ATOMIC STRUCTURE 9.

Which of the following elements has maximum density of nucleus :

UDAAN DPP (1) 14Si30 (2) 15P31 (3) 8O16 (4) All have same density

Cathode rays, Anode rays, Basic definations and Rutherford model' 10. Number of protons, neutrons and electrons in the element 281
89 Ac are respectively :

(1) 89, 231, 89 (2) 89, 89, 242 (3) 89, 142, 89 (4) 89, 192, 89
1 Cathode ray are :
(1) stream of electrons (2) stream of -particles
Nature of Light and photoelectric effects
(3) radiation (4) stream of cations
2 Which of the following rays are affected by electric field : 11 . A photon in X region is more energetic than in the visible region ; X is :

(1) Anode rays (2) Cathode rays (3) Both (1) and (2) (4) None of these (1) Infrared (IR) (2) Ultraviolet (UV) (3) Microwave (4) Radio wave
3 The e/m ratio for Anode rays : 12 Which one of the following is not the characteristic of Planck's quantum theory of radiation-
(1) varies with the element forming the anode in the discharge tube.
(1) The energy is not absorbed or emitted in whole number multiple of quantum.
(2) varies with the gas filled in the discharge tube.
(3) is constant. (2) Radiation is associated with energy.

(4) Both (1) & (2). (3) Radiation energy is not emitted or absorbed continously but in the form of small packets called
4. Millikan's oil drop expriments is used to find - quanta.
(1) e/m ratio of an electron (2) Charge of an electron (4) This magnitude of energy associated with a quantum is proportional to the frequency.
(3) Mass of an electron (4) Velocity of an electron
13 One quantum is absorbed per gaseous molecule of X 2 for converting it into X atoms. If light absorbed
5. An element having atomic number 25 and atomic weight 55 will have
has wave length 1240Å, then bond energy of X 2 will be :
(1) 25 protons and 30 neutrons (2) 25 neutrons and 30 protons
(1) 10 eV/molecule (2) 20 J/mole (3) 48 eV/molecule (4) 184 J/mol
(3) 55 protons (4) 55 neutrons
6. The charge on the atom having 17 protons, 18 neutrons and 18 electrons is 14 The work function for a metal is 4 eV. To eject a photoelectron of zero velocity from the surface of
(1) + 1 (2) 1 (3) 2 (4) zero the metal, the wavelength of incident light should be above :

7. Which of the following are isoelectronic with one another ? (1) 310 Å (2) 1550 Å (3) 155 Å (4) 3100 Å
(1) Na+ and Ne (2) K+ and O (3) Ne and O (4) Na+ and K+
15 Cu metal (work function = 4.8 eV) can show photoelectric effect if wavelength of photon is :
8. When atoms are bombarded with alpha particles, only a few in million suffer deflection, others pass
out undeflected. This is because (1)  = 5000 Å (2)  = 6000 Å (3)  = 2000 Å (4)  = 4000 Å

(1) The force of repulsion on the moving alpha particle is small 16 Calculate frequency of light having wavelength 500 nm is
(2) The force of attraction on the alpha particle to the oppositely charged electrons is very small (1) 6×1014 Hz (2) 5 ×10 10 Hz (3) 2 ×1020 Hz (4) 7 × 1010 Hz
(3) There is only one nucleus and large number of electrons
17. The energy of a photon is 3.03 × 10 19 J, then wavelength of this photon is:
(4) The nucleus occupies much smaller volume compared to the volume of the atom
(Given, h = 6.63 × 10 34 Js, c = 3.00 × 10 8 ms 1)

(1) 6.56 nm (2) 65.6 nm (3) 656 nm (4) 0.656 nm

18 The energy required to remove an electron from a metal X is 3.31 × 10 20 J. Wavelength/s of light that 26 Wavelength of first line of Balmer series in hydrogen spectrum is :
can not photoeject an electron from metal X is
(1) 6656 Å (2) 6266 Å (3) 6626 Å (4) 6566 Å
(1) 4 m (2) 6 m (3) 7 m (4) 5 m
27 Different lines in Lyman series of hydrogen spectrum is present in :
19 Wavelength of a photon having an energy of 2 eV. will be :
(1) Ultra violet (2) Visible (3) Infared (4) None of these
(1) 6.2  10 7 m (2) 6.2  10 6 m (3) 6.2  10 9 m (4) 6.2  10 8 m
28 When an electron in an excited hydrogen atom jumps 5 th orbit to 3rd orbit the spectral line is observed
20 Wave number of radiations having frequency of 4 × 10 4 Hz will be : in the ..........region and in .............series of the hydrogen spectrum.

