SAFETY DATA SHEET

95 Octane Petrol (Premium)

Section 1. Identification
Product name 95 Octane Petrol (Premium)
Product code 0000003076
SDS no. 0000003076
Use of the substance/mixture Use only as a motor fuel for spark ignition engines. NOT for aviation use. Should NOT be
used as a solvent nor cleaning agent.
Product type Liquid.
Supplier BP Oil New Zealand Limited
Ground floor and 1st floor
Watercare House
73 Remuera Road
Newmarket
Auckland
New Zealand

General enquiries
Helpdesk: 0800 800 027
Email: [email protected]
Emergency telephone number Tel: 0800 805 111
New Zealand National Poisons 0800 764 766
Centre

Section 2. Hazards identification

HSNO Classification 3.1 - FLAMMABLE LIQUIDS - Category A
6.3 - SKIN IRRITATION - Category B
6.7 - CARCINOGENICITY - Category B
6.1 - ACUTE TOXICITY (aspiration) (oral) - Category E
9.1 - AQUATIC ECOTOXICITY - Category B
This material is classified as hazardous according to criteria in the Hazardous Substances (Minimum Degrees of
Hazard) Regulations 2001 and has been classified according to the Hazardous Substances (Classifications)
Regulations 2001.
This material is classified as DANGEROUS GOODS according to criteria in New Zealand Standard 5433:2012
Transport of Dangerous Goods on Land.
Routes of entry Dermal contact. Eye contact. Inhalation. Ingestion.
GHS label elements
Signal word Danger
Hazard statements Extremely flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Causes mild skin irritation.
Suspected of causing cancer.
Toxic to aquatic life with long lasting effects.
Precautionary statements
Prevention Obtain special instructions before use. Do not handle until all safety precautions
have been read and understood. Use personal protective equipment as required.
Wear protective gloves. Wear eye or face protection. Keep away from ignition
sources such as heat/sparks/open flame. - No smoking. Use explosion-proof
electrical, ventilating, lighting and all material-handling equipment. Use only non-
sparking tools. Take precautionary measures against static discharge. Keep
container tightly closed. Avoid release to the environment. Keep out of reach of
children. If medical advice is needed: Have product container or label at hand.

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Section 2. Hazards identification
Response Collect spillage. Immediately call a POISON CENTER or doctor/physician. IF
SWALLOWED: Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off
immediately all contaminated clothing. Rinse skin with water [or shower]. IF
exposed or concerned: Get medical advice/attention.
Storage Store locked up. Store in a well-ventilated place. Keep cool.
Disposal Dispose of contents and container in accordance with all local, regional, national
and international regulations.
Symbol

Other hazards which do not Contains Benzene. Prolonged or repeated exposure to benzene can cause
result in classification anaemia and other blood diseases, including leukaemia.

Section 3. Composition/information on ingredients

Substance/mixture Mixture
Methyl tert-butyl ether: <0.2%
Ingredient name % CAS number
Gasoline >90 86290-81-5
Benzene <1 71-43-2
diisopropyl ether <1 108-20-3
Ethanol <1 64-17-5
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require
reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Inhalation If inhaled, remove to fresh air. Get medical attention.
Ingestion Do not induce vomiting. Get medical attention immediately. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and get
medical attention immediately. Aspiration hazard if swallowed. Can enter lungs and
cause damage.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse.
Clean shoes thoroughly before reuse. Get medical attention if symptoms occur.
Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Check for and remove any contact lenses. Eyelids should be held away
from the eyeball to ensure thorough rinsing. Get medical attention if symptoms
occur.
Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.
Product can be aspirated on swallowing or following regurgitation of stomach
contents, and can cause severe and potentially fatal chemical pneumonitis, which
will require urgent treatment. Because of the risk of aspiration, induction of vomiting
and gastric lavage should be avoided. Gastric lavage should be undertaken only
after endotracheal intubation. Monitor for cardiac dysrhythmias.
Protection of first-aiders No action shall be taken involving any personal risk or without suitable training. It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

