Compliant SDS for GHS: HazCom 2012 / United States; WHMIS 2015 / Canada

R
SAFETY DATA SHEET

Diesel Injector Clean

Date : 03/15/2017
Section 1. Identification Version : 7.1

GHS product identifier : Diesel Injector Clean

Code : ADF, ADFP
Product type : Liquid.

Identified uses : Diesel Fuel Additive.

Manufacturer : AMSOIL INC.

One AMSOIL Center
Superior, WI 54880
Tel: +1 715-392-7101
Initial Supplier : AMSOIL INC.
(Canada) Bordner, Ladner, Gervais
Scotia Plaza, 40 King St W
Toronto, ON, Canada M5H 3Y4
Tel: +1 416-367-6547

Emergency telephone : CHEMTREC: Within USA and Canada: 1-800-424-9300;

number (with hours of Outside USA and Canada: +1 703-741-5970 (collect calls accepted)
operation) (24/7)

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
RESPIRATORY SENSITIZATION - Category 1
SKIN SENSITIZATION - Category 1
CARCINOGENICITY - Category 2
TOXIC TO REPRODUCTION (Fertility) - Category 2
TOXIC TO REPRODUCTION (Unborn child) - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
ASPIRATION HAZARD - Category 1
AQUATIC HAZARD (ACUTE) - Category 2
AQUATIC HAZARD (LONG-TERM) - Category 2

GHS label elements

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Hazard pictograms :

Signal word : Danger

Hazard statements : Flammable liquid and vapor.
Causes serious eye irritation.
Causes skin irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Suspected of damaging fertility or the unborn child.
Suspected of causing cancer.
May be fatal if swallowed and enters airways.
May cause respiratory irritation.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Wear respiratory protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep container
tightly closed. Use only outdoors or in a well-ventilated area. Avoid release to the
environment. Avoid breathing vapor. Wash hands thoroughly after handling.
Contaminated work clothing must not be allowed out of the workplace.
Response : Collect spillage. IF exposed or concerned: Get medical attention. IF INHALED: If
breathing is difficult, remove person to fresh air and keep comfortable for breathing.
Call a POISON CENTER or physician if you feel unwell. If experiencing respiratory
symptoms: Call a POISON CENTER or physician. IF SWALLOWED: Immediately call
a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair):
Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON
SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse.
If skin irritation or rash occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise classified (HNOC)
Physical hazards not : None known.
otherwise classified
(PHNOC)
Health hazards not : None known.
otherwise classified
(HHNOC)

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Section 3. Composition/information on ingredients

Substance/mixture : Mixture
Other means of : Not available.
identification

CAS number/other identifiers

CAS number : Not applicable.
Product code : ADF, ADFP
Ingredient name % CAS number
Solvent naphtha, light arom. 80 - 100 64742-95-6
1,2,4-Trimethylbenzene 25 - 40 95-63-6
Hydrogenated Base Oil (64742-94-5) 15 - 25 64742-94-5
Xylene 1-5 1330-20-7
Naphthalene 1-5 91-20-3
Phenol, 4-dodecyl-, branched 1-5 210555-94-5
Cumene 0.1 - 1 98-82-8
Ethylenediamine 0.1 - 1 107-15-3
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it
is suspected that fumes are still present, the rescuer should wear an appropriate mask
or self-contained breathing apparatus. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Get medical attention. If necessary, call a poison center or physician. If unconscious,
place in recovery position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband. In the event of any
complaints or symptoms, avoid further exposure.
Skin contact : Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 20 minutes. Get medical attention. In the event of any
complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean
shoes thoroughly before reuse.

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Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter
lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by mouth to an
unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as a collar,
tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : May be fatal if swallowed and enters airways.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.

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Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet or water-based fire extinguishers.
media

Specific hazards arising : Flammable liquid and vapor. In a fire or if heated, a pressure increase will occur and
from the chemical the container may burst, with the risk of a subsequent explosion. Runoff to sewer may
create fire or explosion hazard. This material is toxic to aquatic life with long lasting
effects. Fire water contaminated with this material must be contained and prevented
from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

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Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities. Collect spillage.