(1) 1.33 × 10 cm
6 1 (2) 1.33 × 10 cm7 1 (3) 9 × 10 11 cm 1 (4) 4 × 10 5 cm 1 (1) Visible, Balmer (2) Visible, Lyman (3) Infrared, Paschen (4) Infrared, Balmer

29 Maximum number of spectral lines in Lyman series will be if electron makes transistion from n th orbit
:
Atomic Spectrum
(1) n (2) n 1 (3) n 2 (4) n (n + 1)
21 The wavelength of a spectral line for an electronic transition is inversly related to :
30 No. of visible lines when an electron returns from 5th orbit to ground state in H spectrum -
(1) No. of electrons undergoing transition
(1) 5 (2) 4 (3) 3 (4) 10
(2) The nuclear charge of the atom
31 Whon the electron of a Hydrogen atom jumps from n = 4 to n = 1 state, then the total number of
(3) The velocity of an electron undergoing transition
spectral line is
(4) The difference in the energy levels involved in the transition
(1) 15 (2) 3 (3) 6 (4) 4
22 The spectral lines corresponding to the radiation emitted by an electron jumping from 6th, 5th and
32 Ratio of wavelength of second line of Lyman series to that of series limit of Paschen series of H-atom.
4th orbits to second orbit belong to :
(1) 1/8 (2) 1/9 (3) 8/9 (4) 9/8
(1) Lyman series (2) Balmer series
33 The wave number of first line of Balmer series of hydrogen atom is 15200 cm 1. What is the wave
(3) Paschen series (4) Pfund series
number of first line of Balmer series of Li2+ ion:
23 Which transition emits photon of maximum frequency in hydrogen like species : (1) 15200 cm 1 (2) 13680000 m 1 (3) 76000 cm 1 (4) 13680 cm 1
(1) 2nd spectral line of Balmer series (2) 2nd spectral line of Paschen series

(3) 5th spectral line of Humphery series (4) 5 th spectral line of Lymen series
Bohr's Model
24 The shortest wave length for the Brakett series for H is : (Given RH = 109678 cm 1)
34 T B
(1) 1459 Å (2) 4052 Å (3) 4052 nm (4) 1459 nm
n 2h 2 n2h2 n 2h 2 n2 h2
25 The transition of electron in H-atom that will emit maximum energy is : (1) r = (2) r = (3) r = (4) r =
4 2 me 4 z 2 4 2 me 2 z 4 2 me 2 z 2 4 2 m 2 e 2 z 2

(1) n3 n2 (2) n4 n3 (3) n5 n4 (4) All have same energy 35 The ratio of radii of second orbits of He+ , Li2+ and Be3+ is :

(1) 1 : 2 : 3 (2) 6 : 4 : 3 (3) 3 : 4 : 6 (4) none of these

 46 Angular momentum in 2nd Bohr orbit of H-atom is x. Then angular momentum

36 If r is the radius of first orbit, the radius of nth orbit of H atom is given by - of electron in Ist excited state of Li+2 is :

(1) r n (2) r n2 (3) r/n (4) r2 n2 x

(1) 3x (2) 9x (3) (4) x
2
37 What is the ratio of speeds of electrons in Ist orbit of H-atom to IVth orbit of He + ion .
47 The maximum energy of an electron in an atom will be at :
(1) 2 : 1 (2) 8 : 3 (3) 3 : 2 (4) 27 : 5
(1) Nucleus (2) Ground state
38 If the speed of electron in second orbit of He + is "v" , then the speed of electron in first Bohr orbit of
hydrogen atom will be : (3) First excited state (4) Infinite distance from the nucleus

(1) v/2 (2) 2v (3) v (4) 4v 48 Energy of first excited state in hydrogen atom is 3.4 eV then, kinetic energy of electron in same
orbit of hydrogen atom is :
39 Which state of the triply ionized Beryllium (Be3+) has the same orbit radius as that of the ground state
of hydrogen atom ? (1) + 3.4 eV (2) + 6.8 eV (3) 13.6 eV (4) + 13.6 eV