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Section 5. Firefighting measures
Extinguishing media
Suitable In case of fire, use water fog, foam, dry chemical or carbon dioxide extinguisher or
spray.
Not suitable The use of a water jet may cause the fire to spread by splashing the burning product.
Do not use water jet.
Specific hazards arising Extremely flammable liquid and vapour. In a fire or if heated, a pressure increase
from the chemical will occur and the container may burst, with the risk of a subsequent explosion. The
vapour/gas is heavier than air and will spread along the ground. Vapours may
accumulate in low or confined areas or travel a considerable distance to a source of
ignition and flash back. Runoff to sewer may create fire or explosion hazard. This
material is toxic to aquatic life with long lasting effects. Fire water contaminated with
this material must be contained and prevented from being discharged to any
waterway, sewer or drain. Liquid will float and may reignite on surface of water.
Hazardous combustion Combustion products may include the following:
products carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)
Hazchem code 3YE
Special precautions for fire- No action shall be taken involving any personal risk or without suitable training.
fighters Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. Move containers from fire area if this can be done without risk. Use
water spray to keep fire-exposed containers cool.
Special protective Fire-fighters should wear appropriate protective equipment and self-contained
equipment for fire-fighters breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency Immediately contact emergency personnel. No action shall be taken involving any
personnel personal risk or without suitable training. Eliminate all ignition sources. Evacuate
surrounding areas. Keep unnecessary and unprotected personnel from entering.
Do not touch or walk through spilt material. Floors may be slippery; use care to
avoid falling. No flares, smoking or flames in hazard area. Avoid breathing vapour
or mist. Provide adequate ventilation. Put on appropriate personal protective
equipment (see Section 8).
For emergency responders Entry into a confined space or poorly ventilated area contaminated with vapour, mist
or fume is extremely hazardous without the correct respiratory protective equipment
and a safe system of work. Wear self-contained breathing apparatus. Wear a
suitable chemical protective suit. Chemical resistant boots. See also the
information in "For non-emergency personnel".
Environmental precautions Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful
to the environment if released in large quantities. Collect spillage. In case of small
spillages in closed waters (i.e. ports), contain product with floating barriers or other
equipment. Collect spilled product by absorbing with specific floating absorbents. If
possible, large spillages in open waters should be contained with floating barriers or
other mechanical means. If this is not possible, control the spreading of the spillage,
and collect the product by skimming or other suitable mechanical means. The use
of dispersants should be advised by an expert, and, if required, approved by local
authorities. Collect recovered product and other contaminated materials in suitable
tanks or containers for recycle, recovery or safe disposal.
Methods and material for containment and cleaning up
Small spill Eliminate all ignition sources. Stop leak if without risk. Use spark-proof tools and
explosion-proof equipment. Move containers from spill area. Absorb with an inert
material and place in an appropriate waste disposal container. The method and
equipment used must be in conformance with appropriate regulations and industry
practice on explosive atmospheres. Dispose of via a licensed waste disposal
contractor.

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Section 6. Accidental release measures
Large spill Eliminate all ignition sources. Stop leak if without risk. Move containers from spill
area. Approach the release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Dike spill area and do not allow product to reach
sewage system and surface or ground water. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth
and place in container for disposal according to local regulations (see Section 13).
Use spark-proof tools and explosion-proof equipment. Contaminated absorbent
material may pose the same hazard as the spilt product. The method and
equipment used must be in conformance with appropriate regulations and industry
practice on explosive atmospheres. Dispose of via a licensed waste disposal
contractor.

Section 7. Handling and storage

Precautions for safe Put on appropriate personal protective equipment (see Section 8). Do not get in
handling eyes or on skin or clothing. Do not swallow. Never siphon by mouth. Avoid
exposure - obtain special instructions before use. Avoid breathing vapour or mist.
Use only with adequate ventilation. Avoid release to the environment. Do not enter
storage areas and confined spaces unless adequately ventilated. Wear appropriate
respirator when ventilation is inadequate. Take precautionary measures against
electrostatic discharges. To avoid fire or explosion, dissipate static electricity during
transfer by earthing and bonding containers and equipment before transferring
material. Wash thoroughly after handling. Eating, drinking and smoking should be
prohibited in areas where this material is handled, stored and processed. Remove
contaminated clothing and protective equipment before entering eating areas.
Workers should wash hands and face before eating, drinking and smoking. Keep in
the original container or an approved alternative made from a compatible material,
kept tightly closed when not in use. Store and use away from heat, sparks, open
flame or any other ignition source. Use explosion-proof electrical (ventilating,
lighting and material handling) equipment. Use only non-sparking tools. Empty
containers retain product residue and can be hazardous. Do not reuse container.
Aspiration hazard if swallowed. Can enter lungs and cause damage. See also
Section 8 for additional information on hygiene measures.
Conditions for safe storage, Store in accordance with local regulations. Store in a segregated and approved
including any area. Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidising materials. Keep
container tightly closed and sealed until ready for use. Store and use only in
equipment/containers designed for use with this product. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not
store in unlabelled containers. Use appropriate containment to avoid environmental
contamination.

