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MSDS - Lime

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REVISION DATE: 03-08-07

SAFETY DATA SHEET


LIME

1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING

PRODUCT NAME LIME


SYNONYMS, TRADE NAMES CALCIUM HYDROXIDE
APPLICATION pH modifier.
SUPPLIER
M-I SWACO.
Holburn House,
475-485, Union Street,
Aberdeen. AB11 6DB
Scotland. UK
T = +44 (0)1224-336336
F = +44 (0)1224-336351
E-mail =
[email protected]
EMERGENCY TELEPHONE (24 Hour) Europe +44 (0) 208 762 8322, Asia Pacific +65 633 44 177, China +86 10 5100 3039, Middle
East and Africa +961 3 487 287.

2 HAZARDS IDENTIFICATION

Irritating to eyes and skin.


CLASSIFICATION Xi;R36/38.

3 COMPOSITION/INFORMATION ON INGREDIENTS

Name EC No. CAS-No. Content Classification

CALCIUM HYDROXIDE 215-137-3 1305-62-0 60-100% Xi;R36/38.

The Full Text for all R-Phrases are Displayed in Section 16

COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives.

4 FIRST-AID MEASURES

INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
INGESTION
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention
immediately.
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes and get medical attention.
5 FIRE-FIGHTING MEASURES

EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials.

UNUSUAL FIRE & EXPLOSION HAZARDS


High concentrations of dust may form explosive mixture with air.

PROTECTIVE MEASURES IN FIRE


Self contained breathing apparatus and full protective clothing must be worn in case of fire.

6 ACCIDENTAL RELEASE MEASURES

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REVISION DATE: 03-08-
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PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.

ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses.

SPILL CLEAN UP METHODS


Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.

7 HANDLING AND STORAGE

USAGE PRECAUTIONS
Avoid inhalation of dust and contact with skin and eyes.

STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.

8 EXPOSURE CONTROLS/PERSONAL PROTECTION

Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3


CALCIUM HYDROXIDE WEL 5 mg/m3

INGREDIENT COMMENTS
WEL = Workplace Exposure Limits

PROTECTIVE EQUIPMENT

ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.

RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Dust filter P2 (for fine dust).
HAND PROTECTION
Use protective gloves made of: Impermeable material. Rubber, neoprene or PVC.

EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.

OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.

9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE Powder, dust


COLOUR White White / off-white
ODOUR Odourless
SOLUBILITY Slightly soluble in water.
MOL. WEIGHT 74 MELTING POINT (°C) 580°C
RELATIVE DENSITY 2.34 s.g @ 20 °c BULK DENSITY 2.24 g/cm3
PARTICLE SIZE (Micron) <500 pH-VALUE, CONC. SOLUTION 12.4
SOLUBILITY VALUE (g/100g 1.7
H2O@20°C)
10 STABILITY AND REACTIVITY

STABILITY
Stable under normal temperature conditions and recommended use.

CONDITIONS TO AVOID
Avoid contact with: Water, moisture. and Creation of dust clouds.

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REVISION DATE: 03-08-
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MATERIALS TO AVOID
Avoid: Acids, oxidising. Acids, non-oxidising. Acids - organic. Organic nitro compounds.

11 TOXICOLOGICAL INFORMATION

INHALATION
May cause irritation to the respiratory system. Symptoms may include sore throat, coughing, shortness of breath and difficulty breathing.

INGESTION
May cause burns in mucous membranes, throat, oesophagus and stomach.

SKIN CONTACT
Irritating to skin. Prolonged or repeated exposure may cause severe irritation.

EYE CONTACT
Irritating to eyes. Repeated exposure may cause chronic eye irritation. Extreme irritation of eyes and mucous membranes, including
burning and tearing.

12 ECOLOGICAL INFORMATION

ECOTOXICITY
Contact M-I Swaco's QHSE Department for ecological information.

13 DISPOSAL CONSIDERATIONS

DISPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.

14 TRANSPORT INFORMATION

GENERAL The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).

15 REGULATORY INFORMATION

LABELLING

Irritant

RISK PHRASES
R36/38 Irritating to eyes and skin.

SAFETY PHRASES
S24/25 Avoid contact with skin and eyes.

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.
S37 Wear suitable gloves.

UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations.

EU DIRECTIVES
Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC.

GUIDANCE NOTES
Workplace Exposure Limits EH40.

16 OTHER INFORMATION

GENERAL INFORMATION
HMIS Health - 2 HMIS Flammability - 0 HMIS Physical Hazard - 0

INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. Micromedex. European
Chemicals Bureau - ESIS (European Chemical Substances Information System).

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REVISION DATE: 03-08-
LI
REVISION COMMENTS
General revision. Compiled or revised by Sandra McWilliam

ISSUED BY
Bill Cameron
REVISION DATE 03-08-07
REV. NO./REPL. SDS GENERATED 4
SDS NO. 10290

RISK PHRASES IN FULL


R36/38 Irritating to eyes and skin.

DISCLAIMER
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of
the data are obtained from sources beyond our direct supervision. We cannot make any assertions as to its reliability or
completeness; therefore, user may rely only at user's risk. We have made no effort to censor or conceal deleterious aspects of
this product. Since we cannot anticipate or control the conditions under which this information and product may be used, we
make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It is the
obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or
implied, nor liability of any nature with respect to this product or to the data herein is made or incurred hereunder.

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