Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718 date of compilation: 2017-03-01

Version: 2.0 en Revision: 2022-04-06
Replaces version of: 2017-03-01
Version: (1)

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Iron ≥99,5 %, p.a., ~10 µm, powder
Article number 3718
Registration number (REACH) 01-2119462838-24-xxxx
EC number 231-096-4
CAS number 7439-89-6
Alternative name(s) Carbonyl Iron powder
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Laboratory chemical
Laboratory and analytical use
Uses advised against: Do not use for products which come into contact
with foodstuffs. Do not use for private purposes
(household).
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany

Telephone:+49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: [email protected]
Website: www.carlroth.de
Competent person responsible for the safety data :Department Health, Safety and Environment
sheet:
e-mail (competent person): [email protected]
1.4 Emergency telephone number
Name Street Postal Telephone Website
code/city

National Poisons Information Dudley Rd B187QH 844 892 0111

Service Birmingham
City Hospital

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Classification according to Regulation (EC) No 1272/2008 (CLP)
Section Hazard class Cat- Hazard class and Hazard
egory category statement

2.7 Flammable solid 2 Flam. Sol. 2 H228

2.11 Self-heating substance and mixture 1 Self-heat. 1 H251

For full text of abbreviations: see SECTION 16

2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)

Signal word Danger

Pictograms

GHS02

Hazard statements
H228 Flammable solid
H251 Self-heating: may catch fire

Precautionary statements
Precautionary statements - prevention
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking
P243 Take action to prevent static discharges
Precautionary statements - response
P370+P378 In case of fire: Use metal fire powder to extinguish

Labelling of packages where the contents do not exceed 125 ml

Signal word: Danger

Symbol(s)

H251 Self-heating: may catch fire.

2.3 Other hazards

Results of PBT and vPvB assessment
According to the results of its assessment, this substance is not a PBT or a vPvB.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

SECTION 3: Composition/information on ingredients

3.1 Substances
Name of substance Iron
Molecular formula Fe
Molar mass 55,85 g/mol

REACH Reg. No 01-2119462838-24-xxxx

CAS No 7439-89-6
EC No 231-096-4

SECTION 4: First aid measures

4.1 Description of first aid measures

General notes
Take off contaminated clothing.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.
Following skin contact
Rinse skin with water/shower. In all cases of doubt, or when symptoms persist, seek medical advice.
Following eye contact
Rinse cautiously with water for several minutes. In all cases of doubt, or when symptoms persist, seek
medical advice.
Following ingestion
Rinse mouth. Call a doctor if you feel unwell.
4.2 Most important symptoms and effects, both acute and delayed
Irritant effects, Nausea, Vomiting
4.3 Indication of any immediate medical attention and special treatment needed
none

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

co-ordinate firefighting measures to the fire surroundings
D-powder, sand

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Unsuitable extinguishing media
water, foam
5.2 Special hazards arising from the substance or mixture
Self-heating: may catch fire.
5.3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas-
onable distance. Wear self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Avoid contact with skin, eyes and clothes. Do not breathe dust.
6.2 Environmental precautions
Keep away from drains, surface and ground water.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains. Take up mechanically.
Advice on how to clean up a spill
Take up mechanically. Control of dust.
Other information relating to spills and releases
Place in appropriate containers for disposal.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Avoid dust formation.
Measures to prevent fire as well as aerosol and dust generation
Removal of dust deposits.
Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
When using do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Store in a dry place. Keep container tightly closed.
Incompatible substances or mixtures
Observe hints for combined storage.
Protect against external exposure, such as
humidity

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Consideration of other advice:
Ventilation requirements
Use local and general ventilation.
Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C
7.3 Specific end use(s)
No information available.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Coun Name of agent CAS No Identifi- TWA STEL Ceil- Nota- Source
try er [mg/ [mg/ ing-C tion
m³] m³] [mg/
m³]

GB dust WEL 10 i EH40/2005

GB dust WEL 4 r EH40/2005

Notation
Ceiling-C Ceiling value is a limit value above which exposure should not occur
i Inhalable fraction
r Respirable fraction
STEL Short-term exposure limit: a limit value above which exposure should not occur and which is related to a 15-
minute period (unless otherwise specified)
TWA Time-weighted average (long-term exposure limit): measured or calculated in relation to a reference period of 8
hours time-weighted average (unless otherwise specified)

8.2 Exposure controls

Individual protection measures (personal protective equipment)
Eye/face protection

Use safety goggle with side protection.