Light hydrocarbon vapours can build up in the headspace of tanks. These can
cause flammability/explosion hazards even at temperatures below the normal flash
point (note: flash point must not be regarded as a reliable indicator of the potential
flammability of vapour in tank headspaces). Tank headspaces should always be
regarded as potentially flammable and care should be taken to avoid static electrical
discharge and all ignition sources during filling, ullaging and sampling from storage
tanks. Do not enter storage tanks. If entry to vessels is necessary, follow permit to
work procedures. Entry to any tanks or other confined space requires a full risk
assessment and appropriate control measures to be put in place in conformance
with appropriate regulations and industry practice on confined space entry. When
the product is pumped (e.g. during filling, discharge or ullaging) and when sampling,
there is a risk of static discharge. Ensure equipment used is properly earthed or
bonded to the tank structure. Electrical equipment should not be used unless it is
intrinsically safe (i.e. will not produce sparks). Explosive air/vapour mixtures may
form at ambient temperature. If product comes into contact with hot surfaces, or
leaks occur from pressurised fuel pipes, the vapour or mists generated will create a
flammability or explosion hazard. Product contaminated rags, paper or material
used to absorb spillages, represent a fire hazard, and should not be allowed to
accumulate. Dispose of safely immediately after use.

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Section 8. Exposure controls/personal protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Gasoline ACGIH TLV (United States).
TWA: 300 ppm 8 hours. Issued/Revised:
5/1996
TWA: 890 mg/m³ 8 hours. Issued/Revised:
5/1996
STEL: 500 ppm 15 minutes. Issued/
Revised: 5/1996
STEL: 1480 mg/m³ 15 minutes. Issued/
Revised: 5/1996

Benzene NZ HSWA 2015 (New Zealand). Absorbed

through skin.
WES-STEL: 2.5 ppm 15 minutes. Issued/
Revised: 9/2010
WES-TWA: 1 ppm 8 hours. Issued/Revised:
9/2010

diisopropyl ether NZ HSWA 2015 (New Zealand).

WES-STEL: 1300 mg/m³ 15 minutes.
Issued/Revised: 1/1994
WES-STEL: 310 ppm 15 minutes. Issued/
Revised: 1/1994
WES-TWA: 1040 mg/m³ 8 hours. Issued/
Revised: 1/1994
WES-TWA: 250 ppm 8 hours. Issued/
Revised: 1/1994

Ethanol NZ HSWA 2015 (New Zealand).

WES-TWA: 1880 mg/m³ 8 hours. Issued/
Revised: 1/1994
WES-TWA: 1000 ppm 8 hours. Issued/
Revised: 1/1994
Recommended monitoring If this product contains ingredients with exposure limits, personal, workplace
procedures atmosphere or biological monitoring may be required to determine the effectiveness
of the ventilation or other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to appropriate monitoring
standards. Reference to national guidance documents for methods for the
determination of hazardous substances will also be required.
Appropriate engineering Provide exhaust ventilation or other engineering controls to keep the relevant
controls airborne concentrations below their respective occupational exposure limits. All
activities involving chemicals should be assessed for their risks to health, to ensure
exposures are adequately controlled. Personal protective equipment should only be
considered after other forms of control measures (e.g. engineering controls) have
been suitably evaluated. Personal protective equipment should conform to
appropriate standards, be suitable for use, be kept in good condition and properly
maintained.
Your supplier of personal protective equipment should be consulted for advice on
selection and appropriate standards. For further information contact your national
organisation for standards. The final choice of protective equipment will depend
upon a risk assessment. It is important to ensure that all items of personal
protective equipment are compatible.
Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Individual protection measures

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Section 8. Exposure controls/personal protection
Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye protection Chemical splash goggles.
Hand protection Wear chemical resistant gloves.

