SDB 5078 GB en

Safety data sheet Safety data sheet
acc. to Regulation (EC) No. 1907/2006 (REACH)
Strontium nitrate ROTI®METIC 99,999 % (5N)
article number: 5078 date of compilation: 2016-10-04

Version: 3.0 en Revision: 2022-06-01
Replaces version of: 2018-07-19
Version: (2)
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Strontium nitrate ROTI®METIC 99,999 % (5N)
Article number 5078
EC number 233-131-9
CAS number 10042-76-9
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for products which come into contact
with foodstuffs. Do not use for private purposes
(household).
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany
Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: [email protected]
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): [email protected]
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city
National Poisons Information Dudley Rd B187QH 844 892 0111

Service Birmingham
City Hospital
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification acc. to GHS
Section Hazard class Cat- Hazard class and Hazard
egory category statement
2.14 Oxidising solid 1 Ox. Sol. 1 H271
3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318
For full text of abbreviations: see SECTION 16
United Kingdom (en) Page 1 / 16

article number: 5078

2.2 Label elements
Labelling
Signal word Danger
Pictograms
GHS03, GHS05
Hazard statements
H271 May cause fire or explosion; strong oxidiser
H318 Causes serious eye damage
Precautionary statements
Precautionary statements - prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking
P280 Wear protective gloves/eye protection
Precautionary statements - response
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 Immediately call a POISON CENTER/doctor
2.3 Other hazards
Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB.
SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance Strontium nitrate
Molecular formula Sr(NO₃)₂
Molar mass 211,6 g/mol
CAS No 10042-76-9
EC No 233-131-9
SECTION 4: First aid measures

4.1 Description of first aid measures
General notes

Take off contaminated clothing.

Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist.
Following ingestion
Rinse mouth. Call a doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Risk of blindness, Risk of serious damage to eyes
4.3 Indication of any immediate medical attention and special treatment needed
none
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media

co-ordinate firefighting measures to the fire surroundings
water, foam, alcohol resistant foam, dry extinguishing powder, ABC-powder
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Oxidising property. Non-combustible.
Hazardous combustion products
In case of fire may be liberated: Nitrogen oxides (NOx)
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas-
onable distance. Wear self-contained breathing apparatus.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel

Use personal protective equipment as required. Avoid contact with skin, eyes and clothes. Do not
breathe dust.


6.2 Environmental precautions
Keep away from drains, surface and ground water.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains. Take up mechanically.
Advice on how to clean up a spill
Take up mechanically. Control of dust.
Other information relating to spills and releases
Place in appropriate containers for disposal.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Avoid dust formation.
Measures to prevent fire as well as aerosol and dust generation
Removal of dust deposits. Keep away from combustible material.
Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilities
Store in a dry place.
Incompatible substances or mixtures
Observe hints for combined storage. Keep/store away from clothing/combustible materials. Take any
precaution to avoid mixing with combustibles.
Consideration of other advice:
Ventilation requirements
Use local and general ventilation.
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values


Occupational exposure limit values (Workplace Exposure Limits)
Coun Name of agent CAS No Identifi- TWA STEL Ceil- Nota- Source
try er [mg/ [mg/ ing-C tion
m³] m³] [mg/
m³]
GB dust WEL 10 i EH40/2005
GB dust WEL 4 r EH40/2005
Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
i Inhalable fraction
r Respirable fraction
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)
Human health values
Relevant DNELs and other threshold levels
Endpoint Threshold Protection goal, Used in Exposure time

level route of exposure
DNEL 7,9 mg/m³ human, inhalatory worker (industry) chronic - systemic effects
DNEL 40,1 mg/kg bw/ human, dermal worker (industry) chronic - systemic effects
day
Environmental values
Relevant PNECs and other threshold levels
End- Threshold Organism Environmental com- Exposure time

point level partment
PNEC 2,1 mg/l aquatic organisms freshwater short-term (single instance)
PNEC 4,2 mg/l aquatic organisms sewage treatment plant short-term (single instance)
(STP)
PNEC 1.811 mg/kg aquatic organisms freshwater sediment short-term (single instance)
PNEC 332 mg/kg terrestrial organisms soil short-term (single instance)
8.2 Exposure controls

Individual protection measures (personal protective equipment)
Eye/face protection
Use safety goggle with side protection.

Skin protection


• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. The times are approximate values from
measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances,
body heat etc. and a reduction of the effective layer thickness by stretching can lead to a consider-
able reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times
larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply
only to the pure substance. When transferred to substance mixtures, they may only be considered as
a guide.
• type of material
NBR (Nitrile rubber)
• material thickness
>0,3 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection
Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P1 (filters at
least 80 % of airborne particles, colour code: White).
Environmental exposure controls
Keep away from drains, surface and ground water.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state solid
Form powder, crystalline
Colour white
Odour odourless
Melting point/freezing point 570 °C
Boiling point or initial boiling point and boiling 645 °C at 1.013 hPa
range
Flammability non-combustible
Lower and upper explosion limit not determined
Flash point not applicable
Auto-ignition temperature not determined
Decomposition temperature not relevant

pH (value) 6,7 (in aqueous solution: 10 g/l, 20 °C) (ECHA)
Kinematic viscosity not relevant

Solubility(ies)
Water solubility ~660 g/l at 20 °C

Partition coefficient
Partition coefficient n-octanol/water (log value): not relevant (inorganic)

Vapour pressure not determined

Density and/or relative density
Density 2,986 g/cm³ at 20 °C
Relative vapour density information on this property is not available

Bulk density ~1.000 kg/m³

Particle characteristics No data available.

