SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Section 1: Identification

Product name : Sikadur®-31 CF Normal Part B

Product code : 100000006804

Manufacturer or supplier's details
Company : Sika (NZ) Ltd.
85-91 Patiki Road
Avondale
Auckland AKL 1026
Telephone : +64 9 820 2900
Emergency telephone num- : 0800 734 607
ber
Telefax : +64 9 828 4091
E-mail address : [email protected]
Recommended use of the chemical and restrictions on use
Product use : Adhesive, Product is not intended for consumer use

Section 2: Hazard identification

GHS Classification
Skin corrosion : 8.2B

Serious eye damage : 8.3A

Skin sensitisation : 6.5B

Carcinogenicity (Inhalation) : 6.7A

Aquatic toxicity (Acute or : 9.1D

Chronic)

Ecotoxic to terrestrial verte- : 9.3C

brates

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H350 May cause cancer by inhalation.
H401 Toxic to aquatic life.

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

H433 Harmful to terrestrial vertebrates.

Precautionary statements :
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P261 Avoid breathing mist or vapours.
P264 Wash skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 IF INHALED: Remove victim to fresh air and keep
at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physi-
cian.
P321 Specific treatment (see supplemental first aid instructions
on this label).
P333 + P313 If skin irritation or rash occurs: Get medical ad-
vice/ attention.
P363 Wash contaminated clothing before reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

Other hazards which do not result in classification

None known.

Section 3: Composition/information on ingredients

Substance / Mixture : Mixture

Components
Chemical name CAS-No. Concentration (% w/w)
Quartz (SiO2) 14808-60-7 >= 50 -< 70
benzyl alcohol 100-51-6 >= 1 -< 10
3-aminomethyl-3,5,5-trimethylcyclohexylamine 2855-13-2 >= 1 -< 10

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

3,6-diazaoctanethylenediamin 112-24-3 >= 2.5 -< 10

(1-methylethyl)-1,1'-biphenyl 25640-78-2 >= 2.5 -< 10
2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 >= 1 -< 10
Adduct IA (epoxy amine adduct) 68609-08-5 >= 1 -< 2.5
Quartz (SiO2) <5µm 14808-60-7 >= 0.1 -< 1

Section 4: First-aid measures

General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with difficul-
ty.

In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.
In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Keep eye wide open while rinsing.

If swallowed : Clean mouth with water and drink afterwards plenty of water.
Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.

Most important symptoms : Health injuries may be delayed.

and effects, both acute and corrosive effects
delayed sensitising effects
Allergic reactions
Dermatitis
See Section 11 for more detailed information on health effects
and symptoms.
May cause an allergic skin reaction.
Causes serious eye damage.
May cause cancer by inhalation.
Causes severe burns.

Notes to physician : Treat symptomatically.

Section 5: Fire-fighting measures

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.

Hazardous combustion prod- : No hazardous combustion products are known

ucts

Specific extinguishing meth- : Standard procedure for chemical fires.

ods

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

Hazchem Code : 2X

Section 6: Accidental release measures

Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Deny access to unprotected persons.
gency procedures

Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.

Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Keep in suitable, closed containers for disposal.

Section 7: Handling and storage

Advice on protection against : Normal measures for preventive fire protection.

fire and explosion

Advice on safe handling : Avoid exceeding the given occupational exposure limits (see
section 8).
Do not get in eyes, on skin, or on clothing.
For personal protection see section 8.
Persons with a history of skin sensitisation problems or asth-
ma, allergies, chronic or recurrent respiratory disease should
not be employed in any process in which this mixture is being
used.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Follow standard hygiene measures when handling chemical
products

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
When using do not eat or drink.
When using do not smoke.
Wash hands before breaks and at the end of workday.

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Conditions for safe storage : Store in original container.

Keep container tightly closed in a dry and well-ventilated
place.
Observe label precautions.
Store in accordance with local regulations.

Section 8: Exposure controls/personal protection

Components with workplace control parameters

Components CAS-No. Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
Quartz (SiO2) 14808-60-7 WES-TWA 0.05 mg/m3 NZ OEL
(Respirable
dust)
Further information: Confirmed carcinogen
Quartz (SiO2) <5µm 14808-60-7 WES-TWA 0.05 mg/m3 NZ OEL
(Respirable
dust)
Further information: Confirmed carcinogen
Personal protective equipment
Respiratory protection : Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
The filter class for the respirator must be suitable for the max-
imum expected contaminant concentration
(gas/vapour/aerosol/particulates) that may arise when han-
dling the product. If this concentration is exceeded, self-
contained breathing apparatus must be used.

