Reviewer in Analytical Chemistry
Reviewer in Analytical Chemistry
Reviewer in Analytical Chemistry
II. Objectives:
After accomplishing this part of the module, you must be able to:
A. determine the different prefixes of fundamental quantities;
B. appreciate the importance of different conversion factors used in converting one quantity to
another; and
C. perform conversion of units using different conversion factors.
III. Material/s:
A. Scientific Calculator
V. Concept:
Sometimes it is necessary to convert units from one measurement system to another or convert
within a system (for example, from kilometers to meters). Conversion factors between SI and US
customary units of length are as follows:
Retrieved from: Serway, R., Jewett, J. (2014), Physics for Scientists and Engineers (9th Edition), USA, Appendix A.
Like dimensions, units can be treated as algebraic quantities that can cancel each other. For
example, suppose we wish to convert 15.0 in. to centimeters. Because 1 in. is defined as exactly 2.54
cm, we find that
Where the ratio in parentheses is equal to 1, we express 1 as 2.54 cm/1 in. (rather than 1 in./2.54 cm) so
that the unit “inch” in the denominator cancels with the unit in the original quantity. The remaining unit is
the centimeter, our desired result.
PROBLEM # 1:
The length of your physics book is 37.0 cm. Convert this measurement in inches.
STEP 1: Identify the desired unit for conversion.
The given length must be converted to inches.
STEP 2: Write the quantity to be converted.
The quantity to be converted is 37.0 cm.
STEP 3: Determine the conversion factor to be used.
The conversion factor to be used is 1 in = 2.54 cm.
STEP 4: Perform the conversion on the quantity using the factor label method.
PROBLEM # 2:
Your house’s storage room has an area of 100,000 cm2. What is this area in square meters?
STEP 1: Identify the desired unit for conversion.
The given area must be converted to square meters (m2).
STEP 2: Write the quantity to be converted.
The quantity to be converted is 100,000 cm2.
STEP 3: Determine the conversion factor to be used.
The conversion factor to be used is 1 m = 100 cm.
STEP 4: Perform the conversion on the quantity using the factor label method.
*Take note that we squared the conversion factor because our desired unit is in square
meters.
STEP 5: Write the converted quantity.
The area of your house’s storage room in square meters is 10 m2.
PROBLEM # 3:
A sports car runs at a maximum speed of 300 km/h along a straight highway. What is this speed in
meters per second?
STEP 1: Identify the desired unit for conversion.
The given speed must be converted to meters per second (m/s).
STEP 2: Write the quantity to be converted.
The quantity to be converted is 300 km/h.
STEP 3: Determine the conversion factor to be used.
The conversion factors to be used are 1 km = 1000 m and 1h = 3600 s.
STEP 4: Perform the conversion on the quantity using the factor label method.
In addition to the fundamental SI units of meter, kilogram, and second, we can also use other units,
such as millimeters and nanoseconds, where the prefixes milli- and nano- denote multipliers of the basic
units based on various powers of ten. Prefixes for the various powers of ten and their abbreviations are
listed in the table below. For example, 1023 m is equivalent to 1 millimeter (mm), and 103 m corresponds
to 1 kilometer (km). Likewise, 1 kilogram (kg) is 103 grams (g), and 1 megavolt (MV) is 106 volts (V).
Retrieved from: Serway, R., Jewett, J. (2014), Physics for Scientists and Engineers (9th Edition), USA, p.6.
PROBLEM # 2:
It is said that the blink of an eye happens as fast as 0.40 seconds. How much is this time in
milliseconds? How about microseconds?
STEP 1: Identify the desired unit for conversion.
The given time must be converted to milliseconds (ms) and microseconds (µs).
STEP 2: Write the quantity to be converted.
The quantity to be converted is 0.4 seconds.
STEP 3: Determine the conversion factor /prefix to be used.
The conversion factors to be used are 1 × 10-3 s = 1 ms and 1 × 10-6 s = 1 µs.
STEP 4: Perform the conversion on the quantity using the factor label method.
PROBLEM # 3:
Neutron stars are created when giant stars die in supernovas and their cores collapse, with the protons
and electrons essentially melting into each other to form neutrons. The masses of these stars is
measured approximately 1.9891 × 1030 kg. Convert this mass into yottagrams (Yg).
STEP 1: Identify the desired unit for conversion.
The given mass must be converted to yottagrams (Yg).
STEP 2: Write the quantity to be converted.
The unit to be converted is 1.9891 × 1030 kg.
STEP 3: Determine the conversion factor/prefixes be used.
The conversion factors to be used are 1000 g = 1 kg and 1 × 1024 g = 1 Yg.
STEP 4: Perform the conversion on the quantity using the factor label method.