Methods and materials for containment and cleaning up

Spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Persons with a
history of skin sensitization problems or asthma, allergies or chronic or recurrent
respiratory disease should not be employed in any process in which this product is used.
Avoid exposure - obtain special instructions before use. Avoid exposure during
pregnancy. Do not handle until all safety precautions have been read and understood.
Do not get in eyes or on skin or clothing. Do not swallow. Avoid breathing vapor or mist.
Avoid release to the environment. Use only with adequate ventilation. Wear
appropriate respirator when ventilation is inadequate. Do not enter storage areas and
confined spaces unless adequately ventilated. Keep in the original container or an
approved alternative made from a compatible material, kept tightly closed when not in
use. Store and use away from heat, sparks, open flame or any other ignition source.
Use explosion-proof electrical (ventilating, lighting and material handling) equipment.
Use only non-sparking tools. Take precautionary measures against electrostatic
discharges. Empty containers retain product residue and can be hazardous. Avoid
contact with used product. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-ventilated
incompatibilities area, away from incompatible materials (see Section 10) and food and drink. Store
locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.

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Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Under conditions which may generate mists, the following exposure limits are recommended:
ACGIH TLV TWA: 5 mg/m³ ; STEL: 10 mg/m³.
United States
Ingredient name Exposure limits
1,2,4-Trimethylbenzene ACGIH TLV (United States, 3/2015).
TWA: 25 ppm 8 hours.
TWA: 123 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 25 ppm 10 hours.
TWA: 125 mg/m³ 10 hours.
Xylene ACGIH TLV (United States, 3/2015).
TWA: 100 ppm 8 hours.
TWA: 434 mg/m³ 8 hours.
STEL: 150 ppm 15 minutes.
STEL: 651 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 100 ppm 8 hours.
TWA: 435 mg/m³ 8 hours.
Naphthalene ACGIH TLV (United States, 3/2015). Absorbed through skin.
TWA: 10 ppm 8 hours.
TWA: 52 mg/m³ 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 10 ppm 10 hours.
TWA: 50 mg/m³ 10 hours.
STEL: 15 ppm 15 minutes.
STEL: 75 mg/m³ 15 minutes.
OSHA PEL (United States, 2/2013).
TWA: 10 ppm 8 hours.
TWA: 50 mg/m³ 8 hours.
Cumene ACGIH TLV (United States, 3/2015).
TWA: 50 ppm 8 hours.
NIOSH REL (United States, 10/2013). Absorbed through skin.
TWA: 50 ppm 10 hours.
TWA: 245 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013). Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 245 mg/m³ 8 hours.
Ethylenediamine ACGIH TLV (United States, 3/2015). Absorbed through skin.
TWA: 10 ppm 8 hours.
NIOSH REL (United States, 10/2013).
TWA: 10 ppm 10 hours.
TWA: 25 mg/m³ 10 hours.
OSHA PEL (United States, 2/2013).
TWA: 10 ppm 8 hours.
TWA: 25 mg/m³ 8 hours.

Canada
Occupational exposure limits

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Ingredient name Exposure limits

1,2,4-Trimethylbenzene CA Alberta Provincial (Canada, 4/2009).
8 hrs OEL: 123 mg/m³ 8 hours.
8 hrs OEL: 25 ppm 8 hours.
CA British Columbia Provincial (Canada, 5/2015).
TWA: 25 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 25 ppm 8 hours.
TWAEV: 123 mg/m³ 8 hours.
CA Ontario Provincial (Canada, 7/2015).
TWA: 123 mg/m³ 8 hours.
TWA: 25 ppm 8 hours.
CA Saskatchewan Provincial (Canada).
STEL: 30 ppm 15 minutes.
TWA: 25 ppm 8 hours.
Naphthalene CA Alberta Provincial (Canada, 4/2009). Absorbed through skin.
15 min OEL: 15 ppm 15 minutes.
8 hrs OEL: 10 ppm 8 hours.
8 hrs OEL: 52 mg/m³ 8 hours.
15 min OEL: 79 mg/m³ 15 minutes.
CA British Columbia Provincial (Canada, 5/2015). Absorbed through
skin.
TWA: 10 ppm 8 hours.
STEL: 15 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
TWA: 10 ppm 8 hours.
TWA: 52 mg/m³ 8 hours.
STEL: 15 ppm 15 minutes.
STEL: 79 mg/m³ 15 minutes.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 10 ppm 8 hours.
TWAEV: 52 mg/m³ 8 hours.
STEV: 15 ppm 15 minutes.
STEV: 79 mg/m³ 15 minutes.
CA Saskatchewan Provincial (Canada). Absorbed through skin.
STEL: 15 ppm 15 minutes.
TWA: 10 ppm 8 hours.

