Welcome To Your Digital Edition of March 2023: Tech Briefs and Battery & Electrification Technology
Welcome To Your Digital Edition of March 2023: Tech Briefs and Battery & Electrification Technology
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March 2023 www.techbriefs.com Vol. 47 No. 3
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Computer Vision AI
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March 2023 • Vol. 47 No. 03
Contents
Features
45
10 Products of Tomorrow
Solutions
27 Aeronautics
37
27 Shark Skin Inspires Functional Surface Film for Aircraft
30 Electrical/Electronics Departments
8 Click
30 Serial Arrayed Waveguide Grating 12 5 Ws
14 Q&A
30 Health Monitoring with Skin-Like Electronics 16 Videos of the Month
47 Advertisers Index
31 Wearable Electronics for Continuous Cardiac,
Respiratory Monitoring
40
Tadiran batteries,
but just don’t know it!
YEAR
OPERATING
LIFE *
Permissions: Authorization to photocopy items for internal or personal use, or the internal or Wood Dr., Danvers, MA 01923). For those organizations that have been granted a photocopy
personal use of specific clients, is granted by Associated Business Publications, provided that license by CCC, a separate system of payment has been arranged. The fee code for users of the
the flat fee of $3.00 per copy be paid directly to the Copyright Clearance Center (222 Rose Transactional Reporting Service is: ISSN 0145-319X194 $3.00+ .00
Interface Structure
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VIDEO PODCAST
BLOG
3 Program Goals for the James Webb Space Adding Vibrations to Electronics to Reduce
Telescope in 2023 Vibrations
This year, the James Webb Space Telescope will transition Researchers have demonstrated a counterintuitive way to
into its second official year of science operations, or Cycle 2. protect atomically thin electronics: adding vibrations to reduce
Will Webb find life-supporting molecules or elements in the vibration issues. The team’s trick is to “squeeze” a thin droplet
atmosphere of other expoplanets? Here are three aspects of of liquid gallium on graphene devices, which are then painted
the observatory’s in-orbit operations to watch for this year. with a protective coating of glass — gallium oxide.
QUESTION
BLOG INTERVIEW
QUIZ
OF THE MONTH
A Drone to Protect Bats from Wind Turbines 6 Pioneering Women in Aerospace and
A research team has found a solution to wind turbines killing Aeronautics
millions of bats who fly into their blades: A drone-mounted From flying planes to leading space missions and conducting
technology that transmits a combination of ultrasonic signals groundbreaking research, women have been contributing to
and light. This deters the bats, forcing them to fly at a higher the aerospace and aeronautics industry for decades. Take this
altitude — allowing the turbines to operate continuously. quiz to learn more about six such trailblazing women.
Find
Read
themore
answer
onon ReadTake
the full
the interview
quiz on at
TechBriefs.com/blog TechBriefs.com/tb/stories/quiz
TechBriefs.com/blog
Instagram: @TechBriefs Twitter: @TechBriefsMag Facebook: @TechBriefsMagazine LinkedIn: Tech Briefs Media
» comsol.com/feature/medical-innovation
This column presents technologies that have
Products of
applications in commercial areas, possibly
creating the products of tomorrow. To learn
Tomorrow
more about each technology, see the contact
information provided for that innovation.
u Metallic
Snowflake
Scientists in New
Zealand and Australia uMolecular Motor
working at the level of A multidisciplinary
atoms have created team led by Northwestern
something unexpect- University has made an
ed: tiny metallic snowflakes. That’s significant be- electric motor you can’t
cause coaxing individual atoms to cooperate in de- see with the naked eye: an
sired ways is leading to a revolution in engineering electric motor on the mo-
and technology via nanomaterials. To create metal- lecular scale. Only 2-nm
lic nanocrystals, the researchers have been experi- wide, the molecular mo-
menting with gallium, a soft, silvery metal which is tor is the first to be produced in abundance. The elec-
used in semiconductors and, unusually, liquifies at tric molecular motor specifically is based on a cat-
just above room temperature. Metals were dissolved enane whose components, a loop interlocked with
in gallium at high temperatures. Once cooled, the two identical rings, are redox active, i.e., they under-
metallic crystals emerged while the gallium re- go unidirectional motion in response to changes in
mained liquid. Such nanoscale structures can aid voltage potential. The motor is easy to make, operates
electronic manufacturing, make materials stronger quickly, and does not produce any waste products.
yet lighter, or aid environmental clean-ups by bind- This early work — a motor that can convert electrical
ing to toxins. energy into unidirectional motion at the molecular
level — has implications for materials science and
Contact: Paul Panckhurst particularly medicine, where the electric molecular
Phone: 022-032-8475 motor could team up with biomolecular motors in
E-mail: [email protected] the human body.
u Screen-Printed Electrodes
The glittering, serpentine structures that power wearable electronics can be cre-
ated with the same technology used to print rock concert t-shirts. The study, led by
Washington State University researchers, demonstrates that electrodes can be
made using just screen printing, creating a stretchable, durable circuit pattern
that can be transferred to fabric and worn directly on human skin. The research-
ers used a multi-step process to layer polymer and metal inks to create snake-like
structures of the electrode. The study showed the electrodes could be stretched by
30 percent and bend to 180 degrees. While this study focused on ECG monitoring, the screen-printing process can
be used to create electrodes for a range of uses, including those that serve similar functions to smart watches or
fitness trackers. Such wearable electronics can be used for health monitoring in hospitals or at home.
EXPERT Insight
Optimizing Connector Designs for Spaceborne Electronics
Low-Earth orbit (LEO) satellite systems are providing the world significant new methods of surveying, communicating, and sharing informa-
tion. With increased focus on LEO, a constant design evolution is occurring from deep space exploration to LEO-based constellations. Satellite
systems are moving rapidly from single units or devices to fully interconnected electronic networks operating on centralized computers. In
this interview, Travis Neumann, Special Project Manager at Omnetics Connector Corporation, discusses how connector designs are evolving to
meet the needs of spaceborne electronics.
Tech Briefs: New satellites and space electronics now require transition into high reliability micro and nano types. Technology like
interconnection design planning for each individual function and that used in servers such as blade mount or stackable connections
where they will be performing. What are some of the key envi- promotes assembly for those looking to create large constellations.
ronmental factors designers need to keep in mind while planning Additionally, there are users of wired investigating flex circuit solu-
circuitry for satellite systems? tions for their CubeSat for better management of the harness and
connections between boards.
Travis Neumann: We already know that in
satellite applications size and weight are a Tech Briefs: Besides size, space, and weight what are additional
big deal. We want the electronics to be small environmental effects to consider?
and lightweight and the first thing to ask
as a designer is what do I need? When you Neumann: A popular one is shielding. There is significant radia-
consider power and signals, there are really tion in space, and the further out you go, the more aggressive it
two ways to slice this. It’s in terms of the becomes. We get a lot of requests for back shells and plated braid-
current or voltage needs. Current will dictate ing. As shielding is an “in addition” type of solution, weight starts
the size of the conductors where voltage can to come into the play. Thermal cycling is another consideration.
affect spacing. Next question relates to how many of these connec- Materials should be chosen with a wide enough operating range
tions do we need? Using the number of connections you need, what they don’t fatigue from repeated hot/cold cycles when orbiting the
the voltage or current rating of those connections is, or signal in Earth. Outgassing is another consideration to prevent deposition
terms of speed, and work from there to determine what’s going to of material onto optics and controls.
be your best solution.
Neumann: Omnetics has been small cable and connectors for quite
some time and we see customers moving down in size. Where they Watch the full interview with Travis Neumann
might have used the traditional large military connectors, there is a
What
The primary challenge in developing ice-shedding materials
is finding materials with both low ice adhesion and good du-
rability. The principle of the new “fracture-controlled materi-
al” lies in the fact that for detachment of any external solid
object from a surface (like ice from an airplane wing), force
must be applied, and that force will inevitably lead to forma-
tion of some cracks at the interface. These cracks, or frac-
tures, grow until full detachment of the object from the sur-
Professor Hadi Ghasemi has developed a de-icing spray in
face. Through a new concept developed by the researchers, which detachment of an object can be accurately controlled
detachment can be accurately controlled and accelerated. and accelerated. (Image: UH Cullen College of Engineering)
According to Ghasemi, in this new concept through material
design, the crack formation and growth can be significantly
accelerated and external objects can be easily removed from
the surface. The concept is implemented to develop materials
that are highly durable, and ice does not attach to these mate-
rials. The coating has been tested by Boeing under erosive
rain conditions at 385 miles per hour and has outperformed
current state-of-the-art aerospace coating technologies.
Where
University of Houston, TX
Why
To combat the dangers of icing. This new concept of fracture-controlled materials paves the way for innovations in
materials for aerospace, wind energy, and other industrial applications where icing is an issue.
When
Ghasemi will continue refining the ice-shedding coating through the company Elemental Coatings, which has been
awarded a $750,000 Small Business Innovation Research (SBIR) Phase II contract from the United States Airforce to
further develop anti-icing protection for large military jets.
Contact Prabhpreet Gill, Technology Licensing Associate, Office of Technology Licensing, at [email protected],
609-258-3653,
For more information, or visit
contact Inez https://innovation.princeton.edu
Hutchinson at [email protected]; 713-743-7593.
12 www.techbriefs.com Tech
Tech Briefs,
Briefs, Month
March 2023
2022
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Q& A
Tunable, Narrow Linewidth, Chip-Scale Lasers
Mateus Corato Zanarella, a Columbia Tech Briefs: What is linewidth?
University researcher is the lead author of
a Nature Photonics article describing the cre- Zanarella: An ideal laser would emit a single wavelength with
ation of tunable visible-light lasers small zero-linewidth, basically the purest color possible. In practice,
enough to fit on a fingertip, which produce a laser always has some linewidth, a small range of frequencies
very pure colors from near-ultraviolet to around the center frequency of the light. That’s due to the fluc-
near-infrared. tuations of the wavelength of the laser. So, narrow linewidth ba-
sically means very pure color.
Tech Briefs: What are some applications that would ben-
efit from a very small, chip-level laser? Tech Briefs: Could you describe some applications?
Mateus Corato Zanarella: The applications depend on the Zanarella: Quantum optics is an important one, where scien-
wavelength of the emitted light. We made lasers at visible wave- tists use light to trap and manipulate atoms or ions to function
lengths from near-ultraviolet, which is about 400 nanometers, up as quantum bits. They do so by targeting very specific atomic
to near infrared (NIR), which is about 780 nanometers, covering transitions using lasers with very narrow linewidth. Through
blue, green, and red in between. There are several applications the manipulation of quantum bits, this technology can enable
for each of these wavelengths. The most notable is quantum op- quantum computing.
tics, which can leverage the narrow linewidth and precise tun- Visible lasers are also used in laser displays, providing wide
ability of the lasers we created. color gamut and enhanced image quality. And miniaturization
is important to enable very compact devices, say for a laser scan-
ning display for AR or VR goggles.
Bioimaging is another application. Fluorescence imaging uses
lasers to excite fluorophores and then collects the light to image
tissues and other biological samples. In neuroscience, there are
THWART MOTHER NATURE neural probes that use light to control and read the response of
TODAY. neurons in the brain using a technique called optogenetics.
Temperature changes will destroy your electronics. Tech Briefs: What’s the approximate size of these
You don’t have to trade the safety of your electronic components?
components for the sake of limited space. Protect
them with a compact & responsive thermo
thermostat. Zanarella: The waveguide cross section changes throughout
the chip, but it’s about 300 nanometers wide and 175 nanome-
ters tall. The chip with the devices to make one laser is about a
millimeter long and less than half a millimeter wide. The laser
diode itself is sub-millimeter, so the chip-scale laser system is on
the order of millimeter long and sub-millimeter wide.
