PBR60 do not

Exist
to
due to stearic

it
wfra.me
bona .
repulsion
becomes unstabl
=

Pll 5cg , → Covalent compound

↳ sp3d hybridised

Pll 5 → Ionic compound .

-0
21345 →
[ pay ]④ CPUs )
⑤ to d
's
sp
sp3d2
lp=0
lp=0
Tetrahedral
octahedral
-

d) What is Hybridisation / shape of cation

part of 1301563
④
And : cation part of pulses, → poly
Sp's
Tetrahedral .
 PBVS -

→ Covalent
ay,

PBVS → Ionic compound

2131385 → (PBR CPBRGO]

PBRS → CPBry7④

ieaan.sn#e,.= .
Bro)
(÷
?
÷÷÷÷ .

Exist

=
 I

BOND PARAMETER

① Bond
length ③ Bond Energy .

② Bond Angle
 BOND LENGTH
a)

L
# Bund length size
of atom

CI
H F H U L
)i -
c -
C H -
Br H -
I

( Bond length)

Ii)
c- c 7 N -
N 7 O -
O ( Bond length,

lots
IF Bond length A
hybrid of orbital

Bond length . a 1-
Bond order .

's
Sp c gp2 C
Sp ( length)

's 's 's

gp2 sp
' '
Sp -

sp > Sp -

sp > gp2 sp
-
> -
> sp sp
-
.

( Bond length ,
Bond order -4 Bond order =L

Bjd
order =3
In
p
c' =D
Ic-=cSp3
Sp Spl
> -

E
's
7 -

Spl
-
- c

Sp Sp
# Resonance :

Due to Resonance
,

Bond order
multiple bond tses
of
.

4 Bond order single bond Tses

of
-

1-
Bmd length L
Bond order

lot
↳ Rest,TE
maaYfmaH
a
R A
B. 0=2 Chien -
un -_ Uz
Bord
µ↳Bo
!
V

§
B- o ( a > c > b) ①
az -
ay

Bond length ( b > c > a , ( Bo > D

f
#
St s
-

'

C C CH cuz
,
f
, Hybrid)
B- O ( L2)
 c. A → central atom , s A-
- =
surrounding Atom .

x
b)
AHA
BOND ANGLE

Oe
Bund
① c. A =
different ,
S A -
= Same
Angle .

Hybridisation -_
different
lone O
no
of part one # =
.
-

Bond Angle A ops of hybrid orbital .

IG : Beck Bolz Kelly

's
sp 8p2 Sp
4. S = 50 33 33
-
25
u a

Aizu l '

U -

B
two
E
1%109028
alla
' '
( soo of a U

lplrse )=0 lpB7=0 Ipcc ) - o

-
② Bond Angle A multiple bind .

⑧ Bmd Angle 2
of s
of Hybrid orbital ,

ez
iii.E.
"
n' 1093ft 1200
.
1800

③ C A
-
=
different ; s A
-
= Same

Hybridization = Same

no
of lone pair CC A)
different
- .
-

I
Bond Angle L -

lone pair central alms

no
of on
- .

H
i O.

N O
C
H #H HT 14 H
'

H
'
H 104.35
paint , wyo 's
's /
Sp3 Sp
Sp

1. p=o 1. f- l l -

p
= 2

Chu > NB 3 tho ( Bond Angle ,

 ④
Same
c. A =
; s A
-
=
different
Hybridization = Same

no
of lone pair CC A) Same
-
- .

I
-
x
Bond Angle E' N of Surrounding atom
⑧
Bund Angle a size atom
of surrounding

eg -

Ofz O Uz O Boz

TTY gp3 gp3 sp3

ee.e.int
nor"
d

"
←
e:

I
÷
:

of:p
a
least
less stearic more stearic
stearic repulsion
repulsion
repulsion '
B- A > yogurt ' B- A > 1109%1
B- A C 10938
B
O
B. A 1120
B A= -
1030 -
A = Ill =

X exception
to
are
Bond Angle
vsEP#
 d) Give Relative Bund Angle order

① 1120 , MHz ,
Ofz ,
Ccly

② MHz PHz Asl} Stoltz

③ Cny Silly Genu Suny

④ BF
, Baz BB.rs BIS

⑤ H2O Hzs Hate Hate

*
*
* o
⑥ 920 402 Close

⑦ NH3 ,
N°112 , NHy⑦
 When hybridisation a No -

of lone pair same

a
↓ ↓

Different s.tt Different c-A

same C- A same S.A

eg ABZ, Acz ABZ , C Bz

# Bond angle has * size

of c. A ↑ses

Least value 1 When Bond Angle trses

F' present
'

is
because ,
distance

'
between 5. A ↑ses
'

# Except F

↑ses repulsion ↓ses .

as , size of 5. A
,

B. A ↑ses ,

because repulsion
between 5. A ↑ set
FFF compare , 01 ,
02 1 03

↑ 02
01
(c)
✓☒ F
F

↳
•Éu
H¥03 U

•¥%¥ %¥¥o?
-

"'

⇐ Ñ¥ f- 1500
"
⑤ PH } PF} Puss PBR}

⑥ this SFZ 542

⑦
←E¥% -É¥%¥É%
.
 AI

D H

n÷¥¥¥¥÷÷FE%s*
mise OT

B-At

✓
01 > 02703

2)

:¥"i¥u a more stearic repulsion due

to Bigger size ce
of
.