(1) 1 (2) 2 (3) 3 (4) 4 49 Potential energy of electron is 27.2 eV in 2nd orbit of He+. Then total energy of electron in first excited
state of Hydrogen atom will be :
40 If the velocity of the electron in first orbit of H atom is 2.18 × 106 m/s,what is its value in third orbit ?
(1) 3.4 eV (2) 13.6 eV (3) 3.4 eV (4) 13.6 eV
(1) 7.27 × 105 m/s (2) 4.36 × 10 6 m/s
50 If the potential energy of electron in hydrogen atom is 3.02eV then in which of the following excited
(3) 1.24 × 10 5 m/s (4) 1.09 × 10 6 m/s
level is electron present :
41 The radius of a shell for H-atom is 4.761 Å. The value of n is.
(1) 1st (2) 2nd (3) 3rd (4) 4th
(1) 9 (2) 3 (3) 5 (4) 4
51 The ionisation energy for the H-atom is 13.6 eV. Then the required energy in eV to excite the electron
42 If the radius of Ist orbit of hydrogen atom is 0.53 Å then radius of I st orbit of He+ is : it from the ground state to next higher state will be : (in eV)

(1) 1.27 Å (2) 0.265 Å (3) 1.59 Å (4) 0.132 Å (1) 3.4 (2) 10.2 (3) 12.1 (4) 1.5

43 Ratio of radii of second and first Bohr orbits of H atom is : 52 The ionization energy of H-atom is 13.6 eV. The ionization energy of Li+2 ion will be :

(1) 2 (2) 4 (3) 3 (4) 5 (1) 54.4 eV (2) 122.4 eV (3) 13.6 eV (4) 27.2 eV

44 The angular momentum of an electron in a given orbit is J, Its kinetic energy will be : 53 The excitation energy of first excited state of a hydrogen like atom is 40.8 eV. The energy needed to
2 2 2
remove the electron from ground state of the ion is :
1 J Jv J J
(1) (2) (3) (4)
2 mr 2 r 2m 2 (1) 54.4 eV (2) 122.4 eV (3) 40.8 eV (4) 13.6 eV

45 When an electron drops from a higher energy level to a low energy level, then : 54 Match the following

(1) energy is absorbed (2) energy is emitted (1) Energy of ground state of He+ (i) + 6.04 eV

(3) atomic number increases (4) atomic number decreases (2) Potential energy of  orbit of H-atom (ii) 27.2 eV

(3) Kinetic energy of  excited state of He+ (iii) 54.4 V

(4) Ionisation potential of He +

(iv) 54.4 eV

(1) A (i), B (ii), C (iii), D (iv) (2) A (iv), B (iii), C (ii), D (i)

(3) A (iv), B (ii), C (i), D (iii) (4) A (ii), B (iii), C (i), D (iv)
55 If the binding energy of first excited state of a hydrogen like species is 54.4 eV, then determine the
atomic number of the H-like species :
65 If wavelength is equal to the distance travelled by the electron in one second, then -
(1) 1 (2) 2 (3) 3 (4) 4
p h h h
(1)  = (2)  = (3)  = (4)  =
56 What is the ratio of energy of electron of Li+2 and Be+3 in 2nd bohr orbit. h m p m

(1)
16
(2)
25
(3)
9
(4)
1 66 The speed of a proton is one hundredth of the speed of light in vacuum. What is its de-Broglie of
9 16 16 4 proton wavelength? Assume that one mole of protons has a mass equal to one gram [h = 6.626 ×
57 Correct relation between total energy (TE) and potential energy (PE) 10 27 erg sec] :

TE PE PE (1) 13.31 × 10 3 Å (2) 1.33 × 10 3 Å (3) 13.13 × 10 2 Å (4) 1.31 × 10 2 Å

(1) PE = (2) TE = PE (3) TE = (4) TE =
2 4 2 34
67 A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be : (h = 6.6 × 10
58 The energy of an electron in an excited H-atom is 1.51 eV. Angular momentum of electron in the Js)
given orbit will be 32 34 35 32
(1) 6.6 × 10 m (2) 6.6 × 10 m (3) 1.0 × 10 m (4) 1.0 × 10 m
(1) 3h/ (2) 3h/2 (3) 2h/ (4) h/
68 The wavelength of a charged particle ________the square root of the potential difference through
59 The ratio of energies of hydrogen atom for first and second excited state is : which it is accelerated :

(1) 4/1 (2) 1/4 (3) 4/9 (4) 9/4 (1) is inversely proportional to (2) is directly proportional to

