AITS 2223 FT V JEEA Paper 1 OFFLINE PDF

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
FULL TEST – V
PAPER –1
TEST DATE: 08-02-2023
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Two Sections: Section-A & Section-B.
Section – A (01 –06, 19 – 24, 37 – 42): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – A (07 – 10, 25 – 28, 43 – 46): This section contains TWELVE (12) Matching List Type Questions.
Each question has FOUR statements in List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II
entries (P), (Q), (R), (S) and (T). The codes for lists have choices (A), (B), (C), (D) out of which, ONLY ONE of
these four options is correct answer.
Section – B (11 – 18, 29 – 36, 47 – 54): This section contains TWENTY FOUR (24) numerical based
questions. The answer to each question is a NUMERICAL VALUE. If the numerical value has more than
two decimal places, truncate/round-off the value to TWO decimal places.
MARKING SCHEME
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
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AITS-FT-V (Paper-1)-PCM-JEE(Advanced)/2023 2
Physics PART – I
Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is (are) correct answer(s).
1. Two vertical conducting cylinders A and B of different cross

sections are connected by a thin tube as shown. An ideal gas is A B
trapped in the cylinders by two airtight pistons of masses 1.0 kg
and 2.0 kg respectively. Initially the pistons are at the same
height 40cm above the base of the cylinders. If an additional 40 cm
mass of 10 g were gently placed on the piston in the cylinder A,
which of the following statements correctly describe the new
steady state ultimately reached.
(A) Pressure of the gas has been increased.
(B) Pressure of the gas remains unchanged.
(C) Height difference between the pistons becomes 30 cm.
(D) Height difference between the pistons becomes 60 cm.
2. Five equal resistances, a capacitor and two batteries are V

A R
connected in a circuit as shown in the figure. The capacitor D
is initially uncharged and each battery has negligible internal
resistance. It is given that R = 1, C = 1F and V = 8 volt. R R
On the basis of above information answer the following E C
questions, if switch ‘S’ is closed at t = 0. (Assume e–1 = 0.37, B R
if required) S R
(A) Current in the branch of capacitor at t = 5/8 s is 2V
(approximately) 6 A
(B) Current in the branch AB at t = 5/8 s is (approximately) 1.7 A
(C) Potential difference between points A and C at t = 5/8 s is (approximately) 2.5 V
(D) Potential difference between points A and C at t = 5/8 s is (approximately) 6 V
3. A point mass m is attached to an ideal string, which in turns is wrapped on a vertical pole. Point
mass is kept on a smooth horizontal surface and string is horizontal. A horizontal velocity is
imparted to the point mass perpendicular to length of string.
(A) Speed of mass will become twice of initial value if length of string between the point mass
and the pole becomes half of the original value.
(B) Kinetic energy of mass increases.
(C) Work done by tension on the point mass is zero.
(D) Energy of the mass remains constant.
3 AITS-FT-V (Paper-1)-PCM-JEE(Advanced)/2023
4. In the adjacent figure, a uniform disc of mass 2m and radius 2m

 / 2 is lying at rest on a smooth horizontal surface. A particle
‘A’ of mass m is connected to a light string of length  , whose
other end is attached to the circumference of the disc. Initially
string is just taut and tangential to the disc, particle A is at rest.
In the same horizontal plane another particle B of same mass

m moving with velocity v0 perpendicular to string collides
elastically with A. Just after impact which of the following
statements will be true m v0
A
B m
2mv 20 v 02
(A) Tension in the string is (B) Acceleration of the centre of the disc is
5 5
5 2v 02
(C) Initial radius of curvature of ‘A’ is (D) Acceleration of the centre of the disc is
2 5
5. Three masses are joined using pin joints (can move

freely). Length of both rods are identical and system starts
from rest. Accelerations of the balls are shown in figure.
Angle between the rods at this moment is 90°. The
horizontal surface is smooth. Choose the correct
option(s).
(A) 2a2 = a1 + ax
(B) 2ay = a1 + a2
(C) 2ax = a1 – a2
(D) 3a1 = 5a2
6. A particle of mass m is subjected to two forces

  
r 
F1  f(r)  and F2  v
r

Where f(r) is a real valued function depends on the distance of particle from origin, r is position

vector of particle and  is positive constant. If at t = 0, v vector is in x-y plane and angular
momentum of the particle about the origin is L0. Choose the correct option(s).
(A) Plane of motion of particle does not change.
t

