What Is Hazardous Waste
What Is Hazardous Waste
What Is Hazardous Waste
Hazardous waste is waste that has substantial or potential threats to public health or the
environment.
Hazardous wastes may be found in different physical states such as gaseous, liquids, or solids.
A hazardous waste is a special type of waste because it cannot be disposed of by common
means like other by-products of our everyday lives. Depending on the physical state of the
waste, treatment and solidification processes might be required.
The international community has defined the responsible management of hazardous waste and
chemicals as an important part of developing a sustainable economy, with Sustainable
Development Goal.
The Target measures two indicators to "achieve the environmentally sound management of
chemicals and all wastes throughout their life cycle".
When it comes to listed wastes, there are four sub-types of listed wastes. Among
these are wastes that fall into the F-list, K-list, P-list and the U-list.
F-List Wastes
Simply put, the F-list includes any wastes that have a nonspecific source, but are
produced from manufacturing and industrial processes. Because they can be
generated in various sectors of industry and manufacturing, their ultimate source
becomes nonspecific.
Of the F-list wastes, depending on the operations that produce the wastes, they can
be divided into seven groups. These source identification groups are as follows:
1. Dioxin-bearing wastes
2. Wood-preserving wastes
3. Spent solvent wastes
4. Petroleum refinery wastewater treatment sludges
5. Chlorinated aliphatic hydrocarbons production
6. Multisource leachate
7. Electroplating and other metal finishing wastes
K-List Wastes
Unlike F-list wastes, K-list wastes are specific wastes that have specific industry
sources. Particular production and treatment processes generate certain types of
wastewater and sludge that become distinguishable as hazardous wastes.
Since their sources are specific, they are classified as source-specific hazardous
wastes. The top 13 industries that generate K-lists are seen below:
2. Characteristic Wastes
Unlike listed wastes, these characteristic wastes follow the identification process
depending on the characteristics they display. Below are the four characteristics that
are identified with wastes.
1. Ignitability
• Any waste (typically acids and bases) that can rust and decompose and has the ability
to melt through steel materials.
• Examples of this include aqueous wastes with an acidity level of equal to or less than
2 pH or equal to or greater than 12.5 pH.
3. Reactivity
1. Class 1: Explosives
2. Class 2: Gases
3. Class 3: Flammable Liquids
4. Class 4: Flammable Solids or Substances
5. Class 5: Oxidizing Substances and Organic Peroxides
6. Class 6: Toxic and Infectious Substances
7. Class 7: Radioactive
8. Class 8: Corrosive Substances
9. Class 9: Miscellaneous Dangerous Substances and Articles
4. Mixed Wastes
Lastly, mixed wastes are wastes that contain both hazardous as well as radioactive
components. Because mixed wastes involve hazardous and radioactive materials,
their treatment and disposals vary.
Mixed wastes are identified as one of three types of mixed waste according to the
US DOE. They can be low-level mixed waste (LLMW), high-level mixed waste
(HLW) and mixed transuranic waste (MTRU).
It’s important to know the proper disposal methods if your company or organization
is producing wastes that are deemed hazardous.
Now that you know all of the types of wastes, their categorizations/classifications
and examples of each, be sure you’re treating their removal properly. If you need
analytical testing services done to determine the levels of hazardousness of your
wastes, then get in touch with Environmental Hazards Services.
Characteristic Hazardous Wastes A RCRA characteristic hazardous waste is a solid waste that
exhibits at least one of four characteristics defined in 40 CFR Part 261 subpart C — ignitability
(D001), corrosivity (D002), reactivity (D003), and toxicity (D004 - D043).
• Ignitability– Ignitable wastes can create fires under certain conditions, are spontaneously
combustible, or have a flash point less than 60 °C (140 °F). Examples include waste oils and
used solvents. For more details, see 40 CFR §261.21. Test methods that may be used to
determine ignitability include the Pensky-Martens Closed-Cup Method for Determining
Ignitability, the Setaflash Closed-Cup Method for Determining Ignitability, the Ignitability of
Solids, Test Method for Oxidizing Solids, and the Test Method to Determine Substances Likely
to Spontaneously Combust.
• Corrosivity – Corrosive wastes are acids or bases (pH less than or equal to 2, or greater than
or equal to 12.5) and/or are capable of corroding metal containers, such as storage tanks, drums,
and barrels. Battery acid is an example. For more details, see 40 CFR §261.22. The test method
that may be used to determine the ability of a waste to corrode steel is the Corrosivity Towards
Steel (Method 1110A)(PDF)(6 pp, 37K). To measure pH electrometrically, see Method 9040C
(PDF)(5 pp, 25K).
