Lesson 2. Atomic Structure Formulas and Names of Compounds
Lesson 2. Atomic Structure Formulas and Names of Compounds
I. Title
Subject General Chemistry 1 Quarter First Module 2
#
Level 12 Duration Day
Topic 1. Isotopes Code (STEM_GC11AMIc-e-19)
2. Formulas and names of (STEM_GC11AMIc-e-21)
compounds (STEM_GC11AMIPIc-c-23)
II. Objectives
1. Recognize common isotopes and their uses.
2. Represent compounds using chemical formulas, structural formulas and models.
3. Name compounds given their formula and write formula given the name of the compound.
(mass number) A
X
( atomic number) Z
As another example, consider two common isotopes of uranium with mass numbers of 235 and 238,
respectively:
The first isotope is used in nuclear reactors and atomic bombs, whereas the second isotope lacks the
properties necessary for these applications. With the exception of hydrogen, isotopes of elements are
identified by their mass numbers. Thus, these two isotopes are called uranium-235 (pronounced
“uranium two thirty-five”) and uranium-238 (pronounced “uranium two thirty-eight”).
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Sodium chloride containing sodium -24 can be injected into the bloodstream to study blood
circulation
A thallium -201 compound injected into the bloodstream will concentrate in normal heart muscle but
will not remain in damaged tissue.
Technetium -99 m is used for locating brain tumors and damaged heart cells
Radium-226 and cobalt -60 are used in cancer therapy
Iodine -131 measuring of thyroid activity and treatment of thyroid disorders
Americium -241 smoke detectors
The chemical properties of an element are determined primarily by the protons and electrons in
its atoms; neutrons do not take part in chemical changes under normal conditions. Therefore, isotopes
of the same element have similar chemistries, forming the same types of compounds and displaying
similar reactivities.
Molecular Models
Molecules are too small for us to observe directly. An effective means of visualizing them is by the use
of molecular models. Two standard types of molecular models are currently in use: ball-and-stick
models and space-filling models (Figure 2.11). In ball-and-stick model kits, the atoms are wooden or
plastic balls with holes in them. Sticks or springs are used to represent chemical bonds. The angles
they form between atoms approximate the bond angles in actual molecules. With exception of the H
atom, the balls are all the same size and each type of atom is represented by a specific color.
In space-filling models, atoms are represented by truncated balls held together by snap fasteners, so
that the bonds are not visible. The balls are proportional in size to atoms. The first step toward building
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a molecular model is writing the structural formula, which shows how atoms are bonded to one
another in a molecule. For example, it is known that each of the two H atoms is bonded to an O atom in
the water molecule. Therefore, the structural formula of water is H – O – H. A line connecting the two
atomic symbols represents a chemical bond.
Ball-and stick models show the three-dimensional arrangement of atoms clearly, and they are
fairly easy to construct. However, the balls are not proportional to the size of atoms. Furthermore, the
sticks greatly exaggerate the space between atoms in a molecule. Space-filling models are more
accurate because they show the variation in atomic size.
All chemicals in nature are composed of compounds. These chemicals may be simple or
complex. In order to understand these compounds, you need to understand first the constituents of
compounds. A chemical formula represents symbol and subscripts. It is a method of short-hand
writing for a name of a compound. The symbol in the chemical formula represents the name of the
atom in a compound while the subscript represents the number of atoms in the chemical formula.
In writing chemical formula, it is important that you know the oxidation number of an element.
The oxidation number or valence number is the charge of an atom for how many electrons could an
atom gain or lose. An atom that tends to gain electron has a negative (-) oxidation number, while an
atom that tends to lose electron has a positive oxidation number. Metals tend to lose electron that is
why metals has positive oxidation number. On the other hand, non-metals tend to gain electron, and
therefore with negative oxidation number.
Chemical Formula – a symbolic way of representing the composition of a substance using symbols of
the elements and subscripts to represent the appropriate number of atoms of each kind.
The following general procedures may be followed in writing the formula of a compound:
1. The symbol/formula of the ion with positive oxidation number is written first followed by the
symbol/formula of ions with negative oxidation number.
2. Balance the charges. The criss-cross method can help. The oxidation number of the positive ion
becomes the subscript of the negative ion. If the subscript is 1, it is not written. If the subscript of the
radical is greater than 1, the radical is enclosed in the parenthesis and the subscript is written outside
the parenthesis. The signs of the oxidation numbers are not written.
(Note: The teacher will show the criss-cross method for the given examples).