Do not re-use gloves. Protective gloves must give suitable protection against
mechanical risks (i.e. abrasion, blade cut and puncture). Protective gloves will
deteriorate over time due to physical and chemical damage. Inspect and replace
gloves on a regular basis. The frequency of replacement will depend upon the
circumstances of use.

Recommended: Nitrile gloves. The presence of aromatic hydrocarbons in the

product will significantly shorten the length of time that nitrile gloves will provide
protection. Do not re-use nitrile gloves if exposed to aromatic hydrocarbons. Gloves
made from fluoroelastomer resistant to hydrocarbons and a wide range of
chemicals.
Wear a chemically resistant multi-layer laminate inner glove inside an outer nitrile
glove. The purpose of the outer glove is to protect the inner glove from cuts and
mechanical damage.
Skin protection Use of protective clothing is good industrial practice. Cotton or polyester/cotton
overalls will only provide protection against light superficial contamination that will
not soak through to the skin. Overalls should be laundered on a regular basis.
When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is
a risk of splashing) then chemical resistant aprons and/or impervious chemical suits
and boots will be required. Wear suitable protective clothing. Footwear highly
resistant to chemicals. When there is a risk of ignition from static electricity, wear
anti-static protective clothing. For greatest effectiveness against static electricity,
overalls, boots and gloves should all be anti-static. When there is a risk of ignition
wear inherently fire resistant protective clothes and gloves. Work clothing / overalls
should be laundered on a regular basis. Laundering of contaminated work clothing
should only be done by professional cleaners who have been told about the hazards
of the contamination. Always keep contaminated work clothing away from
uncontaminated work clothing and uncontaminated personal clothes. When the risk
of skin exposure is high (from experience this could apply to the following tasks:
cleaning work, maintenance and service, filling and transfer, taking samples and
cleaning up spillages) then a chemical protective suit and boots will be required.
Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. If there is a
requirement for the use of a respiratory protective device, but the use of breathing
apparatus (independent of ambient atmosphere) is not required, then a suitable
filtering device must be worn. The filter class must be suitable for the maximum
contaminant concentration (gas/vapour/aerosol/particulates) that may arise when
handling the product. The correct choice of respiratory protection depends upon the
chemicals being handled, the conditions of work and use, and the condition of the
respiratory equipment. Safety procedures should be developed for each intended
application. Respiratory protection equipment should therefore be chosen in
consultation with the supplier/manufacturer and with a full assessment of the
working conditions. Respiratory protection should conform to AS/NZS 1715 and AS/
NZS 1716.

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Section 9. Physical and chemical properties
Appearance
Physical state Liquid.
Colour Pale colour. Light Yellow. to Orange.
Odour Petrol [Strong]
Odour threshold 0.025 ppm (Based on Petrol)
pH Not applicable. Based on: Solubility in Water (insoluble in water.).
Melting point <-60°C (<-76°F) (Based on Petrol)
Boiling point 30 to 210°C (86 to 410°F)
Drop Point Not available.
Flash point Closed cup: <-40°C (<-40°F)
Auto-ignition temperature >350°C (>662°F)
Flammability (solid, gas) Not applicable. Based on physical state.
Lower and upper explosive Lower: 1.4%
(flammable) limits Upper: 7.6%
Vapour pressure 27 to 45 kPa (202.52 to 337.53 mm Hg) [20°C (68°F)]
45 to 95 kPa (337.5 to 712.6 mm Hg) [37.8°C (100°F)]
Vapour density >1 [Air = 1]
Density 750 kg/m³ (0.75 g/cm³)
Solubility insoluble in water.
Partition coefficient: n- 2 to 7 (Based on Gasoline)
octanol/water
Decomposition temperature >210°C (>410°F)
Viscosity Kinematic: 0.4 to 0.55 mm2/s (0.4 to 0.55 cSt) at 40°C
Explosive properties Based on Low boiling point naphtha - Not considered explosive based on structural
and oxygen balance considerations.
Vapours may form explosive mixtures with air.
Oxidising properties Based on Low boiling point naphtha - Not considered oxidizing based on structural
considerations.

