P A P ER - 1

PART-A

Select the correct alternative. (Only one is correct) [99 × 3 = 297]

There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.34 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2A+) is taken. The pka
of –COOH group in methionine is 2.8 and pkb of basic group is 4.8. Pick out only incorrect statement
among the following. [Use log 2 = 0.3]
(A) pH of original amino acid solution was ~ 2.05
(B) pH of solution was ~ 2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution is ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D*) pH of solution is 3.8 when 20 ml 0.05 M NaOH solution is added to original solution

Q.35 Which of the following compound(s) will give blue colour when it is converted into Lassaigne's extract
and FeSO4 is added followed by FeCl3.

(I) (II) (III) CH3–NMe2 (IV) NH2–NH2

(A*) III only (B) II & III (C) II, III & IV (D) I, II, III & IV

Q.36 ZnO shows yellow colour on Heating due to

(A) d–d transition (B) C–T spectra
(C) Higher polarisation caused by Zn2+ ion (D*) F– centres

Q.37 The decomposition of N2O5 in chloroform was followed by measuring the volume of O2 gas evolved :
2N2O5 (CCl4) 2N2O4 (CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In
500 minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min –1) for the rate of
disappearance of N2O5 is
2.303 2.303 100 2.303 90 100
(A*) (B) log (C) log (D)
500 500 90 500 100 10  500

Q.38 What will be the order of rotation barriers about C–N bond among these compounds ?

(I) CH3–CH2–NH2 (II) (III)

(A) I > II > III (B*) I < II < III (C) II > III > I (D) III > I > II

Q.39 Complex compound [Cr(NCS)(NH3)5] [ZnCl4] will be

(A) Colourless & diamagnetic
(B) Green coloured & diamagnetic
(C*) Green coloured & shows coordination isomerism
(D) Diamagnetic & shows linkage isomerism
Q.40 The vapour pressure of pure perflourocyclohexane (C6F12) are given by the following equations:
1890
Solid C6F12 : log10 p(mm Hg) = 8.68 –
T
1530
Liquid C6F12 : log10 p(mm Hg) = 7.60 –
T
The molar enthalpy of fusion of solid C6F12 is approximately
(A*) 1658 cal (B) 360 cal (C) 3420 cal (D) 720 cal

Q.41 + HNO3 + H2SO4  Product.

Product is:

(A*) (B) (C) (D) Both B & C

Q.42 Which of the following is correct.

(A) F2 has higher dissociation energy than Cl2
(B) F has higher electron affinity than Cl
(C) HF is stronger acid than HCl
(D*) Boiling point increases down the group in halogens


Q.43 N H 3 – CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A*) 9.4 (B) 1.2 (C) 7.6 (D) 2.4

Q.44 The product of I– with MnO 4 in alkaline medium is

(A) I2 (B*) IO3 (C) IO– (D) IO 4

Q.45 Which of the following will racemize in presence of acid or base impurities in aqueous medium.

CH 3 H
| |
(A) Me  C  C  Ph (B) Me  C  CH 2  C  CH 3
|| | || |
O Cl O D

H
|
(C) (D*) Ph  C  C  CH 2  CH 3
|| |
O CH 3
Q.46 (X) + K2CO3 + Air Heat  (Y)
(Y) + Cl2  (Z) Pink
Which of the following is correct?
(A) X = black, MnO2 , Y = Blue, K2CrO4, Z = KMnO4
(B) X = green, Cr2O3, Y = Yellow, K2CrO4 , Z = K2Cr2O7
(C*) X = black, MnO2 Y = green , K2MnO4, Z = KMnO4
(D) X = black, Bi2O3, Y = colourless KBiO2, Z = KBiO3

Q.47 Write correct order of stability

(A) I > II > III > IV (B*) III > II > I > IV (C) III > I > II > IV (D) III > II > IV > I

Q.48 The structure of diborane (B2H6) contains

(A) Four (2C–2e–) bonds and two (2C–3e–) bonds
(B) Two (2C–2e–) bonds and two (3C–2e–) bonds
(C) Four (2C–2e–) bonds and four (3C– 2e–) bonds
(D*) None