Cumene CA Alberta Provincial (Canada, 4/2009).

8 hrs OEL: 50 ppm 8 hours.
8 hrs OEL: 246 mg/m³ 8 hours.
CA British Columbia Provincial (Canada, 5/2015).
TWA: 25 ppm 8 hours.
STEL: 75 ppm 15 minutes.
CA Ontario Provincial (Canada, 7/2015).
TWA: 50 ppm 8 hours.
CA Quebec Provincial (Canada, 1/2014).
TWAEV: 50 ppm 8 hours.
TWAEV: 246 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada).
STEL: 74 ppm 15 minutes.
TWA: 50 ppm 8 hours.
Ethylenediamine CA Alberta Provincial (Canada, 4/2009). Absorbed through skin.
8 hrs OEL: 25 mg/m³ 8 hours.
8 hrs OEL: 10 ppm 8 hours.
CA British Columbia Provincial (Canada, 5/2015). Absorbed through
skin. Skin sensitizer.
TWA: 10 ppm 8 hours.
CA Ontario Provincial (Canada, 7/2015). Absorbed through skin.
TWA: 10 ppm 8 hours.
TWA: 25 mg/m³ 8 hours.
CA Quebec Provincial (Canada, 1/2014). Absorbed through skin. Skin
sensitizer.
TWAEV: 10 ppm 8 hours.
TWAEV: 25 mg/m³ 8 hours.
CA Saskatchewan Provincial (Canada). Absorbed through skin.

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STEL: 15 ppm 15 minutes.

TWA: 10 ppm 8 hours.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Amber.
Odor : Aromatic hydrocarbon.

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Odor threshold : Not available.

pH : Not available.
Melting point : <-60°C (<-76°F)
Boiling point : Not available.
Flash point : Closed cup: 46 to 50°C (114.8 to 122°F) [Pensky-Martens.]
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Lower and upper explosive : Not available.
(flammable) limits
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.8833 to 0.8933
Solubility : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic: 0.011 to 0.015 cm2/s (1.1 to 1.5 cSt) (40oC)
Volatility : Not available.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

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Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Solvent naphtha, light arom. LD50 Oral Rat 8400 mg/kg -
1,2,4-Trimethylbenzene LC50 Inhalation Vapor Rat 18000 mg/m³ 4 hours
LD50 Oral Rat 5 g/kg -
Xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LD50 Oral Rat 4300 mg/kg -
Naphthalene LD50 Dermal Rabbit >20 g/kg -
LD50 Oral Rat 490 mg/kg -
Cumene LC50 Inhalation Vapor Rat 39000 mg/m³ 4 hours
LD50 Oral Rat 1400 mg/kg -
Ethylenediamine LD50 Oral Rat 1200 mg/kg -

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
Solvent naphtha, light arom. Eyes - Mild irritant Rabbit - 24 hours 100 µL -
Hydrogenated Base Oil (64742-94-5) Skin - Mild irritant Rabbit - 24 hours 500 µL -
Xylene Eyes - Mild irritant Rabbit - 87 mg -
Eyes - Severe irritant Rabbit - 24 hours 5 mg -
Skin - Mild irritant Rat - 8 hours 60 µL -
Skin - Moderate irritant Rabbit - 24 hours 500 mg -
Skin - Moderate irritant Rabbit - 100 % -
Naphthalene Skin - Mild irritant Rabbit - 495 mg -
Cumene Eyes - Mild irritant Rabbit - 24 hours 500 mg -
Eyes - Mild irritant Rabbit - 86 mg -
Skin - Mild irritant Rabbit - 24 hours 10 mg -
Ethylenediamine Eyes - Severe irritant Rabbit - 24 hours 750 µg -
Eyes - Severe irritant Rabbit - 750 µg -
Skin - Moderate irritant Rabbit - 450 mg -
Skin - Severe irritant Rabbit - 24 hours 10 mg -

Sensitization
There is no data available.
Carcinogenicity
Classification
Product/ingredient name OSHA IARC NTP
Xylene - 3 -
Naphthalene - 2B Reasonably anticipated to be a human carcinogen.
Cumene - 2B Reasonably anticipated to be a human carcinogen.

