QUESTION BANK

CLASS: XII, CHEMISTRY

UNIT: 2 SOLUTION
TRUE & FALSE TYPE QUESTIONS

(1)The solubility of a solid in liquid solution decreases if the dissolution process in endothermic and increases if
the process is exothermic in nature.(I) True (II) False

(2)1M aqueoussolution ismore concentrated than 1maqueoussolution. (I) True (II) False

(3) Alloys are solid in solidtype solution. (I) True (II) False

(4) Deep sea divers dilute O2with He in place of N2because of its high solubility in water. (I) True (II) False

(5) If liquidsA and Bform an idealsolution then the entropyofmixingis zero. (I) True (II) False

(6) IfH2SO4isadded towaterthen the solutionshowsnegative deviation from Raoult's law. (I) True (II) False

(7)The binarymixture of chloroform and benzene showsnegative deviation from Raoult's law. (I) True (II)False

(8) Binaryliquid mixture solution showing positive deviation from Raoult's law form maximum boiling azeotropes.

9 Addition of salt in water lowers the vapour pressure of water.

10 Molality is the number of moles of solute per litre of solution.
11 At high altitudes, the partial pressure of O2 is more than that at ground level.
The value of KH (Henry’s law constant) depends upon the nature of the gas.
12 The solubility of a gas in a liquid is depends on the temperature of the solution.
Increased pressure increases the solubility of atmospheric gases in blood.
13 Unsaturated solution is the one in which more solute can’t be dissolved.

True or False Questions

14 Mole fraction depends on temperature
15 Ideal solutions follow the Raoult’s law at all concentrations

16 If NaCl is added to ice then the melting point of ice will

a. increases
b. decreases
c. remains unchanged
d. first increases then decreases
17 If liquids A and B form an ideal solution
a. enthalpy of mixing is 0
b. entropy of mixing is 0
c. free energy of mixing is 0
d. free energy as well as entropy of mixing is 0
18 Which of the following statement is false
a. 5% of aqueous solution of NaCl and KCl are said to be isomolar
b. 1M sucrose solution and 1M glucose solution are isotonic
c. molecular mass of acetic acid and benzoic acid is higher than normal mass in cryoscopic methods.
∆
d. for the same solution, =
∆
19 Which is false among the following statement
a. Henry’s law is related with solubility of solid and liquid
b. Henry’s law is related with solubility of gas in liquid
c. greater the value of KH lower is the solubility
d. for Henry’s law P= X
20 Choose the True answer:
When non-volatile solute is added in solvent the vapour pressure of solution-
(a) increases
(b) decreases
(c) Remain same
(d) None of these
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21 Choose the true answer :
When non-volatile solute is added in solvent then the boiling point of solution-
a. Increase
b. Decrease
c. Remains same
d. None of these
22 Among the following which depends on temperature , choose the correct answer –
a. Molarity
b. Molality
c. Mole fraction
d. None of these
23 Which is the correct answer –
Amalgum of Hg with Na is example of
a. Gas in gas solution
b. Solid in liquid solution
c. Liquid in solid solution
d. Liquid in liquid solution

24.Brass is an alloy of Zinc and Iron. True/False

25 Amalgum is an example of solution of liquid in solid. True/False
26 If a liquid solute more volatile than the solvent is added to the solvent, the vapour pressure of the solution
may increase i.e. , ps>po
27 If one component of a solution obeys Raoult’s law over a certain range of composition , the other
component will also obey Henry’s law in that range.
28 6.57 mol/kg is the molality of ethanol solution in which mole fraction of water is 0.88
29 Mass percentage of a solution having 20 ppm of fluoride ion in it is 0.002%
30 Positively deviated non ideal solution forms minimum boiling point azeotropes.
31 The lowering of vapour pressure of a solution causes depression in the freezing point. True/False
32 When a solution is separated from the pure solvent by a semi-permeable membrane, the True/False
solvent molecules pass through it from the solution side to pure solvent side.
33 Molecular mass of polymers cannot be calculated using boiling point or freezing point method. True/False
34 Two different solutions of sucrose of same molality prepared in different solvents will have the True/False
same depression in freezing point.
35 The value of molal depression constant depends on nature of solvent. True/False
36 In reverse osmosis, solvent molecules move through a semi-permeable membrane from a True/False
region of lower concentration of solute to a region of higher concentration.
37 Colligative properties do not depend upon either physical or chemical properties of solutions. True/False
38 Addition of non-volatile solute to a liquid raises its boiling point and lowers its freezing point. True/False

