SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

Smoke Flavour
Version 11.0 Revision Date 12 DEC 2022 Print Date 27 FEB 2023

SECTION 1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Sales No. : DF-108-970-2
Smoke Flavour

1.2 Relevant identified uses of the substance or mixture and uses advised against
Intended Use Flavours : Flavouring for foodstuffs. Not for retail sale

1.3 Details of the supplier of the safety data sheet

Company :
Givaudan MEA FZE
JAFZA views 18, 5th floor
Jebel Ali Free Zone
Dubai
UNITED ARAB EMIRATES

Telephone : +97144040300
Telefax : +97143340224
E-mail address : [email protected]
Responsible/issuing person

1.4 Emergency Call

Givaudan 24/7 call : +441235239671

Please refer to section 16 for a full list of emergency phone numbers, from Givaudan's 24/7
provider.

SECTION 2. Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Not a hazardous substance or mixture.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

2.3 Other hazards

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Hazards not Otherwise : May form combustible dust concentrations in air.

Classified.

This substance/mixture contains no components considered to be either persistent,

bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

Ecological information: The substance/mixture does not contain components considered to have
endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

Toxicological information: The substance/mixture does not contain components considered to

have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated
regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

SECTION 3. Composition/information on ingredients

3.2 Mixtures
Remarks : No hazardous ingredients

SECTION 4. First aid measures

4.1 Description of first aid measures

General advice : Do not leave the victim unattended.

If inhaled : If unconscious, place in recovery position and seek medical

advice.
If symptoms persist, call a physician.

In case of skin contact : Take off contaminated clothing and shoes immediately.
If on skin, rinse well with water.

In case of eye contact : Remove contact lenses.

Immediately flush eyes for at least 15 minutes. Get medical
attention.

If swallowed : Keep respiratory tract clear.

Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

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Symptoms : no data available

Risks : no data available

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : no data available

SECTION 5. Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Dry chemical
Alcohol-resistant foam
Carbon dioxide (CO2)
Water spray

Unsuitable extinguishing : no data available

media
5.2 Special hazards arising from the substance or mixture
Specific hazards during : no data available
firefighting
5.3 Advice for firefighters
Special protective equipment : Wear self-contained breathing apparatus for firefighting if
for firefighters necessary.

Further information : Standard procedure for chemical fires.

Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.

SECTION 6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : no data available
6.2 Environmental precautions
Environmental precautions : Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Pick up and arrange disposal without creating dust.
Sweep up and shovel.
Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

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Not applicable

SECTION 7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.

Advice on protection against : Provide appropriate exhaust ventilation at places where dust
fire and explosion is formed.

Temperature class : no data available

Fire-fighting class : no data available
Dust explosion class : St1

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Electrical installations / working materials must comply with
areas and containers the technological safety standards.

Further information on : Ambient / 10-30°C (50-85°F)

storage conditions Preferably full, hermetically sealed
Advice on common storage : no data available
Storage class (TRGS 510) : 11 Combustible Solids
Other data : No decomposition if stored and applied as directed.

7.3 Specific end use(s)

Specific use(s) : no data available

SECTION 8. Exposure controls/personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.

8.2 Exposure controls

Exposure assessment: Exposures are dependent on the product being handled, the
potential for chemical release, and any resulting airborne concentrations or dermal
contact. Since product handling and release scenarios vary, and no two workplaces are
exactly alike, it is recommended that the potential for exposure be assessed prior to the
prod-uct’s use or introduction. Exposure assessments should be performed by an
occupational hygienist, industrial hygienist, or other qualified occupational or

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environmental health professional. An exposure assessment should be conducted to

determine the efficacy of any ventilation and the need for additional PPE. The PPE
indicated below are recommendations for worst-case scenario exposures. An exposure
assessment will identify more applicable measures to be implemented. EN and ANSI
standards are mentioned in the following recommendations, consult equivalent local
standards when required.
PPE is always the last resort to avoid exposure. In any case technical and organisational
measures have to be explored and used prior to the selection of PPE. The PPE selection
is for operators trained to work with chemicals according to good industrial hygiene and
safety practice. Operators have to be trained on the use of PPE.

8.2.1 Engineering measures

Use engineering controls to maintain airborne levels below exposure limit requirements or
guidelines. If there are no applicable exposure limit requirements or guidelines, use the product
only with adequate ventilation.

8.2.2 Personal protective equipment

Eye/face protection : Use safety glasses tested according to EN 166/ANSI Z87.1 or
equivalent local standard.

Hand protection : Use gloves when handling substance in open systems.