• Reactivity – Reactive wastes are unstable under "normal" conditions. They can cause
explosions, undergo violent reactions, generate toxic fumes, gases, or vapors or explosive
mixtures when heated, compressed, or mixed with water. Examples include lithiumsulfur
batteries and explosives.
• Toxicity – Toxic wastes are harmful or fatal when ingested or absorbed (e.g., containing
mercury, lead, etc.). When toxic wastes are land disposed, contaminated liquid may leach from
the waste and pollute ground water. Toxicity is defined through a laboratory 5 procedures
called the Toxicity Characteristic Leaching Procedure (TCLP). The TCLP helps identify
wastes likely to leach concentrations of contaminants that may be harmful to human health or
the environment.
Some hazardous wastes can be recycled into new products. Examples may include lead–acid
batteries or electronic circuit boards. When heavy metals in these types of ashes go through the
proper treatment, they could bind to other pollutants and convert them into easier-to-dispose
solids, or they could be used as pavement filling. Such treatments reduce the level of threat of
harmful chemicals, like fly and bottom ash, while also recycling the safe product. There is a
recycling center facility in Oxnard, CA. The city does not charge for any hazardous materials
being disposed of, but there is a limit to how much you can bring per month. Other than
hazardous waste, the city also allows you to dispose of electronic waste, light-bulbs, and
batteries.
2. Incineration, destruction and waste-to-energy
Hazardous waste may be "destroyed". For example, by incinerating them at a high temperature,
flammable wastes can sometimes be burned as energy sources. For example, many cement
kilns burn hazardous wastes like used oils or solvents. Today, incineration treatments not only
reduce the amount of hazardous waste, but also generate energy from the gases released in the
process. It is known that this particular waste treatment releases toxic gases produced by the
combustion of byproduct or other materials which can affect the environment. However,
current technology has developed more efficient incinerator units that control these emissions
to a point where this treatment is considered a more beneficial option. There are different types
of incinerators which vary depending on the characteristics of the waste. Starved air
incineration is another method used to treat hazardous wastes. Just like in common incineration,
burning occurs, however controlling the amount of oxygen allowed proves to be significant to
reduce the amount of harmful byproducts produced. Starved air incineration is an improvement
of the traditional incinerators in terms of air pollution. Using this technology, it is possible to
control the combustion rate of the waste and therefore reduce the air pollutants produced in the
process.
3. Hazardous waste landfill (sequestering, isolation, etc.)
Hazardous waste may be sequestered in a hazardous waste landfill or permanent disposal
facility. "In terms of hazardous waste, a landfill is defined as a disposal facility or part of a
facility where hazardous waste is placed or on land and which is not a pile, a land treatment
facility, a surface impoundment, an underground injection well, a salt dome formation, a salt
bed formation, an underground mine, a cave, or a corrective action management unit (40 CFR
260.10)."
4. Pyrolysis
Some hazardous waste types may be eliminated using pyrolysis in a high temperature not
necessarily through electrical arc but starved of oxygen to avoid combustion. However, when
electrical arc is used to generate the required ultra heat (in excess of 3000 degree C temperature)
all materials (waste) introduced into the process will melt into a molten slag and this technology
is termed Plasma not pyrolysis. Plasma technology produces inert materials and when cooled
solidifies into rock like material. These treatment methods are very expensive but may be
preferable to high temperature incineration in some circumstances such as in the destruction of
concentrated organic waste types, including PCBs, pesticides and other persistent organic
pollutants.
Treatment, storage, and disposal
Several options are available for hazardous-waste management. The most desirable is to
reduce the quantity of waste at its source or to recycle the materials for some other
productive use. Nevertheless, while reduction and recycling are desirable options, they are
not regarded as the final remedy to the problem of hazardous-waste disposal. There will
always be a need for treatment and for storage or disposal of some amount of hazardous
waste.
Treatment
Hazardous waste can be treated by chemical, thermal, biological, and physical methods.
Chemical methods include ion exchange, precipitation, oxidation and reduction, and
neutralization. Among thermal methods is high-temperature incineration, which not only
can detoxify certain organic wastes but also can destroy them. Special types of thermal
equipment are used for burning waste in either solid, liquid, or sludge form. These include
the fluidized-bed incinerator, multiple-hearth furnace, rotary kiln, and liquid-injection
incinerator. One problem posed by hazardous-waste incineration is the potential for air
pollution.