Section 10. Stability and reactivity

Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions Under normal conditions of storage and use, hazardous polymerisation will not
occur.
Conditions to avoid Avoid all possible sources of ignition (spark or flame). Avoid excessive heat.
Incompatible materials Reactive or incompatible with the following materials: oxidising materials.
Hazardous decomposition Under normal conditions of storage and use, hazardous decomposition products
products should not be produced.

Section 11. Toxicological information

Information on likely routes of exposure
Inhalation Vapours may cause drowsiness and dizziness.
Ingestion Irritating to mouth, throat and stomach. Aspiration hazard if swallowed -- harmful or
fatal if liquid is aspirated into lungs.
Skin contact Causes mild skin irritation.
Eye contact No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics
Inhalation Adverse symptoms may include the following:
nausea or vomiting
headache
drowsiness/fatigue
dizziness/vertigo

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Section 11. Toxicological information
Ingestion Adverse symptoms may include the following:
nausea or vomiting
Skin contact Adverse symptoms may include the following:
irritation
redness
Eye contact Adverse symptoms may include the following:
pain or irritation
watering
redness
Acute toxicity
Product/ingredient Test Species Result Exposure Remarks
name
Gasoline LC50 Inhalation Rat >7630 mg/m³ 4 hours Based on
Vapour Nominal Gasoline

LC50 Inhalation Rat >5610 mg/m³ 4 hours Based on

Vapour analytical Gasoline

LD50 Dermal Rabbit >2000 mg/kg - Based on

Gasoline

LD50 Oral Rat >5000 mg/kg - Based on

Gasoline

diisopropyl ether LC50 Inhalation Rat 40.5 mg/m³ 1 hours -

Vapour

LD50 Dermal Rabbit 2000 mg/kg - -

LD50 Oral Rat 8470 mg/kg - -

Ethanol LC50 Inhalation Rat 124.7 mg/l 4 hours Based on

Vapour Ethanol

LC50 Inhalation Rat 116.9 mg/l 4 hours Based on

Vapour Ethanol

LC50 Inhalation Rat 133.8 mg/l 4 hours Based on

Vapour Ethanol

LD50 Oral Rat 10470 mg/kg - Based on

Ethanol
Conclusion/Summary Not classified. Based on available data, the classification criteria are not met.
Irritation/Corrosion
Product/ingredient Species Result Score Exposure Observation Conc. Remarks
name
Gasoline Rabbit Skin - Irritant - - - - Based on
Gasoline

Rabbit Eyes - Non- - - - - Based on

irritating to Gasoline
the eyes.

Ethanol Rabbit Skin - Non- - - - - Based on

irritant to Ethanol
skin.

Rabbit Eyes - - - - - Based on

Cornea Ethanol
opacity

Rabbit Eyes - Iris - - - - Based on

lesion Ethanol
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Section 11. Toxicological information
Rabbit Eyes - Irritant - - - - Based on
Ethanol
Conclusion/Summary
Skin Causes skin irritation.
Eyes Not classified. Based on available data, the classification criteria are not met.
Respiratory Not available.
Sensitisation
Product/ingredient name Route of Species Result Remarks
exposure
Gasoline skin Guinea pig Not sensitising Based on Gasoline

Conclusion/Summary
Skin Not classified. Based on available data, the classification criteria are not met.
Respiratory Not available.
Potential chronic health effects
General No known significant effects or critical hazards.
Inhalation May be harmful by inhalation after often repeated exposure. Vapour, mist or fume
may irritate the nose, mouth and respiratory tract. Solvent "sniffing" (abuse) or
intentional overexposure to vapours can produce serious central nervous system
effects, including unconsciousness, and possibly death.
Ingestion Not applicable.
Skin contact Not applicable.
Eye contact Not applicable.
Carcinogenicity Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure. May cause cancer Exposure to benzene may result in effects to the
hematopoietic system causing blood disorders including anaemia and leukaemia.
Benzene is classified by EEC as a category 1 carcinogen - substances known to be
carcinogenic to man.
IARC assessment: benzene - carcinogenic to humans (Group 1)
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Carcinogenicity
Product/ingredient name Test Species Result Exposure
Gasoline Rat Inhalation 113 weeks Negative - - Based on
Inhalation - Gasoline
Unspecified

