Naveen's Academy

Basic of Chem + Basics of Org Chem

11th Standard CBSE
Chemistry
"All The Best"
Time : 01:15:00 Hrs

Total Marks : 50

Section -  A 
1) 5.6 litres of oxygen at NTP is equivalent to 1

( a ) 1 mole (b) 1

4
mole (c) 1

8
mole (d) 1

2
mole
2) How many grams are contained in 1 gram atom of Na? 1

( a ) 13 g (b) 1g ( c ) 23 g (d) 1

23
 g

3) 12 g of Mg will react completely with an acid to give: 1

( a ) 1 mole of O2 (b) 1

2
mole of H2 ( c ) 1 mole of H2 ( d ) 2 mole of H2
4) Which of the following has the highest mass? 1
( a ) 1 g atom of C (b) 1

2
mole of CH4 ( c ) 10 mL of water (d) 3.011 x 1023atoms of oxygen
5) Which of the following carbocation is most stable? 1
⊕ ⊕ ⊕ ⊕

(a) (C H3 )3 C C H2 (b) (C H3 ) C
3
(c) C H3 C H2 C H2 (d) C H3 C H C H2 C H3

Section -  B
6) If 2 L of N2 is mixed with 2 L of H2at a constant temperature and pressure,then what will be the volume of 1

NH3 formed?
Answer : N 2 (g) + 3H2 (g) ⟶ 2N H3 (g) 1 L of N2 reacts with 2 L of H2. Therefore, 2 L of N2 will react with 6 L of
H2,but we have only 2 L of H2,therefore,H2is the limiting reactant. 3 L of H2 gives 2 L of NH3.      2 L of H2 gives =
 L of NH3
2 4
× 2 = = 1.33
3 3

7) What is the di erence between 5.0 g and 5.00 g ? 1

Answer : Through the two values seem to be equivalent but scientifically they are di erent. 5.0 g has two
significant figures and hence, its precision is 0.1 part in 5, i.e. 20 ppt 5.00 has three significant figures and hence,
its precision is 0.01 parts in 5, i.e. 2 ppt. Hence, 5.00 g is more precise measurement than 5.0 g.
8) If  6.022 × 10
23
 molecules of N2 react completely with H2 according to the equation  1

N 2 (g) + 3H2 (g) ⟶ 2N H 3 (g).  then calculate the number of molecules of NH3 formed.
Answer : 1.2 × 10
24

9) In DNA and RNA, nitrogen atom is present in the ring system.Can Kjeldahl's method used for the estimation of 1

nitrogen present in these?Give reason

Answer : DNA  and RNA have nitrogen in the heterocyclic rings.Nitrogen present in rings,azo and nitro groups
cannot be converted into (NH4)2SO4 .That's why kjeldahl's method cannot be used for the estimation of nitrogen
present in these.
10) Will CCI4 give precipitate of AgCI on heating it with silver nitrate?Give reason for your answer. CCl4 is a covalent 1
-
compound and does not give CI  ions.
Answer : CCI4 will not give a white ppt of AgCI with AgNO3 solution because CCI4 is a covalent compound.It does
not ionise to give CI- ions required for the formation of AgCI precipate.
Section -  C
11) Which one of the following will have the largest number of atoms? (i)   1g Au ( s ) (ii)  1g Na ( s )  (iii) 1g Li ( s ) (iv) 1g 2

of Cl2 ( g )
Answer : (i) 1g Au = 12

197
mole of Au = 1

197
× 6.022×1023 atoms of Au = 3.057×1021 atoms (ii) 1g Na = 1

23
mole of Na = 1

23

× 6.022×1023 atoms of Na = 2.6× 3.057×1022 atoms (iii) 1g Li =    mole of Li =   ×6.022× 1023 atoms of  Li      = 8.60
1

7
1

× 2222 atoms (iv) 1g  Cl2       =  1

71
mole of Cl2      =  1

71
× 6.022× 1023 atoms Cl2      = 8.48×10-21atoms Hence , 1 g Li have
the largest number of atoms 
12) Calculate the atomic mass (average) of chlorine using the following data: 2

  % Natural Abundance Molar Mass

35
CI75.77 34.9689
37
Cl24.23 36.9659
Answer : Fractional abundance of 35Cl = 0.7577, Molar mass = 34.9689 Fractional abundance of 37Cl = 0.2423, Molar
mass = 36.9659 ∴ Average atomic mass = (0.7577) (34.9689 amu) + (0.2423) (36.9659 amu) = 26.4959 + 8.9568 = 35.4527
13) Write bond-line formulas for: Isopropyl alcohol, 2,3-Dimethylbutanal, Heptan-4-one. 2

Answer :

14) Draw the resonance structures for the following compounds. Show the electron shi using curved-arrow 2

notation.CH3CH=CHCH2

Answer :

15) Which type of compounds are purified by steam distillation? 2

Answer : Steam volatile and insoluble in water.

