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Exercises Student Ed

The document describes several direct and indirect titration methods for standardizing and analyzing various samples, including calculations to determine molarities of acids and bases from titration data using primary standards like TRIS, potassium iodate, sodium carbonate, and mercury oxide. Sample calculations provided include determining the percentage of components in samples like catsup, baking soda, vinegar, and canned tuna.

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0% found this document useful (0 votes)
240 views10 pages

Exercises Student Ed

The document describes several direct and indirect titration methods for standardizing and analyzing various samples, including calculations to determine molarities of acids and bases from titration data using primary standards like TRIS, potassium iodate, sodium carbonate, and mercury oxide. Sample calculations provided include determining the percentage of components in samples like catsup, baking soda, vinegar, and canned tuna.

Uploaded by

Kukkibo
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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DIRECT TITRIMETRIC

METHOD

Sample Exercises
Direct Titration Method:
Standardization of Solutions

The organic base, tris-(hydroxymethyl)aminomethane (or


simply TRIS or THAM) is an excellent primary standard. A
0.2486 g sample of the primary standard grad TRIS,
0.08248 M
(CH2OH)3CNH2 (M.M. = 121.14) was dissolved in distilled
water and required 24.88 mL of a hydrochloric acid
solution. Calculate the molarity of the solution.
The compound potassium hydrogen iodate, KH(IO3)2
(M.M. = 389.91) is a strong monoprotic acid that is also an
excellent primary standard. A 0.9865 g sample of AR
0.1191 M
grade KH(IO3)2 was dissolved in distilled water and
needed 21.24 mL of NaOH to reach the phenolphthalein
end point. Calculate the molarity of the NaOH solution.
Direct Titration Method:
Standardization of Solutions

A solution of nitric acid was standardized


against 0.2167 g primary standard sodium
carbonate, Na2CO3 (M.M. = 105.99). An end
0.1159 M
point was observed after the titration of the
mixture with 35.27 mL of HNO3. Calculate the
molarity of the nitric acid.
How many grams of the primary standard
Na2B4O7•10H2O (M.M. = 381.42) must be
obtained in order to consume about 22 mL of
0.69 g
0.082 M H2SO4 solution?

B4O72- + 2H+ + 5H2O ⎯⎯→ 4H3BO3


Direct Titration Method:
Analysis of Samples

The benzoic acid extracted from 106.3004 g of


catsup required 14.76 mL of 0.0514 M NaOH.
Express the results of this analysis in terms of the 0.1029%
percentage of sodium benzoate, NaC6H5CO2
.(M.M. 144.11)
Titration of 0.7436 g sample of impure Na2B4O7
required 31.64 mL of 0.1081 M HCl. Express the 46.28%
results of this analysis in terms of %Na2B4O7.
Direct Titration Method:
Analysis of Samples: Titration of Aliquot Portions

A 25.00 mL aliquot of vinegar was diluted to 250 mL


in a volumetric flask. Titration of a 50.00 mL aliquot
of the diluted vinegar solution required 31.02 mL of
0.1050 M NaOH. Express the acidity of the vinegar
in terms of %(w/v) CH3COOH (M.M. = 60.06).
A 25.00 mL sample of a household cleaning solution
was diluted to 250.0 mL in a volumetric flask. A
50.00 mL aliquot of this solution required 30.24 mL of
0.1604 M HCl to reach a bromocresol green end
point. Calculate the %(w/v) NH3 in the sample.
(Assume that all the alkalinity results from the
ammonia.)
Direct Titration Method:
Analysis of Samples: Titration of Aliquot Portions

Consider an impure sample of 25.20%


Na2CO3. How many grams of the sample must
be dissolved in a 500-mL solution so that
5.8
titration of a 50-mL aliquot portion will require
only about 22 mL of 0.1250 M HCl to reach the
methyl orange end point?
INDIRECT TITRIMETRIC
METHOD

Sample Exercises
Indirect Titration Method:
Standardization of Solutions

CHAPTER 10, Introduction to ANALYTICAL CHEMISTRY (8th ed., by


Skoog, West, Holler, Crouch and Chen

7-16 A solution of HClO4 was standardized by dissolving 0.3745 g of


primary standard grade HgO (M.M. = 216.59) in a solution of KBr:

HgO + 4Br− + H2O ⎯→ HgBr42− + 2OH−

OH− + HClO4 ⎯→ H2O + ClO4-

The liberated OH− required 37.79 mL of the acid to be neutralized.


Calculate the molarity of the HClO4 solution.

ANSWER: 0.09151 M
Indirect Titration Method:
Standardization of Solutions

A 0.6334 g sample of primary standard grade


HgO (M.M. = 216.59) was dissolved in 100
mL of 0.50 M KI solution. The liberated OH-
0.1643 M
needed 35.60 mL of HNO3 to reach the end
point. Calculate the molarity of the HNO3
solution.
Indirect Titration Method:
Analysis of Samples

CHAPTER 10, Introduction to ANALYTICAL


CHEMISTRY (8th ed., by Skoog, West, Holler, Crouch
and Chen

10-21. A 1.047 g sample of canned tuna was


analyzed by the Kjeldahl method; the liberated 3.886%
ammonia was collected in a boric acid solution and
required 24.61 mL of 0.1180 M HCl to reach the
methyl orange end point. Calculate the %N in the
sample.

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