Observe how the above procedures are applied to the following examples:
a. Sodium chloride (NaCl)
b. Ferric oxide (Fe2O3)
c. Potassium nitrate (KNO3)
d. Magnesium phosphate - Mg3(PO4)2
3. If the oxidation numbers or charges of the positive and the negative ions are equal, these are
cancelled.
a. Magnesium oxide
b. aluminum phosphate
Exercise 1.
Complete the table below by writing the formula of the compounds to be formed by each combination.
After, write the name given the formulas of the following compounds.
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Mg 2+ 6 7 8 9 10
Name Name
1. 6.
2. 7.
3. 8.
4. 9.
5. 10.
Naming of Compounds
Some substances are familiar to us by their common or commercial names. We know baking
soda but only few knows that its chemical name is sodium bicarbonate. We often heard of milk of
magnesia but we seldom hear its chemical name – magnesium hydroxide.
I. IONIC COMPOUNDS
a. Binary Compounds
A binary compound consists of two elements. This kind of compound can be formed by non-
metals and metals or two non-metals.
b) Metals with variable oxidation number. Two methods of naming compound may be employed:
1. Old or Classical system
From Latin name of metal, drop - um, add –ous for lower oxidation number or – ic from
higher oxidation number followed by the stem of name of nonmetal plus ending of –ide.
Exercise 2.
A. Write the chemical formula of the following.
No. Cation Anion Chemical Formula Chemical Name
1 Mn 3+
O 2-
2 Ca2+ Br -
3 Ba2+ F-
4 K+ N3-
5 H+ P3-
A polyatomic ion is a group of atom that carries an electric charge. This is due to the need of
the electron to complete its stability. Generally, polyatomic ions are bonded by covalent bonds. When
these polyatomic ions combine with a metal – this is called polyatomic compound – a ternary
compound. A ternary compound is a type of compound consists of three or more atoms in a
compound.
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NO3- nitrate ClO2- Chlorite
SO3 2- sulfite ClO3- Chlorate
SO4 2- sulfate ClO4- Perchlorate
C2H3O2 acetate ion HCO3- Bicarbonate
CrO4 2- chromate CN - Cyanide
PO3 3- phosphite C2O4 2- Oxalate
PO4 3- Phosphate HSO3 - Bisulfite
CO3 2- Carbonate HSO4 - bisulfate
Example:
Ca (OH)2 – Ca2 OH - = Calcium hydroxide
Fe (OH)2 = ferrous hydroxide
= iron (II) hydroxide
Fe (OH)3 = ferric hydroxide
= iron (III) hydroxide
2+ -
Ag NO3 = Ag(NO3)2 = Silver Nitrate
Ag2+ ClO3 - = Ag(ClO3)2 = Silver Chlorate
Ba2+ PO3 3- = Ba3(PO3)2 = Barium Phosphite
Exercise 3.
A. Write the chemical formula of the following.
No. Cation Anion Chemical Formula Chemical Name
1 Be 2+ OH -
2 Fe 2+ ClO3 -
3 K+ NO2 -
4 K+ MnO4 -
5 Cu 2+ SO4 2-
B. Write the name of the following compounds.
No. Chemical Formula Chemical Name
1 Ba(ClO3)2
2 Hg(NO3)2
3 K2SO4
4 Al(CN)3
5 ZnC2O4 2-
IONIC COMPOUNDS may consist of more than two elements.They may contain oxoanions or negative
ions which consist of the element oxygen with other nonmetals. Oxoanions either end in suffixes –ate
or –ite depending on the number of oxygen atom that combined with nonmetal. Specifically, the suffix –
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ate denotes the anion with the greater number of oxygen atoms while the –ite suffix denotes the anion
with fewer number of oxygen atoms.
Several oxoanions may exist for a given non-metal. To distinguish one from the other, prefixes of per-
and hypo- may be attached to the other oxoanion name. The prefix per- is given to the oxoanion with
the greatest number of oxygen atoms while the prefix hypo- is given to the oxoanion with the least
number of oxygen atoms.
Eg. Oxygen and chlorine
ClO4 - - perchlorate (greatest no. of O atoms)
-
ClO3 - chlorate
ClO2 - - chlorite
-
ClO - hypochlorite (least no. of O atoms)
Oxygen and Iodine
IO4 - - periodate
IO3 - - iodate
IO2 - - iodite
IO - - hypoiodite
When oxoanions combine with metals, the name of the metal is written first followed by the name of the
oxoanion.
