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Assignment 6

This document describes three different titration experiments: 1) A Fajan's method argentometric titration to determine 18.5% NaCl in a 0.800g sample. 2) A EDTA titration using Eriochrome Black T indicator to determine 100.71 ppm hardness as CaCO3 in 100mL drinking water. 3) An iodimetric titration with starch indicator to determine 5.16% w/v NaOCl in a 20mL bleach sample.

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Annagail Dominguez
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85 views3 pages

Assignment 6

This document describes three different titration experiments: 1) A Fajan's method argentometric titration to determine 18.5% NaCl in a 0.800g sample. 2) A EDTA titration using Eriochrome Black T indicator to determine 100.71 ppm hardness as CaCO3 in 100mL drinking water. 3) An iodimetric titration with starch indicator to determine 5.16% w/v NaOCl in a 20mL bleach sample.

Uploaded by

Annagail Dominguez
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd
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1. Five drops of dichlorofluorescein have been added to a solution containing 0.

800 g
sample which required 25.30 mL of 0.100 M AgNO3.

a. Identify the type of argentometric titration method used.


 The argentometric titration method used is the Fajan's method.
b. Identify the indicator and endpoint color.
 The indicator is the dichlorofluorescein and the endpoint color is yellow.
c. Calculate the weight percent NaCl in the original sample.

Given:

(a) 0.800 g sample (c) Na = 22.989


Cl = 35.453
FW = 58.442 g/mol of NaCl

(b) 25.30 mL of 0.100 M AgNO3


1L
25.30 mL × =0.0253 L
1000 mL

RTF: % weight of NaCl

% weight of NaCl=0.0253 L ( 0.100 molL AgNO 3 )( 11molmolAgNO


NaCl
3 1mol NaCl 0.800 g )
)( 58.442 g
)( 100

% weight of NaCl=¿18. 5 %

2. A 100.0 mL sample of drinking water was treated with ammonia buffer and after addition
of Eriochrome Black T indicator, required 18.0mL of 0.00559M EDTA for titration.
a. Identify the role of ammonia buffer in the analysis.
 The ammonia buffer's role in the analysis is to avoid unnecessary precipitation
during the process of titration.
b. Identify the indicator and endpoint color.
 The indicator is the Eriochrome Black T, and the endpoint color is from red to
blue, which is pink.
c. Calculate the total hardness of the water sample as ppm CaCO3.
Given:

(a) 100.0 mL sample of drinking (b) 18.0mL of 0.00559M EDTA


water; 0.1 L (c) FW = 100.9 g/mol of CaCO3

RTF: Total hardness of the water sample as ppm CaCO3

ppm CaCO 3=18.0 mL ( 0.00559mLmmol )( 1mmol


1 mmol EDTA 1 mmol of CaCO 3 0.1 L )
)(
CaCO 3 100.09 g CaCO 3
)( 1

ppm CaCO 3=¿100.71 ppm CaCO3 is the calculated total hardness

3. A 20.0mL sample of commercial bleach was diluted with water to a 250.0mL volumetric
flask. A 50.0 mL aliquot of the diluted sample was treated with excess KI and starch. The
liberated iodine was titrated with 0.399M Na2S2O3, requiring 13.9 mL to reach the end
point.

a. Identify the type of redox titration method used.


 The type of redox titration method that has been used is a Iodimetry.
b. Identify the indicator and endpoint color.
 The indicator is the starch, and the endpoint color is light blue.
c. Calculate the % w/v NaOCl in the sample.
Given:

(a) 20.0mL sample (c) 13.9mL of 0.399M Na2S2O3


50.0 mL aliquot 0.0139 L
250.0mL volumetric flask (d) FW = 74.44 g/mol NaOCl

(b) 20.0 mL ( 250.0 mL )


50.0 mL
= 4 mL

sample

RTF: The % w/v NaOCl in the sample

w
% NaOCl=0.0139 L¿
v
w
% NaOCl=5.16 %
v

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