(B) Angular momentum of particle about the origin is given by L0 e m
(C) Angular momentum of particle about the origin is remains constant.
(D) The value of angular momentum about the origin will depend on f(r)

This section contains FOUR (04) Matching List Type Questions. Each question has FOUR statements in
List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II entries (P), (Q), (R), (S) and (T). The
codes for lists have choices (A), (B), (C), (D) out of which ONLY ONE of these four options is correct
answer.
7. Match List I with List II:

List I (Circuit) List II (Ceq)
3C
(I) (P)
C C C C C C 4
C C C C C C 5C
A B
(II) (Q)
12
C C C C C C
A B 2C
(III) (R)
3
A C C C C C C 3C
B
(IV) (S)
2
(A) I – S; II – Q; III – R; IV – P (B) I – S; II – P; III – Q; IV – R
(C) I – S; II – P; III – R; IV – Q (D) I – S; II – Q; III – P; IV – R
8. One mole of an ideal gas whose adiabatic exponent equals , undergoes a process P = P0 + /v,
where P0 and  are positive constants. Its volume increases from v 1 to v2.
List–I List–II
(I) Heat capacity of gas as a function of its (P) P0 (V2 – V1 )
volume  –1
(II) Internal energy increment of a gas (Q) P0 (v 2 – v1 ) v
  ln 2
 –1 v1
(III) The work performed by it (R) v2
P 0 (v 2 – v1 )   ln
v1
(IV) The amount of heat transferred (S) R R

 – 1 p0 v
(A) I – S; II – P; III – R; IV – Q (B) I – P; II – Q; III – R; IV – S
(C) I – P; II – S; III – R; IV – Q (D) I – S; II – P; III – Q; IV – S
9. Consider a situation in which a projectile is fired at 40 m/s

from the top of a tower in absence of air resistance t =0. 40m/s
37
36m
List–I List–II
(I) Time at which particle moves at right (P) 2.4 s
angles with the initial direction
(II) time at which kinetic energy is least (Q) 6s
(III) Time at which it strikes the ground (R) 20/3 s

(IV) Time when the v make 45 with horizontal (S) 5.6 s
(T) 7.2 s
(A) (I)  (R); (II)  (P); (III)  (S); (IV)  (Q) (B) (I)  (P); (II)  (R); (III)  (Q); (IV)  (S)
(C) (I)  (P); (II)  (Q); (III)  (R); (IV)  (S) (D) (I)  (R); (II)  (P); (III)  (Q); (IV)  (S)
10. A neutron moving with kinetic energy K collides with a hydrogen atom at rest in ground state.
Assume mass of neutron to be equal to that of hydrogen atom. Match the kinetic energy of
neutron with the possible phenomena mentioned in column II. Energy of hydrogen in ground state
is –13.6 ev
List– I List–II
(Kinetic energy of colliding neutron)
I K = 10.2 eV (P) Elastic collision may take place
II K = 13.6 ev (Q) Inelastic collision may take place
III K = 20.4 ev (R) Perfectly inelastic collision may take place
IV K = 22.0 ev (S) Hydrogen atom may get ionised
(A) I-P; II-Q; III-R; IV-S (B) I-P; II-P; III-P, R; IV-P, Q
(C) I-P; II-P; III-P; IV-Q (D) I-P; II-P; III-R; IV-Q
Section – B (Maximum Marks: 24)
This section contains EIGHT (08) numerical based questions. The answer to each question is a
NUMERICAL VALUE. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.
11. Two identical springs each of stiffness k are welded at a point P. If a