Other Disruptive
Visit the website for Broad Agency Announcement and Concepts & Technology
Government Sources Sought Announcement requirements.
www.nro.gov/InnovateNRO/DII
[email protected]
REDPIXEL.PL/Shutterstock.com
Videos of the Month
A New and Improved Method of Solar Water Splitting
Researchers at the University of Michigan have developed a
new kind of solar panel that is nearly 10 times more efficient
than previous tech of its kind. “In the end, we believe that
artificial photosynthesis devices will be much more efficient
than natural photosynthesis, which will provide a path toward
carbon neutrality,” said Zetian Mi, Professor of Electrical and
Computer Engineering.
BATTERY
+ - + - + - + AND + - + - + - +
SUMMIT
ELECTRIFICATION
Topics include:
• Will Solid-State Batteries Become Dominant? • The Future of Electric Cargo Transportation
• Improving Performance With Machine Learning • Recycling and Second Lives of EV Batteries
• The EV Charging Infrastructure • Anode Advancements: The Rise of Silicone
• Thermal Management and Runaway Prevention • Efficient Batteries With Better EV Architecture
B
efore smart components, industry ML and AI can map the big three —
lived in a break/fix mechanical uptime, quality, and energy or any com-
world where maintenance per- bination. ML and AI can be vendor ag-
sonnel practically looked at a ma- nostic, focusing not on the brand of
chine and knew how to correct the issue. component or type but on the data. And
In those days, long runs of the same prod- its presentation of actionable informa-
uct led to fewer changeovers, meaning tion fits comfortably within the end us-
fewer adjustments. Today, machines are er’s workflow. The customer decides on
far more complex and difficult to analyze. where, when, and how to display infor-
Tight margins mean that downtime can mation and is not required to adopt the
be catastrophic to a company and unde- vendor’s ecosystem.
tected quality issues are equally bad. While it is impossible to expect that
Industry has developed from break/fix these systems will perform similarly, it is
to preventative maintenance, to predic- not out of the ordinary for plants to im-
tive maintenance, which relies on smart AI provided early detection of wafer defects in prove process transparency by 100 per-
a wafer sawing process. The AI solution low-
components to detect out of spec condi- ered annual waste per machine by $100,000. cent, lower waste by over 50 percent
tions. Machine learning (ML) and artifi- (Image: Festo) and product rejection costs by over 45
cial intelligence (AI) are taking predictive percent. Machine availability can be
maintenance to a new level of perfor- vanced” predictive maintenance are prac- improved by over 25 percent. Un-
mance through early identification of out- tical tools for improving the bottom line. planned downtime can fall by more
of-spec conditions and being able to com- And they are available now. than 20 percent.
municate with the crew either through These systems typically map data to What data is involved in learning the
trend’s dashboards or in easy-to-under- learn a component, machine, product, healthy state of a system? The answer is
stand sentences presenting key facts of the or energy system’s healthy state. Once basic operational data that may already
situation. This leads to higher uptime, the map is in place, anomalies are easily be resident in the system. This includes
greater quality, and overall improved identified by the AI software, which then speed, distance, pressure, flow, current,
throughout. ML and AI systems for “ad- prompts corrective actions. temperature, environmental factors
Real-World Examples
In an automotive battery assembly
cell, AI monitored motor currents, ac-
tuator position, the presence and ab-
sence of batteries, and battery weight.
After mapping data for a healthy state,
the system recognized anomalies. The
AI system generated messages that were
sent via an IoT gateway to the cloud to
be displayed on a trend’s dashboard.
The data required for healthy versus
unhealthy state already existed based
on the machine’s motion. The develop-
ment team layered AI over this data, At an auto plant, AI continuously monitored the plant’s welding guns. This solution decreased un-
mined it at the bottom where all the planned downtime on the welding line by 25 percent. (Image: Festo)
action occurred, and then provided in-
formation displayed graphically to op- 2,500 welding gun robots equipped AI aggregated the data on the 2,500
erations personnel. with compact servo-pneumatic clamps. robotic welding guns and then, utilizing
At a premium car production plant in Using an AI system, the plant instituted gateways, sent data to cloud-based dash-
Europe produces on average 1,000 cars continuous welding gun monitoring of boards that provided easy-to-understand
per day. Welding is a core body-in-white cylinder and valve operating data and visualization of operating conditions.
process there. The plant has a total of associated parameters. The plant now has, in effect, an asset
management system on every robotic to increase data points for predictive systems. Others wanted alerts sent to mo-
welding gun. Unplanned downtime fell maintenance. The AI solution monitored bile devices. Many asked whether they
by 25 percent. six pneumatic cylinders for predictive could have easily understandable messages
At a silicon wafer plant, wafers are maintenance and monitored compressed identifying what the problem was, where it
sawed from silicon cylinders in a process air consumption for predictive energy sav- was, and what corrective action should be
that takes more than eight hours. Poor ings. Anecdotal information indicates im- taken. These requests led developers to un-
cuts impact quality and lead to high re- proved energy efficiency and uptime. derstand that the system must support the
jection rates. The AI software mapped Adding hardware and sensors to an exist- end user’s workflow or the OEM’s HMI.
healthy cutting data utilizing more than ing machine enabled an AI-based asset To be successful, as mentioned earlier,
40 system parameters, environmental management system. these systems must be vendor agnostic
data such as humidity, and geometrical and must give the operations the ability
data. Anomalies led to early detection of Identification of Anomalies, to decide where the software platform
defects. AI-derived maps were used to Now What? can live directly on the system (on edge),
improve accuracy in quality assessment Early in the ML/AI development pro- on premises servers, or in the cloud. It
sampling. These led to a higher level of cess, the idea was that all the data would must be flexible enough to enable con-
identification of true defects during be pushed into the cloud and displayed nections to internal maintenance man-
quality observation. The wafer plant on vendor-created dashboards. The solu- agement software or spare parts manage-
now saves up to $100,000 per machine tion seemed reasonable — a direct line ment system to create an integrated
per year through reductions in late de- from machine to the cloud for anytime/ end-to-end solution.
fect detection. anywhere monitoring. The hurdle was AI may appear futuristic, but this solu-
This energy savings application for ice that customers had their own dashboards tion has advanced to the point where it is
cream production differs from the previ- and own way of displaying data. experienced by the user as a practical tool
ous examples because the data necessary It became clear that customers wanted for improving the bottom line.
to measure pneumatic air consumption, the AI healthy/not healthy data available
which was the goal of the project, was not in the manner most convenient for them, This article was written by Frank Lati-
available on the machine. To remedy the whether on their own dashboards, resident no, Product Management Electric Auto-
situation, the plant added hardware to on the premises, on edge, or all three. mation, Festo North America (Islandia,
digitally collect air pressure and flow data. Some customers wanted the data integrat- NY). For more information, visit www.
The plant also installed additional sensors ed with their maintenance management festo.com/us/en/.
data in the form of images and videos, manipulation of objects. To do these, the
Computer Vision AI which are images at some frame rate. latest imaging technologies provide accu-
CV AI is a computer processing and The visual data consists of pixels. The rate visual data to the CV system, which is
making sense of visual data. Its capabili- pixels are filtered through many layers then making sense of that visual data by
ties can detect and classify different types when it is inputted and through these detecting and classifying what the images
of defects, people, objects, actions, and layers’ features, such as edges, colors, and video are showing.
22 www.techbriefs.com Tech Briefs, March 2023
Instead of an autonomous robot in two major parts are joined in a welding grounds, shapes, colors, sizes, lighting,
route stopping because an object is in process, cameras can monitor the process and environments.
proximity, the robot is able to understand and CV can determine the weld quality. Because CV AI allows for changes and
more precisely what is in its path and de- In an instance where porosity is detected, updates, it can evolve with a user’s needs.
termine if it can go around it. In a case the welding engineer for the production For example, if new variables need to be
where a robot detects a box in its path, it line or even a machine itself can make ad- detected, the computer vision models
can then confidently adjust its path plan justments to the process in near real-time. can be retrained based on new data, new
to go around the stationary box, virtually By doing so productivity and quality is im- variables, and feedback. It can also learn
losing no time. In more advanced use cas- proved and risks are mitigated. to ignore variables or conditions that
es, drones are used to inspect surfaces of change but do not matter when making
critical assets for damage or defects. CV A Unique Imaging Solution detections and give feedback to improve
is used to detect and classify defects and CV AI is much more powerful than the confidence in the predictions.
provide further analytics on what defects smart AI image sensors or rules-based CV AI can also eliminate the risk of
were found and where. vision as a whole. Usually “smart” vision valuable knowledge leaving with a per-
The factory of the future is connect- sensors leverage pre-trained models that son because it learns and retains visual
ed, intelligent, and needs to be able to are not retrainable from the perspective inspection requirements in complex
ensure highly productive production of the camera. Even “edge” training production environments. Retaining
environments. One of the key enablers smart AI sensors are highly limited to the that tribal knowledge is also impactful
is CV. The technology is empowering most basic applications. Some sensors or when onboarding new employees, as it
AR tools, advanced quality inspections, AI systems rely on open-source tools that reduces weeks and even perhaps months
smarter robots, and intelligent safety are trained on datasets that could be sub- of training time.
and security systems. Design engineers ject to biases or inconsistent labels. One of the most appealing attributes
are integrating cameras into machine Rules-based vision uses decades old of CV AI is that it is camera agnostic and
designs and production lines at the de- rules that are based on the specific ob- can work with any type of imaging tech-
sign phase. ject, lighting, camera, lens, and ambi- nologies on the market, including cam-
Quality and production effectiveness ent conditions. These rules are good era technologies such as resolution im-
is ensured when intelligent tools are in- for simple detection applications but ager, visible light, invisible (NIR, SWIR),
tegrated in critical areas. For instance, fail when contending with detecting X-ray, thermal, industrial cameras, CCTV
in assembly and joining processes where things in changing or challenging back- Cameras, microscopes, and borescopes.
Understanding How CV AI Can What’s Next SCADA, MES, WMS, ERP, Databases,
Impact You If you’ve decided that your design engi- Security, etc.
To understand if CV AI could be neering process can benefit from CV AI, • Partner with proven talent with a track
beneficial to your design engineering there are simple steps you can take to do to of deep-learning AI. Industry-leading
process, you should ask yourself these get started with this technology and ensure engineering is what is empowering the
questions: that it’s a good fit for your organization: greatest gains for manufacturers utiliz-
• Are the challenges faced in your de- • Consult with a CV AI platform compa- ing this technology.
sign engineering process visible by ny that can review your interests, appli-
some form of camera technology or cations, and goals for using CV AI. Industry digital transformation is mak-
any spectrum that provides image or • Consider a PoC trial to learn how the ing its way into all aspects of operations
video? technology can help and integrate into from leveraging tools that have these tech-
• What aspects of your operations can your systems and operations. nologies incorporated into them, to incor-
image or video detections and analyt- • Ensure that it compliments your opera- porating the technologies into new designs.
ics bring value? tions by allowing your cross-functional Manufacturing is expected to grow rapidly
• What insights do you want to gain from departments to build, test, deploy, and across many regions. The competitive ad-
CV AI? manage pre-made and custom detec- vantage will be for those that incorporate
• What systems will CV AI integrate into tors for their needs without needing to technologies which maximize throughput
so that action can be taken because of be a degreed data scientist. and quality. CV AI is one of the key tech-
detections and analytics, i.e., machine, • Ensure suitable deployment modes for nologies that will be incorporated into
MES, or ERP? your needs, such as Cloud (public/pri- new designs of robotics, machines, and
• Is there a one-off need, or can this span vate), On-prem, and edge. production lines within the factories of
across the operations? • Confirm that the CV AI platform is today and tomorrow. This will enable ro-
• Does the platform empower your SMEs camera technology agnostic so that it botics and machines with advanced visual
to easily build their own detectors with- can work with any technology. Applica- perception to do more faster and adapt to
out needing to be data scientists? tion needs vary throughout operations changing conditions and environments.
and different imaging technologies
By looking at these areas of your man- and resolutions may be needed. This article was written by Adam Bennett,
ufacturing process, you can gauge how • Use an application that can integrate Sales Director, Matroid (Palo Alto, CA). For
and where CV AI will be most beneficial. in your current systems, i.e., PLC’s, more information, visit www.matroid.com.
