Reservoir Simulation
Reservoir Simulation
Spring 2021
RESERVOIR
SIMULATION
1.
WHAT IS SIMULATION
Let’s start with a definition of reservoir simulation
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Reservoir simulation
In reservoir simulation we aim to predict the reservoir’s
performance under different operating conditions by
combining:
▷ Physics
▷ Mathematics
▷ Reservoir engineering
▷ and computer programming
Reservoir simulation
What we are going to predict is the flow and reservoir
behavior in a time interval
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Reservoir Geometry
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Reservoir Geometry
For many engineering purposes, however, the actual
flow geometry may be represented by one of the
following flow geometries:
Radial flow
Linear flow
Spherical flow and hemispherical flow
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Reservoir Geometry
Radial flow:
▷ In the absence of severe reservoir heterogeneities,
flow into or away from a wellbore will follow radial
flow lines from a substantial distance from the
wellbore. Because fluids move toward the well from
all directions and coverage at the wellbore, the term
radial flow is given to characterize the flow of fluid
into the wellbore.
Reservoir Geometry
Radial flow:
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Reservoir Geometry
Radial flow:
Radial flow geometry is usually used in well-testing.
The typical analytical solution to the radial flow is
obtained by line-source solution to the fluid flow
equations
Reservoir Geometry
Linear flow:
▷ Linear flow occurs when flow paths are parallel and
the fluid flows in a single direction. In addition, the
cross sectional area to flow must be constant
▷ A common application of linear flow equations is the
fluid flow into vertical hydraulic fractures
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Reservoir Geometry
Linear flow:
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Reservoir Geometry
Spherical flow:
▷ Depending upon the type of wellbore completion
configuration, it is possible to have a spherical or
hemispherical flow near the wellbore.
▷ A well with a limited perforated interval could result
in spherical flow in the vicinity of the perforations
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Reservoir Geometry
Spherical flow:
Wellbore
𝑃 Flow lines
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Reservoir Geometry
Hemispherical flow:
▷ A well that only partially penetrates the pay zone
results in hemispherical flow
▷ The condition could arise where coning of bottom
water is important.
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Reservoir Geometry
Hemispherical flow:
Wellbore
Flow lines
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Fluid Type
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Fluid Type
▷ The isothermal compressibility coefficient is
essentially the controlling factor in identifying the
type of the reservoir fluid
▷ In general, reservoir fluids are classified into three
groups:
1. Incompressible fluids
2. Slightly compressible fluids
3. Compressible fluids
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Fluid Type
▷ The isothermal compressibility coefficient 𝒄 is described
mathematically by the following two equivalent
expressions
▷ In terms of fluid volume:
1 𝜕𝑉
𝑐=−
𝑉 𝜕𝑝
▷ In terms of fluid volume:
1 𝜕𝜌
𝑐=
𝜌 𝜕𝑝
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Fluid Type
Incompressible fluids
▷ An incompressible fluid is defined as the fluid whose volume
(or density) does not change with pressure
𝜕𝑉 𝜕𝜌
= 0 𝑜𝑟 =0
𝜕𝑝 𝜕𝑝
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Fluid Type
Slightly compressible fluids
▷ These “slightly” compressible fluids exhibit small changes in
volume, or density, with changes in pressure.
▷ Knowing the volume 𝑉 of a slightly compressible liquid at a
reference (initial) pressure 𝑃 , the changes in the volumetric
behavior of this fluid as a function of pressure 𝑝 can be
mathematically described by integrating 𝑐 = − to give:
𝑑𝑉
−𝑐 𝑑𝑝 =
𝑉
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Fluid Type
Slightly compressible fluids
𝑉
𝑒 =
𝑉
𝑉= 𝑉 𝑒
where :
▷ 𝑝 = pressure, psia
▷ 𝑉 = volume at pressure 𝑝, ft3
▷ 𝑝 = initial (reference) pressure, psia
▷ 𝑉 = fluid volume at initial (reference) pressure, psia
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Fluid Type
Slightly compressible fluids
The 𝑒 may be represented by a series expansion as:
𝑥 𝑥 𝑥
𝑒 = 1 + 𝑥 + + + …+
2! 3! 𝑛!