particle of mass m is welded at P. The period of oscillation of the k
 Ym  P
particle in the direction of x is . Find Y x
sin  k  m
k
A
12. A body executing SHM with time period T and amplitude A. When it is at from equilibrium
2
position moving toward right. It receives an impulse which doubles its velocity without changing
1  K 
direction. Time taken by the block to reach the right extreme position is t  T cos   . Find
 13 
K.
13. Figure shows a meter bridge wire AC has a uniform cross- X  4 Y

section. The length of wire AC is 100 cm. X is a standard
resistor of 4  and Y is a coil. When Y is immersed in melting
ice the null point is at 40 cm from point A. When the coil Y is
heated to 100°C, a 12  resistor has to be connected in G
parallel with Y in order to keep the bridge balanced at the
same point.
A C
D

14. A circular disc of a diameter d is slowly rotated in a liquid of large 

viscosity  at a small distance h from a fixed surface. An
expression for torque T necessary to maintain an angular
d4  Liquid h
velocity  is . Find the value of X.
Xh
15. A set of parallel rays incident on the bi-convex lens. If f1  15 cm f2  20 cm
after two refractions and one reflection final image
Convex mirror
X
formed at 15 cm left of lens, the value of is
9
16. Three SHM in the same direction in having same amplitude and same period are superposed. If
each differ in phase from the next by 45°. Then, find the energy associated with resulting motion
taking energy associated with each of given SHM as 1 J.
17. Two rods of different materials having coefficient of thermal expansion 1, 2 and Young’s
modulus Y1, Y2 are fixed between two massive walls. The rods are heated such that they undergo
the same increase in temperature. If 1 : 2 = 2 : 3, then thermal stresses in rods are equal, then
the ratio Y1 : Y2 is _____ .
18. A student determines a dimensionless quantity,

en
B .
Z 0hc
Where, e = electric charge,
0 = permittivity of vacuum,
h = Plank’s constant
and c = speed of light.
Find the value of n.
Chemistry PART – II

76
19. An isotone of 32 Ge is
77 77
(A) 32 Ge (B) 33 As
77 78
(C) 34 Se (D) 34 Se
20. For a compound AB crystallises in a rock salt structure with edge length a of the unit cell,
(A) the minimum distance between A and A is a/ 2
(B) the minimum distance between B and B is a/ 2
(C) the minimum distance between A and B is a/2
4 M
(D) the density of the crystal is given by   3 AB
a NA
21. Which of the following statements are not correct

(A) For an ideal binary liquid solution, the plot of 1/xA versus 1/yA (where xA and yA are the mole
fractions of A in liquid and vapour phases, respectively) is linear.
(B) According to Raoult’s law, the relative lowering of vapour pressure is equal to the mole
fraction of solvent in the solution.
(C) The crysoscopic constant Kf is property of solvent.
(D) The value of van’t Hoff factor for CH3COOH in benzene will be 2
22. Which of the following statements are correct?

(A) Linear overlap of two atomic p-orbitals leads to a sigma bond
(B) The bond angle H – N – H in NH3 is greater than the bond angle H – As – H in AsH3.
(C) Anhydrous HCl is a bad conductor of electricity but aqueous HCl is a good conductor
(D) o-nitrophenol is steam volatile whereas p-nitrophenol is not.
23. Which of the following reactions give an alkyne?