60 The ratio of potential energy and total energy of an electron in a Bohr orbit of hydrogen like species is (3) is independent of (4) is unrelated with

(1) 2 (2) 2 (3) 1 (4) 1 69 If the kinetic energy of an electron is increased 4 times, the wavelength of the de-Broglie wave
associated with it would become :
de-Broglie concept & Heisenberg uncertainity principle
(1) four times (2) two times (3) half times (4) one fourth times
61 The de Broglie equation suggests that an electron has
70 What possibly can be the ratio of the de Broglie wavelengths for two electrons each having zero initial
(1) Particle nature (2) Wave nature energy and accelerated through 50 volts and 200 volts ?

(3) Both Particle & wave nature (4) Radiation behaviour (1) 3 : 10 (2) 10 : 3 (3) 1 : 2 (4) 2 : 1

62 de-Broglie wavelength of electron in second orbit of Li2+ ion will be equal to de-Broglie of wavelength
of electron in

(1) n = 3 of H-atom (2) n = 4 of C 5+ ion (3) n = 6 of Be3+ ion (4) n = 3 of He+ ion

63 Select the incorrect relationship among the following :

h h h h
(1) x  p  (2) x p  (3) x  V  (4) E  t 
4  4  m 4  m 4 

64 What is the de-Broglie wavelength associated with the electron in 3rd orbit of hydrogen :

(1) 9.96  10−10 cm (2) 9.96  10−8 cm (3) 9.96  104 cm (4) 9.96  108 cm
Shape of orbitals
81 The electrons present in K-shell of the atom will differ in
71 Which orbital is non-directional
(1) principal quantum number (2) azimuthal quantum number
(1*) s (2) p (3) d (4) All
(3) magnetic quantum number (4) spin quantum number
72. An orbital with l = 0 is symmetrical about the :
82 Number of electrons having l = 1 and m=0 in phosphorous-atom in its ground state :
(1) x-axis only (2) y-axis only (3) z-axis only (4) All
(1) 3 (2) 1 (3) 2 (4) 0
73. Which orbital has two angular nodal planes.

(1) s (2) p (3) d (4) f 83 . Maximum number of electrons that can have n = 3, l = 2, m = +2, s = +½ in an atom are :

74. Which d-orbital does not have four lobes (1) 18 (2) 6 (3) 24 (4) 1

(1) dx 2
− y2
(2) dxy (3) dz 2 (4) dxz 84. Which of the following principles limits the maximum number of electrons in an orbital to two

(1) Aufbau principle (2) Pauli's exclusion principle

75. The number of radial nodes of 5s atomic orbital are
(3) Hund's rule of maximum multiplicity (4) Heisenberg's uncertainty principle
(1) 1 (2) 2 (3) 3 (4) 4
85._ Number of possible orbitals (all type) in n = 3 energy level is
76 A 3p-orbital has
(1) 2 (2) 9 (3) 4 (4) 1
(1) Two non-spherical nodes (2) Two spherical nodes

(3) One spherical and one Radial nodes (4) One spherical and two non spherical nodes

77. Which of the following d-orbitals has dough-nut shape ?

(1) dxy (2) dyz (3) dx 2

− y2
(4) dz 2

Quantum Numbers and Electronic configuration

78 Magnetic quantum number specifies -

(1) Size of orbitals (2) Shape of orbitals

(3) Orientation of orbitals (4) Nuclear stability

79 An orbital containing electron having quantum number n = 4, l = 3, m = 0 and s =

1
2
is called

(1) 3s orbital (2) 3p orbital (3) 4d orbital (4) 4f orbital

80 The maximum number of orbital electrons in a subshell is given by the expression

(1) 4l 2 (2) (2l +1) (3) 2(2l + 1) (4) 2n2
 = 6.56 × 10 7 m
Solution
= 6.56 × 10 7 × 109 nm

= 6.56 × 10 2 nm = 256 nm
1. A
hc (6.63  10 −34 J . s)(3.00  10 8 m / s)
2 C 18 Sol. 3  = = = 6.01 × 10 6 m
E 3.31 10 −20 J
3. B
12400
4. B 19 Sol. 1  = Aº = 6200 Aº
2
5 A 20 A
6 Ans.
21 D
(2)
22 B
@Sol.
23 D
Net charge is 1. (17 e+ 18 p)
24 D
7. Sol. 1 Isoelectronic species should have same number of electrons.
25 A