Mouse Dermal 102 weeks Negative - - Based on

Dermal - Gasoline
Unspecified

Ethanol Mouse Oral 105 weeks Positive - - Based on

Oral - Ethanol
Unspecified

Rat Oral 104 weeks Negative - - Based on

Oral - Ethanol
Unspecified
Conclusion/Summary Benzene: May cause cancer
Mutagenicity

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Section 11. Toxicological information
Product/ingredient name Test Experiment Result Remarks
Gasoline Equivalent to OECD Experiment: In vitro Negative Based on Gasoline
476
Subject: Mammal -
species unspecified

Equivalent to OECD Experiment: In vitro Negative Based on Gasoline

471
Subject: Non-
mammalian species

EPA OPPTS Experiment: In vivo Negative Based on Gasoline

870.5395 vapour condensate
Subject: Unspecified
Cell: Germ

Equivalent to OECD Experiment: In vivo Negative Based on Gasoline

475
Subject: Unspecified
Cell: Germ

Ethanol Equivalent to OECD Experiment: In vitro Negative Based on Ethanol

476
Subject: Mammal -
species unspecified

Equivalent to OECD Experiment: In vitro Negative Based on Ethanol

473
Subject: Non-
mammalian species

Equivalent to OECD Experiment: In vivo Negative Based on Ethanol

478
Subject: Unspecified
Cell: Germ
Conclusion/Summary Benzene: May cause genetic defects.
Reproductive toxicity
Product/ingredient name Maternal Fertility Developmental Species Result Exposure
toxicity toxin
Gasoline - Negative - Rat Inhalation 2
generation

- - Negative Rat Inhalation 14 days

Ethanol - Positive - Rat Oral 2

generation

- - Negative Rat Inhalation 18 days

Conclusion/Summary Development: Not classified. Based on available data, the classification criteria are
not met.
Fertility: Not classified. Based on available data, the classification criteria are not
met.
Effects on or via lactation: Not classified. Based on available data, the classification
criteria are not met.
Aspiration hazard
Name
Gasoline

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Section 11. Toxicological information
Other adverse symptoms Excess exposure to vapors may produce headaches, dizziness, nausea, drowsiness,
irritation of eyes, nose and throat and central nervous system depression. Aspiration
of this material into the lungs can cause chemical pneumonia and can be fatal.
Aspiration into the lungs can occur while vomiting after ingestion of this product.
Inhalation of unleaded gasoline vapors did not produce birth defects in laboratory
animals. Ingestion of this material can cause gastrointestinal irritation and diarrhea.

In a long-term inhalation study of whole unleaded gasoline vapors, exposure-related

kidney damage and kidney tumors were observed in male rats. Similar kidney
effects were not seen in female rats or in mice. At the highest exposure level (2056
ppm), female mice had an increased incidence of liver tumors. Results from
subsequent scientific studies have shown that a broad variety of chemicals cause
these kidney effects only in the male rat. Further studies have discovered the means
by which the physiology of the male rat uniquely predispose it to these effects.
Consequently, the Risk Assessment Forum of the Environmental Protection Agency
has recognized that these responses are not predictive of a human health hazard.
The liver tumors that were increased in the high-dose female mice are likewise of
questionable significance because of their high spontaneous occurrence even
without chemical exposure and because the rate of their occurrence is accelerated
by a broad spectrum of chemicals not commonly considered to be carcinogens (e.g.,
phenobarbital).
Thus, the significance of the mouse liver tumor response in terms of human health
is questionable.

Gasoline is a complex mixture of hydrocarbons and contains benzene (typically no

more than 2 volume%), toluene, and xylene. Chronic exposure to high levels of
benzene has been shown to cause cancer (leukemia) in humans and other adverse
blood effects (anemia). Benzene is considered a human carcinogen by IARC, NTP
and OSHA. Over exposure to xylene and toluene can cause irritation to the upper
respiratory tract, headache and narcosis. Some liver damage and lung inflammation
were seen in chronic studies on xylene in guinea pigs but not in rats.

