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Ch.7 Entropy Change For An Ideal Gas (Reversible Process)

The document discusses four types of entropy changes for an ideal gas undergoing reversible processes: (1) constant volume, (2) constant pressure, (3) isothermal, and (4) adiabatic. Equations are provided relating the entropy change to properties like temperature, heat, and volume for each process type.

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0% found this document useful (0 votes)
51 views3 pages

Ch.7 Entropy Change For An Ideal Gas (Reversible Process)

The document discusses four types of entropy changes for an ideal gas undergoing reversible processes: (1) constant volume, (2) constant pressure, (3) isothermal, and (4) adiabatic. Equations are provided relating the entropy change to properties like temperature, heat, and volume for each process type.

Uploaded by

Iam A gnoom
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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ENTROPY CHANGE FOR

AN IDEAL GAS
(REVERSIBLE PROCESS)
Mr. Firas M. Younis
MSc Mechanical Engineering

1-) Constant Volume Process


P
1
𝛿𝑄 = 𝑚 𝑐𝑣 𝑑𝑇

𝛿𝑄
𝑑𝑆 =
𝑇 𝑟𝑒𝑣
2

2 2 v
𝛿𝑄
න 𝑑𝑆 = න
1 1 𝑇 T
𝑟𝑒𝑣
1
2
𝑑𝑇
𝑆2 − 𝑆1 = 𝑚 𝑐𝑣 න
1 𝑇 𝑟𝑒𝑣
2
𝑇2
𝑆2 − 𝑆1 = 𝑚 𝑐𝑣 ln
𝑇1
s

1
2-) Constant Pressure Process
P
𝛿𝑄 = 𝑚 𝑐𝑃 𝑑𝑇

𝛿𝑄 2 1
𝑑𝑆 =
𝑇 𝑟𝑒𝑣

2 2 v
𝛿𝑄
න 𝑑𝑆 = න
1 1 𝑇 T
𝑟𝑒𝑣
1
2
𝑑𝑇
𝑆2 − 𝑆1 = 𝑚 𝑐𝑃 න
1 𝑇 𝑟𝑒𝑣
2
𝑇2
𝑆2 − 𝑆1 = 𝑚 𝑐𝑃 ln
𝑇1
s

3-) Isothermal Process


𝑉2 𝑉2 P
𝑄 = 𝑃𝑉 ln 𝑄 = 𝑚𝑅𝑇 ln
𝑉1 𝑉1
2
𝛿𝑄
𝑑𝑆 =
𝑇 𝑟𝑒𝑣
1
2 2
න 𝛿𝑄 = 𝑇 න 𝑑𝑠 v
1 1
T
𝑄 = 𝑇 (𝑆2 − 𝑆1 )
𝑉2
𝑇 𝑆2 − 𝑆1 = 𝑚𝑅𝑇 ln 2 1
𝑉1
𝑉2 𝑃1
𝑆2 − 𝑆1 = 𝑚𝑅 ln = 𝑚𝑅 ln
𝑉1 𝑃2 s

2
4-) Adiabatic Process (Isentropic Process)
P
𝛿𝑄
𝑑𝑆 =
𝑇 𝑟𝑒𝑣 2
𝑑𝑆 = 0
𝑆2 − 𝑆1 = 0
1
𝑆2 = 𝑆1 v
T
2

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