(en)3] [Co(NO2)6]
(A) 4, 4, 4 (B) 2, 2, 2 (C) 2, 2, 4 (D) 4, 2, 4

Q.4834 Calculate f H° (in kJ/mol) for Cr2O3 from the rG° and the S° values provided at 27°
4Cr(s) + 3O2(g)  2Cr2O3(s) rG° = – 2093.4 kJ/mol
S°(J/K mole) : S°(Cr, s) = 24 ; S°(O2, g) = 205 ; S° (Cr2O3, s) = 81
(A) –2258.1 (B) –946.35 (C) –1129.05 (D) None

ROUGH WORK
Q.4959 A particle of mass m is projected at an angle of 60° with a velocity of
20 m/s relative to the ground from a plank of same mass m which is
placed on smooth surface. Initially plank was at rest. The minimum length
of the plank for which the ball will fall on the plank itself is (g = 10 m/s2)
(A) 40 3 m (B) 20 3 m (C) 10 3 m (D) 60 3 m
Q.5060 A man pulls a bucket of water from a well of depth h. If the mass of the uniform rope and bucket full of
water are m and M respectively. The value of work done by the man is
m  mM
(A) (m+M) gh (B)   M  gh (C)   gh (D) None of the above
2   2 

Q.5161 If the mass of block is 1 kg and a force of 10 3 N is applied horizontally

on the block as shown in the figure. The frictional force acting on the
block is
10 20
(A) zero (B) N (C) N (D) 5 N
3 3

Q.5262 A beaker contains 200 g of water. The water equivalent of beaker is 20 gm. The initial temperature of
water in the beaker is 20°C. If 440 g of hot water at 92°C is poured in, the final temperature, neglecting
radiation loss, will be nearest to:
(A) 58°C (B) 68°C (C) 73°C (D) none

ROUGH WORK
Q.5363 The friction force acting between surfaces in contact in the adjoining figure is best represented by

(A) (B)

(C) (D)

 
Q.5464 Two particles having position vectors r1  (3î  5 ĵ) m and r2  (5î  3 ĵ) m are moving with velocities
 
v1  (4î  3 ĵ) m/s and v 2  (a î  7 ĵ) m/s. If they collide after 2 sec, the value of 'a' is
(A) 2 (B) 4 (C) 6 (D) 8

Q.5565 In the balance machine shown in the figure, which arm will move downward
after the system is released (assuming string and the pulley to be ideal)
(A) left (B) right
(C) remains stationary (D) none of these

Q.5666 A point moves on a circle of radius 2 meter and its speed depends on the distance covered as v =  S ,
the time taken by the particle in making the full circle is
(A) 2 sec. (B) 3 sec. (C) 4 sec. (D) none

ROUGH WORK
Q.5767 A plane mirror of length 2 m is kept along the line y = –x as shown in the
figure. An insect having velocity of 4 î cm/s is moving along the x-axis
from far away. The time span for which the insect can see its image will
be
(A) 50 sec (B) 25 sec
(C) 25 2 sec (D) 50 2 sec

Q.5868 The U(x)– x curve for system in shown in the figure. Its force curve will be:

(A) (B) (C) (D)

ROUGH WORK
Q.5969 You want to hit a small box on the floor with a marble fired from a spring-loaded gun that is mounted on
a table. The target box is a distance R horizontally from the edge of the table; see the figure. You
compress the spring a distance d, but the center of the marble falls short by a distance r of the center of
the box. How far (x) should you compress the spring to score a direct hit (neglect friction)?

d2 d (R  r ) d (R  r ) Rd
(A) x = (B) x = (C) x = (D) x =
R r R Rr R r

Q.6070 Two particles tied to different strings are whirled in a horizontal circle as shown in figure. The ratio of
length of the strings (L2/L1) so that they complete their circular path with equal time period is
3 2
(A) (B)
2 3
(C) 1 (D) none of these

Q.6171 A small object placed on a rotating horizontal turn table just slips when it is placed at a distance of 4 cm
from the axis of rotation. If the angular velocity of the turn table is doubled, the object slips when its
distance from the axis of rotation is
(A) 8 cm (B) 4 cm (C) 2 cm (D) 1 cm
ROUGH WORK
Q.6272 A small block of mass m is released from A inside the frictionless circular groove of radius 2 m on an
inclined plane as shown in figure. The contact force between the block and inclined plane at point B is

(A) 28 mg (B) 2.5 mg

28
(C) mg (D) 18.5 mg
2

Q.6349 Two isochoric cooling process AB and CD are shown in P-V diagram for the same gas. In which case
heat exchange will be more.

(A) AB (B) same in both cases (C) CD (D) can't say

Q.6450 PV versus T graph of equal masses of H2, He and CO2 is shown in figure. Choose the correct alternative
(A) 3 corresponds to H2, 2 to He and 1 to CO2
(B) 1 corresponds to He, 2 to H2 and 3 to CO2
(C) 1 corresponds to He, 3 to H2 and 2 to CO2
(D) 1 corresponds to CO2, 2 to H2 and 3 to He

ROUGH WORK
Q.65 Two smooth cylindrical bars weighing W N each lie next to each other in contact. A similar third bar is
51
placed over the two bars as shown in figure. Neglecting friction, the minimum horizontal force on each
lower bar necessary to keep them together is

(A) W/2 (B) W (C) W/ 3 (D) W/(2 3 )

Q.6652 A particle of mass m is made to move with a uniform speed v0 along the perimeter of a regular hexagon.
The magnitude of impulse applied at each corner of the hexagon is
   
(A) 2mv0 sin   (B) mv0 sin   (C) mv0 sin   (D) 2mv0 sin  3 
6 6 3  

Q.6753 A river is flowing with velocity 2 m/s. A boat is moving downstream. Velocity of boat in still water is
3 m/s. A person standing on boat throws a ball vertically upwards w.r.t himself with a velocity of
10 m/s. At the top most point, the velocity of ball w.r.t man standing on boat w.r.t river and w.r.t ground
respectively is
(A) 5, 3, 0 m/s (B) 0, 3, 5 m/s (C) 0, 5, 3 m/s (D) none of these

Q.6854 An object starts moving at an angle of 45° with the principal axis as shown in the figure in front of a
biconvex lens of focal length +10 cm. If  denotes the angle at which image starts to move with principal
axis then
3 
(A)  = (B)  =
4 2
 
(C)  = (D)  = –
4 4

ROUGH WORK
Q.69 Two pieces of wire A and B of the same material are stretched by the same force. The ratio of the length
55
of A to that of B is 1:2 and the ratio of their diameters is 2:1. The ratio of the elongation of A to that of B
is
(A) 1:4 (B) 4:1 (C) 1:8 (D) 1:1

Q.7056 A concave mirror of radius of curvature 40 cm forms an image of an object placed on the principal axis
at a distance 45 cm in front of it. Now if the system is completely immersed in water ( = 1.33) then
(A) the image will shift towards the mirror
(B) the magnification will reduce
(C) the image will shift away from the mirror and magnification will increase.
(D) the position of the image and magnification will not change.

Q.7157 A carrom board has queen at the centre. The queen hit by the striker goes in the hole without rebound
when striker is struck perpendicular to striking line. Impact parameter depend upon
(A) coefficient of restitution
(B) masses of striker & queen.
(C) roughness of the surface of board
(D) radius of queen and striker
Q.7258 Imagine a hypothetical material whose average temperature coefficient of linear expansion is 0.1 /°C.
Find the fractional increase in the area of a thin square plate of above material when temperature increase
by 10°C.
(A) 1 (B) 2 (C) 3 (D) None

ROUGH WORK