Biological treatment of certain organic wastes, such as those from the petroleum industry,
is also an option. One method used to treat hazardous waste biologically is called land
farming. In this technique the waste is carefully mixed with surface soil on a suitable tract
of land. Microbes that can metabolize the waste may be added, along with nutrients. In
some cases a genetically engineered species of bacteria is used. Food or forage crops are
not grown on the same site. Microbes can also be used for stabilizing hazardous wastes on
previously contaminated sites; in that case the process is called bioremediation.
The chemical, thermal, and biological treatment methods outlined above change the
molecular form of the waste material. Physical treatment, on the other hand, concentrates,
solidifies, or reduces the volume of the waste. Physical processes include evaporation,
sedimentation, flotation, and filtration. Yet another process is solidification, which is
achieved by encapsulating the waste in concrete, asphalt, or plastic. Encapsulation
produces a solid mass of material that is resistant to leaching. Waste can also be mixed with
lime, fly ash, and water to form a solid, cementlike product.
Temporary on-site waste storage facilities include open waste piles and ponds or lagoons.
New waste piles must be carefully constructed over an impervious base and must comply
with regulatory requirements similar to those for landfills. The piles must be protected from
wind dispersion or erosion. If leachate is generated, monitoring and control systems must
be provided. Only noncontainerized solid, nonflowing waste material can be stored in a
new waste pile, and the material must be landfilled when the size of the pile becomes
unmanageable.
A common type of temporary storage impoundment for hazardous liquid waste is an open
pit or holding pond, called a lagoon. New lagoons must be lined with impervious clay soils
and flexible membrane liners in order to protect groundwater. Leachate collection systems
must be installed between the liners, and groundwater monitoring wells are required.
Except for some sedimentation, evaporation of volatile organics, and possibly some surface
aeration, open lagoons provide no treatment of the waste. Accumulated sludge must be
removed periodically and subjected to further handling as a hazardous waste.
Many older, unlined waste piles and lagoons are located above aquifers used for
public water supply, thus posing significant risks to public health and environmental
quality. A large number of these old sites have been identified and scheduled for cleanup,
or remediation, around the world.
Secure landfills
Landfilling of hazardous solid or containerized waste is regulated more stringently than
landfilling of municipal solid waste. Hazardous wastes must be deposited in so-
called secure landfills, which provide at least 3 metres (10 feet) of separation between the
bottom of the landfill and the underlying bedrock or groundwater table. A secure
hazardous-waste landfill must have two impermeable liners and leachate collection
systems. The double leachate collection system consists of a network of perforated pipes
placed above each liner. The upper system prevents the accumulation of leachate trapped
in the fill, and the lower serves as a backup. Collected leachate is pumped to a treatment
plant. In order to reduce the amount of leachate in the fill and minimize the potential for
environmental damage, an impermeable cap or cover is placed over a finished landfill.
it includes a series of deep wells drilled in and around the site is also required. The wells
allow a routine program of sampling and testing to detect any leaks or groundwater
contamination. If a leak does occur, the wells can be pumped to intercept the polluted water
and bring it to the surface for treatment.
One option for the disposal of liquid hazardous waste is deep-well injection, a procedure
that involves pumping liquid waste through a steel casing into a porous layer of limestone
or sandstone. High pressures are applied to force the liquid into the pores and fissures of
the rock, where it is to be permanently stored. The injection zone must lie below a layer of
impervious rock or clay, and it may extend more than 0.8 km (0.5 mile) below the surface.
Deep-well injection is relatively inexpensive and requires little or no pretreatment of the
waste, but it poses a danger of leaking hazardous waste and eventually polluting subsurface
water supplies.
Remedial action
Disposal of hazardous waste in unlined pits, ponds, or lagoons poses a threat to human
health and environmental quality. Many such uncontrolled disposal sites were used in the
past and have been abandoned. Depending on a determination of the level of risk, it may
be necessary to remediate those sites. In some cases, the risk may require emergency action.
In other instances, engineering studies may be required to assess the situation thoroughly
before remedial action is undertaken.
One option for remediation is to completely remove all the waste material from the site and
transport it to another location for treatment and proper disposal. This so-called off-site
solution is usually the most expensive option. An alternative is on-site remediation, which
reduces the production of leachate and lessens the chance of groundwater contamination.
On-site remediation may include temporary removal of the hazardous waste, construction
of a secure landfill on the same site, and proper replacement of the waste. It may also
include treatment of any contaminated soil or groundwater. Treated soil may be replaced
on-site and treated groundwater returned to the aquifer by deep-well injection.