P
roviding a forward-thinking look into the latest trends • Electronics/Connectivity/Vehicle IoT/Smart City/Infra-
and innovations as well as cutting-edge mobility re- structure/Active Safety: WCX will also feature sessions on
search, SAE’s WCX World Congress Experience, will safety-critical systems, ADAS and autonomous vehicle system,
be held from April 18-20, in Detroit, MI. As the largest AI and ML in vehicle-level application, smart transportation
technical mobility event in North America, WCX will provide and infrastructure, embedded systems and software, chargers
the education, networking, and business development need- and charging electronics, cybersecurity, IoT/Blockchain, and
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ticipate in live panel discussions, keynotes, and breakout tech- • Materials and Lightweighting: Subjects critical to future ve-
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26 www.techbriefs.com Tech Briefs, March 2023
Aeronautics
Shark Skin Inspires Functional Surface Film for Aircraft
A new surface technology improves fuel efficiency and reduces CO2 emissions.
Lufthansa Group, Munich, Germany
are very small. The data that we can get the wing. And that torque is something in the pitch and up-down directions but
from those measurements are limited.” we use to calibrate our model.” With this keep the wing loose along the back-and-
The researchers used muscle anatomy model, the researchers uncovered previ- forth direction, so their wings appear to
literature, computational fluid dynamics ously unknown principles of humming- be flapping back and forth only while
simulation data, and wing-skeletal move- bird wing actuation. their power muscles, or their flight en-
ment information captured using mi- The first discovery, according to Cheng, gines, are actually pulling the wings in all
cro-CT and X-ray methods to inform their was that hummingbirds’ primary muscles, three directions. In this way, the wings
model. They also used an optimization al- that is, their flight engines, do not simply have very good agility in the up and down
gorithm based on evolutionary strategies, flap their wings in a simple back and forth motion as well as the twist motion.”
known as the genetic algorithm, to cali- motion, but instead pull their wings in While Cheng emphasized that the re-
brate the parameters of the model. Ac- three directions: up and down, back and sults from the optimized model are predic-
cording to the researchers, their approach forth, and twisting — or pitching — of the tions that will need validation, he said that
is the first to integrate these disparate parts wing. The researchers also found that it has implications for technological devel-
for biological fliers. hummingbirds tighten their shoulder opment of aerial vehicles. “Even though
“We can simulate the whole recon- joints in both the up-and-down direction the technology is not there yet to fully mim-
structed motion of the hummingbird and the pitch direction using multiple ic hummingbird flight, our work provides
wing and then simulate all the flows and smaller muscles. essential principles for informed mimicry
forces generated by the flapping wing, “It’s like when we do fitness training of hummingbirds hopefully for the next
including all the pressure acting on the and a trainer says to tighten your core to generation of agile aerial systems,” he said.
wing,” Cheng said. “From that, we are be more agile,” Cheng said. “We found For more information, contact Sarah
able to back-calculate the required total that hummingbirds are using similar kind Small at College of Engineering Media Re-
muscular torque that is needed to flap of a mechanism. They tighten their wings lations; [email protected].
10
Voltage (mV)
stant monitoring. 0
cal system involving two ionic forms of 15.5 16 16.5 17 17.5 18 18.5
Time (Sec)
iodine, I– and I3–. A solution containing
these electrolyte substances is placed 5
into a small circular cavity that is capped
Voltage (mV)
The resulting device is only 28-mm the chest contracts and expands during ratory diseases, such as COVID-19, which
wide and is skin-safe, so it can be at- breathing, functioning as a strain sensor. often leads to shortness of breath.
tached directly to the patient’s body. The The other way the sensor detects respira- “Symptoms in the early stage of infec-
device was able to detect the heartbeat tion is due to the way the volume of the tion could be subtle,” said Xu. “Wearable
with high sensitivity. A signal-to-noise ra- chest cavity changes during a breath, devices that are capable of accurate de-
tio of greater than 6:1 was achieved, modulating the heartbeat signal. In this tection of subtle respiratory and cardio-
which is considered good. way, respiration is detected indirectly vascular variation are of great interest,
Respiration can be detected by this de- through changes in the heartbeat. especially during the pandemic.”
vice in two different ways. Because of the The authors suggest their sensor could For more information, contact Larry
sensor’s stretchability, it deforms when potentially be used for diagnosis of respi- Frum at [email protected]; 301-209-3090.
86%
OF VISITORS RATED THE EXPO
EXCELLENT OR GOOD
275+ 30+
EXHIBITORS EXPERT SPEAKERS
SCAN ME
will be applied to the site of the self release antibiotics onto the wound biocompatible and self-healing was the
planned incision. The incision will area, preventing infection. next step, and one that was achieved by
then be made through it. Following Most people discard their late-night postdoctoral fellow Dr. Ning Tang.
the surgery, the two ends of the wound cinema-inspired ideas. Not Haick, who, The new polymer is structured like a mo-
will be brought together, and within the very next day after his Eureka mo- lecular zipper, made from sulfur and nitro-
three seconds the dressing will bind it- ment, was researching and making gen: the surgeon’s scalpel opens it; then
self together, holding the wound plans. The first publication about a pressed together, it closes and holds fast.
closed, similarly to sutures. From then, self-healing sensor came in 2015. At that Integrated carbon nanotubes provide elec-
the dressing will be continuously mon- time, the sensor needed almost 24 hours tric conductivity and the integration of the
itoring the wound, tracking the heal- to repair itself. By 2020, sensors were sensor array. In experiments, wounds
ing process, checking for signs of infec- healing in under a minute, but while closed with the smart dressing healed as
tion like changes in temperature, pH, they had multiple applications, they fast as those closed with sutures and showed
and glucose levels, and report to the were not yet biocompatible, that is, not reduced rates of infection.
medical personnel’s smartphones or usable in contact with skin and blood. For more information, visit www.
other devices. The dressing will also it- Creating a polymer that would be both technion.ac.il.
Unlike conventional wafer-based fabrica- areas at the point where they all con- ry network and facilitate the indirect re-
tion, this laser fabrication provides a new verge and then decouple the informa- mote measurement of human motions,
sensing paradigm for motion tracking. The tion entangled in the converged signals. which is applicable for wearable VR/AR
measuring system extracts signals corre- To maximize users’ usability and mobili- systems. The research team analyzed the
sponding to multiple finger motions by ty, the research team used a single-chan- sensor signal patterns into a latent space
generating cracks in metal nanoparticle nel sensor to generate the signals corre- encapsulating temporal sensor behavior
films using laser technology. The sensor sponding to complex hand motions. and then they mapped the latent vectors
patch was then attached to a user’s wrist to The RSL system collects data from arbi- to finger motion metric spaces.
detect the movement of the fingers. trary parts on the wrist and automatically The system is expandable to other body
The concept of this research started trains the model in a real-time demonstra- parts; for example, it is capable of extract-
from the idea that pinpointing a single tion with a virtual 3D hand that mirrors ing gait motions from a pelvis. This technol-
area would be more efficient for identify- the original motions. To enhance the sen- ogy is expected to find uses in health-moni-
ing movements than affixing sensors to sitivity of the sensor, researchers used la- toring, motion tracking, and soft robotics.
every joint and muscle. To make this tar- ser-induced nanoscale cracking. For more information, contact Pro-
geting strategy work, it needs to accu- This sensory system can track the mo- fessor Sungho Jo at [email protected];
rately capture the signals from different tion of the entire body with a small senso- http://nmail. kaist.ac.kr.
Sponsored by
highlight different strategies to implement concurrently to achieve a successful cardi- tion as well as cardiac function following
vascularization and augment cardiac func- ac repair, because the heart has very little myocardial infarction.
tional properties with respect to electro- ability to regenerate cardiomyocytes or Currently applied patch-based stem
physiological similarities to native tissue. heart cells by itself. cell therapies have shown advanced effi-
Following a myocardial infarction, Employing a 3D bioprinting strategy to cacy, rather than using single-compo-
myocardial tissues and vasculatures are geometrically control the spatial pattern- nent therapies, by providing a tis-
equally and severely damaged. Therefore, ing and using dual stem cell therapy as its sue-friendly environment during the
therapeutic or regenerative approaches co-culture can play a key role in promoting time of host-graft integration.
should be planned to target both of them and synergistically improving vasculariza- “It would be helpful for tracing cells of
the printed patch to investigate the mode
Bioink I Bioink II of action for the transplanted patch,” said
with
vascular author Sanskrita Das.
endothelial “Although there are still inherent limita-
growth tions for the clinical study, the suggested
Cardiac progenitor cells Mesenchymal stem cells factors stem cell delivery platform technology pro-
(CPCs) (MSCs) vides a practical therapeutic perspective for
various tissue engineering applications,”
said author Hyoryung Nam.
Ink I Ink II As enthusiasm for cardiac regeneration
charges and science continues to advance,
3D bioprinted cardiac patches will soon be-
Cs
GF
CP
VE
VE
Cs
+
SC
CP
SC
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Upcoming...
Precision optics are used in a variety of aerospace, industrial, scientific, medical, astronomical, and military applications. Optical per-
formance is often enhanced by material selection, rigorous design specifications and the application of thin film coatings. The problem
most engineers encounter is determining what types of optics will work best for which applications, and which coatings will deliver the
best performance for a given application. This 60-minute Webinar from the editors of Tech Briefs magazine will examine some of the key
considerations one must know to make those decisions.
Speakers:
Chris Cook Christopher Fridd Emiliano “Emi” Ioffe Mark Pontin
Technical Fellow, Product Manager, Process Managing Director,
Edmund Optics Newport Optical Development Resolve Optics Ltd.
Components and Engineering
Manager,
Ophir Optics
SPINOFF
of products and services in the fields of health and
medicine, consumer goods, transportation, public safety,
computer technology, and environmental resources.