Skin protection

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
For special purposes, it is recommended to check the resistance to chemicals of the protective gloves
mentioned above together with the supplier of these gloves. The times are approximate values from
measurements at 22 ° C and permanent contact. Increased temperatures due to heated substances,
body heat etc. and a reduction of the effective layer thickness by stretching can lead to a consider-
able reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times
larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply
only to the pure substance. When transferred to substance mixtures, they may only be considered as

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

a guide.
• type of material
NBR (Nitrile rubber)
• material thickness
>0,11 mm
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection

Respiratory protection necessary at: Dust formation. Particulate filter device (EN 143). P1 (filters at
least 80 % of airborne particles, colour code: White).
Environmental exposure controls
Keep away from drains, surface and ground water.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Physical state solid
Form powder
Colour grey
Odour odourless
Melting point/freezing point 1.538 °C
Boiling point or initial boiling point and boiling 2.735 °C
range
Flammability flammable solid in accordance with GHS criteria
self-heating substance in accordance with GHS
criteria
Lower and upper explosion limit 100 g/m³ (LEL)
Flash point not applicable
Auto-ignition temperature not determined
Decomposition temperature not relevant
pH (value) not applicable
Kinematic viscosity not relevant
 
Solubility(ies)
Water solubility (insoluble (< 1 mg/l))

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

 
Partition coefficient
Partition coefficient n-octanol/water (log value): not relevant (inorganic)
 
Vapour pressure not determined
 
Density and/or relative density
Density 7,87 g/cm³ at 20 °C (ECHA)

Relative vapour density information on this property is not available

Bulk density 2.500 – 3.500 kg/m³

 
Particle characteristics
Particle size ~10 µm
 
Other safety parameters
Oxidising properties none
9.2 Other information
Information with regard to physical hazard There is no additional information.
classes:
Other safety characteristics:
Temperature class (EU, acc. to ATEX) T4
Maximum permissible surface temperature on
the equipment: 135°C

SECTION 10: Stability and reactivity

10.1 Reactivity
It's a reactive substance. Risk of ignition. Self-heating property.
If heated
Risk of ignition. Danger of spontaneous combustion.
10.2 Chemical stability
The material is stable under normal ambient and anticipated storage and handling conditions of tem-
perature and pressure.
10.3 Possibility of hazardous reactions

Violent reaction with: strong oxidiser, Aldehydes, Ammonium compounds, Chlorine, Fluorine, Ni-
trate, Perchlorates, Peroxides, Acids, Hydrogen sulphide (H₂S), Water, Hydrogen peroxide,
=> Explosive properties
10.4 Conditions to avoid
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pro-
tect from moisture.
10.5 Incompatible materials
There is no additional information.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008
Classification according to GHS (1272/2008/EC, CLP)
Acute toxicity
Shall not be classified as acutely toxic.

Acute toxicity

Exposure route Endpoint Value Species Method Source

oral LD50 30.000 mg/kg rat TOXNET

Skin corrosion/irritation
Shall not be classified as corrosive/irritant to skin.
Serious eye damage/eye irritation
Shall not be classified as seriously damaging to the eye or eye irritant.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Germ cell mutagenicity
Shall not be classified as germ cell mutagenic.
Carcinogenicity
Shall not be classified as carcinogenic.
Reproductive toxicity
Shall not be classified as a reproductive toxicant.
Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.

Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
diarrhoea, vomiting, nausea, gastrointestinal complaints
• If in eyes
causes slight to moderate irritation
• If inhaled
Inhalation of dust may cause irritation of the respiratory system
• If on skin
Data are not available.

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

• Other information
Other adverse effects: Cardiovascular system
11.2 Endocrine disrupting properties
Not listed.
11.3 Information on other hazards
There is no additional information.

SECTION 12: Ecological information

12.1 Toxicity
Shall not be classified as hazardous to the aquatic environment.
.
Biodegradation
The methods for determining the biological degradability are not applicable to inorganic substances.
12.2 Process of degradability
Data are not available.
12.3 Bioaccumulative potential
Data are not available.
12.4 Mobility in soil
Data are not available.
12.5 Results of PBT and vPvB assessment
Data are not available.
12.6 Endocrine disrupting properties
Not listed.
12.7 Other adverse effects
Data are not available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.
Recycling/reclamation of metals and metal compounds.
Sewage disposal-relevant information
Do not empty into drains.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process. Waste catalogue ordinance (Germany).