Because the exponent 𝑥 [which represents the term
𝑐 𝑝 − 𝑝 ] is very small, because c is very small, the 𝑒
term can be approximated by:
𝑒 =1+𝑥
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Fluid Type
Slightly compressible fluids
Combining the above approximation with 𝑉 = 𝑉 𝑒
gives us:
𝑉 = 𝑉 1+𝑐 𝑝 −𝑝
Fluid Type
Compressible fluids
▷ These are fluids that experience large changes in volume as a function
of pressure
▷ All gases are considered compressible fluids
▷ The truncation of the series expansion is not valid in this category and
the complete expansion is used
▷ the isothermal compressibility of any compressible fluid is described
by the following expression
1 1 𝜕𝑧 Z in the gas
𝑐 = −
𝑝 𝑧 𝜕𝑝 compressibility factor
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Fluid Type
Incompressible Compressible
Slightly compressible
Density
Volume
Slightly compressible
Compressible
Incompressible
Pressure Pressure
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Flow Regimes
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Flow Regimes
There are basically three
types of flow regimes that Steady-state
must be recognized in
order to describe the fluid
flow behavior and
reservoir pressure
distribution as a function
of time.
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Flow Regimes
Steady-state flow
▷ The flow regime is identified as a steady-state flow if the
pressure at every location in the reservoir remains
constant, i.e., does not change with time.
𝜕𝑝
=0
𝜕𝑡
▷ The above equation states that the rate of change of
pressure 𝑝 with respect to time 𝑡 at any location 𝑖 is zero
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Flow Regimes
Steady-state flow
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Flow Regimes
Transient flow
▷ The unsteady-state flow (frequently called transient flow) is
defined as the fluid flowing condition at which the rate of
change of pressure with respect to time at any position in
the reservoir is not zero or constant
▷ This definition suggests that the pressure derivative with
respect to time is essentially a function of both position 𝑖
and time 𝑡, thus
𝜕𝑝
= 𝑓(𝑖, 𝑡)
𝜕𝑡
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Flow Regimes
Flow Regimes
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Flow Regimes
Steady state
Pressure at location
Transient
Time
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Flow Phases
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Flow Phases
▷ The mathematical expressions that are used to predict the
volumetric performance and pressure behavior of the
reservoir vary in forms and complexity depending upon the
number of mobile fluids in the reservoir
▷ There are generally three cases of flowing systems:
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Flow Phases
▷ As the number of phases increases, we need to solve
additional equations regarding the saturation changes for
each phase present beside the equations for pressure
changes
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Reservoir Type
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Reservoir Type
▷ Reservoirs can be fractured (naturally or hydraulically)
▷ Reservoir type highly influences the fluid flow behavior
▷ Presence of fractures in the reservoir requires implementing
dual-porosity and/or dual-permeability models
▷ In fractured reservoirs we have to take fluid flow from matrix to
fractures and vice versa into account.
▷ In this manner, fracture density, fracture geometry, fracture
intensity, etc. will govern the fluid flow inside the reservoir
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Fracture modeling
Numerical model
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Reservoir Type
▷ In a fractured reservoir, drainage of oil from matrix to the
fractures is driven by water or gas
▷ If the system is a water-oil system, capillary pressure is the
dominant force
▷ If the system is a gas-oil system, gravity drainage is the dominant
force
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Reservoir Type
▷ Consider a matrix containing
oil surrounded by fractures
containing water
▷ By applying Darcy’s Law and
considering the capillary
forces we can derive the
equation of oil recovery
from the matrix
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Reservoir Type
𝑝 𝑝
𝑡 = 1−𝑀 𝑧 − 𝑀+ 1−𝑀 1+ ln 1 + −𝑧
𝐻∆𝜌𝑔 𝐻∆𝜌𝑔
𝑧 =
∆
𝑡 = 𝑡
𝑀=
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Reservoir Type
▷ Consider a matrix containing
oil surrounded by fractures
containing gas
▷ By applying Darcy’s Law and
considering the gravity
forces we can derive the
equation of oil recovery
from the matrix
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Reservoir Type
𝐻∆𝜌𝑔 𝑝
𝑀𝑝 𝑀−1+ ln 𝑧 − 1 +
𝑝 𝐻∆𝜌𝑔
𝑡 = 𝑀𝑧 − 1 𝑀 −
𝐻∆𝜌𝑔
𝑧
𝑧 =
𝐻
𝑘𝑘 ∆𝜌𝑔
𝑡 = 𝑡
𝜇 𝐻𝜑
𝜇 𝑘
𝑀=
𝑘 𝜇
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Reservoir Type
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2.