Trigno Mini sensors are applied to the forearm and hand muscles of professional pianist Rui Urayama SAE MEDIA GROUP
to gain understanding of fine motor control strategies. (Image: Delsys Inc.) 261 Fifth Avenue, Suite 1901, New York, NY 10016
(212) 490-3999
and algorithms capable of pinpointing Institutes of Health is an attempt to let Executive Vice President................................................ Luke Schnirring
Technology Director......................................................Oliver Rockwell
each of those signals, although process- amputees control a prosthetic limb
Director of Digital Products ..................................................Howard Ng
ing the data from a single test still took much like a natural body part. While
Digital Media Associate.............................................. Md Jaliluzzaman
days. As computing power advanced, other robotic prosthetics have communi-
Digital Media Assistant........................................... Rowena Pagarigan
however, Delsys created software that cated with surgically implanted elec-
Digital Media Assistant......................................................... Zita Zhang
now can analyze that firehose of data in trodes, this new, less expensive, and non-
Digital Production Associate....................................Andrew Greenberg
real time. invasive approach would interpret the
Digital Production Associate..............................................Symba Wong
Making the sensors wireless was no less firing of EMG signals directly from a
Credit & Collection Manager............................................Stacie Pointek
daunting, with the biggest challenge be- limb’s remaining muscles without the
Budget & Forecasting........................................................Felecia Lahey
ing to perfectly synchronize signals from risks of surgery. Accounting/Human Resources Manager.............................Sylvia Bonilla
multiple sensors placed across the body. Delsys is also working with several part- A/R Clerk........................................................................... Crystal Ortiz
This is essential for seeing how muscles ners to develop technology that would Office Manager............................................................Alfredo Vasquez
work together to coordinate complex let patients speak after having their lar-
movement. Because wireless protocols ynx, or voice box, removed. The idea is ADVERTISING Account Executives
like Bluetooth can have several millisec- to first use the EMG technology to re- MA, NH, ME, VT, RI, Eastern Canada.................................... Brian Hines
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CT................................ ................................................Stan Greenfield
oped its own wireless language for the the face and neck during speech. Then a ..................................................................................... (203) 938-2418
sensors to transmit the exact timing of program could translate those motor sig- NJ, PA, DE......................................................................... John Murray
each nerve firing. nals back into speech. ..................................................................................... (973) 409-4685
Most customers for Delsys’ systems, sen- As the company has made some of its TX, OK, LA, AR, MS, AL, TN, FL, SC, NC, GA, DC, WV, VA........Ray Tompkins
..................................................................................... (281) 313-1004
sors, and software are still research labora- devices simpler and easier to use, Delsys
NY, OH...........................................................................Ryan Beckman
tories at universities, medical device com- also has begun to find customers outside ..................................................................................... (973) 409-4687
panies, and other scientific institutions, of research laboratories. These include MI, IN, WI ..................................................................... Chris Kennedy
developing cutting-edge technologies. individual neurosurgeons, physical ther- ......................................................................(847) 498-4520 ext. 3008
MN, ND, SD, IL, KY, MO, KS, IA, NE, Central Canada...............Bob Casey
Many are engaged in projects that would apists, athletic trainers, and others who ..................................................................................... (847) 223-5225
once have been thought impossible. are interested in analyzing movement or CA, WA, OR, AZ, NM, Rocky Mountain States.......................Tim Powers
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regenerating damaged nerves to reverse While it’s been over 15 years since Del- Europe............................................................................ Sven Anacker
..................................................................................49-202-27169-11
paralysis, including at least one company sys last worked with NASA, De Luca said
Integrated Media Consultants.........................................Patrick Harvey
that has restored movement to paralyzed the company, now a global operation, ..................................................................................... (973) 409-4686
monkeys in the lab. While motor nerves continues to benefit from the team’s Rick Rosenberg
can sometimes regenerate with the help long relationship with the space agency, (973) 545-2565
Todd Holtz
of electrical stimulation together with which laid the groundwork for its flag- (973) 545-2566
new therapies that are in development, ship products. “A lot of our early devel- Jason Setti
it’s hard to know what paths those nerves opments were seeded by the larger re- (973) 874-0271
are taking. This is where Delsys systems search questions that had their inception Daniel Barrett
(973) 409-4762
can help researchers track progress by with the NASA-focused studies.”
Erik Schenck
detecting the location and the degree of For more information, visit https:// (973) 841-6040
nerve and muscle activity. spinoff.nasa.gov/Electrical-Body-
Another project the company is work- Signals-Help-Researchers-Restore-
ing on with universities and the National Movement-and-More.
46 www.techbriefs.com Tech Briefs, March 2023
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Contents
4 16
March 2023
FEATURES DEPARTMENTS
4 Laser Beam Shaping Increases Welding Speed of EV Battery 33 New Products
Coolers
11 Refining Automotive Battery Management Systems with
Lumped-Approach Thermal Modeling
16 Building Out the EV Battery-Recycling Ecosystem
22 Advancing Higher Speeds and New Techniques for EV
Recharging
ON THE COVER
The ability to charge EVs at a very fast
BRIEFS rate is a key to electrifying mobility across
26 Anode-Free Lithium Batteries with Maximized Energy Density the U.S. It’s a focus of the U.S. Department
of Energy’s Extreme Fast Charger project
26 Simplifying the Production of Lithium-ion Batteries and other companies are also develop-
27 New Hybrid Electrolyte for High-Performance Lithium-ion Batteries ing super-fast electric charging technolo-
gies, including charging without stopping
28 Using Nano-Engineering Techniques to Develop a Safer Battery at all with a roadway-embedded wireless
29 Improving Accuracy of Battery Charge Measurement
charging network. Learn more on page 22.
From
Concept
to
Reality
Make the Leap with
Our Automotive Passive Components
Thin Film Metal Plate Current Sense Specialty Resistors: HV73V
Resistors: RN73H Resistors: TLR Series • Maximum working voltage: 800V,
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at elevated temperatures • High reliability and performance • Suitable for high
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«
4
Battery & Electrification Technology, March 2023
W
hen it comes to plates. The coolant flows through
temperature ex- stamped channels in the base plate,
tremes, electric which is joined to a top plate. To prevent
vehicle (EV) bat- coolant leakage, the base and top plates
teries are a lot must be joined to create a tight, hermet-
like people. EV ically sealed joint (Figure 1). The welded
batteries perform best in the same sort of joints must also be free of cracks that can
temperature ranges as humans do. EV ther- lead to mechanical failure in the field.
mal management systems maximize bat-
tery performance and extend its life. Cooling Plate Brazing
Cooling plates in an EV thermal manage- Challenges
ment system allow liquid coolant to re- Manufacturers started joining battery
move heat from the battery. cooling plates using vacuum brazing
One cooling plate design circulates technology. These earlier plates (Figure
coolant between two thin aluminum (Al) 2) were much smaller than the cooling
capaNCDT
CONTACT US www.micro-epsilon.com/battery
Laser Beam Shaping Methods Figure 3: The deep-penetration welding achieved in the keyhole can overcome many joining
Three broad categories of beam-shap- challenges by producing high-quality welds. (Image: Civan Lasers)
ing include static, vari-
able, and dynamic. Static
and variable methods rely 2048.023 μm
on diffractive optical ele-
ments (DOEs), which pro-
vide cost-effective beam
1341.010 μM
rounding ring beam, DOEs ing to join cooling plates. (Image: Civan Lasers)
Under cut Humping
8
Battery & Electrification Technology, March 2023
can provide variable beam-shaping op- cess — enabling a single machine to carry currently include four options: galvanom-
tions that increase laser flexibility. This out specialized tasks in serial production, eter scanners, piezo-driven actuators, mi-
option requires a single-axis shift or rota- for instance — a static beam cannot ade- cro-electrical-mechanical (MEM) scan-
tion to change the ratio intensity between quately stir the melt pool to accomplish ners, and optical phased arrays (OPAs).
the core and ring beams. Another ap- the frequently changing operations that Galvanometric scanners can be used to
proach uses variable superimposed inten- constitute the daily business of industry.4 oscillate single-mode fiber lasers during
sity distribution with a two-in-one (du- the welding process in the pattern of, for
al-core) fiber. Dynamic Beam Shaping example, a circle or a figure eight.
While such beam-shaping solutions Known for overcoming welding de- However, such solutions have power and
can improve the flexibility of a given pro- fects, dynamic beam shaping methods frequency limitations. Inherent mechani-
cal and kinetic trade-offs related to mov-
ing parts limit the maximum achievable
Shape Sequence Focal length Parameters frequency due to the mass of the scan-
Resize matrix to 32 Shape generation
[um] Max normalization Automatic shapes
ner’s oscillating mirrors. Smaller, light-
1.434
weight mirrors limit laser power.
1.075.5
In contrast, OPA technology, a type of
717 coherent beam combining (CBC), merges
many single-mode laser beams into one
358.5
larger beam (Figure 5). Each laser emits
0
[x,y]:(219.01,-62.57) [µm]
its own light, which overlaps with other
-358.5
ρ:2.11 [w/cm^2]
beams in the far field to create a diffrac-
-717
tion pattern, providing the flexibility to
easily manipulate the beam shape in real
-1.075.5
time, without any moving parts, creating
a dynamic beam laser (DBL).
-1.434 -1.075.5 -717 -358.5 0 358.5 717 1.075.5 1.434
1.434
Selected Points:(50) Cursor
-6,3 manually
-8,-3
-6,-8
max
Laser Welding of Battery
-2,-12
4,-12
Dz : 0
Cooling Plates
-8.-11
12.-8
Reset
To overcome cooling-plate welding
R 15.-4
16,1
Load
challenges, tailored beam shaped were
P 16.5 Reorder
needed and designed (Figure 6). These
ExportShape DelateShape
beam shapes use high shape frequency
together with a sequence of beam shapes,
this enables fast switching between
Figure 5: OPA technology, a type of coherent beam combining (CBC), merges many single-
mode laser beams into one larger beam to manipulate the beam shape in real time, without beam shapes, adding more flexibility. For
any moving parts, creating a dynamic beam laser. (Image: Civan Lasers) example, if one shape stabilizes the key-
hole and prevents spatter while a differ-
ent shape prevents cracking, then a
Aluminum dimple welding Solidification process of melted material
well-designed sequence of these two
shapes can achieve all three goals.
Processes for welding cooling plate con-
figurations have recently been developed,
including designs with channel and dimple
geometries made in Al 3003 and Al 5754
alloys. Simulations created by Professor
Andreas Otto at the Institute for Production
Engineering and Photonic Technologies at
Temperature (K)
the Vienna University of Technology (TU
298.0 1000 1500 2000 2500 3000 3500 Wien), Wein helped optimize the many pro-
T_melting T_evaporation cess parameters (Figure 7).
0.0025 0.0025
Simulations reveal that humping is a
periodic phenomenon. When the melt
pool is long and the speed is fast, cooling
starts from the sides, narrowing the mol-
ten channel. As the molten channel nar-
Figure 6: DBL software makes it easy to design the relevant beam shape, frequency, sequence,
and focus; upload it to the laser; and see the effect on the weld using cross-section analysis. rows, molten material flows up and cre-
(Image: Civan Lasers) ates the hump.5
Battery & Electrification Technology, March 2023 9
Thermal Management
Changing the beam shape to concen- 3. G oppold C., et al., (2017, May). Dynamic Beam 5. Shekel. “Laser beam shaping increases welding speed
Shaping Improves Laser Cutting of Thick Steel of thin foils,” www.laserfocusworld.com. Retrieved
trate energy input on the sides of the melt Plates. Photonics Media. Retrieved January 13, January 14, 2023, from https://www.laserfocusworld.
pool maintains channel width in the trail- 2023, from https://www.photonics.com/Articles/ com/laser-processing/article/14234022/laser-beam-
Dynamic_Beam_Shaping_Improves_Laser_Cutting_ shaping-increases-welding-speed-of-thin-foils.
ing edge, ensuring channel stays open of/a62070.
and reducing the flow velocity of the melt 4. Leavitt DD. Dynamic beam shaping. Med Dosim. This article was written by Ami Shapira,
behind the keyhole, which decreases the 1990 Jun;15(2):47–50. doi:10.1016/0958- Marketing Manager, Civan Lasers. For more
3947(90)90033-e. PMID: 2118358.
risk of humping. Combining this with the information visit, www.civanlasers.com.
introduction of a different period into the
process interrupts the periodicity of the
humping, avoiding the defect altogether.
Switching the beam shapes in sequence Solution Result
every few microseconds eliminates hump-
ing and enables welding at higher speeds
without defects (Figure 8).
For large-scale part production, SLTL
(Sahajanand Laser Technology Limited), a
leading manufacturer of laser welding ma-
chines in India has incorporated DBL tech-
nology in a 3D cutting and welding ma-
chine based on CBC. The project, funded by
the Israeli Innovation Authority and the
Global Innovation & Technology Alliance,
has resulted in defect-free production of
full-scale cooling plates.
References
1. Behzad Fotovvati, Steven F. Wayne, Gladius Lewis,
and Ebrahim Asadi, “A Review on Melt-Pool
Characteristics in Laser Welding of Metals,”
Advances in Materials Science and Engineering
(2018), https://doi.org/10.1155/2018/4920718.
2. E ric Punzel, Florian Hugger, Robert Dörringer,
Thorm Lembit Dinkelbah, and Andreas Bürger,
“Comparison of Different System Technologies for
Continuous-Wave Laser Beam Welding of Copper,” Figure 7: Simulation software from the Institute for Production Engineering and Photonic
Procedia CIRP 94 (2020):587–91, https://doi. Technologies at the Vienna University of Technology helped in the development of laser weld-
org/10.1016/j.procir.2020.09.081. ing processes for several cooling plate configurations. (Image: Civan Lasers)
Figure 8: To overcome the interface cracks, a new beam shape was designed and to eliminate humping a sequence of beam shapes was used
to break the periodicity of the hump-effect mechanism. (Image: Civan Lasers)
10
Battery & Electrification Technology, March 2023
Refining Automotive Battery
Management Systems
Lumped-Approach
with
Thermal Modeling
For India’s transportation sector to meet its ambitious electrification goals, manufacturers must
accelerate the development of essential components, such as battery management systems.