II. Objectives:
After accomplishing this part of the module, you must be able to:
A. describe what scientific notation is;
B. recognize the importance of writing figures in scientific notation; and
C. solve problems with regards to scientific notation.
III. Material/s:
A. Textbook/s for General Physics 1
1. Giancoli, D. C. (2005), Physics: Principles with Applications (6th Edition), USA
2. Arevalo, R. (n.d.), General Physics 1, Diwa Publishing House, Philippines.
B. Scientific Calculator
V. Concept:
You commonly write numbers in “powers of ten,” or scientific notation - for instance, 36,900 as 3.69
× 104 or 0.0021 as 2.1 × 10-3. One advantage of scientific notation is that it allows the number of
significant figures to be clearly expressed (to be discussed in the next module). Another advantage also
is that you can write large numbers in an easy format such as 12,000,000,000 as 1.2 × 10 10 or
0.00000000052 as 5.2 × 10-9. This kind of notation can be expressed in the format:
Where A is a digit between zero to nine (1-9), and n is an integer. Take note that the digits represented
by A cannot be zero or greater than 9.
To convert a number into scientific notation, you move the decimal point of a number until the new
form is a number from 1 up to 9 (A), and then record the exponent (n n) as the number of places the
decimal point was moved. Whether the power of 10 is positive or negative depends on whether you move
the decimal to the right or the left. Moving the decimal to the right makes the exponent negative; moving
it to the left gives you a positive exponent.
The distance between the Sun and Earth is 149,600,000 km. 1.49 × 108 m
II. Objectives:
After accomplishing this part of the module, you must be able to:
A. identify the rules in determining significant figures in a quantity;
B. appreciate the importance of the rules in rounding off numbers; and
C. solve fundamental operations among different quantities by applying rules of significant
figures and rounding off numbers.
III. Material/s:
A. Textbook/s for General Physics 1
1. Giancoli, D. C. (2005), Physics: Principles with Applications (6th Edition), USA
2. Arevalo, R. (n.d.), General Physics 1, Diwa Publishing House, Philippines.
B. Scientific Calculator
V. Concept:
When specific quantities are measured, the measured values are known only to within the limits of
the experimental uncertainty. The value of this uncertainty can depend on various factors, such as the
quality of the apparatus, the skill of the experimenter, and the number of measurements performed. The
number of significant figures in a measurement can be used to express something about the
uncertainty—the number of significant figures on a quantity depending on the value given. To determine
the number of significant figures, the following rules are followed.
2. Any zeros between two non-zero digits are 2007 has four (4) significant figures
significant. 80,582 has five (5) significant figures
3. A final zero or trailing zeros in the decimal 200.0 has four (4) significant figures
portion only are significant. 0.00500 has three (3) significant figures
4. Space holding zeros on numbers less than one is 0.01 has one (1) significant figure
not significant. 0.00012 has two (2) significant figures
5. Zero to the left of the decimal point on numbers 0.00036 has two (2) significant figures
less than one is not significant. 0.984 has three (3) significant figures
6. Trailing zeroes in a whole number is not 20,000 has one (1) significant figure
significant. 11,000,000 has two (2) significant figures
7. Leading zeroes in the whole number are not 00205 has three (3) significant figures
significant. 0003456 has four (4) significant figures
In problem-solving, we often combine quantities mathematically through multiplication, division,
addition, subtraction, and so forth. When doing so, you must make sure that the result has the
appropriate number of significant figures. The following rules are followed in determining the number of
significant figures in adding, subtracting, multiplying, and dividing different quantities or values.
If the number of significant figures in the result of a calculation must be reduced, there are general
rules for rounding numbers which are given as follows:
II. Objectives:
After accomplishing this part of the module, you must be able to:
A. describe how uncertainties in measurements occur;
B. appreciate the significance of accuracy and precision of results in experiments; and
C. perform actual measurements to analyze the occurrence of different types of errors.
III. Material/s:
A. Scientific Calculator
B. Ruler
V. Concept:
Accurate, precise measurements are an essential part of Physics, but no measurement is precise.
There is uncertainty associated with every measurement. Measurements can be accurate but not precise
or the other way around. By technical definition, accuracy refers to how close a measurement is to the
real value. On the other hand, precision in a strict sense refers to the repeatability of the measurement
using a given measurement. To illustrate the difference between the two, analyze the given figure below.
As shown in the figure, accuracy is achieved only when darts hit close to the target (high accuracy).
This is the same for measurements if your values are close to the true value; therefore, it is considered
accurate. On the other hand, darts either far or near the target as long as they are very close with each
other represents precision. If measurements made are very close in terms of values; therefore, it is
considered precise. This kind of measurement is given by the table below, in which a set of students tried
to measure the length of a string in several trials.
Due to this kind of error that may occur in measurements, it is essential to state the estimated
uncertainty on it. For example, the width of a board might be written as 8.8 ± 0.1 cm. The ± 0.1 cm (read
as “plus or minus 0.1 cm”) represents the estimated uncertainty in the measurement so that the actual
width most likely lies between 8.7 and 8.9 cm. The percent uncertainty is simply the ratio of the
uncertainty to the measured value multiplied by 100. In a mathematical expression, it can be written as:
(EQ. 8)
EXAMPLE CALCULATION:
What is the percent uncertainty if the measurement is 8.8 cm, and the estimated uncertainty is 0.1 cm?