Q.49 This question consist of two statements each, printed as assertion and reason, while answering this
question you are required to choose any one of the following responses.
(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertion is true but the reason is false.
(D) If assertion is false but the reason is true.
Assertion : Me MgBr give CH4 with acetone.
Reason :  – H of carbonyl compounds are active (acidic). [Ans. D]

Q.50 Nitrogen dioxide can not be obtained from

(A) Cu(NO3)2 (B) Hg(NO3)2 (C*) NaNO3 (D) AgNO3

Q.51 PhCHO & HCHO will behave differently with which of the following reagents
(A) Tollen's Reagent (B*) Fehling Solution (C)Schiff's reagent (D) NaBH4

Q.52 The oxide does not have coordinate bond is

(A) N2O (B*) NO (C) N2O5 (D) NO2
Q.53 & are:

(A*) chain isomers (B) positional isomers (C) conformers (D) enantiomers

Q.54 FeSO4 is a very good absorber for NO, the new compound formed by this process is found to contain
number of unpaired electrons
(A) 4 (B) 5 (C*) 3 (D) 6

Q.55 Most stable form of ethylene glycol is:

(A) anti (B*) gauche (C) fully eclipsed (D) partially eclipsed

Q.56 The formation of PH 4 is difficult compared to NH 4 because

(A) lone pair of phosphorus is optically inert
(B) lone pair of phosphorus resides at almost pure p-orbital
(C) lone pair of phosphorus resides at sp3 orbital
(D*) lone pair of phosphorus resides at almost pure s-orbital

Q.57 Which of the following heptanols are chiral 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol.
(A) All are chiral (B*) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol

Q.58 What products are formed during, the electrolysis of a concentrated aqueous solution of NaCl?
(I) Cl2 (g) (II) NaOH (aq) (III) H2 (g)
(A) I only (B) I & II only (C) I & III only (D*) I, II & III

Q.59 Predict the major product P in following reaction:

NaNO
 
2  P
HCl

(A*) (B)

(C) (D)
Q.60 The product Octalone is obtained by Michael addition followed by aldol condensation of reactants R
and S in presence of a base. S gives positive iodoform test.

B ,
R + S 

Octalone
R and S are respectively:

(A) + CH3–CH=O (B) + CH 2  CH  C  H

||
O

(C*) + CH 2  CH  C  CH 3 (D) + CH 3  CH 2  C  CH 3
|| ||
O O

Question No. 61 & 62 (2 questions)

Q.61 Step C (refining) involved in purification of Pb metal

(A) Distillation (B) Bessemerization
(C) Cupelation (D*) Electrolytic refining

Q.62 Which of the following metals are obtained by auto reduction method:
Pb, Mn, Cu, Cr, Fe, Al.
(A) Cu, Fe (B) Cu, Pb, Mn (C) Mn, Cr, Pb (D*) Pb, Cu

Q.63 This compound on ozonolysis gives which of the following compounds

O
||
(I) (II) OHC  C  C  CH 2  C  CHO
|| ||
O O

O
||
(III) CHO (IV) OHC  C  C  CH 2  CH  O
| ||
CHO O
(A) I, II, III & IV (B) I, III, IV (C*) I, II, III (D) I, II, IV
 CH ONa
Q.64 In the reaction; 3 ; the product is
CH 3OH

(A) (B*) (C) (D)

Q.65 The correct IUPAC name of the following compound is:

O  C  CH 2  CH  CHO
| |
OH HC  O
(A) 3,3-diformyl propanoic acid (B*) 3-formyl-4-oxo-butanoic acid
(C) 3,3-dioxo propanoic acid (D) 3,3-dicarbaldehyde propanoic acid

HBr
Q.66 CH2=CH–CH2–CH2–CCH ( Product is
1eq )
(A) BrCH2–CH2–CH2–CH2–CCH (B) CH2=CH–CH2–CH2–CH = CH–Br
(C) CH 2  CH  CH 2  CH 2  C  CH 2 (D*) CH 3  CH  CH 2  CH 2  C  CH
| |
Br Br
 P A P ER - 1

PART-A

Select the correct alternative. (Only one is correct) [99 × 3 = 297]

There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.34 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2A+) is taken. The pka
of –COOH group in methionine is 2.8 and pkb of basic group is 4.8. Pick out only incorrect statement
among the following. [Use log 2 = 0.3]
(A) pH of original amino acid solution was ~ 2.05
(B) pH of solution was ~ 2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution is ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D*) pH of solution is 3.8 when 20 ml 0.05 M NaOH solution is added to original solution

Q.35 Which of the following compound(s) will give blue colour when it is converted into Lassaigne's extract
and FeSO4 is added followed by FeCl3.