I
ndia is a fast-growing market for electric vehicles (EVs), The Role of Simulation in Developing
with one study predicting that over 30 percent of the Accurate BMS
vehicles sold in India will be electric by 2030. The battery Exicom Tele-Systems Pvt. Ltd. designs, develops, and deploys
packs that power EVs are one of the main drivers of the energy solutions, including the latest lithium-ion (Li-ion) battery
electric mobility revolution in India. To monitor and man- technologies. To date, it has deployed Li-ion battery solutions
age battery pack performance and safety, packs are usu- totaling more than 1.8 GWh — among the highest in the world
ally equipped with a battery management system (BMS). A BMS by a single company. Exicom also offers charging solutions and
is an electronic system that monitors a battery’s voltage, tem- BMS for electric two-wheelers and light electric vehicles, which
perature, coolant flow, and health and predicts several other are driving the growth of electric mobility in India.
performance parameters, such as current variation and heat At Exicom’s R&D center in Gurugram, India, the tech-
generation, helping to extract optimum performance from a nology team led by Dr. Parmender Singh has developed
battery pack. a BMS that can be used to precisely monitor and manage
Li-ion batteries in applications across a
broad voltage range (up to 1000 V).
throughout the pack. This is where COMSOL Figure 1. The temperature distribution in a cylindrical cell at 1C discharge (left) and the contour
Multiphysics® plays an integral part, by al- distribution of temperature (right). (Image: Exicom)
lowing for accurate computation and colla-
tion of the inputs, like heat profile informa- Exicom team began by analyzing the heat of the cell. The visualization on the right
tion, that are required to develop a BMS generated in cylindrical cells with different shows the contour distribution of tempera-
with surgical precision. form factors and further extended this ture, where the maximum temperature is
model to the pack level using the heat located in the active material of the cell.
Predicting and Preventing profile generated for the cells. “We were The simulation results, when validated
Potential Thermal Runaway especially interested in improving the tem- with experimental findings, were observed
Dr. Singh’s team at Exicom used COMSOL perature gradient across the pack for air- to be within the error limits of ±5 percent
Multiphysics to perform a number of anal- cooled battery packs,” said Dr. Singh. at the standard charge–discharge profile.
yses on the thermal behavior of battery The results for thermal modeling at the The model was then further extended for
cells. They also used simulation to analyze cell level for cylindrical cells during a 1C 2C discharge at 100 percent state of charge
potential external short circuits, which discharging are shown in Figure 1. The visu- (SOC) according to Standard UL1642, which
could cause thermal runaway — an uncon- alization on the left in Figure 1 shows the is defined for external short circuit testing.
trolled self-heating process that can dam- temperature distribution, where the maxi- The positive and negative terminals of
age equipment or even cause fires. The mum temperature is observed in the middle the cell were shorted via an 80 ±20 mΩ
Temperature change
2.5
Cell current (A)
-70
R_short_ext=0.008 Ω, Cell potential
-80
∆T (K)
Figure 2. The temperature profile in a cell after thermal runaway (left) and the electrochemical profile in a cell after thermal runaway (right).
(Image: Exicom)
12
Battery & Electrification Technology, March 2023
pring!
t h i s s
ning
Retur
BATTERY
+ - + - + - + AND + - + - + - +
SUMMIT
ELECTRIFICATION
Topics include:
• Will Solid-State Batteries Become Dominant? • The Future of Electric Cargo Transportation
• Improving Performance With Machine Learning • Recycling and Second Lives of EV Batteries
• The EV Charging Infrastructure • Anode Advancements: The Rise of Silicone
• Thermal Management and Runaway Prevention • Efficient Batteries With Better EV Architecture
3.5 70
1.98
3.4 65
3.3 1.97 60
3.2 55
1.96
3.1
50
3
1.95 45
2.9
2.8 40
1.94
2.7 35
2.6 1.93 30
2.5 25
1.92
0 20000 40000 20
0 1000 2000 3000
Time (S)
Figure 3. Simulated and experimental data during external short-circuit testing. (Image: Exicom)
resistance. The COMSOL® software’s thermal conductivity, heat capacity, drive able to efficiently study charge and dis-
lumped approach-based thermal model cycle, and open-circuit voltage (OCV)-SOC charge profiles, thermal behavior at dif-
was validated against experimental data table — that are readily available from ferent charge and discharge rates, and
for charge–discharge profiles of the cell. battery pack manufacturers. thermal runaway (Figure 2) due to exter-
They also developed: Extracting these parameters experi- nal or internal short circuits for different
• Cyclic and calendric capacity-fade mod- mentally is not only a time-consuming cell chemistries (Figure 3).
els for cylindrical cells based on the process but also prone to errors due to The team was also able to identify
optimization features available in variable experimental conditions. For ex- the hotspots in the battery pack and
COMSOL® ample, ambient temperature fluctuates, determine the cell grading based on
• A high-fidelity pseudo two-dimensional so extracting an accurate heat profile of a capacity fade analysis with high accu-
(P2D) model for cylindrical cells using cell requires performing an extensive racy. These results had direct applica-
extracted electrochemical parameters series of tests at different ambient tions in reducing the development cycle
They found that the lumped approach temperatures. time of the BMS, as the hotspots indi-
enabled them to construct models using Using simulation, however, Dr. Singh cated the best positions for deploying
a minimal number of parameters — such and the team were able to perform these the thermal sensors within the BMS to
as cell geometry, electrode thickness, experiments with great ease. They were function most efficiently.
×10-11
External magnetic field
10.0
Cathode 0.52
Applied current density Magnetic field response_ at epsl_neg = 0.12
Magnetic field response_ at epsl_neg = 0.36
9.0 0.47
Battery polarization at epsl_neg = 0.12
Magnetic field response (A/m)
0.37
Anode
7.0 0.32
0.27
6.0
0.22
5.0
0.17
z
y x 4.0 0.12
0 500 100 1500 2000
Time (s)
3D-designed cell geometry (left). Variation of magnetic field response and polarization behavior during discharging at 0.12 and 0.36 anode
porosity values (right). (Image: Exicom)
14
Battery & Electrification Technology, March 2023
According to Dr. Singh, “COMSOL is an COMSOL to evaluate the magnetic field predictive analysis. In the future, they
easy-to-learn and adaptable finite ele- response, battery polarization, and inter- also plan to implement a reduced order
ment tool for battery design and thermal nal resistance of the Li-ion response model for SOC and SOH and export the
modeling.” (Figure 4). model to MATLAB® for code generation
The team observed that variation in up to the ASIC level.
Future Scope: Extending Battery electrode porosity has a significant influ- With the accelerating transition to
Simulations to Predict Aging ence on the magnetic field response. electric mobility in India and world-
In addition to the thermal simulations, Though this research is currently in its wide, research on battery technology is
Dr. Singh has expanded the use of simula- preliminary stages, the potential applica- expected to increase significantly in the
tions to investigate another important tions are far reaching. “We expect that coming years. Simulation offers a cru-
phenomenon: battery aging. During the further investigation into this phenome- cial head start to companies in the
lifetime of a battery, its state of health non will allow for developing and deploy- electric mobility space that want to
(SOH) progressively deteriorates due to ing monitoring features for battery aging provide more effective solutions and
irreversible physical and chemical as well as better protection mechanisms improve the time to market for their
changes, such as the growth of a solid against it in the BMS itself,” said Dr. Singh. products.
electrolyte interphase (SEI) layer, which The Exicom team is currently working on
can lead to loss of porosity in a battery electrochemical P2D modeling for thermal COMSOL Multiphysics® and COMSOL®
cell, which in turn can lead to an increase and capacity-fading analysis at the cell are registered trademarks of COMSOL AB.
in polarization and internal resistance. level. It intends to further extend the model MATLAB is a registered trademark of The
Magnetic field probing (MFP) is a non- with additional thermal exothermic equa- MathWorks, Inc.
invasive method for monitoring a bat- tions at the electrodes and SEI layer for
tery’s SOH. With the aim of demonstrating better accuracy during thermal runaway. This article was written by Neena Picardo,
the potential of the MFP method, Dr. They also plan to use the lumped ca- COMSOL, Inc. (Burlington, MA). For more
Singh developed a multiphysics model in pacity fade model for cyclic and calendric information, visit www.comsol.com.
www.cshyde.com
800-461-4161
[email protected]
D
evelopment of a robust ing up of the world’s battery production. panies, including one founded by former
electric vehicle (EV) bat- Additionally, the sourcing of these mate- longtime CTO at Tesla, are taking on the
tery-recycling indus- rials raises numerous red flags in terms recycling challenge and partnering with
try has moved from a of conditions for workers, site pollution, carmakers. Automakers are also concen-
net-positive sideline to a geopolitical complications, and concen- trating on proven technologies such as
necessity as automakers, tration of ownership. hydrometallurgy (often leaching, which
and their suppliers, transition away from The good news is that the Biden involves immersing the cells in acid to
internal combustion. Experts say that Administration’s recently enacted dissolve the acids into a solution) and
global mining operations are simply not Inflation Reduction Act provides incen- pyrometallurgy (burning and smelting) to
on track to produce the virgin raw mate- tives for automakers to use recycled efficiently recover a very high percentage
rials needed to meet the dramatic ramp- minerals in their batteries. Startup com- of key metals from used lithium-ion (Li-
16
Battery & Electrification Technology, March 2023
ion) EV batteries. But there’s a conun-
drum: Battery companies are working to
reduce the amount of problematic, hard-
to-source metals in their cells, which
has the potential to also reduce their
viability for cost-effective recycling.
Another approach, which has drawn
federal research funding, is direct re-
cycling or recovery, with the advantage
of retaining the intact cathode material.
According to Jeffrey Spangenberg, the
Materials Recycling Group Leader in the
applied materials division of Argonne
National Laboratory and Head of the
national ReCell Center R&D initiative,
the hydrometallurgy process destroys
the cathode. “If we can keep the cathode
as a cathode, then it can go right back
into a battery and save quite a bit of
money,” he explained. “But there are a
lot of challenges with it. For instance,
battery cars are likely to last 20 years, New battery cells proceeding through the final stage of the cell manufacturing process at the
in which time technology doesn’t stand GM-LG Energy Solution Ultima Cells factory in Ohio. (Image: Roger Mastroianni/GM)
still. We have to figure out how to make
old cathodes marketable.” a new book that focuses on the prob- Lithium is heavily sourced through
lematic materials in Li-ion batteries. “We evaporation processes in arid basins in
Problematic Materials have to open our eyes to the supply chain Chile, Argentina, and Bolivia. According to
One key aspect of the looming materi- behind the move away from fossil fuels,” the Natural Resources Defense Council,
als problem is the need for nickel, which Sanderson told SAE Media. “It is hidden, the practice “contributes to the ecologi-
often gets overlooked as the focus is on almost opaque, and currently mostly cal damage of internationally recognized
lithium and, to a lesser extent, on cobalt. controlled by China. And it involves more wetlands and protected areas, where
According to Sam Abuelsamid, than putting up some solar panels — it’s water resources are already exhausted
Principal Research Analyst for E-mobility about raw materials and mining.” for local and indigenous people. Many of
at Guidehouse Insights, for every 100
kilowatt-hours of battery in an EV, 61 to
66 kilograms of nickel are needed. If EV Electolyte
Recovery
Battery
Shredding
penetration reached 100 percent (un-
likely until the 2040s), something like
Cathode,
5.8 million metric tons of nickel would Anode, and Metals
be needed annually if we rely solely on Seperation
LIN
DIR
BATTERIES
AND PVDF
than double worldwide production —
unless recycling was a factor.
“Recycling is absolutely essential,”
Abuelsamid said. “We don’t want to be Carbon Black
and PVDF
dumping batteries with these essential Removal Battery
Use
metals into landfills. We need to recapture
as much as possible, because we will need
way more EV batteries than we currently Relithiation Battery
and Upcycling Manufacturing
can build with available virgin materials.”