Solvent "sniffing" (abuse) or intentional overexposure to vapors can produce serious

central nervous system effects, including unconsciousness, and possibly death.

Gasoline as a mixture is classified as a 2B (possible human) carcinogen by IARC.

Gasoline engine exhaust is classified as possibly carcinogenic to humans by IARC

(2B). This classification is based primarily on animal and in vitro studies of gasoline
engine exhaust condensates/extracts. Studies of the gaseous exhaust stream in
animals did not provided sufficient evidence for classification as a carcinogen.

Section 12. Ecological information

Ecotoxicity Water polluting material. May be harmful to the environment if released in large
quantities. This material is toxic to aquatic life with long lasting effects.
Aquatic and terrestrial toxicity
Product/ingredient Species Result/Test Exposure Effects Remarks
name
Gasoline Micro-organism Acute EC50 40 hours growth inhibition -
15.41 mg/l
Nominal Fresh
water

Algae Acute EL50 3.1 72 hours (growth rate) Based on

mg/l Nominal Gasoline
Fresh water

Algae Acute EL50 3.7 96 hours (growth rate) Based on

mg/l Nominal Gasoline
Fresh water

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Section 12. Ecological information
Daphnia Acute EL50 4.5 48 hours Mobility Based on
mg/l Nominal straight-run light
Fresh water gasoline

Fish Acute LL50 10 96 hours Mortality Based on

mg/l Nominal Naphtha
Fresh water (petroleum),
isomerisation

Fish Acute LL50 8.2 96 hours Mortality Based on

mg/l Nominal Naphtha
Fresh water (petroleum), light
alkylate

Algae Acute NOELR 72 hours (growth rate) Based on

0.5 mg/l Nominal Gasoline
Fresh water

Daphnia Acute NOELR 48 hours Mobility Based on

0.5 mg/l Nominal Straight run gas
Fresh water oil

Daphnia Chronic EL50 10 21 days Reproduction Based on

mg/l Nominal Naphtha
Fresh water (petroleum), light
alkylate

Daphnia Chronic EL50 21 days Mobility Based on

>40 mg/l Naphtha
Nominal Fresh (petroleum), light
water alkylate

Fish Chronic EL50 10 21 days Reproduction Based on:

mg/l Nominal Naphtha
Fresh water (petroleum), light
alkylate; read
across between
species

Fish Chronic LL50 14 days Mortality Based on

5.2 mg/l Nominal Naphtha
Fresh water (petroleum), light
catalytic
reformed

Daphnia Chronic NOELR 21 days Reproduction Based on

2.6 mg/l Nominal Naphtha
Fresh water (petroleum), light
alkylate

Daphnia Chronic NOELR 21 days Mobility Based on

16 mg/l Nominal Naphtha
Fresh water (petroleum), light
alkylate

Fish Chronic NOELR 14 days Mortality Based on

2.6 mg/l Nominal Naphtha
Fresh water (petroleum), light
catalytic
reformed

Fish Chronic NOELR 21 days Reproduction Based on:

2.6 mg/l Nominal Naphtha
Fresh water (petroleum), light
alkylate; read
across between
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Section 12. Ecological information
species

soil, plants Chronic PNEC - - -

>0.4 mg/kg

Ethanol Algae EC50 675 mg/l 4 days - Based on

Ethanol

Aquatic plants EC50 4432 mg/l 7 days - Based on

Ethanol

Daphnia Acute LC50 48 hours - Based on

5012 mg/l Ethanol

Fish Acute LC50 153 96 hours - Based on

g/l Ethanol

Fish Acute LC50 14.2 96 hours - Based on

g/l Ethanol

Daphnia Chronic LC50 2 10 days - Based on

mg/l Ethanol

Daphnia Chronic LC50 9 days - Based on

9.6 mg/l Ethanol
Conclusion/Summary Toxic to aquatic life with long lasting effects.
Persistence and degradability
Expected to be biodegradable.
Product/ingredient name Test Result Remarks
Ethanol EPA 95 % - Readily - 15 days Based on Ethanol