(I) (II) (III) CH3–NMe2 (IV) NH2–NH2

(A*) III only (B) II & III (C) II, III & IV (D) I, II, III & IV

Q.36 ZnO shows yellow colour on Heating due to

(A) d–d transition (B) C–T spectra
(C) Higher polarisation caused by Zn2+ ion (D*) F– centres

Q.37 The decomposition of N2O5 in chloroform was followed by measuring the volume of O2 gas evolved :
2N2O5 (CCl4) 2N2O4 (CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In
500 minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min –1) for the rate of
disappearance of N2O5 is
2.303 2.303 100 2.303 90 100
(A*) (B) log (C) log (D)
500 500 90 500 100 10  500

Q.38 What will be the order of rotation barriers about C–N bond among these compounds ?

(I) CH3–CH2–NH2 (II) (III)

(A) I > II > III (B*) I < II < III (C) II > III > I (D) III > I > II

Q.39 Complex compound [Cr(NCS)(NH3)5] [ZnCl4] will be

(A) Colourless & diamagnetic
(B) Green coloured & diamagnetic
(C*) Green coloured & shows coordination isomerism
(D) Diamagnetic & shows linkage isomerism
Q.40 The vapour pressure of pure perflourocyclohexane (C6F12) are given by the following equations:
1890
Solid C6F12 : log10 p(mm Hg) = 8.68 –
T
1530
Liquid C6F12 : log10 p(mm Hg) = 7.60 –
T
The molar enthalpy of fusion of solid C6F12 is approximately
(A*) 1658 cal (B) 360 cal (C) 3420 cal (D) 720 cal

Q.41 + HNO3 + H2SO4  Product.

Product is:

(A*) (B) (C) (D) Both B & C

Q.42 Which of the following is correct.

(A) F2 has higher dissociation energy than Cl2
(B) F has higher electron affinity than Cl
(C) HF is stronger acid than HCl
(D*) Boiling point increases down the group in halogens


Q.43 N H 3 – CH(R)– CO2H has its Ka1 = 10–7. The isoelectric point of the -amino acid occur at pH = 8.2
hence pKa2 of the conjugate acid of -amino acid is equal to
(A*) 9.4 (B) 1.2 (C) 7.6 (D) 2.4

Q.44 The product of I– with MnO 4 in alkaline medium is

(A) I2 (B*) IO3 (C) IO– (D) IO 4

Q.45 Which of the following will racemize in presence of acid or base impurities in aqueous medium.

CH 3 H
| |
(A) Me  C  C  Ph (B) Me  C  CH 2  C  CH 3
|| | || |
O Cl O D

H
|
(C) (D*) Ph  C  C  CH 2  CH 3
|| |
O CH 3
Q.46 (X ) + K 2CO3 + Air Heat
 (Y)
(Y) + Cl2  (Z) Pink
Which of the following is correct?
(A) X = black, MnO2 , Y = Blue, K2CrO4, Z = KMnO4
(B) X = green, Cr2O3, Y = Yellow, K2CrO4 , Z = K2Cr2O7
(C*) X = black, MnO2 Y = green , K2MnO4, Z = KMnO4
(D) X = black, Bi2O3, Y = colourless KBiO2, Z = KBiO3

Q.47 Write correct order of stability

(A) I > II > III > IV (B*) III > II > I > IV (C) III > I > II > IV (D) III > II > IV > I

Q.48 The structure of diborane (B2H6) contains

(A) Four (2C–2e–) bonds and two (2C–3e–) bonds
(B) Two (2C–2e–) bonds and two (3C–2e–) bonds
(C) Four (2C–2e–) bonds and four (3C– 2e–) bonds
(D*) None