03 7 02 > Oy
 Suzfz Souclz
9
6
01
# Hse
%%→a
ˢ¥¥¥
F-
⇐ ¥9
sp3
BA < 10902ft 04C 1090281

But , 03cL 1090281 027109° Vol

01 7) 1090281

01 > Oz ) 04 703
=
 8-
④ IT 1:

off:◦s-
s
°
"◦→ 8-

1090281

ˢ¥ →

1099028
'
BAC

A a
⑤ H p h P
- -

l%BA=9o° ftp.F u
"
Drago @ Tess stearic
rep
.

p.BR/lBTBrPBr37PU37PF37PHz more
Shan
't

repulsion
É9°
?⃝?⃝
 ⑥ A A A
# →
test
\⑥
#*

BA ≈ 90°
④ F ④
muse
Size
Drago En

592 > sFz > this -

→
ñ 1¥ "w '
?
"
-
_

Hoek O
,
Bu = It
t 8- .

CPO) =
1.25

of 19
% Ii
p µ
/P
'
-00
foˢ
/
✗
¥00
-

n µ

8 Bit
1-11-2
Bu =
It
b- more Bond order = i. 5

133
=
?⃝
more Bund order,

multiple bond character ↑ set ,

I. Repulsion ↑sb

03 3 02 > Oy
 01702

n n if
Suhihm o, a

① Clly 7 NIB 7 H2O ) Ofz

1090281 104935 1030
'

lot

② NIB > ( Drago theory

plz >
Ashy 353113 ,
Bmd Angle L E N of central alms
-
.

H
③ city =
Silly =
Greeny =
Sntly I 109%1
Chiron Drago theory)
Iced
← TH
→

H
4
④ Bfs =
Buz =
1313oz =
BIZ gligioiur
I
HI 'M
F u Br n

;¥w g¥w # #
'w
lui
, ,
F Br Br I I
F U u

⑤ H2O > Has > these > tzte (

Drago theory,
Z

O
⑥ f a close
aka 1*0 I
%=u Csps)
Iii 1170
lp= 2

CLOP L 092C ( 102 .

( Bond Anstey B- AL 10902T
'
 ⑦ O

⑦ N'3
Ntiy Nth
SN = 4 ( Sp's )
Sp's logo pg ,

lp= 2
lp=l sp3
lp=0 B- A cc 1oq°zf
( similar turbo)

Why
④
7 NB > N%h ( Bund Angle)
 BOND
( KJ / moi )
C) ENERGY
.

IBE)

↳ amount of Energy required

to break one more

bind

0¥ B E
-
✗ Bund order

C- c < c=c < CIC ( B- E)

C- N L C=N C CEN ( B- E)

# BE a 1-
( Sigma) Bund length
i Bt si )
) ( c c c si
-
-

c -
c > Si -
Si ( B- E)

H -
F > H -
a > H -

Br > H -
I
CB E)
f
f.
-

week
au 'd
easily given
by braving bond
so Any
strong
 bind gets
Sim
so

repulsion
is Active ,

Easily broken
Inter electronic
.

inter electronic is inactive

A repulsion

.ci it
:
L :
CBE) Efc are
:
:
-

[ Bind
.

length
is Active
A Repulsion

E -
a -

I .
-

CBE )

is Active
a Repulsion

ii - ii c its CBE)

l
B E
- L -

lone pair Repulsion of

single covalent bond
.

Q) Give Correct Bund Energy order .

Fz ,
Az, Brz Iz
 d) Gave correct Bond energy order .

( Sigma )

1) Fz ,
U2, Bre Iz
,

B 155 240 190 149

( 151m01 )
O_O S S se se Te -
Te
2) ,
-

,
-
,

B- E 142
=
226 1722 126

3) N -
N
, P
-
P ,
As -
As ,
Sb -
Sb

BE 167 146 121

201

4) C -
C Si - Si ,
G- e- G- e , Sn -
Sn .

346 222 188 146

And : 1) Iz ÑFz C Expected B- E)

Iz C Fz < Boz C Uz Cobserred B- E)

↳ Roster electronic
repulsion attire
-

2) Te -

Te < se -

☒ c s s ⇐
-
o_0

✓ ( expelled B-E)

Te -
Te c o_O < se -
secs - S

C observed B- E)
M
3) Sb Sb -
< As☒AsC PENN (
Expected

sb-sbcmnscnrwcp-p.IE Sn - Sn

CNO
C Ge -

inter electronic
Ge Csi -
Sic C-C

repulsion
( B-E)

=
 bond
* Tf n = Same .
-
Energy
⑨
* 25-25 C 2s Zpz < Zpz ( strength
Zpz of
-
-

covalent bind ?
S -

orbital non diffused B- Ed B.

strength .

So its e- cannot easily

shared as it
stringy
'

attracted by nucleus wit P' orbital nucleus .

.

# dit -

dit > dit -

PIT 7 PIT -

PIT
#
Ff n =
different

Bmd
1-
length ✗

Ginter nuclear - Bund strength ⑧

distance Bund
Energy
N Enter Electronic
repulsion must be
absent
Bmdcnersy ✗ Bmd strength .

Is Is > IS up IS 3 ( Bmd
> p strength )
- - -

( Bmd Entry
)

H H -
H -
F H -
U

Htt 711*71111 (Bond

.

hmm
#
BMd9nhf
11117 H - U

II
Hit > H -

a > clue
IS -
IS 15-310 3p bp
-

( B-
F)