Henry Sanderson, a former Financial REJUVENATED
CATHODE
Times commodities and mining reporter
who now works for Benchmark Mineral The EV battery ‘circle of life’ as seen by Argonne National Laboratory’s ReCell R&D center.
Intelligence, is the author of Volt Rush, (Image: ANL)
these communities have no say in — and ium-ion batteries,” said Lewis Black, The Big Ramp-Up
receive little benefit from — the mining who heads Almonty Partners and has Kunal Phalpher is the Chief Strategy
operations.” Chile, a major producer, has 15-years experience in mining tung- Officer at Canada-based Li-Cycle, whose
debated nationalizing its lithium re- sten, another battery metal with a 50 stated purpose is to “recover critical
source, for both economic and environ- percent-recycled supply. materials from Li-ion batteries and re-
mental reasons. The battery industry — aware of introduce them back into the supply
More than 70 percent of the world’s these issues — has steadily reduced the chain.” Phalpher said Li-Cycle takes
cobalt comes from the Democratic amount of cobalt in its cells, but so far whole packs and shreds them, producing
Republic of the Congo, where there are it remains an essential metal. Nickel, plastic, copper, and aluminum that can
severe child labor issues (up to 40 per- also problematic, often is mined in an be sold on to recyclers. Using hydromet-
cent of the cobalt work force), ongoing environmentally destructive way. The allurgy, the company develops so-called
human rights abuses, and horrendous massive Chinese-owned Ramu nickel “black mass,” containing cobalt, lithium,
working conditions with minimal safety. mine in Papua, New Guinea, for in- and nickel. “At high purity levels, it can
Like lithium, cobalt is mostly re- stance, was estimated to dump 680,000 go back into the supply chain and help
fined in China, and Chinese companies, tons of waste into Basamuk Bay annu- create domestic sources,” Phalpher said.
operating through the massive ‘Belt ally, leading to a $5.2 billion lawsuit Li-Cycle, which went public on the NY
and Road’ international development from a local coalition. Stock Exchange in 2021 through a SPAC
initiative, own or have financed major Sustainable lithium mining, including deal, estimates that approximately 15
stakes in lithium and cobalt mines a U.S. domestic supply, is under develop- million tons of Li-ion batteries will have
— including 80 percent of the cobalt ment but recovering the metal from used reached the end of life by 2030, up from
in the DRC, reports GlobalEDGE. After EVs is a proven process. A ton of bat- 1.7 million tons by 2020. The company
an international outcry, the leading tery-grade lithium can be produced from has a “hub and spoke” organization: The
Chinese companies have made some 250 tons of ore and 750 tons of brine, or spokes create the black mass from scrap
modest improvements in DRC mining from just 28 tons of used Li-ion batteries, batteries, and the hubs separate out the
practices. And some crude refining is the U.S. Department of Energy (DoE) said. metals and prepare them to re-enter the
now done locally, economically bene- The only problem is that less than supply chain. Last April, LG Chem and LG
fiting locals in the DRC. five percent of battery lithium was being Energy Solution chose Li-Cycle as their
The metal remains a flash point. recovered in 2019, said DoE. But the in- preferred recycling partner for North
“Cobalt is a ‘dead man walking’ in lith- dustry is growing fast. American operations, providing black
METALS NICKEL
REFINING
CATHODE
CELL METALS PRODUCTION
PRODUCTION REFINING
OEM
COBALT NICKEL
NICKEL COBALT
COBALT
NICKEL
COBALT
LITHIUM LITHIUM
CATHODE SUPPLY
CHAIN EXAMPLE
The average metal atom travels 50,000 miles from the mine before it’s used in an EV battery pack, according to Redwood Materials. Recycled
metals will make up 30 percent of the materials in the company’s cathodes by 2025. (Image: Redwood Materials)
18
Battery & Electrification Technology, March 2023
mass to the hubs. Soon after, Glencore those materials into new cathodes and Also in 2022, Volkswagen Group of
said it would supply scrap and end-of-life anode copper foils — critical components America said it was partnering with
Li-ion batteries to Li-Cycle and like LG now mainly made in Asia. According to Redwood to recycle batteries from
Chem, will “offtake” black mass and other Redwood, it can recapture 95 percent Volkswagen, Porsche, and Audi ve-
materials from the recycler. of the elements, including nickel, cobalt, hicles. Steven Rufo, VW’s Director of
Another Li-Cycle partner is General lithium, and copper, from Li-ion batteries, Group Service and Technology, said that
Motors. By 2023, Li-Cycle will launch a then reprocess them into new battery Redwood has already begun recycling
recycling center near GM’s Ultium bat- materials for its customers. the company’s packs and modules, and
tery-cell plant in Ohio. Li-Cycle opened The company currently processes six that the pickup will be free for its dealer
its third spoke facility in Arizona last May, gigawatt-hours of Li-ion batteries an- network. “The volume is still very low,” he
with the ability to process up to 10,000 nually but is expanding rapidly. By 2025, said. “Our plan was to sign with Redwood
tons of battery manufacturing scrap and Redwood said it aims to ramp up to an- before we ramped up so we could learn
depleted Li-ion batteries annually. nual production of 100 gigawatt-hours about what worked and what didn’t. So
Tim Grewe, Director of Electrification of cathode active material and anode far, we’re seeing mostly defective modules
Strategy and Cell Engineering at GM, said copper foil, enough to supply a mil- replaced under warranty. Complete pack
the company is pursuing various paths to lion EVs. The hope is to expand up to replacements are likely to be kind of rare.”
keep batteries out of landfills and deliver 500 gigawatt-hours of these materials Alexis Georgeson, VP of Communica-
metals at less than the cost of mining annually by 2030 — sufficient for five tions and Government Relations at
them, including the partnership with Li- million EVs. Redwood said that the company is not
Cycle in Ohio. “There’s the recycling path, The company operates a 175-acre cam- primarily a recycler. “Our core business is
the secondary-use path and the refur- pus in Nevada, close to California’s large creating anode and cathode material,” she
bished path,” he said. “We don’t yet know EV market. Production of the anode cop- said. “We’re not selling black mass; we’re
where the market will go.” per foil will begin in Nevada at the end using it as a feedstock for ourselves.”
of 2022, with Panasonic’s Gigafactory the Georgeson stresses the need for a
Redwood: Full-Circle Pioneer first customer. A partnership with Ford closed-loop domestic production pro-
Redwood Materials, which said in 2021 was announced in 2022, and the company cess that does not involve shipments to
that it had raised $775 million from in- also has agreements with Volvo, Proterra, Asia. “We’re not solving the full equation
vestors and venture firms, is headed by and Panasonic. In 2022, Redwood linked unless we keep our materials in the
former Tesla CTO JB Straubel. The com- up with Toyota, initially focusing on end- country and start making cathodes here,”
pany intends to not only capture met- of-life solutions for the hybrid batteries she said. “The average metal atom trav-
als from old batteries, but also process for vehicles like the Prius. els 50,000 miles from the mine before
Input
Process
INPUT MATERIALS RECYCLING OPERATIONS HYDROMETALLURGY Output
BATTERY FOILS
CAM precursor
Redwood Materials considers itself more of a source for anode and cathode materials than a recycler. The company has partnerships and
agreements with Ford, Toyota, Volvo, Proterra, and Panasonic. (Image: Redwood Materials)
Ramping Up Domestic
Supplies
The race is on to develop U.S. domes- Product Innovation
tic supplies of the metals that go into Processing of different cell shapes
EV batteries. Currently, three companies and cell chemistries
are working in California’s Salton Sea to Continuous Recycling Operation
develop lithium as a byproduct of the Capacity of up to 24 tons/day
existing geothermal production there. At
one time the industry jettisoned lithium Innovative Technology
as a waste product but, with interna- Robust and efficient Pyrolysis Kiln –
tional prices for the metal soaring and fully developed technology
automakers asking for less-problematic Efficient removal of binders,
sourcing, the resource is under inten- organics and fluorine sources
sive development. Most EV batteries use Regeneration of commercially available
lithium from water-intensive processes recycled materials of the highest quality
in dry regions of South America, so
California’s supply could be far more
environmentally friendly.
The three companies are Controlled
Thermal Resources (CTR, with backing
from GM and a purchase agreement from
Stellantis), Berkshire Hathaway Energy
Renewables, and EnergySource Minerals.
None currently are producing commercial
amounts of lithium, but EnergySource www.riedhammer.de A company of
T
he ability to charge electric vehicles at a very stration were “phenomenal,” said Jim Khoury, Senior Manager
fast rate is a key to electrifying mobility across of Global Electrification at GM.
the U.S. It’s a focus of the U.S. Dept. of Energy’s The parameters for the extreme fast charger were established
Extreme Fast Charger project, whose potential in an earlier test that also involved a Hummer EV. That test, span-
was demonstrated convincingly on a production ning nine minutes at 500 amps at an average 725 volts, yielded
GMC Hummer EV at the American Center for nearly 55 kWh before the EV’s battery started to limit the current.
Mobility (ACM) in Ypsilanti, MI, last fall. “While other DC fast chargers can also charge at 500 amps, the
The Hummer EV observed by SAE Media featured an 800- power capability is lower, so it power-limits sooner in the charge
volt electrical architecture — considered state-of-the-art for cycle. Our power limit is 400 kW,” said Dr. Charles Zhu, VP of the
DC “extreme fast” charging. Both GM and Delta Electronics Automotive Business Group for Delta Electronics, and the Principal
(Americas) Ltd., which provided the charging system, are part- Investigator for the DoE project. He said that generally, the Delta
nering with DoE on the program. The results of the demon- extreme fast charging system can deliver 66.7 kWh in 10 minutes.
Suwin/Shutterstock.com
22
Battery & Electrification Technology, March 2023
Medium-Voltage Benefits
Delta Electronics developed the sol-
id-state transformer (SST), power cabinet,
and the charging stand/dispenser that are
vital to the project. The SST converts the
“medium voltage” (13,200V AC) into 1000V
DC. The power cabinet uses the DC voltage
to create a current source, providing up to
500 amps. The dispenser communicates
with the vehicle and provides current to
the battery pack.
Current-generation fast chargers
are considered low-voltage. Tesla’s
Supercharger, for example, runs at 480V.
The move to medium voltage presented
hurdles, explained Zhu. “Medium voltage
can jump a wider gap because of its
higher potential energy,” he said, not-
ing special wire, materials, and designs
Delta Electronics’ Charles Zhu and GM’s Jim Khoury recharge a GMC Hummer EV with the 400-kW
were needed to accommodate the higher extreme fast charger during a demo at the American Center for Mobility. (Image: Delta Electronics)
voltages. From a safety standpoint, the
DoE-Delta extreme fast charger has a me- go out in heat, and you pay for the electric-
dium-voltage switch to isolate the system ity that you’re wasting,” Standing said, add-
from the grid. A licensed electrician with ing that the extreme fast-charging system
proper personal protection equipment would eventually be a less-expensive way
must close the switch. to charge a vehicle.