EPA 84 % - Readily - 20 days Based on Ethanol

EPA 74 % - Readily - 5 days Based on Ethanol

EPA 74 % - Readily - 10 days Based on Ethanol

Product/ingredient name Aquatic half-life Photolysis Biodegradability

Gasoline - - Inherent

Ethanol - - Readily
Bioaccumulative potential
This product is not expected to bioaccumulate through food chains in the environment.
Product/ingredient name LogPow BCF Potential
Gasoline 2 to 7 - high
diisopropyl ether 2.4 - low
Ethanol -0.35 - low
Mobility in soil
Mobility Spillages may penetrate the soil causing ground water contamination.
Soil/water partition Not available.
coefficient (KOC)
Other ecological information Spills may form a film on water surfaces causing physical damage to organisms.
Oxygen transfer could also be impaired.

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Section 13. Disposal considerations
Disposal methods The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Waste should not be
disposed of untreated to the sewer unless fully compliant with the requirements of
all authorities with jurisdiction. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible. This material and
its container must be disposed of in a safe way. Care should be taken when
handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapour from product
residues may create a highly flammable or explosive atmosphere inside the
container. Do not cut, weld or grind used containers unless they have been cleaned
thoroughly internally. Avoid dispersal of spilt material and runoff and contact with
soil, waterways, drains and sewers.

Section 14. Transport information

Regulatory UN number Proper shipping Classes PG* Label Additional
information name information
New Zealand UN1203 MOTOR SPIRIT or 3 II The marine pollutant
Class GASOLINE or mark is not required
PETROL when transported by
road or rail.
Hazchem code 3YE

ADG Class UN1203 MOTOR SPIRIT or 3 II Hazchem code 3YE

GASOLINE or Initial emergency
PETROL response guide 14

IATA Class UN1203 MOTOR SPIRIT or 3 II The environmentally

GASOLINE or hazardous substance
PETROL mark may appear if
required by other
transportation
regulations.
IMDG Class UN1203 MOTOR SPIRIT or 3 II The marine pollutant
GASOLINE or mark is not required
PETROL. Marine when transported in
pollutant sizes of ≤5 L or ≤5 kg.
Emergency
schedules
F-E, S-E

PG* : Packing group

Section 15. Regulatory information

New Zealand Regulatory Information
HSNO Approval Number HRC000003
HSNO Group Standard Petrol (unleaded)
HSNO Classification 3.1 - FLAMMABLE LIQUIDS - Category A
6.3 - SKIN IRRITATION - Category B
6.7 - CARCINOGENICITY - Category B
6.1 - ACUTE TOXICITY (aspiration) (oral) - Category E
9.1 - AQUATIC ECOTOXICITY - Category B
Regulation according to other foreign laws
REACH Status For the REACH status of this product please consult your company contact, as
identified in Section 1.

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Section 15. Regulatory information
United States inventory Not determined.
(TSCA 8b)
Australia inventory (AICS) Contact local supplier or distributor.
Canada inventory status Not determined.
China inventory (IECSC) Not determined.
Japan inventory (ENCS) Not determined.
Korea inventory (KECI) Not determined.
Philippines inventory Not determined.
(PICCS)
Taiwan Chemical Not determined.
Substances Inventory (TCSI)

Section 16. Other information

History
Date of issue/Date of 10 March 2021
revision
Date of previous issue No previous validation.
Version 1
Prepared by Not available.
Key to abbreviations Varies = may contain one or more of the following 64741-88-4, 64741-89-5,
64741-95-3, 64741-96-4, 64742-01-4, 64742-44-5, 64742-45-6, 64742-52-5,
64742-53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-57-0, 64742-58-1,
64742-62-7, 64742-63-8, 64742-65-0, 64742-70-7, 72623-85-9, 72623-86-0,
72623-87-1
Notice to reader
Indicates information that has changed from previously issued version.
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information
contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information in this data sheet.

The data and advice given apply when the product is sold for the stated application or applications. You should not use the product
other than for the stated application or applications without seeking advice from BP Group.

It is the user’s obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP
Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from
any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for
supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the
product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of
any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that
this document is the most current available. Alteration of this document is strictly prohibited.

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