Specific target organ toxicity (single exposure)

Name Category Target organs
1,2,4-Trimethylbenzene Category 3 Respiratory tract irritation
Phenol, 4-dodecyl-, branched Category 3 Respiratory tract irritation
Cumene Category 3 Respiratory tract irritation

Specific target organ toxicity (repeated exposure)

There is no data available.
Aspiration hazard

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Name Result
Solvent naphtha, light arom. ASPIRATION HAZARD - Category 1
Hydrogenated Base Oil (64742-94-5) ASPIRATION HAZARD - Category 1
Cumene ASPIRATION HAZARD - Category 1

Information on the likely : Dermal contact. Eye contact. Inhalation. Ingestion.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : May cause respiratory irritation. May cause allergy or asthma symptoms or breathing
difficulties if inhaled.
Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : May be fatal if swallowed and enters airways.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
wheezing and breathing difficulties
asthma
reduced fetal weight
increase in fetal deaths
skeletal malformations
Skin contact : Adverse symptoms may include the following:
irritation
redness
reduced fetal weight
increase in fetal deaths
skeletal malformations
Ingestion : Adverse symptoms may include the following:
nausea or vomiting
reduced fetal weight
increase in fetal deaths
skeletal malformations

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : No known significant effects or critical hazards.
effects
Potential delayed effects : No known significant effects or critical hazards.
Long term exposure
Potential immediate : No known significant effects or critical hazards.
effects
Potential delayed effects : No known significant effects or critical hazards.
Potential chronic health effects

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General : Once sensitized, a severe allergic reaction may occur when subsequently exposed to
very low levels.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : Suspected of damaging the unborn child.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : Suspected of damaging fertility.

Numerical measures of toxicity

Acute toxicity estimates
Route ATE value
Oral 15381.8 mg/kg
Dermal 78867.2 mg/kg
Inhalation (gases) 358487.1 ppm
Inhalation (vapors) 85.71 mg/L

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
1,2,4-Trimethylbenzene Acute LC50 4910 µg/l Marine water Crustaceans - Elasmopus pectenicrus - 48 hours
Adult
Acute LC50 7720 µg/l Fresh water Fish - Pimephales promelas 96 hours
Naphthalene Acute EC50 1600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Acute LC50 2350 µg/l Marine water Crustaceans - Palaemonetes pugio 48 hours
Acute LC50 213 µg/l Fresh water Fish - Melanotaenia fluviatilis - Larvae 96 hours
Cumene Acute EC50 2600 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours
Acute EC50 7400 µg/l Fresh water Crustaceans - Artemia sp. - Nauplii 48 hours
Acute EC50 10600 µg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours
Acute LC50 2700 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours
Ethylenediamine Acute EC50 151000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours
Acute LC50 115.7 mg/L Fresh water Fish - Pimephales promelas 96 hours

Persistence and degradability

There is no data available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Solvent naphtha, light arom. - 10 to 2500 high
1,2,4-Trimethylbenzene 3.63 243 low
Hydrogenated Base Oil (64742-94-5) 2.8 to 6.5 99 to 5780 high
Xylene 3.12 8.1 to 25.9 low
Naphthalene 3.4 36.5 to 168 low
Cumene 3.55 94.69 low
Ethylenediamine -7.02 - low

Mobility in soil
Soil/water partition : There is no data available.
coefficient (KOC)

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Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable products via a licensed waste
disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material and its container must be disposed of in a safe
way. Care should be taken when handling empty containers that have not been cleaned
or rinsed out. Empty containers or liners may retain some product residues. Vapor
from product residues may create a highly flammable or explosive atmosphere inside
the container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil,
waterways, drains and sewers.
United States - RCRA Toxic hazardous waste "U" List
Ingredient CAS # Status Reference
number
Xylene 1330-20-7 Listed U239
Naphthalene 91-20-3 Listed U165

Section 14. Transport information

DOT TDG IMDG IATA
UN number UN1993 UN1993 UN1993 UN1993

UN proper FLAMMABLE LIQUIDS, N.O.S. FLAMMABLE LIQUIDS, N.O. FLAMMABLE LIQUIDS, N.O.S. FLAMMABLE LIQUIDS, N.O.S.
(Solvent naphtha, light arom.) S. (Solvent naphtha, light (Solvent naphtha, light arom.). (Solvent naphtha, light arom.)
shipping name RQ (Xylene, Naphthalene) arom.) Marine pollutant (1,2,
4-Trimethylbenzene,
Naphthalene)

Transport 3 3 3 3
hazard class(es)

Packing group III III III III

Environmental No. Yes. Yes. Yes. The
hazards environmentally
hazardous substance
mark is not required.