A less costly alternative is full containment of the waste. This is done by placing an
impermeable cover over the hazardous-waste site and by blocking the lateral flow of
groundwater with subsurface cutoff walls. It is possible to use cutoff walls for this purpose
when there is a natural layer of impervious soil or rock below the site. The walls are
constructed around the perimeter of the site, deep enough to penetrate to the impervious
layer. They can be excavated as trenches around the site without moving or disturbing the
waste material. The trenches are filled with a bentonite clay slurry to prevent their collapse
during construction, and they are backfilled with a mixture of soil and cement that solidifies
to form an impermeable barrier. Cutoff walls thus serve as vertical barriers to the flow of
water, and the impervious layer serves as a barrier at the bottom.
Hazardous waste disposal began to grip public consciousness in the US in the mid-1900s
for four key reasons:
These growing concerns eventually led to the Resource Conservation and Recovery Act
(RCRA) passage of 1976. The RCRA outlined a model of environmentally sound and cost-
effective approaches for managing and disposing of hazardous wastes.
Due to the health and environmental risks posed by this waste, the RCRA framework was
comprehensive. Based on its mandates, the EPA created a “cradle-to-grave” regulatory
program that managed its full lifecycle:
• Production
• Transport
• Treatment
• Storage
• Disposal.
This article focuses on the final stage: disposal. There are a few different standard
hazardous waste disposal methods. Another increasingly popular way to handle it is to
recycle it. While recycling is preferable to other methods, it is not always viable. Treatment
is another way to approach waste rather than simply disposing of it. Below, we
explore treatment options and the three top disposal methods (along with assessing
sustainability), closing out with recycling. By exploring these options, you can figure out
which form of hazardous waste disposal is best for your business.
Ways to Dispose of Hazardous Waste
The first three categories transform waste at the molecular level, while the fourth results in
waste solidification, concentration, or volume decrease.
To destroy some organic wastes in addition to detoxifying them, you can use high-
temperature incineration. Equipment used for this purpose includes:
• liquid-injection incinerators,
• multiple-hearth furnaces,
• fluidized-bed incinerators, and
• rotary kilns
Landfarming can be used to treat organic wastes from the petroleum industry or elsewhere.
An area of land is designated, and the surface soil is conscientiously blended with the waste.
Nutrients and waste-metabolizing microbes can be added to enhance treatment.
The only way this method is compliant is when the hazardous waste is brought to mines
that are either inactive or partially active (along with meeting additional geological and
technical specifications). Many companies need to dispose of radioactive waste, whether
from medical treatments, laboratory experiments, nuclear fuel production, or radioactive
ore mining. For those cases, this method is considered a strong, cost-effective option.
These hazardous waste facilities will vary in their sustainability, per the EPA. The agency
is responsible for protecting people and the natural world by verifying that these units’
design, operation, and maintenance adhere to its standards.
These landfills are lined with clay, HDPE, or other non-porous materials to prevent the
waste from leaching into the ground. Wind dispersal controls, leak protection systems, and
a double liner are additional protections so that humans and the environment come into
contact with as little of the waste as possible.
A federal analysis revealed that 1.5 tons of hazardous waste were managed through
recycling in 2017. Recycling is preferable to disposing of hazardous wastes for numerous
reasons. It results in economic benefits, decreases our raw material reliance nationally,
conserves natural resources, prevents pollution, and cuts energy use.
Are you considering your options for hazardous waste disposal? At AOTC, we design our
industrial waste management services to control your costs and minimize your long-term
liability. We even tailor our programs to meet your specific needs. Contact us today to
discover how we can help your business.
Transboundary movement:
What is the meaning of Transboundary movement?
Term. Any movement of hazardous wastes or other wastes from an area under the
national jurisdiction of one State to or through an area under the national jurisdiction of
another State or to or through an area not under the national jurisdiction of any State,
provided at least two States are involved in the movement.
The overarching objective of the Basel Convention is to protect human health and the
environment against the adverse effects of hazardous wastes. Its scope of application covers a
wide range of wastes defined as “hazardous wastes” based on their origin and/or composition
and their characteristics, as well as two types of wastes defined as “other wastes” - household
waste and incinerator ash.
The provisions of the Convention center around the following principal aims:
These Rules came into effect in the year 1989 and have been amended later in the years 2000,
2003 and with final notification of the Hazardous Waste ( Management, Handling and
Transboundary Movement) Rules, 2008 in supersession of former notification.