Section -  D
16) What volume of 0.250 M HCl (aq) is required to react completely with 22.6 g of sodium carbonate according to the 3
reaction ? N a 2 C O3 (s) + 2H C i(aq) ⟶ 2N aC l(aq) + H2 o(l) + C O2 (g)

Answer : 1.7 L
17) Calculate the percentage by mass of chromium in the following oxide. 'CrO3' 3

Answer : 52.00%
18) Give a brief description of the principles of the following techniques taking an example in each case: 3

Chromatography.
Answer : Chromatography: Chromatography is based on the principle of selective distribution of the components of a
mixture between two phases, a stationary phase and a moving phase. The stationary phase can be a solid or liquid,
while the moving phase is a liquid or a gas. When the stationary phase is solid the basis is adsorption and when it is a
liquid the basis is partition. Chromatography is generally used for the separation of coloured substances such as plant
pigments or dyestu s.
19) (a) What do you understand by Homolytic fission? (b) What are carbanions? Give an example. 3

Answer : Homolytic fission is breaking of a bond in such a manner that each atom takes one electron each to form free
radicals. A − B ⟶ A. +B (b) Organic ions which contain a negatively charged carbon atom are called carbanions.
e.g., C H  is carbanion.
⊖

20) Discuss the chemistry of Lassaigne's test. 3

Answer : Lassaigne's test: Nitrogen, sulphur, halogens and phosphorous present in an organic compound are
detected by Lassaigne's test. First of all compounds are converted to ionic form by fusing the compound with sodium
metal. Na+C+N ⟶  NaCN 2Na + S ⟶ Na S Na+X ⟶ NaX                   [X = cl, Br, I] Cyanide, sulphide or halide of sodium
△ △ △

2
are extracted from the fused mass by boiling it with distilled water. This extract is known as sodium fusion extract.
Section -  E
21) Calcium carbonate reacts with aqueous HCI to give CaCI2 and CO2 according to the reation, CaCo3(s) + 2HCI(aq)  5

⟶  CaCl2(aq) + CO2 (g) + H2O (l) What mass of CaCo3 is required to react completely with 25 mL of 0.75 M HCI?
Answer : (i)Calculate for mass of HCI in 25 mL of 0.75 M HCI Molarity =  (Molar mass of HCI
w×1000 w×1000
⇒ 0.75 =
m×vol(mL) 36.5×25

= 1 + 35.5 = 36.5g/mol) w = 0.75× 36.5× 25

1000
 =0.6844 g (ii) Calculation for required mass of CaCO3 to react completely
with 0.6844 g HCI. CaCo3(s) + 2HCI(aq) ⟶ 100g            2×36.5=73 g                                                 Cac12(aq) + CO2(g) +H2O(l)
According to balanced chemical equation, 73 g HCI completely reacts with 100 g CaCO3 1 g HCI completely reacts with 
100

73
 g CaCo3 ∴  0.6844 g HCI will completely reacts with                                   100×0.6844

73
= 0.9375  g

22) (a) Wfult is the basic principle involved in the estimation of nitrogen by Dumas method. (b) In a Dumas nitrogen 5
3
estimation method, 0.30 g of an organic compound gave 50 cm of N2 collected at 300 K and 715 mm Hg pressure.
Calculate the percentage composition of nitrogen in the compound. (Vapour pressure of water at 300 K is 15 mm
Hg)
Answer : (a) This method is based upon the fact that nitrogenous compound is heated with copper oxide in an
atmosphere of carbon dioxide yield free nitrogen. (b)

P1 = 715 -15 = 700 mm Hg, P2 = 760 mm Hg T1 = 300 K, T2 = 273 K V1 = 50 crrr', V2 = ? V = 41.9

P1 V1 P2 V2 700×50×273
= 2 =
T1 T2 300×760

cm3 % of  N =
28

22400
× 41.9 ×
100

W
= 17.46%
23) Hoe does the inductive e ect of an alkyl group a ect the stability of these three intermediates? 5

Answer :