“If something goes wrong, the ‘blast ra- Delta Electronics has multiple extreme
dius’ is about 30 ft [91.4 m], which is why all fast-charger system patents relating to
others must stand clear when the switch is power-conversion topology and control.
actuated,” Zhu said. To reach production readiness, the system
There are strong reasons to opt for would need to undergo additional devel-
medium voltage, according to Zhu. “The opment, system integration, and testing.
advantages that we gain from pull- Regulatory certification also is required.
ing directly from medium voltage in-
clude higher efficiency, as a conven- Charging On-the-Go
tional transformer can be about 95 per- Then there’s the ultimate time-saver:
cent efficient,” he said. A conventional charging without stopping at all. A road-
transformer needs to have energy pass way-embedded wireless charging network
through a conversion stage — another for EVs is coming to a stretch of urban
loss — to create the DC current needed highway in Detroit, marking a pilot-pro-
to charge a vehicle battery, he added. gram first on a U.S. public road. “Our
Delta Electronics’ Dr. Charles Zhu stands
The medium-voltage system provides electric vehicle receiver units are modu- next to the extreme fast-charging stand.
an approximate 96.5 percent output and lar and compatible with passenger vehi- (Image: Delta Electronics)
eliminates the conventional transformer cles and with light-, medium- and heavy-
from the charging process. duty commercial vehicles,” said Oren Ezer, Central, a mobility-innovation district under
“13.8 kW medium voltage and charging CEO of Electreon, based in Tel Aviv, Israel. development by Ford Motor Co.
current up to 500 amps are key features to Michigan is expected to operate the first “The wireless charging infrastructure
enable energy efficient and highly scalable electrified roadway in early 2025. will support a suite of use cases in-
extreme fast charging,” Zhu said. Electreon’s patented wireless in-road EV volving various vehicle types, including
Michael Standing, Delta Electronics charging technology already is in use in autonomous vehicles, and it will support
Program Manager for the extreme various European demonstration projects, partners, like Ford,” said Jim Buczkowski,
fast-charger system, said that eliminating a including a 0.7-mile (1.05 km) intercity toll the company’s Executive Director of
traditional transformer in favor of a power road in Italy and a 1-mi (1.65 km) public Research and Advance Engineering.
conversion via a solid-state transformer road in Sweden. Sweden’s policymakers aim
equates to about a 3 percent efficiency gain. to have 1,243 miles (2,000 km) of electrified Cloud-Based System Monitoring
“When you’re talking about 400 kW, three roadway in operation by 2030. Detroit’s The $1.9 million-plus Michigan project
percent starts to be significant. The losses electrified roadway will be near Michigan involves one lane of public roadway for a
Battery & Electrification Technology, March 2023 23
EV Recharging
Electreon has integrated its technology at the ‘Arena of the future’ project in Brescia, Italy.
Shown are an Iveco electric bus and a Fiat 500-e being charged while driving. (Image: Electreon)
minimum of one mile (1.6 km). After the receiver via magnetic resonance induc-
existing road surface is removed, rub- tion as the EV moves or is parked di-
ber-coated copper coil segments will be rectly above the coils. A power-manage-
buried 3.15 inches (8 cm) under a new ment unit located either underground
road surface. “Non-electric vehicles are or above-ground near the roadside will
able to use the roadway as usual without transfer the energy from the electric grid An Electreon employee signs her name on an
any disruption,” said Dr. Stefan Tongur, to the roadway’s copper-coil infrastruc- in-road charging coil before road resurfacing is
completed in Gotland, Sweden. The Smartroad
Electreon’s VP. ture. “Cloud-based management software Gotland project began operations in early
The roadway’s coil segments transmit enables live monitoring and provides 2020 as a pre-commercial demonstration of an
power to an EV undercarriage-mounted smart-charging insights,” Ezer explained. electrified roadway. (Image: Electreon)
An electric truck is being wirelessly charged in Gotland, Sweden, as part of Electreon’s ‘Smartroad Gotland’ project. Image includes technology
overview graphics. (Image: Electreon)
24
Battery & Electrification Technology, March 2023
Electreon’s technology solution has 19 patents covering vari-
ous proprietary aspects, including the engineered system archi-
tecture and the communication mechanism between an EV fitted
with a power receiver and the embedded roadway coils. “The
intellectual property of our vehicle receivers will be released to
OEMs for free,” Ezer promised.
Both the battery size and the number of receivers connected
to an EV influence the charging time. “The driving speed
has a negligible effect on the charging performance,” Ezer
explained. He said to date, Electreon has tested its receivers
up to a speed of 49.7 mph (80 kph). As an example, if a com-
mercial truck with five receivers is traveling at 37 mph (60
kph), 37 miles (60 km) of electrified road is needed to fully
charge the battery. If the vehicle is traveling at 12.4 mph (20
kph), 12.4 miles (20 km) of electrified road are needed to fully
charge the battery.
Larger vehicles can support multiple Electreon receivers. For
instance, Class 8 trucks can be fitted with up to seven undercar-
riage receivers. Buses could have three receivers, while passen-
ger vans might have two receivers. “The number of receivers on
an electric vehicle depends on the use case, the vehicle size, and
the vehicle type,” Ezer said. Each Electreon receiver for heavy-
duty EVs is capable of supplying up to 25 kW to the battery.
Based on the power transfer rate requirements of light-duty
passenger EVs, Electreon offers 7 kW and 11 kW receiver options.
Michele Mueller, MDOT Senior Project Manager for connected
and automated vehicles, said that electrified roadways could BET Ellsworth Ad 0323.indd 1 1/30/23 2:37 PM
This article was written by Kami Buchholz, an automotive 154 Hobart Street, Hackensack, NJ 07601 USA
journalist and longstanding contributor to the SAE Media Group, +1.201.343.8983 • [email protected]
who specializes in a wide spectrum of technology coverage for
the automotive and commercial-vehicle industries. For more www.masterbond.com
information, visit www.mobilityengineeringtech.com.
Battery & Electrification Technology, March 2023 25
Anode-Free Lithium Batteries with Maximized
Energy Density
The newly developed battery has a volumetric energy density 40 percent higher than the conventional batteries.
Pohang University of Science and Technology, South Korea
T
he core materials that determine the
Fabrication process of anode-free electrode
battery life and charging speed of
now commonly seen electric vehicles Carbon Branched N-rich Stable Li
SEI deposition
(EVs) are anode materials. Korea’s domes- black PEI
W
hen it comes to battery innova- costs by up to 40 percent. The approach Establishing large-scale production
tions, the importance of produc- also improves the batteries’ energy den- lines is only the first phase of 24M’s
tion processes for bringing down sity, safety, and recyclability. plan. Another key draw of its battery
costs is often overlooked. Now the MIT “The SemiSolid platform has been design is that it can work with different
spinout 24M Technologies has simplified proven at the scale of hundreds of mega- combinations of Li-ion chemistries. That
lithium-ion (Li-ion) battery production watts being produced for residential en- means 24M’s partners can incorporate
with a new design that requires fewer ergy-storage systems. Now we want to better-performing materials down the
materials and steps to manufacture each prove it at the gigawatt scale,” said 24M line without substantially changing
cell. According to the company the de- CEO Naoki Ota, whose team includes manufacturing processes.
sign, which it calls “SemiSolid” for its use 24M Co-Founder, Chief Scientist, and MIT The kind of quick, large-scale produc-
of gooey electrodes, reduces production Professor Yet-Ming Chiang. tion of next-generation batteries that
26
Battery & Electrification Technology, March 2023
24M hopes to enable could have a dra-
matic impact on battery adoption across
society — from the cost and performance
of electric cars to the ability of renewable
energy to replace fossil fuels.
The main components of batteries are
the positive and negatively charged elec-
trodes and the electrolyte material that
allows ions to flow between them.
Traditional Li-ion batteries use solid
electrodes separated from the electrolyte
by layers of inert plastics and metals,
which hold the electrodes in place.
Stripping away the inert materials of
traditional batteries and embracing the
gooey electrode mix gives 24M’s design a
number of advantages. For one, it elimi-
nates the energy-intensive process of dry-
ing and solidifying the electrodes in tradi-
tional Li-ion production. According to the
company, it also reduces the need for more
than 80 percent of the inactive materials
in traditional batteries, including expen-
sive ones like copper and aluminum. The
design also requires no binder and fea-
tures extra thick electrodes, improving the The MIT spinout 24M Technologies uses fewer materials to make its batteries than conventional
energy density of the batteries. Li-ion cells. (Image: Courtesy of 24M Technology, edited by MIT News)
“This is a platform technology,” Ota
said. “We’re not just a low-cost and Our tech can address the issue today companies are planning to build gigafac-
high-reliability operator. That’s what we and tomorrow.” tories (factories with gigawatt-scale an-
are today, but we can also be competi- Judging by industry interest, 24M is nual production capacity) based on 24M’s
tive with next-generation chemistry. We onto something. Since coming out of technology in India, China, Norway, and
can use any chemistry in the market stealth mode in 2015, 24M has licensed the United States.
without customers changing their sup- its technology to multinational compa- For more information, contact Abby
ply chains. Other startups are trying to nies including Volkswagen, Fujifilm, Lucas Abazorius at [email protected]; 617-
address that issue tomorrow, not today. TVS, Axxiva, and Freyr. Those last three 253-2709.
L
ithium-ion (Li-ion) batteries are one Normally, organic electrolytes such as proposed as impact-resistant Li-ion
of the most used batteries that sup- liquid ethylene carbonate (EC) and their electrolytes. However, PEG-based poly-
port modern ITC society, including gels have been used as the Li-ion elec- mer electrolytes crystallize near room
smartphones and EVs. These batteries are trolyte due to their voltage resistance temperature, resulting in a significant
repeatedly charged and discharged by and ionic conductivity. However, as liquids drop in Li-ion conductivity to around
Li-ions passing back and forth between and gels are flammable, a switch to safer 10-6 S/cm at room temperature.
the positive and negative electrodes, polymeric solid electrolytes is preferable. To solve this problem, a research
with the Li-ion electrolyte acting as a Polymeric solid electrolytes such as group has invented a new type of poly-
passageway for the ions. polyethylene glycol (PEG) have been meric solid electrolyte by combining a
Battery & Electrification Technology, March 2023 27
porous polymer membrane with several
micron pores and a photo-cross-linkable
polyethylene glycol PEG-based polymer
electrolyte. The polymeric solid electro-
lyte realized a wide potential window
(4.7 V), a high Li-ion conductivity in the
10-4 S/cm class, which is equivalent to a
liquid and sufficient for practical use, and
a high Li-ion transference number (0.39).
Li-ions transferring in the electrolyte
move in various directions due to natural
diffusion. The distance is several µm to A photograph (left), scanning electron microscope image (center), and schematic illustration
10 µm and does not always move lin- of composite electrolyte structure (right), respectively. (Image: Grewal and Yabu)
early between electrodes, which is one of
the reasons for the decrease in ionic con- This polymeric solid electrolyte not membrane. Through the realization of
ductivity. In the current study, therefore, only shows high performance as an elec- safe, high-performance Li-ion batteries,
the performance of photo-cross-linked trolyte but is also expected to be effective this achievement will contribute to the
PEG-based solid polymer electrolytes in deterring the formation of Li dendrites realization of a sustainable energy supply.
improved by compositing them with mi- (dendritic crystals), which can cause ig- For more information, contact Hiroshi
cron-sized porous membranes. nition, due to the inclusion of a porous Yabu at [email protected].
A
research team at the University of
Central Florida has developed tech-
nology that could prevent electric
vehicle fires, like those caused by saltwa-
ter flooding from Hurricane Ian.
The technology, an aqueous battery,
replaces the volatile and highly flamma-
ble organic solvents found in electric
vehicle Li-ion batteries with saltwater to
create a battery that is safer, faster
charging, just as powerful and won’t
short circuit during flooding. The work is
detailed in a new study in Nature
Communications.
“During Hurricane Ian, a lot of electric
cars caught fire after they were soaked in
floodwater,” said Yang Yang, an Associate
Professor in UCF’s NanoScience
Technology Center who led the research.