FLOW EQUATIONS
Governing fluid flow equations and examples
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Flow Equations
▷ The fluid flow equations that are used to describe the flow
behavior in a reservoir can take many forms depending
upon the combination of variables presented previously,
(i.e., types of flow, types of fluids, etc.).
▷ By combining the conservation of mass equation with the
transport equation (Darcy’s equation) and various
equations-of-state, the necessary flow equations can be
developed
▷ Since all flow equations to be considered depend on
Darcy’s Law, it is important to consider this transport
relationship first.
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Darcy’s Law
▷ The fundamental law of fluid motion in porous media is
Darcy’s Law
▷ The mathematical expression developed by Henry Darcy in
1856 states the velocity of a homogeneous fluid in a
porous medium is proportional to the pressure gradient
and inversely proportional to the fluid viscosity
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Darcy’s Law
▷ 𝜈 is the apparent velocity in centimeters per second and is
equal to 𝒒/𝑨, where 𝒒 is the volumetric flow rate in cubic
centimeters per second and 𝑨 is total cross-sectional area
of the rock in square centimeters.
▷ 𝑨 includes the area of the rock material as well as the area
of the pore channels. The fluid viscosity, 𝝁, is expressed in
centipoise units, and the pressure gradient, 𝒅𝒑/𝒅𝒙, is in
atmospheres per centimeter, taken in the same direction
as 𝜈 and 𝑞
▷ The proportionality constant, 𝒌, is the permeability of the
rock expressed in Darcy units
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Darcy’s Law
▷ The negative sign in the linear equation is added because
the pressure gradient is negative in the direction of flow.
Direction of flow
𝑝
Pressure
𝜕𝑝
<0
𝜕𝑥
𝑝
𝑥
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Darcy’s Law
▷ For a horizontal-radial system, the pressure gradient is
positive and Darcy’s equation can be expressed in the
following generalized radial form:
𝑞 𝑘 𝜕𝑝
𝑣= =
𝐴 𝜇 𝜕𝑟
▷ 𝑞 = volumetric flow rate at radius 𝑟
▷ 𝐴 = cross-sectional area to flow at radius 𝑟
▷ = pressure gradient at radius 𝑟
▷ 𝑣 = apparent velocity at radius 𝑟
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Darcy’s Law
Direction of flow
𝑝
𝜕𝑝
>0
𝜕𝑟
𝑟 𝑟
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Darcy’s Law
▷ The cross-sectional area at radius r is essentially the
surface area of a cylinder. For a fully penetrated well with a
net thickness of h, the cross sectional area 𝐴 is given by:
𝐴 = 2𝜋𝑟ℎ
Darcy’s Law
▷ For turbulent flow, which occurs at higher velocities, the
