Grade 10 Chemistry Week 8 Lesson 1
Grade 10 Chemistry Week 8 Lesson 1
Grade 10 Chemistry Week 8 Lesson 1
GRADE 10
CHEMISTRY
WEEK 8 Lesson 1
describe ionic crystals, simple molecular crystals and giant molecular crystals.
Content:
Ionic Crystals
An ionic crystal consists of ions bound together by electrostatic attraction. The arrangement of
ions in a regular, geometric structure is called a crystal lattice and varies depending on the ions’
sizes or the radius ratio (ratio of radii of the positive to the negative ion). Example: NaCl
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Properties of Ionic Crystals
Property Explanation
form crystals An ionic crystal is a regular structure, with the cation and anion
alternating with each other and forming a three-dimensional structure
based largely on the smaller ion evenly filling in the gaps between the
larger ion. Eg. NaCl
High melting and High temperatures are required to overcome the attraction between the
boiling points. positive and negative ions. Therefore, a lot of energy is required to melt
ionic compounds or cause them to boil.
Conducts When ionic compounds are dissolved in water the dissociated ions are
electricity when free to conduct electric charge through the solution. Molten ionic
dissolved in water compounds also conduct electricity.
Solubility Ionic compounds are usually soluble in polar solvents such as water, in
which ions are free to move and interact with the solvent molecules.
They are usually insoluble in non-polar solvents which do not allow
free, movement of ions and interactions with solvent molecules.
Molecular Crystals
Liquids and solids composed of molecules are held together by van der Waals (or
intermolecular) forces, and many of their properties reflect this weak binding.
Intermolecular Forces
All covalent molecules, whether polar or non-polar, develop temporary or instantaneous dipoles.
This results from the uneven distribution of electronic charge lead to positive and negative
charges within molecules. Van der Waals forces are weak attractions between oppositely charged
ends of molecules with temporary dipoles. Example: Helium molecule
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Diagram Showing Induced Dipole
When a helium molecule with an instantaneous dipole is brought close to another helium
molecule that is not polarized, it is attracted to the instantaneous dipole. This causes the
uncharged non-polar helium molecule to develop induced dipoles by attracting or repelling its
electrons. Hence a resultant attractive force (Van der Waals Force – London dispersion).
Dispersion forces exist between all molecules, but they are the only forces that exist between
nonpolar molecules. Polar molecules and ions can also induce dipoles in nonpolar molecules.
This effect partially accounts for the solubility of molecular oxygen (nonpolar) in water and the
ability of blood (which contains Fe cations) to bind oxygen.
Hydrogen Bonds
The hydrogen bond is a weak attraction between the slightly positive hydrogen atom in
one molecule and the slightly electronegative atom in another polar molecule of the same
type or a different type. Because of water’s polarity, individual water molecules are
attracted to one another. Example: water and ammonia
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Hydrogen Bonding in Water Hydrogen Bonding in Ammonia
Properties of Simple Molecular Crystals
Property Explanation
Low melting point Because of the weak intermolecular attractive forces between
and boiling point molecules, little energy is required to separate the molecules.
Electrical There are no charged particles (ions or electrons) delocalized
conductivity throughout the molecular crystal lattice to conduct electricity. They
cannot conduct electricity in either the solid or molten state.
Solubility Molecular crystals tend to dissolve in non-polar solvents such as
alcohol.
They are usually insoluble in polar solvents such as water. However,
some may dissolve in water as a result of forming hydrogen bonds
with it.
Giant molecular solids are a class of extended-lattice compounds in which each atom is
covalently bonded to its nearest neighbors. This means that the entire crystal is, in effect, one
giant molecule. These compounds exist as macromolecules in which strong covalent bonds
extend in three dimensions. Examples of giant molecular solids are polymers, silicon dioxide,
diamond, and graphite.
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Properties of Giant Molecular Solids
Property Explanation
Very high melting Very high melting points and boiling points because their very strong
and boiling points covalent bonds are not easily broken.
Solubility Macromolecular crystals are very stable and are insoluble in a polar or
non-polar solvent.
Variable electrical Diamond does not conduct electricity, whereas graphite contains
conductivity free electrons so it does conduct electricity. Silicon is a semiconductor
– it is midway between non-conductive and conductive.
References:
1. https://courses.lumenlearning.com/boundless-chemistry/chapter/types-of-crystals/
2. https://courses.lumenlearning.com/introchem/chapter/allotropes-of-carbon/
3. http://www.scienceskool.co.uk/intermolecular-forces.html
4. https://www.easybiologyclass.com/how-hydrogen-bond-is-formed-in
5. water/https://chemistryskills.com/hydrogen-bonding/
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