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Additional This product may be re- Product classified as per the The marine pollutant mark is
The environmentally
classified as "Combustible following sections of the not required when transported
hazardous substance mark
information Liquid," unless transported by Transportation of Dangerous in sizes of ≤5 L or ≤5 kg. may appear if required by
vessel or aircraft. Non-bulk Goods Regulations: 2.18-2. other transportation
packages (less than or equal 19 (Class 3), 2.7 (Marine Emergency schedules (EmS) regulations.
to 119 gal) of combustible pollutant mark). F-E, S-E
liquids are not regulated as Remarks
hazardous materials in The marine pollutant mark is Remarks Limited Quantity Exemption
package sizes less than the not required when Limited Quantity Exemption
product reportable quantity. transported by road or rail.

Reportable quantity Remarks

5302.6 lbs / 2407.4 kg [0. Limited Quantity Exemption
14237 gal / 0.53893 L]
Package sizes shipped in
quantities less than the
product reportable quantity are
not subject to the RQ
(reportable quantity)
transportation requirements.

Remarks
Limited Quantity Exemption

AERG : 128
DOT-RQ Details : Xylene 100 lbs / 45.4 kg [13.946 gal / 52.791 L]
Naphthalene 100 lbs / 45.4 kg

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to Annex II of MARPOL and
the IBC Code

Section 15. Regulatory information

U.S. Federal regulations : United States inventory (TSCA 8b): All components are listed or exempted.
Clean Water Act (CWA) 307: Naphthalene
Clean Water Act (CWA) 311: Xylene; Naphthalene; Ethylenediamine; Formaldehyde
Clean Air Act Section 112 : Listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304

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Composition/information on ingredients
SARA 302 TPQ SARA 304 RQ
Name EHS (lbs) (gallons) (lbs) (gallons)
Ethylenediamine Yes. 10000 1337.1 5000 668.5
Formaldehyde Yes. 500 73.9 100 14.8

SARA 304 RQ : 1186957.7 lbs / 538878.8 kg [31.9 gal / 120.6 L]

SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
Composition/information on ingredients
Name Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
Solvent naphtha, light arom. Yes. No. No. Yes. No.
1,2,4-Trimethylbenzene Yes. No. No. Yes. No.
Xylene Yes. No. No. Yes. No.
Naphthalene Yes. No. No. Yes. Yes.
Phenol, 4-dodecyl-, branched No. No. No. Yes. Yes.
Cumene Yes. No. No. Yes. Yes.
Ethylenediamine Yes. No. No. Yes. No.

SARA 313
Product name CAS number %
1,2,4-Trimethylbenzene 95-63-6 25 - 40
Form R - Reporting Xylene 1330-20-7 1-5
requirements Naphthalene 91-20-3 1-5
1,2,4-Trimethylbenzene 95-63-6 25 - 40
Supplier notification Xylene 1330-20-7 1-5
Naphthalene 91-20-3 1-5

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: 1,2,4-Trimethylbenzene; Xylene; Naphthalene
New York : The following components are listed: Xylene; Cumene; Naphthalene
New Jersey : The following components are listed: 1,2,4-Trimethylbenzene; Xylene; Cumene;
Naphthalene
Pennsylvania : The following components are listed: 1,2,4-Trimethylbenzene; Xylene; Cumene;
Naphthalene
California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer.
WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or
other reproductive harm.

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Ingredient name Cancer Reproductive No significant risk Maximum

level acceptable dosage
level
Naphthalene Yes. No. Yes. No.
Cumene Yes. No. No. No.
Formaldehyde Yes. No. Yes. No.
Methanol No. Yes. No. 23000 µg/day (ingestion)
47000 µg/day (inhalation)

Canada
Canadian lists
Canadian NPRI : The following components are listed: Solvent naphtha, light arom.; 1,2,
4-Trimethylbenzene; Xylene; Hydrogenated Base Oil (64742-94-5); Naphthalene
CEPA Toxic substances : The following components are listed: Naphthalene
Canada inventory : All components are listed or exempted.

Section 16. Other information

History
Date of issue mm/dd/yyyy : 03/15/2017
Date of previous issue : 02/15/2017
Version : 7.1
Prepared by : AMSOIL INC.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its
subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be
used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

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