Other safety parameters
Oxidising properties
9.2 Other information
Information with regard to physical hazard There is no additional information.
classes:
Other safety characteristics: There is no additional information.
SECTION 10: Stability and reactivity

10.1 Reactivity
It's a reactive substance. Oxidising property.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions
Violent reaction with: Magnesium-Powder, Metal powder, PVC: polyvinyl chloride, Sulphur,
Danger of explosion: Combustible materials, Reducing agents, Acetic anhydride, Heat, Hydrides
10.4 Conditions to avoid
There are no specific conditions known which have to be avoided.
10.5 Incompatible materials
combustible materials, PVC: polyvinyl chloride
10.6 Hazardous decomposition products

Hazardous combustion products: see section 5.
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Classification acc. to GHS
Acute toxicity
Shall not be classified as acutely toxic.
Acute toxicity
Exposure route Endpoint Value Species Method Source
oral LD50 >2.000 mg/kg rat ECHA
inhalation: dust/ LC50 >4,5 mg/l/4h rat ECHA

mist
Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
Data are not available.
• If in eyes
Causes serious eye damage, risk of blindness
• If inhaled
Inhalation of dust may cause irritation of the respiratory system


• If on skin
Irritating to skin
• Other information
none
11.2 Endocrine disrupting properties
Not listed.
11.3 Information on other hazards
There is no additional information.
SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
.
Aquatic toxicity (acute)
Endpoint Value Species Source Exposure

time
LC50 >92,8 mg/l fish ECHA 96 h
ErC50 >43,3 mg/l algae ECHA 72 h
EC50 >43,3 mg/l algae ECHA 72 h
Aquatic toxicity (chronic)
Endpoint Value Species Source Exposure

time
EC50 >100 mg/l microorganisms ECHA 3h
Biodegradation
The methods for determining the biological degradability are not applicable to inorganic substances.
12.2 Process of degradability
12.3 Bioaccumulative potential
12.4 Mobility in soil
12.5 Results of PBT and vPvB assessment
12.6 Endocrine disrupting properties
Not listed.
12.7 Other adverse effects

SECTION 13: Disposal considerations

13.1 Waste treatment methods
This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process. Waste catalogue ordinance (Germany).
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.
SECTION 14: Transport information

14.1 UN number or ID number
ADRRID UN 1507
IMDG-Code UN 1507
ICAO-TI UN 1507
14.2 UN proper shipping name
ADRRID STRONTIUM NITRATE
IMDG-Code STRONTIUM NITRATE
ICAO-TI Strontium nitrate
14.3 Transport hazard class(es)
ADRRID 5.1
IMDG-Code 5.1
ICAO-TI 5.1
14.4 Packing group
ADRRID III
IMDG-Code III
ICAO-TI III
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.


14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Proper shipping name STRONTIUM NITRATE
Particulars in the transport document UN1507, STRONTIUM NITRATE, 5.1, III, (E)
Classification code O2
Danger label(s) 5.1
Excepted quantities (EQ) E1

Limited quantities (LQ) 5 kg
Transport category (TC) 3
Tunnel restriction code (TRC) E
Hazard identification No 50
Emergency Action Code 1Z
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID)Additional
information
Classification code O2
Danger label(s) 5.1

Transport category (TC) 3
Hazard identification No 50
International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name STRONTIUM NITRATE
Particulars in the shipper's declaration UN1507, STRONTIUM NITRATE, 5.1, III
Marine pollutant -
Danger label(s) 5.1
Special provisions (SP) -



EmS F-A, S-Q
Stowage category A
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Strontium nitrate
Particulars in the shipper's declaration UN1507, Strontium nitrate, 5.1, III
Danger label(s) 5.1

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Seveso Directive
2012/18/EU (Seveso III)
No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements
P8 oxidising liquids and solids 50 200 55)
Notation
55) Oxidising liquids, category 1, 2 or 3, or oxidising solids, category 1, 2 or 3
Deco-Paint Directive
VOC content 0%
0 g/l
Industrial Emissions Directive (IED)
VOC content 0%
VOC content 0 g/l
Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
not listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
not listed