Eg. A. Ionic compounds with suffixes –ate and –ite
K2SO4 - potassium sulfate
K2SO3 -
potassium sulfite
NaNO3 sodium nitrate
NaNO2 sodium nitrite
B. Ionic compounds with prefixes per- and hypo-
KClO4 potassium perchlorate
Ca (BrO4)2 calcium perbromate
Ca (ClO)2 calcium hypochlorite
Al (BrO)3 aluminum hypobromate
Example:
CO - Carbon Monoxide SF6 - Sulfur Hexafluoride
CO2 - Carbon Dioxide N2O3 - Dinitrogen Trioxide
P2O5 - Diphosphorous Pentoxide CCl4 - Carbon Tetrachloride
Exercise 4
A. Name the following compounds.
1. NO ____________________________
2. SO2 ____________________________
3. P2O3 ____________________________
4. PCl5 ____________________________
5. I6Cl (g) ____________________________
6. NCl3 ____________________________
7. NI3 ____________________________
8. IF5 ____________________________
9. SeF4 ____________________________
10. CCl4 ____________________________
III. ACIDS
An acid can be described as a substance that yields hydrogen ions (H+) when dissolved in water.
1. Binary Acids: Hydrogen and a Non-metal
A Hydrogen element and a non-metal combination is considered a binary compound. A
Hydrogen element may combine to a more electronegative atom.
Prefix the word hydro- to the stem of the nonmetal and add –ic acid.
Example:
H+ Br - = HBr (g) = hydrobromic acid
H+ N3- = H3N (g) = hydronitric acid
H+ F - = HF (g) = hydrofluoric acid
Exercise 5
A. Write the formula of the following.
No. Cation Anion Chemical Formula Chemical Name
1 H+ Se 2-
2 H+ P 3-
3 H+ Te 2-
4 H+ Cl -
5 H+ I-
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2. Oxyacids: Hydrogen + polyatomic ions
Oxyacids are acids that contain hydrogen, oxygen, and another element (the central element)
When a Hydrogen element combines with a polyatomic ion, an Acid is formed. This acid is composed
of three or more elements.
Name the stem of the central atom in the polyatomic ion. Drop -ate and change to –ic, and drop –ite
and change to –ous and attach the name acid.
Example:
H+ + C2O4 2- - H2C2O4 - Oxalic Acid
H+ + CO3 2- - H2CO3 - Carbonic Acid
H+ + ClO3 - - HClO3 - Chloric Acid
H+ + ClO4 - - HClO4 - Perchloric Acid
H+ + NO2 - - HNO2 - Nitrous Acid
H+ + SO3 2- - H2SO3 - Sulfurous Acid
H+ + ClO2 - - HClO2 - Chlorous Acid
Exercise 6
A. Write the formula of the following.
No. Cation Anion Chemical Formula Chemical Name
1 H+ AlO2 -
2 H+ BrO3 -
3 H+ CNO -
4 H+ SnO2 2-
5 H+ AsO3 3-
V. Hydrates – compounds that have a specific number of H2O molecules attached to them.
Na2CO3 . 10H2O - sodium carbonate decahydrate
MgSO4 . 7H2O - magnesium sulfate heptahydrate
CuSO4 . 5H2O - copper (II) sulfate pentahydrate
Enrichment Activity
1. Fill in the following table with the formula of the compounds by combining each cation with each
anion. The formula of aluminum nitrate is provided as an example.
Cl - NO3 - SO4 2- PO4 3-
H+ 1 2 3 4
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Ag + 5 6 7 8
Ba 2+ 9 10 11 12
3+
Al 13 14 Al (NO3)3 15 16
+
NH4 17 18 19 20
Name of the given compounds
1. ____________________________________ 11. ______________________________________
2. ____________________________________ 12. ______________________________________
3. ____________________________________ 13. ______________________________________
4. ____________________________________ 14. ______________________________________
5. ____________________________________ 15. ______________________________________
6. ____________________________________ 16. ______________________________________
7. ____________________________________ 17. ______________________________________
8. ____________________________________ 18. ______________________________________
9. ____________________________________ 19. ______________________________________
10. ___________________________________ 20. ______________________________________
SrCl2
Fe 3+ NO2 -
SnBr4
Co 2+ PO4 3-
Hg2 2+ I–
Cu2CO3
Lithium Nitride
Al 3+ S 2-
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e. Ammonium molybdate _______________________ j. Sodium perchlorate
__________________
References:
Chang, R. and Overby, J. (2011) General Chemistry: The Essential Concepts. 6th Ed. New York: The
McGraw-Hill Companies, Inc.
Mingi, R. and Merlin, M. (2020) General Chemistry 1
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