pressure gradient increases at a greater rate than does the
flow rate and a special modification of Darcy’s equation is
needed. When turbulent flow exists, the application of
Darcy’s equation can result in serious errors.
▷ Consequently, Darcy’s Law has to be modified to take into
account the turbulence effect of the flow
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𝑑𝑥
𝐿 57
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For example, if a point is above the datum depth, ∆𝑧 will be negative, and
Φ will be less than 𝑝
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0.001127𝑘𝐴(Φ − Φ )
𝑞=
𝜇𝐿
▷ It should be pointed out that the fluid potential drop (Φ − Φ )
is equal to the pressure drop (𝑝 − 𝑝 ) only when the flow
system is horizontal
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(0.001127)(100)(6000)(40.84)
𝑞= = 6.9 𝑏𝑏𝑙/𝑑𝑎𝑦
(2)(2000)
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6.9 (5.615)
𝐴𝑐𝑡𝑢𝑎𝑙 𝑣𝑒𝑙𝑜𝑐𝑖𝑡𝑦 = = 0.043𝑓𝑡/𝑑𝑎𝑦
(0.15)(6000)
70
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0.001127𝑘𝐴 1+𝑐 𝑝 −𝑝
𝑞 = ln
𝜇𝑐𝐿 1+𝑐 𝑝 −𝑝
72
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0.111924𝐴𝑘 𝑝 − 𝑝
𝑄 =
𝑇𝐿𝑧𝜇
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80
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𝑞 𝑞 1+𝑐 𝑝 −𝑝 𝑘 𝑑𝑝
= = 0.001127
𝐴 2𝜋𝑟ℎ 𝜇 𝑑𝑟
84
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𝑝 𝑧𝑇
𝑄 =𝑞
5.615𝑇 𝑝
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2𝑝 2𝑝 2𝑝
𝑑𝑝 = 𝑑𝑝 − 𝑑𝑝
𝜇 𝑧 𝜇 𝑧 𝜇 𝑧
▷ Combining the above relationships yields
𝑇𝑄 𝑟 2𝑝 2𝑝
ln = 0.703 𝑑𝑝 − 𝑑𝑝
𝑘ℎ 𝑟 𝜇 𝑧 𝜇 𝑧
88
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89
90
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92
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𝑝
𝜇 𝑧 Pseudo pressure Pressure method
method
Pressure
squared method
𝑝 < 2000 𝑝𝑠𝑖 2000 < 𝑝 < 3000 𝑝 > 3000 𝑝𝑠𝑖 Pressure
95
96
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𝑞 = 0.001127 𝑘
𝑞 = 0.001127 𝑘
97
98
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𝑄 = 0.00708 𝑟ℎ𝑘
𝑄 = 0.00708 𝑟ℎ𝑘
𝐵 = 0.005035 ; 𝑏𝑏𝑙/𝑠𝑐𝑓
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Oil phase
0.00708 𝑘ℎ 𝑘 𝑝 −𝑝
𝑄 =
𝜇 𝐵 ln 𝑟 /𝑟
Water phase
0.00708 𝑘ℎ 𝑘 𝑝 −𝑝
𝑄 =
𝜇 𝐵 ln 𝑟 /𝑟
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𝑘ℎ 𝑘 𝑝 −𝑝
𝑄 =
1422 𝜇 𝑧 𝑇 ln 𝑟 /𝑟
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102
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103
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107
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Source/sink
(𝑥, 𝑦, 𝑧)
∆𝒛
∆𝒚
∆𝒙
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∅
𝛽 ∆𝑥 + 𝛽 ∆𝑦 + 𝛽 ∆𝑧 + 𝑞 =
