CHEMISTRY - (13th) (OIP) Paper-2

PART-A
Select the correct alternative. (More than one are correct) [3 × 5 = 15]
Q.4 Which of the following is(are) wrong

(A) A molecular orbitals of Benzene has two non bonding molecular orbitals
(B) Carbene is sp2 hybridised only
(C) On adding solute in volatile solvent reduced the entropy
(D) MeCONH2 gives bad swelling substance with CHCl3 + KOH
Q.5 Which is/are correct statement(s)?

(A) Yellow ammonium sulphide is suitable reagent for the sepration of CdS and As2S3.
(B) When borax is added in water the pH is remains constant (almost) on adding small amount of HCl
and NaOH seprately.
(C) Na2B4O7.4H2O is known as borax.
(D) The pH and structure of B(OH)3 is different at different concentrations.
Q.6 Which of the following will decolourise bromine water
(A*) CH2 = CH2 (B*) HC  CH (C) (D)
PART-B
MATCH THE COLUMN [2 × 8 = 16]
There is NEGATIVE marking. 0.5 mark will be deducted for each wrong match within a question.
INSTRUCTIONS:
Column-I and column-II contains four entries each. Entries of column-I are to be matched with some
entries of column-II. One or more than one entries of column-I may have the matching with the same entries
of column-II and one entry of column-I may have one or more than one matching with entries of column-II.
Q.3 Column I Column II

(Pair of complexes) (Property which is similar in given pair)
(A) (P) Cis
(B) (Q) trans
(C) (R) CH3 (diaxial)

(D) (S) CH3 (diequitorial)
[Ans. (A) P, (B) QS, (C) PS, (D) Q ]
Q.4 Column-I (Carbanions) Column -II (Half lives)
(a) (P) 4.3 × 10–8 s
(b) (Q) 2.5 × 10–5 s
(c) (R) 8.7 × 10–7 s
(d) (S) 1.4 × 10–4 s
[Ans. (A) R, (B) S, (C) Q, (D) P ]
PART-C
Q.6 Calculate the number of moles of gas present in the container of
volume 10 lit at 300 K. If the manometer containing
glycerin shows 5m difference in level as shown in diagram.
Given: dglycerin = 2.72 gm/ml, dmercury = 13.6 gm/ml.
[Sol. hgdg = hHgdHg

5 × 2.72 = 13.6 hHg
hHg = 1 m
Pgas = 0.76 dg + 1 dg
= 1760 mm of Hg
1760
×10 = n × R × 300
760
n = 0.94 mole ]
Q.7 A gaseous mixture containing N2 & H2 in mole ratio 1 : 3 is used to carry out the reaction in a sealed
container.
N2 (g) + 3H2(g)  2NH3 (g)
The total pressure was 0.8 atm at 25°C before the reaction. Determine final pressure at 323°C assuming
60% dissociation of reaction. [8]
[Sol: Let PN 2 = P & PH 2 = 3P (initially)
 P + 3P = 0.8 atm
P = 0.2 atm
 PN 2 = 0.2 atm & PH 2 = 0.6 atm
N2(g) + 3H2(g)  2NH3(g)
t=0 0.2 0.6
't' 0.2(1 – 0.6) 0.6 (1 – 0.6) 2(0.2 × 0.6)
= 0.08 = 0.24 = 0.24
Total pressure = 0.08 + 0.24 + 0.24 = 0.56 atm
P1 P2
Now 
T1 T2
0.56 P2
 
298 596
P2 = 1.12 atm ]
Q.8 Equimolar mixture of two gases A2 and B2 is taken in a container of volume 'V' at temperature 300 K.
At constant temperature the gases reacts according to given equations:
A2 (g) 2A (g) kp = ?
B2 (g) 2B (g) kp = ?
A2 (g) + B2 (g) 2AB kp = 2 atm
If the initial pressure in the container was 2 atm and final pressure developed at equilibrium is 2.75 atm
in which equilibrium partial pressure of gas AB was 0.5 atm, find equilibrium constant kp for the reaction.
AB (g) A (g) + B (g)
(Temperature & Volume of container remain constant throughout the experiment). [8]
[Ans.1]
[Sol. Initial partial pressure of A2 and B2 1 atm each.
A 2 (g ) B2 (g ) A(g ) B(g ) AB(g )

Initial 1 1
Change x y 2x 2y  2z
z z
At eq. 1  x  z 1  y  z 2 x 2y 2z
3 3
x y 2x 2y 0 .5
4 4
1+ 1 + x + y = 2.75  x + y = 0.75 .....(1)