“That is because the saltwater corrodes
the battery and causes a short circuit,
which ignites the flammable solvents
and other components. Our battery uses Electric vehicles flooded in saltwater could pose a fire risk, as saltwater can corrode the bat-
saltwater as an electrolyte, eliminating tery and cause a short circuit, igniting flammable solvents and other components. (Image:
the highly volatile solvents.” Adobe Stock)
28
Battery & Electrification Technology, March 2023
Also key to the battery’s design is its By using saltwater as the battery’s forest, allows the researchers to pre-
novel, nano-engineering that allows the liquid electrolyte, the UCF researchers cisely control electrochemical reactions,
battery to overcome limitations of previ- were able to use naturally occurring thereby increasing the battery’s stability
ous aqueous batteries, such as slow metal ions found in the saltwater, such and quick charging ability. Furthermore,
charging times and poor stability. as sodium, potassium, calcium, and mag- the zinc-oxide layer prevented dendritic
Yang is an expert in developing ma- nesium, to create a dual-cation battery growth of zinc, which was confirmed
terials for renewable energy devices that stores more energy. This implemen- using optical microscopy.
such as batteries with improved safety. tation allowed them to overcome the “These batteries using the novel mate-
The UCF-designed battery is fast sluggishness of previous single-cation rials developed in my lab will remain safe
charging, reaching full charge in three aqueous battery designs. even if they are used improperly or are
minutes, compared to the hours it takes To solve problems with instability, den- flooded in saltwater,” Yang said. “Our work
Li-ion batteries. drite growth and corrosion, the research- can help improve electric vehicle tech-
Previous aqueous battery designs have ers engineered a forest-like 3D zinc-cop- nology and continue to advance it as re-
suffered from low energy output, instabil- per anode containing a thin zinc-oxide liable and safe form of travel.”
ity, the growth of harmful metallic struc- protective layer on top. For more information, contact Andrea
tures called dendrites on the negative The novel, nano-engineered surface, Adkins at [email protected];
electrode and corrosion. which looks like a birds-eye-view of a 407-823-0138.
T
he issue of battery usage inefficiency leads to an ambiguity of around 10 per- generated by two microwave genera-
in electric vehicles (EVs) resulting cent in the battery charge estimation. tors to trace the magnetic resonance
from an inaccurate battery charge What this means is that the driving frequencies of the quantum sensor over
measurement may finally get resolved, range of EVs could be extended by 10 a bandwidth of 1 gigahertz. This al-
thanks to a diamond quantum sensor percent. This, in turn, would reduce inef- lowed for a large dynamic range (ratio
prototype developed in the MEXT Q-LEAP ficient battery usage. of largest to smallest current detected)
Flagship project with researchers from Now, a team of researchers from Japan, of ±1000 A. Moreover, a wide operating
Tokyo Tech and Yazaki Corporation. The led by Professor Mutsuko Hatano from temperature range of −40 to +85 °C
sensor can measure currents in a wide Tokyo Institute of Technology (Tokyo was confirmed to cover general vehicu-
range as well as detect milliampere-level Tech), has come up with a solution. In lar applications.
currents in a noisy environment, improv- their study published in Scientific Finally, the team tested this proto-
ing the detection accuracy from 10 per- Reports the team has reported a dia- type for Worldwide Harmonized Light
cent to within 1 percent. mond quantum sensor-based detection Vehicles Test Cycle (WLTC) driving, a
The popularity of EVs as an environ- technique that can estimate the battery standard test for energy consumption
mentally friendly alternative to conven- charge within 1 percent accuracy while in EVs. The sensor accurately traced the
tional gasoline vehicles has been on the measuring high currents typical of EVs. charge/discharge current from -50 A to
rise. This has led to research efforts di- In their work, the team made a proto- 130 A and demonstrated the battery
rected toward developing high-efficiency type sensor using two diamond quan- charge estimation accuracy within 1
EV batteries. However, a major ineffi- tum sensors that were placed on either percent.
ciency in EVs results from inaccurate esti- side of the busbar (electrical junction for According to Professor Hatano, “Increas
mations of the battery charge. The charge incoming and outgoing currents) in the ing battery usage efficiency by 10 per-
state of an EV battery is measured based car. They then used a technique called cent would reduce battery weight by 10
on the current output of the battery. This “differential detection” to eliminate the percent, which will reduce 3.5 percent
provides an estimate of the remaining common noise detected by both the running energy and 5 percent production
driving range of the vehicles. sensors and retain only the actual signal. energy of 20 million new EVs in 2030 WW.
Typically, the battery currents in EVs This, in turn, enabled them to detect a This, in turn, corresponds to a 0.2 percent
can reach hundreds of amperes. However, small current of 10 mA amid background reduction in CO2 emissions in 2030 WW
commercial sensors that can detect such environmental noise. transportation field.”
currents cannot measure small changes Next, the team used a mixed ana- For more information, contact Mutsuko
in the current at milliampere levels. This log-digital control of the frequencies Hatano at [email protected].
Battery & Electrification Technology, March 2023 29
Sodium-Ion Battery Anode for Energy Storage
Carbonaceous anodes based on organic pigments exhibit a high sodium-ion storage performance and
excellent cycle stability.
Pusan National University, Busan, South Korea
L
ithium-ion batteries have high energy anodes. “Organic pigments such as quina- bridging along the parallel packing direc-
density and a long cycle life, making cridones have a variety of structures and tion. Further, nitrogen- and oxygen-contain-
them indispensable in portable elec- functional groups. As a result, they develop ing functional groups in 2,9-DMQA re-
tronics as well as electric vehicles. However, different thermal decomposition behav- leased gases, creating disordered domains
the high cost and limited supply of lithium iors and microstructures. When used as a in the microstructure. In contrast, pyrolyzed
necessitate the development of alternative precursor for energy storage materials, unsubstituted quinacridone developed
energy storage systems. To this end, re- pyrolyzed quinacridones can greatly vary highly aggregated structures. This sug-
searchers have suggested sodium-ion bat- the performance of secondary batteries. gested that the morphological develop-
teries (SIBs) as a possible candidate. Therefore, it is possible to implement a ment was significantly affected by the
Besides having physicochemical prop- highly efficient battery by controlling the crystal orientation of the precursor.
erties similar to that of lithium, sodium is structure of organic pigments precursor,” In addition, 2,9-DMQA pyrolyzed at 600
both sustainable and cost-effective. explained Lee. °C exhibited a high rate capability (290
However, its ions are large with sluggish The researchers focused on 2,9-dimeth- mAh/g at 0.05 A/g ) and excellent cycle
diffusion kinetics, hindering their accom- ylquinacridone (2,9-DMQA) in their study. stability (134 mAh/g at 5 A/g for 1000 cy-
modation within the carbon microstruc- 2,9-DMQA has a parallel molecular pack- cles) as an SIB anode. The nitrogen- and
tures of the commercialized graphite an- ing configuration. Upon pyrolysis (thermal oxygen-containing groups further en-
odes. Consequently, SIB anodes suffer decomposition) at 600 °C, 2,9-DMQA hanced battery storage via surface confine-
from structural instability and poor stor- turned from reddish to black with a high ment and interlayer distance increment.
age performance. In this regard, carbona- char yield of 61 performed. The research- “Organic pigments such as quinacrid-
ceous materials doped with heteroatoms ers next performed a comprehensive ex- ones can be used as anode materials in
are showing promise. However, their perimental analysis to describe the under- sodium-ion batteries. Given the high effi-
preparation is complicated, expensive, lying pyrolysis mechanism. ciency, they will provide an effective strat-
and time-consuming. They proposed that the decomposition egy for mass production of large-scale en-
A team of researchers, led by Professor of methyl substituents generates free radi- ergy storage systems,” said Lee.
Seung Geol Lee from Pusan National cals at 450 °C, which form polycyclic aro- For more information, contact Professor
University in Korea, used quinacridones as matic hydrocarbons with a longitudinally Seung Geol Lee at seunggeol.lee@
precursors to prepare carbonaceous SIB grown microstructure resulting from bond pusan.ac.kr.
A
new battery design could help ease “We showed that this new molten salt tery technologies, while using a more
integration of renewable energy into battery design has the potential to charge Earth-abundant material.”
the nation’s electrical grid at lower and discharge much faster than other Imre Gyuk, Director of DOE’s Office of
cost, using Earth-abundant metals, accord- conventional high-temperature sodium Electricity, Energy Storage Program, which
ing to a study just published in Energy batteries, operate at a lower temperature, supported this research, noted “This battery
Storage Materials. A research team, led by and maintain an excellent energy storage technology, which is built with low-cost
the Department of Energy’s Pacific capacity,” said Guosheng Li, a Materials domestically available materials brings us
Northwest National Laboratory, demon- Scientist at PNNL and the Principal one step closer toward meeting our na-
strated that the new design for a grid en- Investigator of the research. “We are get- tion’s clean energy goals.”
ergy storage battery built with the low- ting similar performance with this new The new sodium-based molten salt bat-
cost metals sodium and aluminum pro- sodium-based chemistry at over 212 °F tery uses two distinct reactions. The team
vides a pathway toward a safer and more lower temperatures than commercially previously reported a neutral molten salt
scalable stationary energy storage system. available high-temperature sodium bat- reaction. The new discovery shows that this
30
Battery & Electrification Technology, March 2023
sodium-aluminum battery design has the
advantage of being inexpensive and easy
to produce in the United States from much
A Cathode more abundant materials.
+ “With optimization, we expect the spe-
Molten salt cific energy density and the life cycle could
reach even higher and longer,” added Li.
A PNNL scientists collaborated with col-
Aluminum wool leagues at the U.S.-based Nexceris to
assemble and test the battery. Nexceris,
B B Solid-state electrolyte through their new business Adena Power,
C supplied their patented solid-state, sodi-
C Sodium ions um-based electrolyte to PNNL to test
the battery’s performance. This crucial
D – battery component allows the sodium
D Sodium anode ions to travel from the negative (anode)
to the positive (cathode) side of the bat-
tery as it charges.
The new sodium-aluminum battery design allows only sodium (depicted as yellow balls) to “Our primary goal for this technology is
move through the solid-state electrolyte to charge the battery. Being constructed of inexpen-
sive Earth-abundant materials such as sodium salts and aluminum wool, a scrap product of to enable low-cost, daily shifting of solar
aluminum manufacturing, is an advantage. (Image: Sara Levine, PNNL) energy into the electrical grid over a 10- to
24-hour period,” said Vince Sprenkle, a
PNNL battery technology expert with more
than 30 patented designs for energy stor-
age systems and associated technology.
“This is a sweet spot where we can start to
think about integrating higher levels of re-
newables into the electrical grid to provide
true grid resiliency from renewable re-
sources such as wind and solar power.”
Sprenkle was part of the team that de-
veloped this battery’s new flexible design,
which also shifted the battery from a tradi-
tional tubular shape to a flat, scalable one
that can more easily be stacked and ex-
panded as the technology develops from
coin-sized batteries to a larger grid-scale
demonstration size. More importantly, this
flat cell design allows the cell capacity to
be increased by simply using a thicker
cathode, which the researchers leveraged
in this work to demonstrate a triple capac-
ity cell with sustained discharge of 28.2-
hours under laboratory conditions.
Research teams at Pacific Northwest National Laboratory study how to integrate a utility-scale solar Most current battery technologies, in-
energy and battery storage facility into the grid at a facility near its Richland, WA, headquarters.
Here they monitor and analyze data to evaluate the financial benefits of storing renewable energy cluding Li-ion batteries, are well suited for
and incorporating intermittent renewables onto the grid. (Image: Andrea Starr, PNNL) short-term energy storage. To meet the
demand for 10-plus hours of energy stor-
neutral molten salt can undergo a further energy density, which is expressed as “watt age will require the development of new,
reaction into an acidic molten salt. Crucially, hour per kilogram” (Wh/kg). Although the low-cost, safe, and long duration battery
this second acidic reaction mechanism in- battery is in early-stage or “coin cell” test- concepts beyond current state-of-the-art
creases the battery’s capacity. Specifically, ing, the researchers speculate that it could battery technologies. This research pro-
after 345 charge/discharge cycles at high result in a practical energy density of up to vides a promising lab-scale demonstra-
current, this acidic reaction mechanism re- 100 Wh/kg. In comparison, the energy den- tion toward that goal.
tained 82.8 percent of peak charge capacity. sity for lithium-ion batteries used in com- For more information, contact Karyn
The energy that a battery can deliver in mercial electronics and electric vehicles is Hede at [email protected]; 509-
the discharge process is called its specific around 170–250 Wh/kg. However, the new 375-2144.
Battery & Electrification Technology, March 2023 31
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