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𝛽𝐴 𝑘 ∆𝑥 + 𝛽𝐴 𝑘 ∆𝑦 + 𝛽𝐴 𝑘 ∆𝑧 + 𝜇𝐵𝑞 =
113
114
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𝛽 ∆𝑥 + 𝛽 ∆𝑦 + 𝛽 ∆𝑧 + 𝑞 =
115
1+𝑐 𝑝−𝑝 𝛽𝐴 𝑘 ∆𝑥 + 𝛽 𝐴 𝑘 ∆𝑥 + 1 + 𝑐 𝑝 −
𝑝 𝛽𝐴 𝑘 ∆𝑦 + 𝛽 𝐴 𝑘 ∆𝑦 + 1 + 𝑐 𝑝 −
∅
𝑝 𝛽𝐴 𝑘 ∆𝑧 + 𝛽 𝐴 𝑘 ∆𝑧 + 𝐵 𝜇𝑞 = 116
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𝛽𝐴 𝑘 ∆𝑥 + 𝛽𝐴 𝑘 ∆𝑦 + 𝛽𝐴 𝑘 ∆+𝐵 𝜇𝑞 =
117
118
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𝛽 ∆𝑥 + 𝛽 ∆𝑦 + 𝛽 ∆𝑧 +
∅
𝑞 =
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0.006328 𝜕 𝑘 𝜕𝑝 𝜕𝑝 𝜕𝜌
𝜌𝑟 = 𝜌𝜑𝑐 + 𝜑
𝑟 𝜕𝑟 𝜇 𝜕𝑟 𝜕𝑡 𝜕𝑡
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0.006328 𝑘 𝜕 𝜕𝑝 𝜕𝑝 𝜕𝑝
𝑟𝜌 = 𝜌𝜑𝑐 + 𝜑
𝜇𝑟 𝜕𝑟 𝜕𝑟 𝜕𝑡 𝜕𝑡
122
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𝑘1 𝜕𝑝 𝜕 𝑝 𝜕𝑝 1 𝜕𝑝
0.006328 + +
𝜇𝑟 𝜕𝑟 𝜕𝑟 𝜕𝑟 𝜌 𝜕𝑟
𝜕𝑝 𝜕𝑝 1 𝜕𝑝
= 𝜑𝑐 + 𝜑
𝜕𝑡 𝜕𝑡 𝜌 𝜕𝑟
123
𝑘 1 𝜕𝑝 𝜕 𝑝 𝜕𝑝
0.006328 + = 𝜑 𝑐 +𝑐
𝜇 𝑟 𝜕𝑟 𝜕𝑟 𝜕𝑡
Taking 𝑐 = 𝑐 + 𝑐
𝜕 𝑝 1 𝜕𝑝 𝜑𝜇𝑐 𝜕𝑝
+ =
𝜕𝑟 𝑟 𝜕𝑟 0.006328𝑘 𝜕𝑡
This is called the diffusivity equation. 𝑡 is in days 124
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131
132
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10 ℎ𝑟 ≫ 0.153 𝑠𝑒𝑐
133
. ( )( . )( . ) ( . )( . )( × )( . )
𝑝 = 4000 + 𝐸 =
( )( ) ( )( )
3358 𝑝𝑠𝑖
134
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1 𝜕 𝑝 𝜕𝑝 𝜇𝜑𝑐 𝑝 𝜕𝑝
𝑟 =
𝑟 𝜕𝑟 𝜇𝑧 𝜕𝑟 0.000264 𝑘 𝜇𝑧 𝜕𝑡
136
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137
138
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Pseudo steady
State Eqs.
141
142
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𝑡 𝑡 𝑡 𝑡 𝑡 𝑡 𝑡 𝑡 𝑡 𝑡
𝑡 𝑡
𝑡 𝑡
𝑃
Pseudo steady state
Boundary Boundary
143
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𝜕 𝑝 1 𝜕𝑝 𝜑𝜇𝑐 −0.23396𝑞
+ =
𝜕𝑟 𝑟 𝜕𝑟 0.006328𝑘 𝑐 𝐴ℎ𝜑
1𝜕 𝜕𝑝 887.22𝑞𝜇
𝑟 =−
𝑟 𝜕𝑟 𝜕𝑟 (𝜋𝑟 ) ℎ𝑘
145
0.00708 𝑘ℎ 𝑝 − 𝑝
𝑄=
𝑟
𝜇𝐵 ln − 0.75
𝑟
146
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149
150
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153
𝛽𝐴 𝑘 −𝛾 ∆𝑥 + 𝛽𝐴 𝑘 −𝛾 ∆𝑦 +
𝛽𝐴 𝑘 −𝛾 ∆z = −𝑞 Oil phase
𝛽𝐴 𝑘 −𝛾 ∆𝑥 + 𝛽𝐴 𝑘 −𝛾 ∆𝑦 +
𝛽𝐴 𝑘 −𝛾 ∆z = −𝑞 Water phase
154
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𝛽𝐴 𝑘 −𝛾 +𝛽 𝐴 𝑘 −𝛾 ∆𝑥 +
𝛽𝐴 𝑘 −𝛾 +𝛽 𝐴 𝑘 −𝛾 ∆𝑦 +
𝛽𝐴 𝑘 −𝛾 +𝛽 𝐴 𝑘 −𝛾 ∆z = + −
𝑞 Gas phase
155
Here, water is the wetting phase, gas is the non-wetting phase, and oil is
the intermediate wetting phase.
Usually, the equations are written using the water saturation, oil pressure
and capillary pressure 156
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𝛽𝐴 𝑘 −𝛾 ∆𝑥 + 𝛽𝐴 𝑘 −𝛾 ∆𝑦 +
( )
𝛽𝐴 𝑘 −𝛾 ∆z = −𝑞 Oil phase
𝛽𝐴 𝑘 − −𝛾 ∆𝑥 + 𝛽𝐴 𝑘 −
𝛾 ∆𝑦 + 𝛽𝐴 𝑘 − −𝛾 ∆z = −
𝑞 Water phase
157
𝛽𝐴 𝑘 + −𝛾 +𝛽 𝐴 𝑘 −𝛾 ∆𝑥 +
𝛽𝐴 𝑘 + −𝛾 +𝛽 𝐴 𝑘 −𝛾 ∆𝑦 +
𝛽𝐴 𝑘 + −𝛾 +𝛽 𝐴 𝑘 −𝛾 ∆z = +
( )
−𝑞 Gas phase
158
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3.