Kolbe 's
(A) sodium fumarate  electrolysis

(B) CH3 CBr2 CHBr2 
Zn alcohol 

NaNH3 
(C) CH3 CH2CHBr2  
NaNH2
(D) CH3 CHBr  CHBr  

24. Which of the following reactions give n-propyl alcohol as the major product?
H
(A) CH3 – CH = CH2 + H2O 
 3 2 i CH CH MgBr
(B) HCHO 
 ii hydrolysis 
  cold aq KMnO
(C) CH3 – CH = CH2  4

Ni
(D) CH2  CH  CHO  H2 

answer.
25. Match the entries in List-I for the spectral series of hydrogen atom with those given in List-II. The
symbols n1 and n2 are the quantum level in the expression
List -I List-II
(I) Lyman series (P) n1 = 2 and n2 = 3, 4, 5,…
(II) Balmer series (Q) n1 = 4 and n2 = 5, 6, 7
(III) Paschen series (R) n1 = 5 and n2 = 6, 7,…
(IV) Pfund series (S) n1 = 1 and n2 = 2, 3, 4,…
(T) n1 = 3 and n2 = 4, 5, 6,….
Which of the following is correct match
(A) I–S; (B) II–Q
(C) III–R (D) IV – T
26. Match the list -I and List- II
List -I List-II
(I) Electrophilic substitution (P) NaOH
C6H5N2Cl + C6H5 OH  
(II) Nucleophilic substitution (Q) Toluene + NBS 
(III) Free radical substitution (R) Dow’s process
(IV) Coupling reaction (S) Phenol  picric acid
(T) C6H5ONa + CH3Br 
(A) I–R, (B) II–P
(C) III-Q (D) IV–T
27. Match the list -I and List- II
List -I List-II
(I) 2p – 3 p (P) F 2C = O
(II) 3p – 3 d (Q) F 3P = O

(III) 2p – 3 d (R) F 3P = S
(IV) 2p – 2 p (S) F 2S = O
(T) F 2C = S
(A) I–R, (B) II–T
(C) III-Q (D) IV–P
28. List-II give the values of  (- Cp, m/CV, m) at high temperature of gases which are shown in column I.
Identify the gas with the corresponding  values.
List -I List-II
(I) Monatomic (P) 1.154
(II) Diatomic (Q) 1.286
(III) Linear Triatomic (R) 1.167
(IV) Nonlinear Triatomic (S) 1.407
(T) 1.667
Which of following is correct match
(A) I–Q (B) II–T
(C) III-P (D) IV–R

29. The ionization potential of hydrogen atom is 13.6 eV. The energy in electron volt required to
remove an electron in the n = 2 state of the hydrogen atom is
30. The density of a gas is 1.5 g L–1 at STP. Its density at 27 ºC and 1000 Torr would be
31. Ammonium chloride crystallizes in a body-centred cubic lattice with edge length of 387 pm. If the
–
size of NH4 is 154 pm, the size of Cl ion would be
32. A container of volume ‘V’ litre contains an equilibrium mixture which consists of 2 mol each of
PCl5, PCl3 and Cl2. The equilibrium pressure is 3 atm and temperature is ‘T’ kelvin. A certain
amount of Cl2 gas is now introduced into the container keeping the temperature and presence
constant, until the equilibrium volume becomes ‘2V’ litre. How many moles of Cl2 were added?
33. The conductivity of a saturated solution of silver oxalate is 4.5 × 10–5 S cm–1. If its Ksp = 1.35 ×
10–11M3, the molar conductivity of the saturated solution would be
34. How many grams of potassium perchlorate (KClO4) must be mixed with 108 g of water in order to
1
obtain a solution, which has a mole fraction of KClO4 equal to ?
7
35. Calculate effective nuclear charge on last electron of Cl. (using Slater rule)
36. The number of isomers possible for complex K2[PtClBr2SCN]:
Mathematics PART – III

37. A point P  
3,1 moves on the circle x 2  y 2  4 and after covering a quarter of the circle
leaves it tangentially. The equation of a line along which the point moves after leaving the circle is
(A) y  3x  4 (B) 3y  x  4
(C) 3y  x  4 (D) y  3x  4
38. A chord PP’ of a parabola cuts the axis of the parabola at O. The feet of the perpendiculars from
P and P’ on the axis are M and M’ respectively. If V is the vertex then VM, VO, VM’ are in
(A) AP (B) GP
(C) HP (D) none of these
39. ,  and  are three angles given by   2 tan1  