Inspect gloves prior to use. Train operators for proper use.If
only incidental exposure is expected: (work without direct
contact to substance) use gloves tested according EN 16523-
1/ASTM F739 or equivalent local standard breakthrough times
at least 10 minutes, tested for chemicals indicated in chapter 3
of this SDS. Change gloves frequently.
If direct skin contact is expected: use gloves tested according
to EN 16523-1/ASTM F739 or equivalent local standard,
tested for chemicals indicated in chapter 3 of this SDS.
Permeation time must exceed contact time.

Other skin protection : Wear working clothes covering arms and legs.

Respiratory protection : Respiratory protection should be worn when workplace

exposures exceed exposure limit requirements or guidelines.
If there are no applicable exposure limits or guidelines, use an
approved respirator where there is a potential for adverse
effects, including but not limited to respiratory irritation or odor,
or where indicated by the exposure assessment. Selection of
air-purifying or positive-pressure supplied-air will depend on
the results of the exposure assessment which includes an
evaluation of the specific operations and the potential airborne
concentrations. For emergency conditions, use an approved
positive-pressure self-contained breathing apparatus.

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In case a risk analysis proved the cartridge respirator as

acceptable, use type:
P3 (EN 149) OR P100 (42CFR84.193; ANSI Z88.7) or
equivalent local standard as a backup to engineering controls.
Use respirators and components tested and approved under
appropriate government standards such as CEN (EU) or
NIOSH 42 CFR 84(US).

Thermal hazards : Wear appropriate thermal protective clothing, when

necessary.

Hygiene measures : Remove contaminated clothing and protective equipment

before entering eating areas.
Do not eat, drink or smoke during work.
Wash hands any time after handling the product.
Avoid breathing dust.

8.2.3 Environmental exposure controls

General advice : Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.

SECTION 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : solid
Form : Spray dried powder
Colour : Brownish to Pale brown
Taste : Smoky, Phenolic
Odour : not determined
Odour Threshold : Not applicable
Flash point : Not applicable
Lower explosion limit : not determined
Upper explosion limit : not determined
Flammability : May form combustible dust concentrations in air.
Dust explosion class : St1
Oxidizing properties : no data available
Auto-ignition temperature : not determined
Decomposition temperature : no data available
pH : not determined
Melting point : not determined
Boiling point : not determined
Vapour pressure : no data available
Density : Not applicable
Bulk density : 0,42 Kg/l
Water solubility : not determined
Solubility/qualitative : soluble

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Partition coefficient: n- : Not applicable

octanol/water
Viscosity, kinematic : no data available
Relative vapour density : no data available
Evaporation rate : no data available
Explosive properties : no data available

9.2 Other information

Not applicable

SECTION 10. Stability and reactivity

10.1 Reactivity
none
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable under recommended storage conditions., No hazards
to be specially mentioned.

10.4 Conditions to avoid

Conditions to avoid : no data available

10.5 Incompatible materials

Materials to avoid : no data available

10.6 Hazardous decomposition products

Hazardous decomposition : no data available
products
Thermal decomposition : no data available

SECTION 11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity
Acute oral toxicity : No data is available on the product itself.

Acute inhalation toxicity : No data is available on the product itself.

Acute dermal toxicity : No data is available on the product itself.

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Acute toxicity (other routes : No data is available on the product itself.

of administration)

Skin : No data is available on the product itself.

corrosion/irritationSkin
irritation

Serious eye damage/eye irritation

Eye irritation : No data is available on the product itself.

Respiratory or skin sensitisation

Sensitisation : No data is available on the product itself.

Germ cell mutagenicity

Germ cell mutagenicity : No data is available on the product itself.

Carcinogenicity
Carcinogenicity : No data is available on the product itself.

Reproductive toxicity : No data is available on the product itself.

Target Organ Systemic Toxicant - Single exposure

Target Organ Systemic : No data is available on the product itself.
Toxicant - Single exposure

Target Organ Systemic Toxicant - Repeated exposure

Target Organ Systemic : No data is available on the product itself.
Toxicant - Repeated
exposure

Aspiration hazard
Aspiration toxicity : No data is available on the product itself.

Phototoxicity
Phototoxicity : No data is available on the product itself.

Further information : no data available

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11.2 Information on other hazards

Endocrine disrupting properties
Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

Further information
Product:
Remarks : no data available

SECTION 12. Ecological information

12.1 Toxicity
no data available
12.2 Persistence and degradability
no data available
12.3 Bioaccumulative potential
no data available
12.4 Mobility in soil
no data available
12.5 Results of PBT and vPvB assessment
Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

12.6 Endocrine disrupting properties

Product:
Assessment : The substance/mixture does not contain components
considered to have endocrine disrupting properties according
to REACH Article 57(f) or Commission Delegated regulation
(EU) 2017/2100 or Commission Regulation (EU) 2018/605 at
levels of 0.1% or higher.