Hand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is nec-
essary.

Eye protection : Safety eyewear complying with an approved standard should

be used when a risk assessment indicates this is necessary.

Skin and body protection : Choose body protection in relation to its type, to the concen-
tration and amount of dangerous substances, and to the spe-
cific work-place.

Section 9: Physical and chemical properties

Appearance : paste

Colour : dark grey

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Odour : amine-like

Odour Threshold : No data available

pH : > 11 (20 °C (68 °F))

Concentration: 500 g/l 50 %

Melting point/range / Freezing : No data available

point
Boiling point/boiling range : No data available

Flash point : > 101 °C (214 °F)

(Method: closed cup)

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : 0.07 hPa

Relative vapour density : No data available

Density : ca. 1.94 g/cm3 (20 °C (68 °F))

Solubility(ies)
Water solubility : insoluble

Solubility in other solvents : No data available

Partition coefficient: n- : No data available

octanol/water
Auto-ignition temperature : Not applicable

No data available

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : No data available

Viscosity, kinematic : > 20.5 mm2/s ( 40 °C (104 °F))

Explosive properties : No data available

Oxidizing properties : No data available

Volatile organic compounds : Directive 2010/75/EU of 24 November 2010 on industrial

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

emissions (integrated pollution prevention and control)

Volatile organic compounds (VOC) content: 8.13% w/w

Section 10: Stability and reactivity

Reactivity : No dangerous reaction known under conditions of normal use.

Chemical stability : The product is chemically stable.

Possibility of hazardous reac- : Stable under recommended storage conditions.

tions

Conditions to avoid : No data available

Incompatible materials : No data available

Section 11: Toxicological information

Acute toxicity
Not classified based on available information.
Components:
benzyl alcohol:
Acute oral toxicity : LD50 Oral (Rat): 1,620 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 4.178 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist

3-aminomethyl-3,5,5-trimethylcyclohexylamine:
Acute oral toxicity : LD50 Oral (Rat): 1,030 mg/kg

Acute inhalation toxicity : LC50 (Rat): > 10 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist

Acute dermal toxicity : LD50 (Rabbit): > 2,000 - 5,000 mg/kg

3,6-diazaoctanethylenediamin:
Acute oral toxicity : LD50 Oral (Rat): 1,716 mg/kg

Acute dermal toxicity : LD50 Dermal (Rabbit): 1,465 mg/kg

(1-methylethyl)-1,1'-biphenyl:
Acute oral toxicity : LD50 Oral (Rat): 4,650 mg/kg
Method: OECD Test Guideline 401

2,4,6-tris(dimethylaminomethyl)phenol:
Acute oral toxicity : LD50 Oral (Rat): 2,169 mg/kg

Adduct IA (epoxy amine adduct):

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Acute oral toxicity : LD50 Oral (Rat, female): 300 - 2,000 mg/kg
Method: OECD Test Guideline 423

Skin corrosion/irritation
Causes severe burns.
Components:
2,4,6-tris(dimethylaminomethyl)phenol:
Species : Rabbit
Assessment : Corrosive
Method : OECD Test Guideline 404

Serious eye damage/eye irritation

Causes serious eye damage.
Components:
2,4,6-tris(dimethylaminomethyl)phenol:
Species : Rabbit
Assessment : Causes serious eye damage.

Respiratory or skin sensitisation

Skin sensitisation
May cause an allergic skin reaction.
Respiratory sensitisation
Not classified based on available information.

Chronic toxicity

Germ cell mutagenicity

Not classified based on available information.
Carcinogenicity
May cause cancer by inhalation.
Reproductive toxicity
Not classified based on available information.
STOT - single exposure
Not classified based on available information.
STOT - repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Section 12: Ecological information

Ecotoxicity

Components:
benzyl alcohol:
Toxicity to fish : LC50 (Fish): > 100 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h

3-aminomethyl-3,5,5-trimethylcyclohexylamine:
Toxicity to algae/aquatic : ErC50 (Desmodesmus subspicatus (green algae)): > 10 - 100
plants mg/l
Exposure time: 72 h

NOEC (Desmodesmus subspicatus (green algae)): 1.5 mg/l

Exposure time: 72 h

3,6-diazaoctanethylenediamin:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 100 mg/l
Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia (water flea)): 10 - 100 mg/l
aquatic invertebrates Exposure time: 48 h

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (green algae)): 10 -

plants 100 mg/l
Exposure time: 72 h

(1-methylethyl)-1,1'-biphenyl:
Toxicity to daphnia and other : LC50 (Daphnia magna (Water flea)): 0.167 mg/l
aquatic invertebrates Exposure time: 48 h