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.

SECTION 14: Transport information

14.1 UN number or ID number
ADRRID UN 3089
IMDG-Code UN 3089
ICAO-TI UN 3089
14.2 UN proper shipping name
ADRRID METAL POWDER, FLAMMABLE, N.O.S.
IMDG-Code METAL POWDER, FLAMMABLE, N.O.S.
ICAO-TI Metal powder, flammable, n.o.s.
14.3 Transport hazard class(es)
ADRRID 4.1
IMDG-Code 4.1
ICAO-TI 4.1
14.4 Packing group
ADRRID III
IMDG-Code III
ICAO-TI III
14.5 Environmental hazards non-environmentally hazardous acc. to the dan-
gerous goods regulations
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Maritime transport in bulk according to IMO instruments
The cargo is not intended to be carried in bulk.

14.8 Information for each of the UN Model Regulations

Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional
information
Proper shipping name METAL POWDER, FLAMMABLE, N.O.S.
Particulars in the transport document UN3089, METAL POWDER, FLAMMABLE, N.O.S.,
4.1, III, (E)
Classification code F3
Danger label(s) 4.1

Special provisions (SP) 552

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Excepted quantities (EQ) E1
Limited quantities (LQ) 5 kg
Transport category (TC) 3
Tunnel restriction code (TRC) E
Hazard identification No 40
Emergency Action Code 4Y
Regulations concerning the International Carriage of Dangerous Goods by Rail (RID)Additional
information
Classification code 4.1
Danger label(s) 4.1

Special provisions (SP) 552

Excepted quantities (EQ) E1
Limited quantities (LQ) 5 kg
Transport category (TC) 3
Hazard identification No 40
International Maritime Dangerous Goods Code (IMDG) - Additional information
Proper shipping name METAL POWDER, FLAMMABLE, N.O.S.
Particulars in the shipper's declaration UN3089, METAL POWDER, FLAMMABLE, N.O.S.,
4.1, III
Marine pollutant -
Danger label(s) 4.1

Special provisions (SP) 223

Excepted quantities (EQ) E1
Limited quantities (LQ) 5 kg
EmS F-G, S-G
Stowage category A
Segregation group 7 - Heavy metals and their salts
15 - Powdered metals
International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information
Proper shipping name Metal powder, flammable, n.o.s.
Particulars in the shipper's declaration UN3089, Metal powder, flammable, n.o.s., 4.1, III
Danger label(s) 4.1

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Special provisions (SP) A3
Excepted quantities (EQ) E1
Limited quantities (LQ) 10 kg

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
Restrictions according to REACH, Annex XVII

Dangerous substances with restrictions (REACH, Annex XVII)

Name of substance Name acc. to inventory CAS No Restriction No

Iron flammable / pyrophoric R40 40

Legend
R40 1. Shall not be used, as substance or as mixtures in aerosol dispensers where these aerosol dispensers are intended
for supply to the general public for entertainment and decorative purposes such as the following:
- metallic glitter intended mainly for decoration,
- artificial snow and frost,
- ‘whoopee’ cushions,
- silly string aerosols,
- imitation excrement,
- horns for parties,
- decorative flakes and foams,
- artificial cobwebs,
- stink bombs.
2. Without prejudice to the application of other Community provisions on the classification, packaging and labelling of
substances, suppliers shall ensure before the placing on the market that the packaging of aerosol dispensers referred
to above is marked visibly, legibly and indelibly with:
‘For professional users only’.
3. By way of derogation, paragraphs 1 and 2 shall not apply to the aerosol dispensers referred to Article 8 (1a) of
Council Directive 75/324/EEC (2).
4. The aerosol dispensers referred to in paragraphs 1 and 2 shall not be placed on the market unless they conform to
the requirements indicated.