2z = 0.5  z = 0.25 .....(2)
2
1
 
2
PAB 2
also =2  3  3  =2
PA ; PB   x   y
2 2
4  4 
(3 – 4x) (3 – 4y) = 2 .....(3)
Putting value of x from (1) in (3)
(4y) (3–4y) =2
12y – 16y = 2
6y – 8y2 =1
 1 1
y  , 
 2 4
1 1
taking y = x=
2 4
1
  (1)
2
Kp = = 1 atm Ans. ]
1
2
Q.9 Fluorocarbon polymers can be made by fluorinating polyethylene according to the reaction
(CH2)n + 4nCoF3  (CF2)n + 2nHF + 4nCoF2, where n is a large integer. The CoF3 can be
regenerated by the reaction 2 CoF2 + F2  2CoF3. If HF can be recovered and electrolyzed to
hydrogen and fluorine, and if this fluorine is used for regenerating CoF3, what is the net consumption of
fluorine per kg of fluorocarbon ? [Ans: 0.76 kg] [8]
[Sol: (CH2)n + 4nCoF3  (CF2)n + 2nHF + 4nCoF2
a mole 2n a 4n a
2CoF2 + F2  2CoF3
2HF  H2 + F2
2na na na
2CoF2 + F2  2CoF3
2na na 2na
"na" mole of F2 used for  'a' moles of (CF2)n
'a' moles of (CF2)n  na moles of F2
1 moles of (CF2)n  'n' moles of F2
20 moles of (CF ) 20
2 n  n x n moles of F2
n
 20 moles of F2
 20 x 38 gm of F2
 760 gm of F2  0.76 Kg of F2 ]
Q.10 For the reaction,
Cl2O (g) + H2O (g) 2HOCl (g) : Kp = 0.1 at 300 K
º
The value of equilibrium constant is 0.1. From the given data, find H f [HOCl (g ) (in kJ/mol). (All data
given at 300 K)
H of [Cl2O(g)] = + 77 kJ/mol
H of [H2O(g)] = –242 kJ/mol
 r So = 15.91 J/K mole
ln X
Take [R = 8.3 JK–1 mol–1 ; log X = 2.3] [8]
[Ans. 77.25 kJ / mole]

[Sol. G° = – RT ln Kp
= 8.3 × 300 × 2.3 [log 0.1]
G° = + 8.3 × 300 × 2.3 = H° – TS°
H° = {8.3 × 2.3 + 15.91} × 300
= 35 × 300
H° = 10.500 kJ
H f (Cl 2 O)  H f [H 2 O(g)]  10.500
H fº [HOCl (g ) = | |
2
77  242  10.5
=| |
2
= 77.25 kJ /mole ]
PART-D
Q.1 How many gm of solid NaOH must be added to 100 ml of a buffer solution which is 0.1 M each w.r.t.
Acid HA and salt Na + A – to make the pH of solution 5.5. Given pk a (HA) = 5.
(Use antilog (0.5) = 3.16) [5]
[Ans. 2.07 × 10–1]
s  x 
[Sol. 5.5 = 5 + log  
a  x 
sx 
0.5 = log  
ax
 10  x 
3.16 =  
 10  x 
10 (3.16) – 3.16 = 10 + x
10 (2.16) = 4.16 x
 2.16  40
x = 10 ×   gm = 0.207 gm = 2.07 × 10–1 Ans.]
 4.16  1000
k
Q.2 The kinetic data for the given reaction A (aq) + 2B (aq) 
 C is provided in the following table for
three experiments at 300 K
Ex. No. [A / M ] [B / M ] Initial rate (M sec 1 )

1 0.01 0.01 6.930 10 6
2 0.02 0.01 1.386  10 5
3 0.02 0.02 1.386  10 5
In another experiment starting with initial concentration of 0.5 and 1 mole respectively for A & B at 300
K, find the rate of reaction after 16.667 minutes from start of experiment in (M/sec).
[8]
[Ans. 1.73 × 10–4]
[Sol. a b
r1 = k [0.01] [0.01] = 6.93 × 10 6 .....(1)
a b
r2 = k [0.02] [0.01] = 1.386 ×10 –6 .....(2)
a b –6
r3 = k [0.02] [0.02] = 1.386 × 10 .....(3)
(0.02)a = 2  a = 1
(0.02)b =1  b = 0
 k = 6.93 × 10–4 sec–1
A + 2B  P
0.5 1  overall order = 1
3 Ao
6.93 × 10–4 = ln A
50  60 t
Ao Ao
0.693 = ln A  A = 2  At = 0.25
t t
1
 rate = 6.93 × 10–4 ×  
4
rate = 1.73 × 10 M sec–1
–4 Ans. ]

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PART-A

Q.4 Which of the following is(are) wrong

Q.5 Which is/are correct statement(s)?

Q.6 Which of the following will decolourise bromine water

(A*) CH2 = CH2 (B*) HC  CH (C) (D)

Q.3 Column I Column II

(A) (P) Cis

(B) (Q) trans

(C) (R) CH3 (diaxial)

[Ans. (A) P, (B) QS, (C) PS, (D) Q ]

Q.4 Column-I (Carbanions) Column -II (Half lives)

(a) (P) 4.3 × 10–8 s

(b) (Q) 2.5 × 10–5 s

(c) (R) 8.7 × 10–7 s

(d) (S) 1.4 × 10–4 s

[Ans. (A) R, (B) S, (C) Q, (D) P ]

[Sol. hgdg = hHgdHg

A 2 (g ) B2 (g ) A(g ) B(g ) AB(g )

1+ 1 + x + y = 2.75  x + y = 0.75 .....(1)

H of [H2O(g)] = –242 kJ/mol

 r So = 15.91 J/K mole

[Ans. 77.25 kJ / mole]

Ex. No. [A / M ] [B / M ] Initial rate (M sec 1 )

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(A) CH2 = CH2 (B) HC  CH (C) (D)