Q39. Relative lowering in vapour pressure of solution is equal to mole fraction of solvent.
Q40. When a non-volatile solute dissolved in a given solvent, then the resultant solution has high
Boiling point than boiling point of that solvent.
Q41. Molarity and molality are the colligative properties.
Q42. Two solutions having the same osmotic pressure known as Isotonic solution.
Q43. Colligative properties are extensive properties.
Q44. Ethylene glycol is used in many commercial antifreeze products.
Q45. Only freezing point data can be used to determine molar mass.
Q46. The lowering in vapour pressure depends on the no. of dissolved solute particles.
47.When a volatile solute is added to a volatile solvent elevation in boiling point is observed.

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48.For the same solution, the elevation in boiling point has higher values than depression in freezing point.
49.WhenNaCl is added to water a depression in freezing point is observed.
50.When a solution is separated from the pure solvent by a semipermeable membrane, the solvent molecules pass
through it from pure solvent side to the solution side.
51.The values of colligative properties are smaller order as compared to values shown by true solutions at same
concentrations. T

52.0.1M solution of glucose has same increment in the freezing point than 0.1M0.1M solution of urea.

53.Diffusion of solvent occurs from a region of high concentration solution to a region of low concentration

solution.

54.The lowering of vapour pressure of a solution causes depression in the freezing point.

True/False
55 Bloodcellsretaintheirnormalshapeinsolutionwhichare hypotonictoblood.
True/False
56 According to Raoult’s law,the relative lowering of vapour pressure for a solution is equal to mole
fraction of solute.
True/False
57 At 100°C the vapour pressure of a solution of 6.5g of a solute in100g water is 732mm. If
Kb=0.52,the boiling point of this solution will be 1000C.
True/False
58 Isotonic solutions must have the same solute.
59 When a volatile solute is added to a volatile solvent elevation in boiling point is observed. True/False
True/False
60 Relative lowering of vapour pressure is a colligative property as it depends on the concentration
of a non electrolyte solute in solution and does not depend on the nature of the solute molecules.
61 Relative lowering of vapourpressure, is a dimensionless quantity.True/False
62 In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower
concentration of solute to a region of higher concentration.True/False

63 Molarity and mole fraction is temperature independent True/False

64 Dissolution of a gas in a liquid is always endothermic. True/False
65 Alloys are interstitial solid solutions. True/False
66 Azeotropes are not formed by non ideal solutions True/False
67 Mountain climbers often suffers from symptoms of Bends. True/False
68 The Henrys law constant for a highly soluble gases are high. True/False
69 Vapour pressure of a solution containing non volatile solute is lower than pure solvent. True/False
70 Dissolution of solid in water may be Exoor endothermic. True/False

71 Desalisation of sea water is based on Reverse Osmosis. True/False

72 The semipermeable membrane generally used in the reverse osmosis is made up of Cellulose acetate. True/False
73 The solutions having the same osmotic pressure are called hypotonic True/False
74 The rupturing of a plant or animal cell due to flow of water into it is called edema. True/False
75 The shrinking of a plant or animal cell due to outflow of water is called Plasmolysis. True/False
76 Red blood cells (RBC) are isotonic with 9.0% NaCl solution. True/False
77 The molal elevation constant of water is 0.52 K.kg/mol while that of benzene is 2.53 K.kg/mol True/False
78 The most colligative property to determine the molecular masses of polymers is elevation in boiling True/False
point.