Water Framework Directive (WFD)
List of pollutants (WFD)
Name of substance Name acc. to inventory CAS No Listed in Remarks
Strontium nitrate Substances which contribute to a)

eutrophication (in particular, ni-
trates and phosphates)
Strontium nitrate Metals and their compounds a)
Legend
A) Indicative list of the main pollutants
Regulation on the marketing and use of explosives precursors

not listed
Regulation on drug precursors
not listed
Regulation on substances that deplete the ozone layer (ODS)
not listed
Regulation concerning the export and import of hazardous chemicals (PIC)
not listed
Regulation on persistent organic pollutants (POP)
not listed
National regulations(GB)
List of substances subject to authorisation (GB REACH, Annex 14) / SVHC - candidate list
not listed
Restrictions according to GB REACH, Annex 17
not listed
Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status
AU AIIC substance is listed
CA DSL substance is listed
CN IECSC substance is listed
EU ECSI substance is listed
EU REACH Reg. substance is listed
JP CSCL-ENCS substance is listed
KR KECI substance is listed
MX INSQ substance is listed
NZ NZIoC substance is listed
PH PICCS substance is listed

Country Inventory Status
TW TCSI substance is listed
US TSCA substance is listed
Legend
AIIC Australian Inventory of Industrial Chemicals
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act
15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.
SECTION 16: Other information

Indication of changes (revised safety data sheet)
Alignment to regulation:
Restructuring: section 9, section 14
Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant
2.1 Classification acc. to GHS: yes

change in the listing (table)
2.2 Pictograms: yes

2.2 Labelling of packages where the contents do yes

not exceed 125 ml:
Signal word: Danger

not exceed 125 ml:

not exceed 125 ml:

not exceed 125 ml:
2.3 Other hazards: Other hazards yes

There is no additional information.
2.3 Results of PBT and vPvB assessment: yes

According to the results of its assessment, this
substance is not a PBT or a vPvB.


Abbreviations and acronyms
Abbr. Descriptions of used abbreviations
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)
ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-
ing the International Carriage of Dangerous Goods by Road)
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
Ceiling-C Ceiling value
DGR Dangerous Goods Regulations (see IATA/DGR)
DNEL Derived No-Effect Level
EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing
50 % changes in response (e.g. on growth) during a specified time interval
EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)
EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EmS Emergency Schedule
ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control
GB REACH The REACH etc. (Amendment etc.) (EU Exit) Regulations 2019, SI 2019/758 (as amended)
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
ICAO-TI Technical instructions for the safe transport of dangerous goods by air
IMDG International Maritime Dangerous Goods Code
IMDG-Code International Maritime Dangerous Goods Code
LC50 Lethal Concentration 50%: the LC50 corresponds to the concentration of a tested substance causing 50 %
lethality during a specified time interval
LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval
NLP No-Longer Polymer
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)
STEL Short-term exposure limit

Abbr. Descriptions of used abbreviations
TWA Time-weighted average
VOC Volatile Organic Compounds
vPvB Very Persistent and very Bioaccumulative
WEL Workplace exposure limit
Key literature references and sources for data

Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations
concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan-
gerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).
List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text
H271 May cause fire or explosion; strong oxidiser.
H318 Causes serious eye damage.
Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

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Safety data sheet Safety data sheet

acc. to Regulation (EC) No. 1907/2006 (REACH)

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078 date of compilation: 2016-10-04

SECTION 1: Identification of the substance/mixture and of the company/

Telephone:+49 (0) 721 - 56 06 0

National Poisons Information Dudley Rd B187QH 844 892 0111

SECTION 2: Hazards identification

2.14 Oxidising solid 1 Ox. Sol. 1 H271

3.3 Serious eye damage/eye irritation 1 Eye Dam. 1 H318

For full text of abbreviations: see SECTION 16

United Kingdom (en) Page 1 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

Signal word Danger

SECTION 3: Composition/information on ingredients

SECTION 4: First aid measures

United Kingdom (en) Page 2 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

Take off contaminated clothing.

SECTION 5: Firefighting measures

Suitable extinguishing media

SECTION 6: Accidental release measures

For non-emergency personnel

United Kingdom (en) Page 3 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

United Kingdom (en) Page 4 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

GB dust WEL 10 i EH40/2005

GB dust WEL 4 r EH40/2005

Human health values

Relevant DNELs and other threshold levels

Endpoint Threshold Protection goal, Used in Exposure time

Relevant PNECs and other threshold levels

End- Threshold Organism Environmental com- Exposure time

PNEC 2,1 mg/l aquatic organisms freshwater short-term (single instance)

PNEC 332 mg/kg terrestrial organisms soil short-term (single instance)

8.2 Exposure controls

Use safety goggle with side protection.

United Kingdom (en) Page 5 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

SECTION 9: Physical and chemical properties

United Kingdom (en) Page 6 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

pH (value) 6,7 (in aqueous solution: 10 g/l, 20 °C) (ECHA)

Kinematic viscosity not relevant

Relative vapour density information on this property is not available

SECTION 10: Stability and reactivity

United Kingdom (en) Page 7 / 16

Strontium nitrate ROTI®METIC 99,999 % (5N)

article number: 5078

Hazardous combustion products: see section 5.