ADVANCED EQUATIONS
Governing fluid flow equations for advanced flows
160
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161
= 𝛽𝐴 𝑘 −𝛾 ∆𝑥 +
,
𝛽𝐴 𝑘 −𝛾 ∆𝑦 + 𝛽𝐴 𝑘 −
, ,
𝛾 ∆z + 𝑞 Water phase
∗
+ 𝑉𝜌 𝐶 = 𝛽𝐴 𝑘 −
,
𝛾 ∆𝑥 + 𝛽𝐴 𝑘 −𝛾 ∆𝑦 +
,
𝛽𝐴 𝑘 −𝛾 ∆z 𝐶 + 𝑞 𝐶 Polymer
, 162
phase
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= 𝛽𝐴 𝑘 −𝛾 ∆𝑥
,
+ 𝛽𝐴 𝑘 −𝛾 ∆𝑦 + 𝛽𝐴 𝑘
, ,
−𝛾 ∆z + 𝑞 𝐶 Brine equation
𝑉 ∗ = 𝑉(1 − 𝑆 )
163
𝑹𝒌 the relative permeability reduction factor for 𝒒𝐰𝐬𝐜 is the water production rate
the aqueous phase due to polymer retention
𝑪𝒑 , 𝑪𝒏 the polymer and salt concentrations
respectively in the aqueous phase
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+ 𝜌𝐶 = 𝛽𝐴 𝑘 −
,
𝛾 ∆𝑥 + 𝛽𝐴 𝑘 −𝛾 ∆𝑦 +
,
𝛽𝐴 𝑘 −𝛾 ∆z 𝐶 + 𝑞 𝐶
,
165
166
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167
+ 𝜌𝐶 = 𝛽𝐴 𝑘 𝑀 −
𝛾 ∆𝑥 + 𝛽𝐴 𝑘 𝑀 −𝛾 ∆𝑦 +
𝛽𝐴 𝑘 𝑀 −𝛾 ∆z 𝐶 + 𝑞 𝐶 − 𝜆 𝑆 ,𝑆 𝐶
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+ 𝜌𝐶 = 𝛽𝐴 𝑘 −𝛾 ∆𝑥 +
𝛽𝐴 𝑘 −𝛾 ∆𝑦 + 𝛽𝐴 𝑘 −
𝛾 ∆z 𝐶 + 𝑄 𝐶 − 𝜆 𝑆 , 𝑆 𝐶
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172
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𝑆 −𝑆
𝑘 = 𝑘 𝑆
𝑆 −𝑆 −𝑆
𝑆 −𝑆
𝑘 = 𝑘 𝑆
𝑆 −𝑆 −𝑆
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176
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𝜇 , =𝜇 𝜇
▷ The value of ω thus controls the degree of fluid mixing within each grid
cell
177
𝑆 = 𝑆 +𝑆
178
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179
𝑆 𝜇 𝜇 ,
−𝜇
=
𝑆
𝜇 ,
𝜇 −𝜇
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𝑆 𝑆
𝜌 , =𝜌 +𝜌 1−
𝑆 𝑆
181
182
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183
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186
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▷ The presented models are used along with the three-phase three-
dimensional flow equations to model a miscible gas injection
187
− 𝑥 𝜌 , 𝑣 + 𝑦 𝜌 , + = 𝜑 𝑆 𝑥 𝜌 , +
𝑆 𝑦 𝜌 ,
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− 𝑥 𝜌 , 𝑣 + 𝑦 𝜌 , + = 𝜑 𝑆 𝑥 𝜌 ,
+ 𝑆 𝑦 𝜌 ,
Diffusion phenomena in the liquid phase
𝑣 =𝑣 + 𝑣 can be about hundred times less
significant than diffusive effects within a
𝑣 =𝑣 + 𝑣 gas phase, therefore,
189
𝑣 =
,
Darcy’s Law Fick’s Law 𝑣 = −𝜑𝑆
,
𝑣 =
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𝑥 𝜌 , 𝐴 𝑘 +𝑦 𝜌 , 𝐴 𝑘 +
,
𝑦 𝑆 𝐴 ∆𝑥 + 𝑀 = 𝜑 𝑆 𝑥 𝜌 , +𝑆 𝑦 𝜌 ,
. .
𝑚 = 1,2, … , 𝑛
𝑛 is the number of components
𝑥 is the gas fraction
𝑦 is the liquid fraction 191
96