STEP 2: Identify the quantity that is required to find the problem.
You are asked to find the percent uncertainty of a measurement.
STEP 3: Determine the given quantities.
You are given the uncertainty and the measured value.
II. Objectives:
After accomplishing this part of the module, you must be able to:
A. describe how to calculate uncertainties in measurements;
B. appreciate the importance of computing the uncertainty using mean, variance, and standard
deviation; and
C. solve problems regarding uncertainties in measurements.
III. Material/s:
A. Scientific Calculator
V. Concept:
wherein:
σ is the standard deviation
σ2 is the variance
PROBLEM # 1:
Sakura wants to measure how much time it would take for a coin to hit the ground if it is dropped 1-m
above the ground. So, she experimented with five consecutive trials. In those trials, the following time
in seconds was measured: 0.47 s, 0. 45 s, 0.50 s, 0.46 s, and 0.44 s. (a) What is the uncertainty in
Sakura’s measurements? (b) What is the percent uncertainty of her measurements?
STEP 1: Illustrate the problem through diagrams.
(1)
(2)
(3)
(4)
TRIALS
1 0.47 0.47 – 0.46 = 0.01 (0.01)2 = 0.0001
2 0.45 0.45 – 0.46 = -0.01 (-0.01)2 = 0.0001
3 0.50 0.50 – 0.46 = 0.04 (0.04)2 = 0.0016
4 0.46 0.46 – 0.46 = 0 (0)2 = 0
5 0.44 0.44 – 0.46 = -0.02 (-0.02)2 = 0.0004
check if that is correct by calculating the actual time using the equation: .
PROBLEM # 2:
A group of students is told to use a meter stick to find the length of a hallway. They make six
independent measurements: 4.402 m, 4.217 m, 4.345 m, 4.925 m, 4.372 m, and 4.289 m. How
should they report their best estimate of the length of the hallway?
STEP 1: Illustrate the problem through diagrams.
(1)
(2)
(3)
(4)
STEP 5: Write your calculations/computations.
Start first with calculating the mean of the given values:
TRIALS
1 4.402 4.402 – 4.425 = -0.023 (-0.023)2 = 0.000529
2 4.217 4.217 – 4.425 = -0.208 (-0.208)2 = 0.043264
3 4.345 4.345 – 4.425 = -0.08 (-0.08)2 = 0.0064
4 4.925 4.925 – 4.425 = 0.5 (0.5)2 = 0.25
5 4.372 4.372 – 4.425 = -0.053 (-0.053)2 = 0.002809
6 4.289 4.289 – 4.425 = -0.136 (-0.136)2 = 0.018496
Now, you can compute for the standard deviation:
For the last problem, you will have to try to solve this using your scientific calculator. Any scientific
calculator will do, but on this problem, CASIO fx-991 ClassWiz calculator will be used. In case you are
using other brands or models of calculator, there should be no problem. You may seek the help of your
teacher to teach you how to solve the problem on your calculator. If you still want to use the CASIO
model and you have an available laptop or PC, you may download the calculator emulator from the
CASIO website. The emulator is the one used on this problem.
Please check this official website of CASIO scientific calculators to download the calculator
emulator: https://edu.casio.com/softwarelicense/index.php#col3. Select the ClassWiz model on the site
given. For further instructions on how to download and install the emulator, seek the help of your teacher.
PROBLEM # 3:
A gold pawnshop was presented with a mass of gold. The pawnshop owner and two of his attendants
measured the mass of gold on balance. Their measurements are as given as follows: 12.1 g, 11.6 g,
and 14.3 g. To give a price to the gold, how should they report the final measurement for the mass of
it?
STEP 1: Illustrate the problem through diagrams.
MEASUREMENT MASS (m)
1 12.10
2 11.60
3 14.30
(1)
(2)
(3)
(4)
*The first three equations will not be used, for it can be easily calculated using the CASIO
calculator fx - 991 ClassWiz models. For the last equation, the percent uncertainty, you will
still have to solve this one.
STEP 5: Write your calculations/computations.
STEPS FIGURES
1. Set your calculator into the “Statistics”
mode. To do this, press the SETUP
button. Move through the screen using
the directional buttons to select “6:
Statistics”. Then, press the = (equal sign)
button.
2. After pressing the = (equal sign) button,
the screen will change and will present
your first four choices numbered from 1
to 4. Select “1: 1 – Variable” by pressing
1 in the Numpad buttons.
= mean
σ2 (σ2×) = variance
σ (σ×) = standard deviation
Therefore, from the results on your calculator, the values for mean, variance, and standard
deviation are:
II. Objectives:
After accomplishing this part of the module, you must be able to:
A. determine how to perform fundamental operations on measurements with uncertainties;
B. recognize the importance of absolute and relative uncertainties; and
C. solve problems regarding fundamental operations on uncertainties.
III. Material/s:
a)
B. Scientific Calculator
V. Concept:
Rules in performing fundamental operations (addition, subtraction, multiplication, and division), are
given in the following tables below: