ECSS-Q-ST-70-01C - Cleanliness and Contamination Control
ECSS-Q-ST-70-01C - Cleanliness and Contamination Control
15 November 2008
Space product
assurance
Cleanliness and contamination
control
ECSS ‐Q ‐ST ‐70‐01C
15 November 2008
ECSS Secretariat
ESA-ESTEC
Requirements & Standards Division
Noordwijk, The Netherlands
Foreword
This Standard is one of the series of ECSS Standards intended to be applied together for the
management, engineering and product assurance in space projects and applications. ECSS is a
cooperative effort of the European Space Agency, national space agencies and European industry
associations for the purpose of developing and maintaining common standards. Requirements in this
Standard are defined in terms of what shall be accomplished, rather than in terms of how to organize
and perform the necessary work. This allows existing organizational structures and methods to be
applied where they are effective, and for the structures and methods to evolve as necessary without
rewriting the standards.
This Standard has been prepared by the ECSS‐Q‐ST‐70‐01 Working Group, reviewed by the ECSS
Executive Secretariat and approved by the ECSS Technical Authority.
Disclaimer
ECSS does not provide any warranty whatsoever, whether expressed, implied, or statutory, including,
but not limited to, any warranty of merchantability or fitness for a particular purpose or any warranty
that the contents of the item are error‐free. In no respect shall ECSS incur any liability for any
damages, including, but not limited to, direct, indirect, special, or consequential damages arising out
of, resulting from, or in any way connected to the use of this Standard, whether or not based upon
warranty, business agreement, tort, or otherwise; whether or not injury was sustained by persons or
property or otherwise; and whether or not loss was sustained from, or arose out of, the results of, the
item, or any services that may be provided by ECSS.
Change log
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ECSS‐Q‐70‐01A First issue
11 December 2002 Transforming ESA PSS‐01‐701 into an ECSS Standard
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Table of contents
1 Scope.......................................................................................................................8
2 Normative references.............................................................................................9
3 Terms, definitions and abbreviated terms..........................................................10
3.1 Terms from other standards.....................................................................................10
3.2 Terms specific to the present standard ....................................................................10
3.3 Abbreviated terms ....................................................................................................14
4 Principles ..............................................................................................................16
5 Requirements........................................................................................................17
5.1 Cleanliness and contamination control programme .................................................17
5.1.1 General.......................................................................................................17
5.1.2 Documentation ...........................................................................................17
5.1.3 Contamination budget ................................................................................18
5.1.4 Contamination predictions..........................................................................18
5.1.5 Contamination prediction with respect to budget........................................19
5.1.6 Cleanliness and contamination process flow chart.....................................19
5.2 Phases .....................................................................................................................20
5.2.1 Design ........................................................................................................20
5.2.2 MAIT...........................................................................................................22
5.2.3 pre-launch and launch................................................................................23
5.2.4 Mission .......................................................................................................24
5.3 Environments ...........................................................................................................25
5.3.1 Cleanrooms................................................................................................25 5.3.2
Vacuum facilities.........................................................................................33
5.3.3 Other facilities.............................................................................................34
5.4 Activities ...................................................................................................................34
5.4.1 Cleaning of hardware .................................................................................34
5.4.2 Cleanliness monitoring of space hardware.................................................36
5.4.3 Cleanliness verification...............................................................................39
5.4.4 Packaging, containerization, transportation, storage..................................42
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Annex A (normative) Cleanliness requirement specification (CRS) - DRD ........44
Annex B (normative) Cleanliness and contamination control plan (C&CCP) -
DRD ....................................................................................................................47
Annex C (informative) Cleanliness and contamination control process
overview...............................................................................................................51
Annex D (informative) Guidelines for general cleanliness and contamination
control.........................................................................................52
D.1 General.....................................................................................................................52
D.2 Contamination attributes ..........................................................................................52
D.2.1 Typical contaminants and their sources.....................................................52
D.2.1.1. On ground .....................................................................................................52
D.2.1.2. On launch......................................................................................................54
D.2.1.3. During mission...............................................................................................55
D.2.2 Transport mechanisms...............................................................................58
D.2.2.1. Overview .......................................................................................................58
D.2.2.2. Contaminants transport on ground................................................................58
D.2.2.3. Contaminants transport in space ..................................................................58
D.2.3 Main effects of contamination on space systems.......................................59
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M.2.1
Overview.....................................................................................................73
M.2.2 Mechanical
cleaning...................................................................................73 M.2.3 Solvent and
detergent cleaning..................................................................73 M.2.4 Films
trapping.............................................................................................73 M.2.5 Gas
jet cleaning..........................................................................................73 M.2.6
Plasma cleaning.........................................................................................74
M.2.7
Bakeout ......................................................................................................74
M.2.8 Ultra-violet-ozone
cleaning.........................................................................74
Figures
Figure 5-1: Graphical representation of ISO-class concentration limits for selected ISO
classes.................................................................................................................27
Figure C-1 : Cleanliness and contamination control process overview..................................51
Tables
Table 5-1: Outgassing criteria for materials in the vicinity of sensitive items around RT .......21
Table 5-2: Outgassing criteria for materials in the vicinity of sensitive items at
temperature below RT .........................................................................................21 Table 5-3:
Outgassing criteria for materials in the vicinity of cryogenic surfaces...................21
Table 5-4: Selected airborne particulate cleanliness classes for cleanrooms and other
controlled environment ........................................................................................28 Table 5-5:
Correlation airborne and PFO for cleanrooms ......................................................29 Table G-1
: Classification system...........................................................................................64
Table H-1 : Correlation between ideal class of IEST-STD-CC1246D and obscuration
factor....................................................................................................................66
Table I-1 : Examples of compatibility of various solvents with listed materials ......................68
Table J-1 : Commercially available solvents evaporation residue..........................................69
Table K-1 : Molecular contaminant content of some wipe materials......................................70
Table L-1 : Effect of humidity on materials and components .................................................71
Introduction
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• performance assessment versus contamination,
• planning of activities.
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1 Scope
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2 Normative references
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3.2.3 bakeout
activity of increasing the temperature of hardware to accelerate its outgassing
rates with the intent of reducing the content of molecular contaminants within
the hardware
NOTE Bakeout is usually performed in a vacuum
environment, but can be done in a controlled
atmosphere.
3.2.4 biocontamination
contamination of materials, devices, individuals, surfaces, liquids, gases or air
with viable particles
[ISO 14698‐1:2003, 3.1.4] [ISO 14698‐2:2003, 3.4]
3.2.5 cleaning
actions to reduce the contamination level
3.2.9 cleanroom
room in which the concentration of airborne particles is controlled, and which is
constructed and used in a manner to minimize the introduction, generation and
retention of particles inside the room, and in which other relevant parameters,
e.g. temperature, humidity and pressure, are controlled as necessary
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[ISO 14644‐6]
3.2.11 contaminant
any unwanted molecular or particulate matter (including microbiological
matter) on the surface or in the environment of interest, that can affect or
degrade the relevant performance or life time
3.2.12 contaminate, to
act of introducing any contaminant
3.2.16 fibre
particle with a length to diameter ratio of 10 or more
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3.2.20 molecular contamination
airborne or surface contamination (vapour, gas, liquid, or solid) without
observable dimensions (i.e. with dimensions at molecular level)
3.2.21 monitoring
to perform routine, quantitative measurements of environmental parameters in
and around cleanrooms, clean zones, and other clean areas, including
contamination parameters
3.2.24 offgassing
evolution of gaseous products from a liquid or solid material into an
atmosphere
3.2.26 outgassing
evolution of gaseous species from a material, usually in vacuum
NOTE Outgassing also occurs in a higher‐pressure environment.
3.2.27 particle
unit of matter with observable length, width and thickness
3.2.30 particulate
of or relating to minute separate particles
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3.2.31 particulate contamination (PAC)
airborne or surface contamination due to particles
3.2.32 plume
exhaust (molecules or particles) of thrusters and engines
3.2.33 purging
supply of clean gas to protect the critical hardware from contamination
3.2.38 venting
conveying unwanted gaseous products through an aperture
Abbreviation Meaning
ACS American Chemical Society
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AIT assembly, integration and testing
AIV assembly, integration and verification
AO atomic oxygen
BOL beginning of life
CC contamination control
C&CCP cleanliness and contamination control plan
CRS cleanliness requirement specification
CVCM collected volatile condensable material
DIW deionised water
DML declared materials list
DOP dioctylphthalate
ECLS environmental control and life support
EGSE electrical ground support equipment
EMC electromagnetic compatibility
EOL end of life
EVA extra vehicular activity
FTIR Fourier transform infrared
GSE ground support equipment
HEPA high‐efficiency particulate air filter
ICC internal contamination control
IPA isopropyl alcohol
IR infrared
LEO low Earth orbit
MGSE mechanical ground support equipment
MLI multi layer insulation
MOC molecular contamination
MRR manufacturing readiness review
NVR non‐volatile residue
OF obscuration factor
RH relative humidity
RT room temperature
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RML recovered mass loss
TB thermal balance
TV thermal vacuum
UV ultra‐violet
4 Principles
The cleanliness and contamination control process is applied all along the
project life cycle, from the definition of the C&CCP programme during the early
phases (see clause 5.1) until its implementation during phases B, C, D, E and F
(see clause 5.2) through the systematic verification of the cleanliness
requirements baseline including: predictions through contamination modelling
and the establishment of agreed procedures (see clause 5.3 and 5.4) for:
environments control (see clause 5.3) packaging, containerization,
transportation and storage of the space system.
NOTE Figure C‐1 of Annex C gives an overview of an example of a
cleanliness and contamination process.
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5 Requirements
5.1.1 General
a. The supplier shall define and implement a cleanliness and contamination
control programme for each level of configuration.
NOTE 1 Surveys can also be made to determine the
contamination control requirements, based on mission
objectives and scenarios.
NOTE 2 The objective of this programme is, starting from the
mission performance requirements, to establish
cleanliness and contamination levels to
be achieved at different manufacturing, AIT and
mission stages.
NOTE 3 In general, the organization of regular workshops
dedicated to cleanliness and contamination control for
a specific programme is a good practice.
b. The supplier shall establish measures for the coordination and resolution of
cleanliness and contamination control issues among the parties involved
in the project.
5.1.2 Documentation
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d. In case the CRS cannot be produced at an early stage of the design, a
cleanliness control policy document shall be used.
NOTE 1 The cleanliness control policy document gives the
correlation data between acceptable performance
losses and the contamination levels from library
search or from tests that are performed.
NOTE 2 The cleanliness control policy document can become
the CRS during the development of the design.
d. For each on ground activity, for launch and in‐orbit phases, the following
items shall be identified in the contamination prediction:
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2. the sensitive surfaces,
5.2 Phases
5.2.1 Design
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NOTE 2 Such design can contribute to achieve the
contamination levels defined by the CRS on ground as
well during the launch and mission.
NOTE 3 A way to achieve the target contamination levels can be
found in Annex D.
e. For the outgassing screening of materials, the supplier shall apply ECSS‐
Q‐ST‐70‐02.
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occur on adjacent surfaces.
Table 5‐1: Outgassing criteria for materials in the vicinity of
sensitive items around RT
Mass of material concerned
(g) CVCM (%) RML (%)
>100 < 0,01 <1
10 ‐ 100 < 0,05 <1
< 10 < 0,1 <1
5.2.2 MAIT
5.2.2.1 Manufacturing
a. Personnel involved in the manufacturing of sensitive items shall be
trained with respect to the cleanliness control policy.
d. Elements that can be cleaned after manufacturing shall be cleaned till the
cleanliness requirements are met.
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e. For elements that cannot be cleaned after manufacturing, then
manufacturing and assembling areas shall meet the cleanliness level
requirements specification.
d. A set of assembly tools and equipment for assembly and integration shall
be used and maintained in clean conditions.
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5.2.2.3 Testing
a. Involved personnel shall be trained with respect to the cleanliness policy.
5.2.3.1 General
a. Personnel involved in pre‐launch activities shall be trained with respect
to the cleanliness policy.
b. The space system shall be shipped to the launch base under clean
conditions as defined in the CRS and controlled by the C&CCP.
b. The materials of the hardware in the vicinity of the space system shall
meet the same outgassing and surface‐cleanliness requirements as the
space system itself.
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contaminants, especially the “unknown” figure of
particle transfer during launch.
NOTE 2 A second design aspect is the location of the
contamination‐sensitive items with respect to the
position of thrusters and of pyrotechnics or other
contamination sources.
NOTE 3 The reflection by atmospheric molecules (i.e.
atmospheric scattering) or by
outgassing molecules (i.e. self‐scattering) can take
place and some form of modelling is of interest.
5.2.4 Mission
a. External contamination control during mission shall be done through
preventive actions, specific design provisions and operations.
NOTE 1 Preventive actions include materials selection (see
clause 5.5.3 in ECSS‐Q‐ST‐70‐02), bakeout (see
clause 5.4.3.2) and purging (see clause 5.4.3.3).
NOTE 2 Specific design provisions include
the implementation of heaters for
decontamination of sensitive surfaces, of shutters and
baffles.
NOTE 3 Operations include shielding during dumping,
thrusters firing or venting,, decontamination of
sensitive surfaces through exposure to the Sun.
5.3 Environments
5.3.1 Cleanrooms
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b. The covering floor shall consist of one piece or, if this is not feasible, shall
have a minimum number of joints.
d. The room shall be designed such that only one door or entrance can be
opened at one time, except in case of emergency.
f. Anterooms shall be equipped for the changing of clothes and the storage
of clothing, personal belongings and cleaning equipment.
c. In laminar flow cleanrooms, the air flow velocity through the cross
section of the room shall be maintained at 27 m/min with a uniformity
within ± 20 % throughout the undisturbed room.
5.3.1.3 Filters
a. In laminar flow cleanrooms, (HEPA) filters shall cover either one entire
wall or the entire ceiling, except when diffusion ceiling or wall systems
are used or when built‐in benches are included in the incoming air end of
the room.
b. Monitoring shall be done and any work with highly sensitive equipment
shall not be performed before the defined ISO class for the hardware has
been reached. as specified in the C&CCP for the following situations:
1. after the installation of new filters,
2. after “at rest “ period,
3. after stand by period.
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c. The air flow inside cleanrooms and independent HEPA filtering systems
shall be maintained during “at‐rest” periods, except for the maintenance
operations.
NOTE 1 For example, during filters replacement.
NOTE 2 Independent HEPA filtering systems can be like those used
for the laminar flow tents and benches.
NOTE 3 This is to avoid the risk of redistribution of particles at
restart of the flow.
NOTE 4 Exception can be made for independent HEPA
filtering systems that can work with a reduced air flow
rate during stand‐by periods.
e. When charcoals filters are used, the initial charge shall be assessed on
installation and analysed regularly.
NOTE It can be useful to evaluate the charge in contaminants
of the filtering system which can release its charge
in contaminants trapped. in order to be able to
monitor the evolution and when a failure occurs.
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classification numbers can be specified,
with 0,1 the smallest permitted increment
of N.
D is the considered particle size,
in micrometres.
0,1 is a constant, with a dimension of micrometres.
NOTE 4 From the particle point of view, the number of 5 μm
particles per given volume of air is much more
critical than the number of smaller particles, since
the fallout is mainly determined by particles of 5
μm or larger. The cleanliness level of a cleanroom
can only be selected when the specified
obscuration factors for critical spacecraft surfaces
are known. The particle size 5 μm is often used as a
criterion, because for optical surfaces particles
larger than 5 μm are critical, whereas for bearings
and gears, particles in the range 10 μm to 40 μm are
more harmful.
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Table 5‐4: Selected airborne particulate cleanliness classes for cleanrooms
and other controlled environment
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NOTE This can be done through the exposure of test surfaces
or samples to the environment and counting the
settled particles by appropriate methods.
5 2,0
6 10
7 52
8 275
NOTE
The data contained in this table are based on several
measurements performed in different cleanrooms. They
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c. For each location, one of the two witness plates shall be analyzed at least
once month.
d. The other witness plate is cumulative and shall be analyzed after more
than one month.
g. For those hardware items where the accumulation from the air becomes a
major issue, the use of charcoal filters as molecular contamination trap
should be considered.
NOTE Example of such a hardware are coated mirrors.
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5.3.1.9 Pressure control
a. A positive pressure differential shall be maintained between the
cleanroom and the outside.
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g. Regular cleaning shall be performed depending on the ISO class.
k. Cleaning tools, solvents and gases that are used for cleaning purposes
shall be chosen not to have a detrimental effect on the hardware within
the cleanroom.
NOTE Cleanroom air of better than class ISO 8 is transported
in a close loop. Since only a limited percentage of
fresh air is fed to the loop, excessive use of solvents
offgassing into the air, even if not flammable or
toxic, can cause health problems.
d. Visitors and personnel without a work order shall not be allowed to enter
the cleanroom.
f. Racks or cabinets for street clothing shall be separated from those used
for cleanroom clothing.
g. Barriers or similar means separating clean and not clean zones inside the
airlock shall be placed.
NOTE Similar means can be tacky mats.
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h. Lint‐free clothing shall be available and worn by all personnel within
cleanroom area.
r. If air showers are used, only suitably clothed personnel shall be allowed
to enter.
s. Paper, pencils or erasers shall be kept outside the clean facilities. Only
special non‐shedding papers and ball‐points shall be used.
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5.3.2 Vacuum facilities
a. Procedures shall be available for:
1. The cleaning of the test facilities.
NOTE Handling of solvents and running a bakeout
2. The pump‐down and recovery sequences with respect to
contamination redistribution.
NOTE A good solution, for chamber repressurization, is to add
an HEPA filter to the repressurization piping
b. For a test in a vacuum facility, it shall be ensured that the item under test
does not pose any risk of contamination of the facility.
e. During the pre‐test, test equipment and cabling shall be included in the
facility.
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5.4 Activities
b. Aids, such as wipe tissues, papers, cloths, brushes and foams shall be
non‐fluffing, lint free and dust free.
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d. NVR of cleaning wipe materials shall be less than 0,01g/m 2 for wiping
extremely clean surfaces when extracted with IPA.
NOTE Different examples of NVR for common tissues are given in
Annex K.
c. For precision cleaning, solvents of high purity shall be used (see Annex J).
d. The cleaning gas shall be free of oil and filtered to remove particulate
contamination according to the needs.
b. Surfaces shall be examined with the naked eye or with the aid of
magnification devices under grazing incident light level of, at least,
1000 lux.
NOTE 1 Different kinds of lights can be used: portable diving
light or “white light” is often used for standard
inspection. In addition, ultra‐violet lamp or “black
light” (365 nm) can be used for inspection of
organic residues and dust particles as it increases
their visibility.
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NOTE 2 Typical methods are the
measurement of transmission or reflection loss
and nephelometry (i.e. scattering of light). These
methods can be used for all types of contaminants,
both organic and inorganic. Photographic
determination of dust particles on surfaces is also
possible, as is automatic counting.
NOTE 3 There are commercially available instruments (e.g.
PFO photometers) that automatically measure the
particle fallout level on sensor plates, exposed
during phases of interest.
NOTE 4 The method for measuring of the PFO level is described in
the ECSS‐Q‐ST‐70‐50 but another
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in accordance with ECSS‐Q‐ST‐70‐05. This method,
applied to a wiped area of 100 cm 2, permits
detection of organic contamination levels down to
3 10‐9 g/cm2. The results of this method depend
very much on the surface roughness, on the type of
tissue and on the solvent used. Particular attention
is paid to the compatibility between solvent and
surface.
NOTE 3 A surface of a known area is rinsed with a solvent
and the residue is weighed after evaporation
according to ASTM‐E1235M‐95.. The accuracy and
detection limit of this method depend greatly upon
the sensitivity of the balance, the substrate water
absorption, the washing efficiency and the solvent
background. The NVR measurement is expressed
in mass per unit area and the residue can be used
for further analyses). Direct measurements can be
made in situ using quartz crystal microbalances
(QCM).
NOTE 4 Further analyses can be performed to characterize
molecular contamination (e.g. gas
chromatography, mass spectrometry, ultra‐violet
degradation, SEM).
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5.4.2.5 Contamination monitoring during launch
a. QCM shall be used to monitor molecular contamination.
NOTE 1 The QCMs can be installed on the launcher and the
measuring time is limited to a few minutes; if the
QCMs are installed on the space system, the
measurements can continue during mission.
NOTE 2 The temperature of QCM can be either
uncontrolled or kept constant.
NOTE 3 For the interpretation, the thermal fluxes and the
solar fluxes can affect the QCM readings and
corrections can then be necessary.
NOTE 4 For the monitoring of particles during launch, no
specific method is established at present time.
5.4.2.6 Contamination monitoring in space
a. Contamination of external surfaces should be monitored.
NOTE 1 particulate contamination can be measured by
light scattering (e.g. using the Sun or a laser as the
a light source) or using QCMs with a crystal
having a surface to which particles stick.
NOTE 2 Molecular contamination can be measured using
QCM located near a sensitive item and maintained
at the same temperature as the item or using a
mass spectrometer.
NOTE 3 Measurements of contamination in space are not
often made because the policy of cleanliness
control is based upon the basic principle of
achieving the lowest possible contamination levels
with existing knowledge and within the allocated
financial budgets. However, it is advisable to
implement an “in space contamination
monitoring” as part of the spacecraft
housekeeping. When appropriate sensor elements
are applied it is possible to predict design life‐
times at system, subsystem, component or
equipment levels.
b. For internal environments monitoring of particulate, molecular and
microbiological contamination shall be assessed.
5.4.3.1 General
a. The cleanliness verification activities shall be specified in the C&CCP.
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cleanrooms or the vacuum chambers conform to the applicable standards
or the applicable CRS (specific to a certain project).
c. The cleanliness verification shall make use of recognized methods for the
determination or the monitoring of the contamination levels.
e. The cleanliness verification shall take place under one or more of the
following conditions:
1. At predetermined intervals, independently of the current activity,
to confirm the efficiency of the established cleanliness control
measures.
2. After the occurrence of an incident or anomaly that can have
influenced the cleanliness conditions of the space system or
cleanroom.
5.4.3.2 Bakeout
a. When contamination predictions exceed the allocated contamination
budget, a bakeout shall be performed.
NOTE 1 The aim of the bakeout is:
• To improve the outgassing behaviour of a
material/item.
• To reduce the level of surface contamination collected
during processing or testing.
NOTE 2 Typical materials on which bakeout can be applied are:
• Harness
• MLI
• Carbon and glass fibre components
• Glued, coated or potted materials.
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temperature constraints at higher assembly level)
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i. Independently of any stopping and verification criteria, the minimum
bakeout duration shall be 72 hours.
j. Baking time shall start when the material/item under baking has reached
the predefined bakeout temperature.
5.4.3.3 Purging
a. The purging shall be performed inside a cavity to maintain a constant
exchange of the gas present in the cavity.
NOTE 1 This exchange depends on the entry flow rate of the
gas and the total surface leaks.
NOTE 2 The aim of the purging is not only to protect the
critical hardware such as optics from
contamination by injecting a non‐ionized high‐
purity dry gas inside a cavity but also a way for
decontamination (e.g. removal of water for
dimensional stability of composite).
NOTE 3 The purging can be implemented at instrument or
spacecraft level during functional and performance
tests at ambient conditions, during
repressurization after TB/TV and TV tests, during
all the phases without activities and during
storage, transport and pre‐launch phases up to the
final close of the fairing. (In case of an aborted
launch, purging can be not re‐installed).
b. The purity of the gas and the cleanliness of all the pipes shall be verified
before the first use of the purging system.
c. Filtering systems (both for MOC and PAC) shall be provided before the
gas comes into contact with the hardware.
c. The container for clean item shall maintain the cleanliness levels specified
for the product.
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d. Storage areas shall provide adequate protection to the package and the
product for the intended storage period.
k. The design of the container shall facilitate easy cleaning and inspection of
its surfaces, avoiding any kind of dirt traps.
q. When used, desiccants shall be in bags that are clean and do not produce
particulate contamination.
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<1> Introduction
a. The CRS shall give a general overview of the item to which the CRS
refers, describing sensitive items and contamination sources, in
consideration of:
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3. their impact as potential sources of contamination.
b. The CRS shall specify the pressures (or other molecular fluxes) that can be
reached in connection with voltage breakdown, arcing, corona
discharges, multipaction, opening time of shutters and ejection time of
covers.
b. The CRS shall specify the flight environmental factors (natural and
induced) that affect the contamination phenomena, such as solar
radiation, electron, proton and AO fluxes, together with the planned
mission profile/duration.
c. The CRS shall specify sensitive item temperatures to be used for the
analyses during ground and in‐flight operations.
NOTE The expected temperatures and temperature profiles
of these items can be important for condensation
and the residence times of the contaminants.
<3> Contaminants
a. The CRS shall describe all possible contamination sources to be analysed
and the maximum acceptable emissions.
NOTE For example: Materials outgassing, lubricants
escaping from bearings, wear particles from moving
parts, terrestrial contaminants such as dust, plume
contaminants from thrusters and engines, leaks from
fuel systems and from hermetically sealed components,
dumps and EVA, co‐passengers, fairing and equipment
bay items of the launcher.
b. The CRS shall specify the chemical nature of the contaminants listed
under <3>a. with their vapour pressures or relevant condensation
conditions.
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NOTE For example, molecular column density, maximum
molecular deposition on the sensitive items.
b. The CRS shall specify acceptable contamination levels of MOC and PAC
for all on ground and in‐flight phases.
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• System
• Subsystem
• Equipment
The C&CCP is based on the requirements defined by the cleanliness
requirements specification (CRS).
The supplier is responsible for this document.
The C&CCP is prepared in collaboration with experimenters and engineers.
<1> Introduction
a. The C&CCP shall contain description of the purpose, objective, content and
the reason prompting its preparation.
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<2> Applicable and reference documents
a. The C&CCP shall list the applicable and reference documents to support the
generation of the document.
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<5.4> Mitigation and corrective actions
a. The C&CCP shall describe the measures for the coordination and
resolution of cleanliness and contamination control issues among the
parties involved in the project.
b. The C&CCP shall list all phases where contamination can be expected
and where the levels can exceed the allocated levels.
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NOTE List of items and process parameters (e.g. for a
bakeout: temperature, pressure and minimum
durations, stop criteria are part of the information of
this clause.
control flow
a. The C&CCP shall define:
1. the sampling plan for PAC and MOC,
2. cleaning operations (when planned), and
3. inspection points.
<7.6> Responsibilities
a. Responsibility and authority shall be assigned for the implementation of
the cleanliness and contamination control tasks.
<8> Forms
a. The C&CCP shall define the forms that are used to document the
cleanliness and contamination control activities defined by the C&CCP.
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D.1 General
Contamination control cannot be applied effectively without an understanding
of the contaminant, the contaminant source and the detrimental effect that the
contaminant has.
The known causes of failure and degraded performance of space elements
attributed to contamination, including their sources, are given in this Standard.
When they are not known, tests and analyses can be performed (e.g. outgassing
rates as a function of time, chemical composition of outgassing products,
condensation rates or degradation as result of radiation).
The results of these tests and analyses can be used to calculate expected
contamination levels and their subsequent effects if other relevant parameters
are known.
Preventive cleanliness control is becoming more important as space systems
become more sophisticated and mission durations are extended.
A problem frequently encountered in space technology is the lack of data
enabling a good correlation between contaminant levels and mission
performance requirements.
NOTE This kind of information can be available in the
mass production areas of electronics and precision
mechanical devices.
D.2.1.1. On ground
• Human sources
⎯ Hair cosmetics, dead human skin cells.
⎯ Fibres and lint from clothing, dust carried in on hair and clothes.
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• MAIT
⎯ Chips and burrs from machined surfaces, solder and weld spatters.
⎯ Particles produced by wear or shedding, corrosion products, flakes
from coatings and air filters.
⎯ Coolants
⎯ Lubricants
⎯ Solder fluxes
⎯ Cosmetics
⎯ alkaline
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⎯ corrosion products
⎯ oxidation products
⎯ finger prints
⎯
stains.
D.2.1.2. On launch
D.2.1.2.1 Particulate contamination
Launch contaminants can come from the acoustic noise and mechanical
vibrations. The contamination source is then the space system itself and the
fairing and structural parts during the first minutes of the launch.
Redistribution of the released particles can occur so that clean surfaces are
covered by particles.
Also the co‐passengers can be the source of contamination in the case of
multiple launches.
During the initial lift‐off, the pressure inside the fairing drops from atmospheric
pressure to high vacuum within a few minutes, and the turbulence of the air can
also redistribute the particles.
The contamination environment during launch can be severe and there is
basically no control of the contamination during this period.
Predictions of the molecular transfer during this period can be estimated: this
type of estimation can be made for co‐passengers when the outgassing
requirements are less stringent than those for the space system of interest.
D.2.1.3.1 Overview
Even with a good contamination and cleanliness control policy, contamination
during mission can not be completely avoided. Indeed, lessons learned from
space systems returned to Earth after quite a long exposure to space e.g. LDEF,
EURECA and solar arrays from the Hubble Space Telescope, indicated visible
contamination especially near venting holes and at locations where
photodeposition and photopolymerization occurred due to solar radiation, or
where atomic oxygen has converted the volatile contaminants into non‐volatile
contaminants.
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Natural environments and induced environment are normally taken into
consideration.
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and of other parameters such as solar radiation. In most cases the effect of
thermal AO on deposited contaminants can be neglected. However, due
to the relative velocity between AO and the space system (approx 8 km/s)
the collisional energy in the ram direction is around 5 eV.
The items and surfaces in the ram direction of the space system can be
attacked by AO, whereas the items and surfaces in the wake direction are
hardly attacked.
The effect of AO can be described as an oxidation and some materials can
become resistant to AO, e.g. non‐volatile oxides can be formed on some
metals.
Organic materials can be oxidized to volatile products such as CO and
H2O. The presence of silica contaminants on space system surfaces can be
explained by the attack of condensed silicone species by AO and the
formation of SiOx.
f. Micrometeoroids (debris)
Micrometeoroids have no direct effect on outgassing and on condensed
contaminants. Micrometeoroids can pierce some materials and can also
result in partly destruction of some materials, which causes release of a
large amount of new particles which escape into space or affect
neighbouring items. Impacts can also cause evaporation of the
micrometeoroid and of the impacted surface.
Redistribution of particles, which were already on space system surfaces
by micrometeoroid collisions, have been reported, but the effects are very
small.
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a. Gas and fluid leakage from pressurized systems
In space systems one can expect sealed pressurized units, such as
batteries and gyros; for these units leak rates have been specified which
do not result in unacceptable performance losses of those units. However,
the level of their leak rate or their location in the space system can be
such that the performances of sensitive items can be affected. Also the
leaks from pressurized units such as containers holding propulsion gases
or fluids (e.g. hydrazine) can affect contamination sensitive items.
Within long‐term space (station) programmes a number of fluids are
used, which potentially emerge from containments such as tanks, lines
and pressure shells to the exterior by leakage, venting or purging.
All fluids contribute to contamination.
e. Secondary products
Secondary products are generated by various intermolecular interactions
and chemical or physical processes due to payload or experiment
operations or interactions of the natural and induced environment
constituents and the space
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D.2.2 Transport mechanisms
D.2.2.1. Overview
Most of the effects of contamination occur in space, especially when solar
radiation is involved.
D.2.2.2.1 Overview
Surfaces can become contaminated by particles during all on ground phases
(e.g. MAIT, pre‐launch, and transportation).
• Direct flux
Contaminants in space move in straight lines from the space system into
deep space and can sometimes contaminate items located in the direct
view.
In order to mitigate this effect, design provision are generally a solution.
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• Indirect flux
Contaminants from space systems can impinge on a surface and after
reflection (specular) or re‐evaporation (diffusive) these contaminants can
affect other items or areas.
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• Degradation of thermal control surfaces (absorptivity/emissivity ration,
α/ε) especially in the case of molecular contamination on optical solar
reflectors at low temperatures.
• Loss of efficiency in heat pipes.
• Effects on conductive and non‐conductive surfaces (leak paths in
electronics).
• Loss of efficiency in solar cell generators.
• Corrosion of electrical contacts due to the presence of halogenated solder
fluxes.
• Space charge and discharge effects related to contaminants.
• Thermal radiation from particles.
• Disorientation due to erroneous reaction of star trackers to luminous
particles.
• Multipaction in waveguides.
• Bad closing of a valve.
• Explosion of a cryotechnic motor (Oil + O2).
• HF for a motor.
• Disturbance of gas flux and combustion within thrusters.
• Disturbance and propagation within RF wave guides.
• For the space environment around the space system, the “column
density”, local gas pressures and gas composition can be limiting factors
for some experiments.
Annex E (informative)
Cleanliness-oriented design
b. Position the sensitive items so that the view factors with respect to
contaminant sources (e.g. solar arrays, antennas and thrusters) are as low
as possible.
1. Locate the vent holes of the space system and the instruments
away from the sensitive items (= backdoor venting).
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3. Design baffles or shields for the sensitive items or even for the
contaminant sources.
10. Where sensitive items are expected, the design of the instruments
or space system should be such that purging is feasible in the
periods of assembly, integration, tests and launch preparations or
even up to launch.
11. Based upon these effects, the venting holes and other contaminant
sources should be located in the wake side of the space system.
c. On the other hand, the wake side of a space system can be used for
special experiments for which extremely low pressures in relatively low
Earth orbit are required.
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g. Ground support equipment, packaging, containerization, transportation
and storage.
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Annex F (informative)
Modelling guidelines
Annex G (informative)
Airborne particulate cleanliness classes
equivalence
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Annex H (informative)
Particulate levels on surfaces
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H.2.1 Overview
The obscuration factor (OF) is the ratio of the projected area of all particles to
the total surface area on which they rest.
This OF is in principle independent of the number‐size distribution of the
particles and even independent of the shape and colour of the particles. In
general the levels are expressed in parts per million (mm 2/m2) and acceptable
values are roughly between 10 mm2/m2 and 10 000 mm2/m2.
The OF has the advantage that a number of performance loss parameters are
directly related to the particle coverage of the critical item.
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Annex I (informative)
Compatibility of various solvents with
listed materials
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Table I‐1: Examples of compatibility of various solvents with listed materials
Type of material methanol ethanol IPA acetone MEK dichloromethane chloroform
polymer abbreviation
epoxy B A A B C C
Ethylene‐chlorotrifluoroethylene
E‐CTFE A A A B A C A
copolymer (HALAR®)
Ethylene‐tetrafluoroethylene
ETFE A A A B A B A
(TEFZEL®)
TEFLON® (Fluoroethylene
FEP A A A A A A A
propylene)
polycarbonates PC B A A D D D D
polyketone PK (PEEK) A A A A C
Polystyrene PS B A A D D D D
polysulfone PSF A A B D D D D
Polyethylene terephthalate
PET A A A C A D D
(MYLAR®)
polypropylene PP A A A B B C D
polyurethane PUR C C C D D D D
Polyvinylidene fluoride
PVDF A A A D D A A
(KYNAR®)
silicone A C A D D D D
Vinylidene fluoride –
hexafluoropropylene C A A D D A
(VITON A®)
metal
aluminum A B B A B B
Copper B A B A A A
Titanium B A B A A A
miscellaneous
Al2O3 A A A A A A
SiC A A A A A A
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Ratings on chemical effects @ 20°C:
A: excellent ‐ no damage after 30 days of constant exposure
B: resistant ‐ little or no damage after 30 days of constant exposure
C: fair to poor ‐ some effect after 7 days of constant exposure
D: not recommended ‐ immediate damage can occur
Blank: No data available
Sources: http://www.nalgenelabware.com
http://www.coleparmer.com/techinfo/chemcomp.asp
Annex J (informative)
evaporation residue of commercially
available solvents
chloroform
(with ethanol as stabilizer) ≥99,8 % ≤0,001 % <0,001 %
dichloromethane ≥99,5 % ≤0,002 % ≤0,002 %
absolute ≤0,001 % ‐
ethanol denatured ‐ ≤0,0005 %
isopropyl alcohol ≥99,5 % ≤0,001 % ≤0,001 %
methanol ≥99,8 % ≤0,001 % ≤0,001 %
methyl ethyl ketone ≥99 % ≤0,0025 % <0,0005 %
*Source : Sigma Aldrich
Annex K (informative)
Molecular contaminant content of some
wipe materials
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IPA DIW
Vectra alpha 10 ISO class 3‐4 0,05 0,02
absorbond ISO class 6‐7 0,01 0,005
Kimtech pure CL5 ISO class 5 0,01 0,03
Kimtech pure CL6 ISO class 6 0,01 0,03
Annex L (informative)
Effects of humidity on materials and
components
% RH
Range Effect
NOTE For some materials, humidity has an effect on the material dimensional stability
Annex M (informative)
Cleaning methods
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M.1.1 Overview
The removal of particulate contamination can be performed with, but not
limited to, the methods described in M.1.2 to M.1.4
• Cleaning with dry ice (e.g. CO2 jet spray) can be very effective.
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M.2.1 Overview
The removal of molecular contamination can be performed with, but not limited
to, the methods described in M.2.2 to M.2.8.
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M.2.7 Bakeout
• Volatilizing under vacuum is especially successful for cleaning assembled
units, or when solvent cleaning is too delicate an operation.
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Bibliography
72