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12.7 Other adverse effects

Product:
Additional ecological : no data available
information

SECTION 13. Disposal considerations

13.1 Waste treatment methods

Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.

Dispose of in accordance with local regulations.

SECTION 14. Transport information

14.1 UN number

N/A
14.2 UN proper shipping name

Not regulated as a dangerous good

14.3 Transport hazard class(es)

N/A
14.4 Packing group

N/A
14.5 Environmental hazards

N/A
14.6 Special precautions for user

IMDG
IMDG Code Segregation : None
Group
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

SECTION 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or

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mixture

REACH - Candidate List of Substances of Very High : Neither banned nor restricted
Concern for Authorisation (Article 59).
Major Accident Hazard : Not applicable
Legislation

Water hazard class : WGK 3 highly hazardous to water

(Germany) Classification according to AwSV, Annex 1 (5.2)

15.2 Chemical safety assessment

A Chemical Safety Assessment is not required for this substance.

SECTION 16. Other information

Full list of Emergency response numbers worldwide.

Country Phone nr Country Phone nr

All East/South
All Europe +44 1235 239670 +65 3158 1074
East Asia
France +33 1 72 11 00 03 Sri Lanka +65 3158 1195

Germany +49 89 220 61012 Taiwan +886 2 8793 3212

Spain +34 91 114 2520 Japan 0120 015 230
Italy 800 699 792 Indonesia 007 803 011 0293
Netherlands +31 10 713 8195 Malaysia +60 3 6207 4347
0800 621 2139
Turkey Thailand 001 800 120 666 751
+44 1235 239670
Europe +65 3158 1198
Norway +47 2103 4452 India
000 800 100 7479
APAC
Greece +30 21 1198 3182 Pakistan +65 3158 1329
Portugal +351 30880 4750 Bangladesh +65 3158 1200
Denmark +45 8988 2286 Philippines +63 2 8231 2149
Sweden +46 8 566 42573 Vietnam +84 28 4458 2388
Poland +48 22 307 3690 Korea +65 3158 1285
Czech
+420 228 882 830 South Korea +82 2 3479 8401
replublic
Finland +358 9 7479 0199 Australia +61 2 8014 4558
All Middle
+44 1235 239671 New Zealand +64 9 929 1483
Middle East/Africa
East/Africa Bahrain and
+44 1235 239671 China +86 532 8388 9090
Middle East

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Africa/South
+27 21 300 2732 Mexico +52 55 5004 8763
Africa
USA and
+1 866 928 0789 Brazil +55 11 3197 5891
Canada
USA and
NOAM +1 215 207 0061 LATAM Chile +56 2 2582 9336
Canada
USA and
+1 202 464 2554 Colombia +57 1 508 7337
Canada
Global Global +44 1865 407333 Argentina +54 11 5984 3690

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Key or legend to abbreviations and acronyms used in the safety data sheet

ADN - European Agreement concerning the International Carriage of Dangerous Goods by

Inland Waterways; ADR - Agreement concerning the International Carriage of Dangerous
Goods by Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging
Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive
Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic
Substances List (Canada); ECHA - European Chemicals Agency; EC-Number - European
Community number; ECx - Concentration associated with x% response; ELx - Loading rate
associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New
Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate
response; GHS - Globally Harmonized System; GLP - Good Laboratory Practice; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association;
IBC - International Code for the Construction and Equipment of Ships carrying Dangerous
Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil
Aviation Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG -
International Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL -
Industrial Safety and Health Law (Japan); ISO - International Organisation for Standardization;
KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test
population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL -
International Convention for the Prevention of Pollution from Ships; n.o.s. - Not Otherwise
Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No Observed
(Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New Zealand
Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development;
OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent,
Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of Chemicals and
Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH -
Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the
Registration, Evaluation, Authorisation and Restriction of Chemicals; RID - Regulations
concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating
Decomposition Temperature; SDS - Safety Data Sheet; SVHC - Substance of Very High
Concern; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand Existing Chemicals
Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Substances
Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very
Bioaccumulative

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with
any other materials or in any process, unless specified in the text.

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Information displayed in section 3 (Composition/information on ingredients) is additional

information to understand the hazards of the product and ensure safe handling, storage and
transportation. This information, including CAS numbers, is not meant to be used for
registration, notification or any other purposes. Any additional information and documentation
needed may be provided by Givaudan.

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