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 79 The colligative property inverse proportional of molar mass of solute True/False
80 Colligative property of a solution is not direct proportional of no. Of particles of solute True/False
81 The additional pressure required to stop the flow of solvent is known as the osmotic pressure True/False
82 The nonvolatile solute’s solution represent deviation of Roult’s law True/False
83 Relative lowering in vapour pressure of a solvent is not equal to the mole fraction of solute True/False
84 Molecular mass of a solvent is a colligative property True/False
85 Elevation in b.p. is inverse proportional to molality True/False
86 The osmatic pressure is a single collagative property which is depend of the volume of solution True/False

87. Vapour pressure is a colligative property True/False

88. Addition of nonvolatile solute to a volatile solvent decreases the vapour pressure of solution True/False

89. The best colligative property to determine the molecular mass of polymers is osmotic pressure True/False

90. RBC neither swell up nor undergo plasmolysis in 0.9%soluton of pure NaCl as it is isotonic with True/False
human blood cell.
91 The solubility of a solute increases with increase in temperature if dissolution is exothermic. True/False

92 When 2 liters of 3 M AgNO3 is mixed with 3 liters of 1 M BaCl2 solution, the molarity of NO3 – ions True/False
in the final mixture will be 1.2M.
93. The relative lowering of vapour pressure of solvent at a given temperature due to dissolution of a non- True/False
volatile solute is equal to mole fraction of solute in the solution.
94 When a thin slice of sugar beet is placed in concentrated solution of NaCl, it will lose water due to True/False
osmosis.
95. Benzoic acid, when dissolved in benzene, then observed molar mass of benzoic acid in benzene will less than
normal molar mass. True/False
96. The measurement of osmotic pressure method is widely used to determine molar masses of proteins, polymers
and other macromolecules. True/False
97. Units of atmospheric pressure and osmotic pressure are same. True/False
98. Two different solutions of sucrose of same molality prepared in different solvents will have the same
depression in freezing point. True/False
99. Relative lowering of vapour pressure, is a dimensionless quantity. True/False
100. Two solutions having different osmotic pressure at a given temperature are called isotonic solutions.
True/False
101. In a solution containing several non-volatile solutes, the lowering of the vapour pressure depends on the sum
of the mole fraction of different solutes. True/False
102. The value of molal depression constant is independent on nature of solvent. True/False

103 Between molarity and molality, the second quantity is more reliable to measure concentration of a solution
and to use it in different situations (True/False).
104 The expression poA - p/poA= χB is the expression for relative lowering in vapour pressure of an ideal solution
containing non-volatile solute at a given temperature . (True/ False)
105 The sum of all the components in a binary mixture is greater than 1. (True/ False)
106 At higher altitudes people suffer from anoxia disease because there partial pressure of oxygen is much
greater than that at the ground level. (True/ False)
107 The solubility of lithium sulphate in water decreases with rise in temperature because the dissolution
process of this salt is exothermic. (True/False)
108 The expression p = KH.χ is meant for Raoult’s law. (True/ False)
109 Henry’s law is valid if the pressure is high. (True / False)
110 n-hexane and n-heptane will form non-ideal solution (True/False)

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 ANSWER-KEY

1 F 23 C 45 F 67 F 89 T
2 T 24 F 46 T 68 F 90 T
3 T 25 T 47 F 69 T 91 F
4 F 26 T 48 F 70 T 92 T
5 F 27 F 49 T 71 T 93 T
6 T 28 F 50 T 72 T 94 T
7 T 29 T 51 T 73 F 95 F
8 F 30 T 52 T 74 F 96 T
9 T 31 T 53 F 75 T 97 T
10 F 32 F 54 T 76 F 98 F
11 F 33 T 55 F 77 T 99 T
12 T 34 F 56 T 78 F 100 F
13 T 35 T 57 F 79 T 101 T
14 T 36 F 58 F 80 F 102 F
15 T 37 T 59 F 81 T 103 T
16 B 38 T 60 T 82 T 104 T
17 A 39 F 61 T 83 F 105 F
18 A 40 T 62 F 84 F 106 F
19 B 41 F 63 T 85 F 107 T
20 B 42 T 64 F 86 T 108 F
21 A 43 T 65 F 87 F 109 F
22 A 44 T 66 F 88 T 110 F

The questions submitted by the PGTs (Chemistry) of KVs of Bhubaneswar, Guwahati,

Kolkata, Ranchi, Silchar and Tinsukia Regions.
Vetted by: Guwahati Region

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