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    1. The reaction between ethene (C2H4) and ozone (O3) has a rate order of 1 with respect to both O3 and C2H4. The rate law is rate = k[O3][C2H4] and the value of the rate constant k is calculated to be 2 × 103 dm3 mol-1 s-1. 2. The reaction that produces ozone involves oxygen molecules reacting to produce ozone and has nitric oxide (NO) as a catalyst. 3. The reaction between hydrogen gas (H2) and nitrogen dioxide (NO2) has a rate order of 1 with respect to H2 and 2 with respect to NO

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    1. The reaction between ethene (C2H4) and ozone (O3) has a rate order of 1 with respect to both O3 and C2H4. The rate law is rate = k[O3][C2H4] and the value of the rate constant k is calculated to be 2 × 103 dm3 mol-1 s-1. 2. The reaction that produces ozone involves oxygen molecules reacting to produce ozone and has nitric oxide (NO) as a catalyst. 3. The reaction between hydrogen gas (H2) and nitrogen dioxide (NO2) has a rate order of 1 with respect to H2 and 2 with respect to NO

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    1. The reaction between ethene (C2H4) and ozone (O3) has a rate order of 1 with respect to both O3 and C2H4. The rate law is rate = k[O3][C2H4] and the value of the rate constant k is calculated to be 2 × 103 dm3 mol-1 s-1. 2. The reaction that produces ozone involves oxygen molecules reacting to produce ozone and has nitric oxide (NO) as a catalyst. 3. The reaction between hydrogen gas (H2) and nitrogen dioxide (NO2) has a rate order of 1 with respect to H2 and 2 with respect to NO

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    33 views5 pages

    How Fast MS

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    saad
    1. The reaction between ethene (C2H4) and ozone (O3) has a rate order of 1 with respect to both O3 and C2H4. The rate law is rate = k[O3][C2H4] and the value of the rate constant k is calculated to be 2 × 103 dm3 mol-1 s-1. 2. The reaction that produces ozone involves oxygen molecules reacting to produce ozone and has nitric oxide (NO) as a catalyst. 3. The reaction between hydrogen gas (H2) and nitrogen dioxide (NO2) has a rate order of 1 with respect to H2 and 2 with respect to NO

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    of 5

    F325: Equilibria, Energetics and Elements

    5.1.1 How Fast? / 71


    1. (i) O3: Exp 2 has 4 times [H2] as Exp 1
    and rate increases by 4 (1),
    so order = 1 with respect to O3 (1)
    C2H4: Exp 3 has 2 × [C2H4] and 2 × [O3] as Exp 2;
    and rate has increased by 4 (1),
    so order = 1 with respect to C2H4 (1)
    rate = k [O3] [C2H4] (1) 5

    (ii) use of k = rate / [O3] [C2H4] = 1.0 × 10–12 / (0.5 × 10–7 × 1.0 × 10–8)
    to obtain a calculated value (1)
    k = 2 × 103 (1)
    units: dm3 mol–1 s–1 (1) 3

    (iii) rate = 1.0 × 10–12 /4 = 2.5 × 10–13 (mol dm–3 s–1) (1) 1

    (iv) rate increases and k increases (1) 1


    [10]

    2. 1½O2(g) → O3(g)/
    O2(g) + ½O2(g) → O3(g) (1)
    NO is a catalyst (1) as it is (used up in step 1 and) regenerated in step 2/
    not used up in the overall reaction(1)
    allow 1 mark for ‘O/NO2 with explanation of regeneration.’
    [3]

    3. (i) H2: Exp 2 has 2.5 times [H2] as Exp 1


    and rate increases by 2.5 (1),
    so order = 1 with respect to H2 (1) 2
    NO: Exp 3 has 3 x [NO] as Exp 2;
    and rate has increased by 9 = 32 (1),
    so order = 2 with respect to NO (1) 2
    QWC At least two complete sentences where the meaning is clear. 1

    (ii) rate = k[NO]2 [H2] (1) 1

    1
    rate 2 .6
    (iii) k= / (1)
    [NO] [H 2 ] 0.10 2 × 0.20
    2

    = 1300 (1) units: dm6 mol–2 s–1 (1)


    allow 1 mark for 7.69 × 10–4 or 1.3 × 10x (x not 3) 3
    [9]

    4. (i) 1½O2(g) → O3(g)/


    O2(g) + ½O2(g) → O3(g) (1)
    NO is a catalyst (1) as it is (used up in step 1 and)
    regenerated in step 2/
    not used up in the overall reaction(1)
    allow 1 mark for ‘O/NO2 with explanation of regeneration.’ 3

    (ii) Rate = k[NO] [O3] (1)


    Species in rate equation match those reactants in the slow
    step / rate determining step (1) 2
    [5]

    5. (a) (i) Curve downwards starting at t = 0 2


    with slope gradually levelling off with no increase
    (don’t worry about hitting the x axis)

    (ii) Tangent shown at start 1


    (iii) Half-life is constant 1
    OR: draw tangents and then plot a 2nd graph of tangent
    or rate against concentration, which is a straight line
    through the origin.

    2
    rate determining step involves species in rate equation (1)
    two steps that add up to give the overall equation (1)
    The left hand side of a step that contains the species in rate-determining step (1)
    i.e., for marking points 2 and 3:
    CH3COCH3 + H+ → [CH3COHCH3]+
    [CH3COHCH3+] + I2 → CH3COCH2I + HI + H+ 3
    organises relevant information clearly and coherently,
    using specialist vocabulary where appropriate
    Use of the following four words/phrases:
    constant, half-life, order, doubles/x2 (1) 1
    [14]

    7. (i) The slowest step (1) 1


    (ii) 2NO2 → NO + NO3 (1)
    NO3 + CO → NO2 + CO2 (1) 2
    (or similar stage involving intermediates)
    [3]

    8. HCl and CH3COOH have same number of moles/


    release same number of moles H+ /
    1 mole of each acid produce ½ mol of H2 (1)

    [H+] in CH3COOH < [H+] in HCl/


    CH3COOH is a weaker acid than HCl (ora) (1)
    Mg + 2HCl → MgCl2 + H2 (1)
    Mg + 2CH3COOH → (CH3COO)2Mg + H2 (1)
    or
    Mg + 2H+ → Mg2+ + H2 (1)(1) 4
    [4]

    9. (i) constant half-life (1) 1


    (ii) rate = k[N2O5] (1) 1
    Common error will be to use ‘2’ from equation.

    (iii) curve downwards getting less steep (1)


    curve goes through 1200,0.30; 2400,0.15; 3600,0.075 (1) 2
    (iv) tangent shown on graph at t = 1200 s (1) 1

    4
    (v) 3.7(2) × 10–4 (1) mol dm–3 s–1 (1)
    ecf possible from (ii) using [N2O5]x
    (2nd order answer: 2.2(3) × 10–4) 2
    [7]

    10. (i) slow step (1) 1


    (ii) (CH3)2C=CH2 + H2O → (CH3)3COH (1) 1

    (iii) H+ is a catalyst (1)


    H+ used in first step and formed in second step/
    regenerated/ not used up (1) 2
    (iv) rate = k [(CH3)2C=CH2] [H+] (1)
    common error will be use of H2O instead of H+ 1
    [5]

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