THE INTERNATIONAL UNIVERSITY (IU) – VIETNAM NATIONAL UNIVERSITY – HCMC

CHEMISTRY FOR ENGINEERS

Solid --> Melting, Sublimation
ASSIGNMENT 3 Gas --> Condensation, Deposition
Liquid --> Freezing, Vaporization

18/1/2023
Date : 04/05/19
Duration : 729/1/2023
days

MULTIPLE CHOICE QUESTIONS (10pts)

1. Some solids can be converted directly to 5. Calculate the closet mole fraction of ethyl alcohol,
the vapor phase by heating. The process is C2H5OH, in a solution that contains 230 grams of C2H5OH
called: and 312 grams of benzene, C6H6.
a) fusion tan chảy melting SOLID --> LIQUID
b) sublimation thăng hoa SOLID --> GAS a) 2.3
c) vaporization bay hơi LIQUID --> GAS b) 0.57
d) condensation ngưng tụ GAS --> LIQUID c) 0.44
d) 1.8
2. In a body-centered cubic lattice, how
many atoms are present per in a unit cell? 6. The spectator ion(s) in the following reaction is/are:
a) one Na2CO3(aq) + Ba(NO3)2(aq) BaCO3(s) + 2NaNO3(aq)
b) two +
a) Na and Ba 2+
c) three b) Ba2+ and CO32-
d) four c) CO32- and NO3-
d) Na+ and NO3-
3. Which of the following descriptions of
solid type is INCORRECT? 7. Determine the oxidation number of carbon
a) Cu ; metallic metal in K2CO3.
b) CaCl2 ; ionic + - a) 0
c) H2O ; molecular - - b) +2
d) All of them are correct. c) +4
d) -2
4. What the closet mass of water must be used
to dissolve 20.0 grams of ethanol, C2H5OH, 8. Consider three 1 – L flasks containing gases
to prepare a 0.0500 molality solution of at STP. Flask A contains H2 gas, flask B
ethanol? contains O2 gas and flask C contains H2S gas
a) 20.1 kg n=m/M and. Which contains the largest number
b) 11.0 kg m = n*m molecules?
M=m/n
c) 8.80 kg
d) 9.10 kg molality = mol / kg a) Flask A b) Flask B
c) Flask C d) All of them.
 Molar mass: M

dm3 = litre
D=m/v

9. The concentration of [Ag+] ion when putting 10. Metal oxides are _____________ and
1.00 mole of AgCl into 1.00 L distilled water? react with water to generate ___________.
a) basic, H+ b) acidic, H+
a) 1.00 M b) 10.0 M c) basic, OH -
d) acidic, OH
c) 0.1 M d) Can not calculated!!!

CONSTRUCTED QUESTIONS (90pts)

1. (8pts) Calcium carbide, CaC2, is an important preliminary chemical for industries producing
synthetic fabrics and plastics. CaC2 may be produced by heating calcium oxide with coke:
CaO + 3C CaC2 + CO
0.85 0.85/3 --> m Cac2 = (0.85/3) * 64 = 18.13g
What is the amount of CaC2 which can be produced from the reaction of excess calcium oxide
and 10.2 g of carbon? (Assume 100% efficiency of reaction for purposes of this problem.)

??? 2. (25pts) Complete chemical reactions below, write net ionic equation (if possible) and figure
out what types of those reaction.
a) 2 CxHyOzNt + O2 → 2xCO +yH O + tN (ΔH <0)
2 2 2
b) Cu + Cl2 → …… The solubility
c) H3PO4 + Ba(OH)2 → of a
compound in
d) FeCl2 + H2SO4 + HNO3 → Fe2(SO4)3 + FeCl3 + NO + H2O water
e) SO3 + H2O → H2SO4 depends on
the
secondary
3. Arrange the following substances in order of increasing solubility in water and show your interaction
between the
??? reasons: (10pts) solute and
3) Order of increasing solubility in water:
C5H1202 > C5H12O > C5H11CL = C5H12 solvent. In the
C5H12O2 is axit cacboxylic so it’s highly soluble in water, C5H12O is partially soluble case of water
because it contains -OH group and can form hydrogen bond with water but the C5H12 acting as the
is nonpolar. And the rest C5H11Cl and C5H12 are insoluble due to their hydrocarbon solvent,
part. solubility is
highest in
compounds
which have
hydrogen
bonding, than
in those
which have
dipole-dipole
4. There is a relationship between intermolecular forces, temperature, and the temperatures interactions,
and lowest in
at which the solid, liquid, and gas phases exist. Each blank will be filled in with ONE of the those which
words in bold. You may use each word more than once. (12pts) have only
dispersion
forces1.
solid
A. At low temperatures, materials are in the ___________(1)___________ phase. In this
(2)Intermolecular force
phase, ___________(2)___________ are strong enough to keep the particles in the material

(atoms, ions, or molecules) close enough such that the particles have 3- dimensional order.

There are five basic types of chemical reactions:

- combination, decomposition, single-replacement, double-replacement, and combustion
However, there are many other types of chemical reactions that can occur, such as
- redox reactions, acid-base reactions, and precipitation reactions.
|
neutralization react
 liquid
B. Evaporation is a phase transition from the _______(3)_______ phase to the
gas The temperature
________(4)________ phase that occurs at _______(5)_________ below the boiling point at

a given pressure. For molecules of a liquid to evaporate, they must be located near the surface,

be moving in the proper direction, and have sufficient kinetic energy to overcome liquid-phase
intermolecular forces
___________(6)___________.

5. What total gas volume (in liters) at 520oC and 880 torr would result from the decomposition
of 33.0 g of potassium bicarbonate according to the equation: (10pts)

2KHCO3(s) K2CO3(s) + CO2(g) + H2O(g)

Given that: R = 0.0821 L.atm.mol-1.K-1 and 760 torr = 1 atm.

6. Calculate the concentration of CO2 in a soft drink after the bottle is opened and equilibrates at
25oC under a CO2 partial pressure of 3.0 x 10-4 atm. The Henry’s law constant for CO2 in water
at this temperature is 3.4x10-2 mol/L.atm. (5pts)

7. Show the Ideal – Gas Equation and relationship between temperature, pressure and volume in
laws that you have learnt. (10pts)

8. Nguyen Hoang Long, a first year student, wants to learn about gases, therefore students, based
on what you have learnt, please briefly describe the physical and chemical properties of
gases.(10pts)
Good luck!!!
8.
7.
Physical properties of gases include:
PV = nRT
They are highly compressible, meaning that their volume can be easily
Where,
changed by applying pressure.
They are highly expandable, meaning that they will fill any container they
P is the pressure of the ideal gas.
are placed in.
V is the volume of the ideal gas.
They have low density compared to solids and liquids.
n is the amount of ideal gas measured in terms of moles.
They are poor conductors of heat and electricity.
R is the universal gas constant.
They have low viscosity and surface tension.
T is the temperature.
They are relatively easy to pump and compress.
Boyle's law Charles' law Avogadro's law
Chemical properties of gases include:

They are highly reactive and can participate in a wide variety of chemical
reactions.
They are typically colorless, odorless, and tasteless.
They often have low boiling and melting points.
They can be flammable or explosive under certain conditions.
They can be toxic or harmful if inhaled in large quantities.
They can be oxidizing or reducing agents.
They can be chemically inert or active.