2,4,6-tris(dimethylaminomethyl)phenol:
Toxicity to algae/aquatic : EC50 (Scenedesmus capricornutum (fresh water algae)): > 10
plants - 100 mg/l
Exposure time: 72 h

Adduct IA (epoxy amine adduct):

Toxicity to algae/aquatic : EC50 (Pseudokirchneriella subcapitata (algae)): 3.13 mg/l
plants Exposure time: 72 h

Toxicity to fish (Chronic tox- : LC50 (Danio rerio (zebra fish)): 1.62 mg/l
icity) Exposure time: 96 h

Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 1.75 mg/l
aquatic invertebrates (Chron- Exposure time: 48 h
ic toxicity)

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

Persistence and degradability

No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Other adverse effects

Product:
Additional ecological infor- : An environmental hazard cannot be excluded in the event of
mation unprofessional handling or disposal.
Harmful to aquatic life with long lasting effects.

Section 13: Disposal considerations

Disposal methods
Waste from residues : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with chemi-
cal or used container.
Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.

Section 14: Transport information

International Regulations

IATA-DGR
UN/ID No. : UN 1759
Proper shipping name : Corrosive solid, n.o.s.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine, (1-
methylethyl)-1,1'-biphenyl)
Class : 8
Packing group : III
Labels : Corrosive
Packing instruction (cargo : 864
aircraft)
Packing instruction (passen- : 860
ger aircraft)
IMDG-Code
UN number : UN 1759
Proper shipping name : CORROSIVE SOLID, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine, (1-

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

methylethyl)-1,1'-biphenyl)
Class : 8
Packing group : III
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
IMDG-Code
Alkalis
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
National Regulations

NZS 5433
UN number : UN 1759
Proper shipping name : CORROSIVE SOLID, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine, (1-
methylethyl)-1,1'-biphenyl)
Class : 8
Packing group : III
Labels : 8
Hazchem Code : 2X
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely based
upon the properties of the unpackaged material as it is described within this Safety Data Sheet.
Transportation classifications may vary by mode of transportation, package sizes, and variations in
regional or country regulations.

Section 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture
International Chemical Weapons Convention (CWC) : Not applicable
Schedules of Toxic Chemicals and Precursors
HSNO Approval Number
HSR002660
HSW Controls
Certified handler certificate not required.
Tracking hazardous substance not required.
Refer to the Health and Safety at Work (Hazardous Substances) Regulations 2017, for further infor-
mation.

The components of this product are reported in the following inventories:

NZIoC : On the inventory, or in compliance with the inventory

Section 16: Other information

Full text of other abbreviations

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SAFETY DATA SHEET

Sikadur®-31 CF Normal Part B

Version Revision Date: SDS Number: Date of last issue: 2020/04/30

3.0 2022/02/15 100000006804 Date of first issue: 2017/10/18

NZ OEL : New Zealand. Workplace Exposure Standards for Atmospher-

ic Contaminants
NZ OEL / WES-TWA : Workplace Exposure Standard - Time Weighted average
ADG : Australian Dangerous Goods Code.
ADR : European Agreement concerning the International Carriage of
Dangerous Goods by Road
CAS : Chemical Abstracts Service
DNEL : Derived no-effect level
EC50 : Half maximal effective concentration
GHS : Globally Harmonized System
IATA : International Air Transport Association
IMDG : International Maritime Code for Dangerous Goods
LD50 : Median lethal dosis (the amount of a material, given all at
once, which causes the death of 50% (one half) of a group of
test animals)
LC50 : Median lethal concentration (concentrations of the chemical in
air that kills 50% of the test animals during the observation
period)
MARPOL : International Convention for the Prevention of Pollution from
Ships, 1973 as modified by the Protocol of 1978
OEL : Occupational Exposure Limit
PBT : Persistent, bioaccumulative and toxic
PNEC : Predicted no effect concentration
REACH : Regulation (EC) No 1907/2006 of the European Parliament
and of the Council of 18 December 2006 concerning the Reg-
istration, Evaluation, Authorisation and Restriction of Chemi-
cals (REACH), establishing a European Chemicals Agency
SVHC : Substances of Very High Concern
vPvB : Very persistent and very bioaccumulative

The information contained in this Safety Data Sheet corresponds to our level of knowledge at the
time of publication. All warranties are excluded. Our most current General Sales Conditions shall
apply. Please consult the product data sheet prior to any use and processing.

Changes as compared to previous version !

NZ / EN

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