List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list

Not listed.
Seveso Directive

2012/18/EU (Seveso III)

No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements

not assigned

Deco-Paint Directive

VOC content 0%
0 g/l

Industrial Emissions Directive (IED)

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

VOC content 0%

VOC content 0 g/l

Directive on the restriction of the use of certain hazardous substances in electrical and
electronic equipment (RoHS)
not listed
Regulation concerning the establishment of a European Pollutant Release and Transfer
Register (PRTR)
not listed
Water Framework Directive (WFD)

List of pollutants (WFD)

Name of substance Name acc. to inventory CAS No Listed in Remarks

Iron Metals and their compounds a)

Legend
A) Indicative list of the main pollutants

Regulation on the marketing and use of explosives precursors

not listed
Regulation on drug precursors
not listed
Regulation on substances that deplete the ozone layer (ODS)
not listed
Regulation concerning the export and import of hazardous chemicals (PIC)
not listed
Regulation on persistent organic pollutants (POP)
not listed

Other information
Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un-
der the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
National inventories
Country Inventory Status

AU AICS substance is listed

CA DSL substance is listed

CN IECSC substance is listed

EU ECSI substance is listed

EU REACH Reg. substance is listed

KR KECI substance is listed

MX INSQ substance is listed

NZ NZIoC substance is listed

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Country Inventory Status

PH PICCS substance is listed

TR CICR substance is listed

TW TCSI substance is listed

US TSCA substance is listed

Legend
AICS Australian Inventory of Chemical Substances
CICR Chemical Inventory and Control Regulation
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances (PICCS)
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act

15.2 Chemical Safety Assessment

No Chemical Safety Assessment has been carried out for this substance.

SECTION 16: Other information

Indication of changes (revised safety data sheet)
Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU

Restructuring: section 9, section 14

Section Former entry (text/value) Actual entry (text/value) Safety-
relev-
ant

2.1 Classification according to Regulation (EC) No yes

1272/2008 (CLP):
change in the listing (table)

2.2 Pictograms: yes

change in the listing (table)

2.3 Other hazards: Other hazards yes

There is no additional information.

2.3 Results of PBT and vPvB assessment: yes

According to the results of its assessment, this
substance is not a PBT or a vPvB.

Abbreviations and acronyms

Abbr. Descriptions of used abbreviations

ADN Accord européen relatif au transport international des marchandises dangereuses par voies de naviga-
tion intérieures (European Agreement concerning the International Carriage of Dangerous Goods by In-
land Waterways)

ADR Accord relatif au transport international des marchandises dangereuses par route (Agreement concern-
ing the International Carriage of Dangerous Goods by Road)

CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)

Ceiling-C Ceiling value

CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

Abbr. Descriptions of used abbreviations

DGR Dangerous Goods Regulations (see IATA/DGR)

EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identi-
fier of substances commercially available within the EU (European Union)

EH40/2005 EH40/2005 Workplace exposure limits (http://www.nationalarchives.gov.uk/doc/open-government-li-

cence/)

EINECS European Inventory of Existing Commercial Chemical Substances

ELINCS European List of Notified Chemical Substances

EmS Emergency Schedule

GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Na-
tions

IATA International Air Transport Association

IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)

ICAO International Civil Aviation Organization

ICAO-TI Technical instructions for the safe transport of dangerous goods by air

IMDG International Maritime Dangerous Goods Code

IMDG-Code International Maritime Dangerous Goods Code

LD50 Lethal Dose 50 %: the LD50 corresponds to the dose of a tested substance causing 50 % lethality during a
specified time interval

LEL Lower explosion limit (LEL)

NLP No-Longer Polymer

PBT Persistent, Bioaccumulative and Toxic

REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regula-
tions concerning the International carriage of Dangerous goods by Rail)

STEL Short-term exposure limit

SVHC Substance of Very High Concern

TWA Time-weighted average

VOC Volatile Organic Compounds

vPvB Very Persistent and very Bioaccumulative

WEL Workplace exposure limit

Key literature references and sources for data

Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures.
Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU.
Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations
concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan-
gerous Goods Code (IMDG). Dangerous Goods Regulations (DGR) for the air transport (IATA).

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Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Iron ≥99,5 %, p.a., ~10 µm, powder

article number: 3718

List of relevant phrases (code and full text as stated in section 2 and 3)
Code Text

H228 Flammable solid.

H251 Self-heating: may catch fire.

Disclaimer
This information is based upon the present state of our knowledge. This SDS has been compiled and
is solely intended for this product.

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