Q.49 This question consist of two statements each, printed as assertion and reason, while answering this
question you are required to choose any one of the following responses.
(A) If both assertion and reason are true and the reason is a correct explanation of assertion.
(B) If both assertion and reason are true but reason is not a correct explanation of assertion.
(C) If assertion is true but the reason is false.
(D) If assertion is false but the reason is true.
Assertion : Me MgBr give CH4 with acetone.
Reason :  – H of carbonyl compounds are active (acidic). [Ans. D]

Q.50 Nitrogen dioxide can not be obtained from

(A) Cu(NO3)2 (B) Hg(NO3)2 (C*) NaNO3 (D) AgNO3

Q.51 PhCHO & HCHO will behave differently with which of the following reagents
(A) Tollen's Reagent (B*) Fehling Solution (C)Schiff's reagent (D) NaBH4

Q.52 The oxide does not have coordinate bond is

(A) N2O (B*) NO (C) N2O5 (D) NO2
Q.53 & are:

(A*) chain isomers (B) positional isomers (C) conformers (D) enantiomers

Q.54 FeSO4 is a very good absorber for NO, the new compound formed by this process is found to contain
number of unpaired electrons
(A) 4 (B) 5 (C*) 3 (D) 6

Q.55 Most stable form of ethylene glycol is:

(A) anti (B*) gauche (C) fully eclipsed (D) partially eclipsed

Q.56 The formation of PH 4 is difficult compared to NH 4 because

(A) lone pair of phosphorus is optically inert
(B) lone pair of phosphorus resides at almost pure p-orbital
(C) lone pair of phosphorus resides at sp3 orbital
(D*) lone pair of phosphorus resides at almost pure s-orbital

Q.57 Which of the following heptanols are chiral 1-heptanol, 2-heptanol, 3-heptanol, 4-heptanol.
(A) All are chiral (B*) 2-heptanol and 3-heptanol
(C) 2-heptanol, 3-heptanol & 4-heptanol (D) 3-heptanol and 4-heptanol

Q.58 What products are formed during, the electrolysis of a concentrated aqueous solution of NaCl?
(I) Cl2 (g) (II) NaOH (aq) (III) H2 (g)
(A) I only (B) I & II only (C) I & III only (D*) I, II & III

Q.59 Predict the major product P in following reaction:

NaNO
 
2  P
HCl

(A*) (B)

(C) (D)
Q.60 The product Octalone is obtained by Michael addition followed by aldol condensation of reactants R
and S in presence of a base. S gives positive iodoform test.

B ,
R + S 

Octalone
R and S are respectively:

(A) + CH3–CH=O (B) + CH 2  CH  C  H

||
O

(C*) + CH 2  CH  C  CH 3 (D) + CH 3  CH 2  C  CH 3
|| ||
O O

Question No. 61 & 62 (2 questions)

Q.61 Step C (refining) involved in purification of Pb metal

(A) Distillation (B) Bessemerization
(C) Cupelation (D*) Electrolytic refining

Q.62 Which of the following metals are obtained by auto reduction method:
Pb, Mn, Cu, Cr, Fe, Al.
(A) Cu, Fe (B) Cu, Pb, Mn (C) Mn, Cr, Pb (D*) Pb, Cu

Q.63 This compound on ozonolysis gives which of the following compounds

O
||
(I) (II) OHC  C  C  CH 2  C  CHO
|| ||
O O

O
||
(III) CHO (IV) OHC  C  C  CH 2  CH  O
| ||
CHO O
(A) I, II, III & IV (B) I, III, IV (C*) I, II, III (D) I, II, IV
 CH ONa
Q.64 In the reaction; 3 ; the product is
CH 3OH

(A) (B*) (C) (D)

Q.65 The correct IUPAC name of the following compound is:

O  C  CH 2  CH  CHO
| |
OH HC  O
(A) 3,3-diformyl propanoic acid (B*) 3-formyl-4-oxo-butanoic acid
(C) 3,3-dioxo propanoic acid (D) 3,3-dicarbaldehyde propanoic acid

HBr
Q.66 CH2=CH–CH2–CH2–CCH ( Product is
1eq )
(A) BrCH2–CH2–CH2–CH2–CCH (B) CH2=CH–CH2–CH2–CH = CH–Br
(C) CH 2  CH  CH 2  CH 2  C  CH 2 (D*) CH 3  CH  CH 2  CH 2  C  CH
| |
Br Br