2  1 ,
1  1 1
 3 sin 1  sin 1    and   cos 1 . Then
2  2  3
(A)  >  (B)  > 
(C)  <  (D) none of these
8
40. 
4
16x  64  x  x  16x  64 dx 
6 10
(A) 2  16x  64  x  x  16x  64 dx  (B) 2   16x  64  x  x  16x  64 dx
4 8
9
(C) 2  16x  64  x  x  16x  64 dx  (D) 16
7
41. If M is the skew symmetric matrix of order n × n, then

(A) det (M – I) = det (M + I) (B) det (M – I) = – det (M + I) if n is odd
–1
(C) det (M – I) = det (M + I) if n is even (D) det (I – M) (I + M) ) = 1, det (I + M)  0
   
42. If the unit vectors a and b are inclined at an angle 2 such that a  b  1 and 0     , then 
lies in the interval
(A) [0, /6) (B) (5/6, ]
(C) (/6, /2] (D) [/2, 5/6)

answer.
43. Match the List– I & List–II

List–I List–II
A straight line with negative slope passing through (1, 4) meets the
I coordinate axes at A and B. The minimum length of OA + OB, O being the P 52
origin, is
II If the point P is symmetric to the point Q(4, –1) with respect to the bisector Q 32
of the first quadrant, then the length of PQ is
III On the portion of the straight line x + y = 2 between the axis a square is R 9/2
constructed away from the origin, with this portion as one of its sides. If d
denotes the perpendicular distance of a side of this square from the origin
then the maximum value of d is
IV If the parametric equation of a line is given x = 4 + /2 and y = – 1 + 2, S 9
where  is a parameter, then the intercept made by the line on the x-axis is
(A) I  R; II P; III  Q; IV  S (B) I  S; II P; III  Q; IV  R
(C) I  S; II R; III  Q; IV  P (D) I  P; II S; III  Q; IV  R
44. Match the List–I & List–II

List–I List–II
1 1
I The smallest integer greater than  is P 10
log3  log4 
II Let 3a  4, 4b  5, 5c  6, 6 d  7, 7e  8, and 8 f  9. Then the value Q 3
of the product (abcdef) is
III Characteristic of the logarithm of 2008 to the base 2 is R 1
IV If log2  log2  log3 x    log2 log3 log2 y    0, then the value of (x – y) S 2
is
(A) I  R; II  S; III  P; IV  Q (B) I  S; II  Q; III  P; IV  R
(C) I  Q; II  S; III  P; IV  R (D) I  Q; II  R; III  P; IV  S
45. Match the following List-I with List–II

List–I List–II
1  cos2x
I lim x2 equals to P 1
x 0
e  ex  x
II  3 / x   1
1/ x Q 2
If the value of lim   can be expressed in the form of
x 0   3 / x   1 
p/q
e , where p and q are relative prime, then (p + q) is equal to
III tan3 x  tan x 3 R 4
lim 5
equals to
x 0 x
IV x  2sin x S 5
lim equals to
x 0
x 2  2sin x  1  sin 2 x  x  1
(A) I  R; II  S; III  P; IV  Q (B) I  Q; II  S; III  S; IV  P
(C) I  R; II  P; III  S; IV  Q (D) I  Q; II  S; III  P; IV  R
46. Let  be the plane parallel to y-axis and containing the points (1, 0, 1) and (3, 2, -1). A  (4, 0, 0)
and B  (6, 0, –2) are two points and P  (x0, y0, z0) is a variable point on the plane  = 0.
Match List – I with List – II and select the correct answer using the code given below the list.
List - I List - I
I If the equation of the plane  = 0 is x + ay + bz = c, then |a + b + c| is P 16
II If (PA + PB) is minimum, then 4 x0  y 0  2z0 is Q 12
III If |PA + PB|  [0, N) , then N is R 3
IV If the reflection of the line AB in the plane S 8
x2 y z 4 4
  0 is   , then ( +  )
1 0 1
T 10
(A) I  R, II  Q, III  P, IV  S (B) I  Q, II  R, III  S, IV  P
(C) I  R, II  Q, III  S, IV  P (D) I  R, II  S, III  Q, IV  P