8. Sol. 4 It is fact. 26 Sol. 4 For 1st line of Balmer series (3 2)

9. D hc
E3 E2 =

10. D
27 A
11. Sol. 2 More energy means less wavelength.
28 C
12. A
29 Sol. 2 When electron falls from n to 1, total possible number of lines = n 1
13 A
30 Sol. 3 Visible lines Balmer series 3 lines. (5 2, 4 2, 3 2).
12400 eVÅ
14 Sol. 4 (in Å) = = 3100 Å 31 C
4eV

15 C 32 A

16 A 33 B

hc 34 B
17 Sol. 3 According to formula, E =

35 B
hc
3.03 × 10 19 = 36 B


6.63  10 −34  3.00  108 37 A

=
3.03  10 −19
38 C
 1 Ze2
3.4 eV = −
2 r
39 B
1 Ze 2
Radius of ground state of hydrogen atom = 0.529 Å  KE =
2 r

= + 3.4 eV

n2 49 A
So, 0.529 = 0.529 ×
Z
50 B
n2
0.529 = 0.529 × 51 B
4

 n=2 52 Sol. 2 E1 for Li+2 = E1 for H × Z2 [for Li, Z = 3]

= 13.6 × 9 = 122.4 eV

Z 53 Sol. 1 40.8 = ( E)2→1 × Z2  40.8 = 10.2 × Z2  Z2 = 4 or Z = 2

 Sol. 1 v3 = v 1 ×  
n
IE = 13.6 Z2 = 13.6 × 4 = 54.4 eV
 1
v3 = 2.18 × 106 ×   = 7.27 × 10 5 m/s 54 Sol. 3
3
(1) Energy of ground state of He+ = 13.6 × 22 = 54.4 eV (iv)
41 B
(2) Potential energy of  orbit of H-atom = 27.2 × 12 = 27.2 eV (ii)
0.53
42 Sol. 2 Radius of He+ is = = 0.265Å
2 22
(3) Kinetic energy of  excited state of He+ = 13.6 × = 6.04 eV (i)
32
r (2)2
43 Sol. B Bohr radius = = 2 = 2 = 4
r1 (1) (4) Ionisation potential of He + = 13.6 × 22 = 54.4 V (iii)

44 Sol. A Angular momentum J = mvr 55 Sol. 4

J2 = m2v2r2 Given binding energy of Ist excited state (n = 2) = 54.4 eV

J2 1  J2  3.4 Z2 = 54.4 eV  Z2 = 16  Z=4

or =  mv 2  mr 2 or K.E. =
2 2  2mr 2
56 C
45 B 57 D
46 D 58 B

47 Sol. D It is fact 59 D

48 Sol. Total energy (En) = KE + PE 60 A

1  ze2 
In first excited state = mv 2 +  − 
2  r 

1 Ze2 ze2
=+ −
2 r r
 73 C

61 Sol. C An electron has particle and wave nature both. 74 C

z h n n n 2 4 75 D
62 Sol. 2 V , = ,   1 = 2 or = (n = 4 of C5+ ion)
n mv Z Z1 Z2 3 6
76 Sol. C Spherical node = n l 1
63 B
non spherical = l
z
64 Sol. 2 v = 2.18 × 106 m/s
n
77 Sol. D Factual
–34
h 6.62 10 3 78 C
= = = 9.96  10 – 8 cm
mv 9.1 10 – 31  2.188  10 6  1
79 D

80 Sol. B Maximum no. of electrons in a subshell = 2 (2l + 1) = 4+ 2.

65 Sol. D  = v
1 1
h h h 81 Sol. D Two electrons in K shell will differ in spin quantum number s = + or .
then = or 2 = So,  = . 2 2
mV m m
82 A
h 6.62  10 –34  6.02  10 23  100
66 Sol. B  = =
mv 10 – 3  3  10 8 83 D

h 84 Sol. 2 No two electrons in an atom can have identical set of all the four quantum numbers
67 Sol C According to de-Broglie equation,  =
mv
85 B
Given, h = 6.6 × 10 34 J s

m = 0.66 kg

v = 100 m s 1

6.6  10 −34
 = = 1 × 10 35 m
0.66  100

h 1
68 Sol. A For a charged particle  = ,  .
2mqV V

69 C

1 V2 200 2
70 Sol. D = = = .
2 V1 50 1

71 Sol. A s orbital is spherical so non-directional.

72 D