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Model Question Paper Organic Chemistry-2nd Sem

This document contains a model question paper for organic chemistry 2nd semester. It includes the following types of questions: [1] short answer questions testing IUPAC naming, identification of R/S configuration, and completion of chemical reactions; [2] longer answer questions requiring drawing of molecular shapes, explanation of concepts like boiling points and acidity, drawing of energy diagrams, and more; [3] multi-part questions requiring explanation of reaction mechanisms and concepts in organic chemistry. The question paper tests a wide range of topics in organic chemistry including functional groups, stereochemistry, reaction mechanisms, isomerism and more.

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Pragyan Chutia
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2K views4 pages

Model Question Paper Organic Chemistry-2nd Sem

This document contains a model question paper for organic chemistry 2nd semester. It includes the following types of questions: [1] short answer questions testing IUPAC naming, identification of R/S configuration, and completion of chemical reactions; [2] longer answer questions requiring drawing of molecular shapes, explanation of concepts like boiling points and acidity, drawing of energy diagrams, and more; [3] multi-part questions requiring explanation of reaction mechanisms and concepts in organic chemistry. The question paper tests a wide range of topics in organic chemistry including functional groups, stereochemistry, reaction mechanisms, isomerism and more.

Uploaded by

Pragyan Chutia
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd
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Model Question Paper

Organic chemistry-2nd sem.

Q. Write the following question. 1×4

1. Write IUPAC name of the following compounds.

2. Indentified as a R or S

OH

NH3 . COOH

C2H5OH

3. Complete the following reactions

2CH3-CH2-Cl. + Na(dry ethar)--------→

4. Predict the aromiticity

Q.Answer the following 2×10=20

1. Drow the shape of following molecules.

a) CH3=CH=CH2. b). CH3CH=O

2. Why NF3 has higher boiling point than NH3

3. In case of phinol and cyclohexane which one is more acidic and why ?

4. Drow the energy level diagram of two step endothermic reactions.

~OR

1.
What do you mean by Carben. Drow the different types of shapess of carbene.

5. Convert the following in to Ficher projectio.

Cl NH3. CH3 C2H5

C C

CH3. OH. H OH

6. Define alternating axis of symmetry with the help of example.

7. Write short note on geometrical isomer of oxime compounds.

8. Write short note on Weldon inversion.

9. Explain that the presence of chiral center is neither sufficient nor necessary condition on showing an
enantiomers.

10. Explaim (±) tartaric acide can convert in to optically active compounds.

~OR

What do you mean by gemetrical isomer ? Write two necessary condition on showing gemetrical
isomerism.

Q. Answer the following. (15×2=30)

1. Write the mechanism of chlorination of methane.

2. How would you prepared butane by court house synthesis ?

3. How would you prepared acidic acid and formaldehyde by ozonolysis ?

4. How would you prepared alkene by pyrolysis of eeste ?

5. Discuss the mechanics of hypothalamus acid in unsymmetrical alkene.

6. Addition of bromide in presence of CCl4 to cis butanr give (±)2,3 dibromobutane,while trans butane
give meso 2,3 dibromobutane.Explain with mechanism.

7.Identify X,Y and Z

CH3CHCH2+ NaNH3,CH3CH2Br →X H2/PdBaSO4→Y alc.KMnO4 →Z

8. Using hydrobiration reaction prepared butanol

9. Explain Hoffmann’s bromide elemination reaction with example.

~OR

Write short note on wittting reactions.

10. Write short note on Bayera statin theory.

1.
11. With the help of Newmann projection formula,drow the possible confirmation of n-butane and give
their name.

12. Why tartiary alkyl butyl always exists in equitorial possition of cyclobutane.

13. Explain 1,3 diaxial integration in chair form of methyl cycolhexane.

14. Define angular strain.Calculate the angular strain of cyclobutane.

15. Drow the energy profile diagram of confirmation of cycolhexane.why boat confirmation is less
stable than chair.

Q. Answer the following.:2×4=8

1. Classifiy as aromatic or not

2. Write the mechanism and complete the reactio

+ CH3CH2CH2Cl(Anh AlCl3) ------------------------------→

3 .Chlorine is o/p directing towerds the electrophilic substitution reaction and ring deactivate,Explain.

4. Indemnity the following as a o/p directing or mata directing

a) -CH3. b) OCH3. c) OH. d) NH3

----------------********------------------

1.
1.

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