47. In the coordinate plane, the region M consists of all the points (x, y) satisfying the inequalities
y  0, y  x y and y  2  x simultaneously. The region N, which varies with the parameter t,
consists of all the points (x, y) satisfying the inequalities t  x  t  1and 0  t  1
2 1
simultaneously. The area of M  N is k 1t  k 2 t  , then k1 + k2 is ______ .
2
48. The slope of the tangent to the curve represented by x = t2 + 3t – 8 and y = 2t2 – 2t – 5 at the

point M  2, 1 is   , then value of  is ?
7
49. Let 1  3x  4x 2   a0  a1x  a2 x 2  ..  a20 x 20 . Then value of a3 is –
cos 2  cos  sin   sin 

 
50. Find the value of f   , where f     cos  sin  sin 2  cos 
6
sin   cos  0
51. If , ,  are such that  +  +  = 4,  2  2   2  6, 3  3   3  8 , then the value of

  4  4   4  must be equal to (where [.] denotes the greatest integer function)
 
52. Find the Coefficient of x103 in (1 + x + x2 + x3 + x4)199 (x – 1)201.
x 1 2021
 1  1 
53. If  1    1   , then |x| is equal to
 x  2021 
54. If two events A and B are such that P( A ) = 0.3, P(B) = 0.4, P(A  B ) = 0.5, then the value of
P(B/(A B )) is

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FIITJEE

ALL INDIA TEST SERIES

 The test consists of total 54 questions.

Section – A (Maximum Marks: 24)

1. Two vertical conducting cylinders A and B of different cross

2. Five equal resistances, a capacitor and two batteries are V

4. In the adjacent figure, a uniform disc of mass 2m and radius 2m

5. Three masses are joined using pin joints (can move

6. A particle of mass m is subjected to two forces

Section – A (Maximum Marks: 12)

7. Match List I with List II:

9. Consider a situation in which a projectile is fired at 40 m/s

11. Two identical springs each of stiffness k are welded at a point P. If a

13. Figure shows a meter bridge wire AC has a uniform cross- X  4 Y

14. A circular disc of a diameter d is slowly rotated in a liquid of large 

18. A student determines a dimensionless quantity,

Section – A (Maximum Marks: 24)

21. Which of the following statements are not correct

22. Which of the following statements are correct?

23. Which of the following reactions give an alkyne?

Section – A (Maximum Marks: 12)

(II) 3p – 3 d (Q) F 3P = O

Section – B (Maximum Marks: 24)

36. The number of isomers possible for complex K2[PtClBr2SCN]:

Mathematics PART – III

Section – A (Maximum Marks: 24)

39. ,  and  are three angles given by   2 tan1  

41. If M is the skew symmetric matrix of order n × n, then

Section – A (Maximum Marks: 12)

43. Match the List– I & List–II

44. Match the List–I & List–II

45. Match the following List-I with List–II

Section – B (Maximum Marks: 24)

49. Let 1  3x  4x 2   a0  a1x  a2 x 2  ..  a20 x 20 . Then value of a3 is –

cos 2  cos  sin   sin 

51. If , ,  are such that  +  +  = 4,  2  2   2  6, 3  3   3  8 , then the value of

52. Find the Coefficient of x103 in (1 + x + x2 + x3 + x4)199 (x – 1)201.

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