Term-II Examination 2022-23

CLASS: 11 JA-MA SUBJECT: CHEMISTRY MM: 70 Time: 3 Hrs.

Instructions:
1. Section A (1 to 18) consists of 18 Questions carrying 1 mark each [Multiple Choice Questions 1 to 14 , Assertion
Reason 15 to 18].
2. Section B (19 to 25) consists of 7 questions carrying 2 marks each [Very Short Answer Questions].
3. Section C (26 to 30) consists of 5 questions carrying 3 marks each [Short Answer Questions].
4. Section D (31 to 32) consists of 2 Questions carrying 4 marks each [Case Based Questions].
5. Section E (33 to 35) consists of 2 Questions carrying 5 marks each [Long Answer Questions].
SECTION-A
1. The prefix 1018 is
(a) giga (b) exa (c) kilo (d) nano(e) mega
2. Rutherford’s experiment which established the nuclear model of the atom used a beam of
(a) β-particles which impinged on a metal foil and got absorbed
(b) γ-rays, which impinged on a metal foil and got absorbed
(c) helium atoms which impinged on a metal foil and got reflected
(d) helium nuclei which impinged on a metal foil and got scattered.
3. Azimuthal quantum number determines the
(a) size (b) spin (c) orientation (d) angular momentum of orbitals
4. Correct order of radii is
(a) N < Be < B (b) F– < O2- < N3- (c) Na < Li < K(d) Fe3+ < Fe2+ < Fe4+
5. Eka-alurninium and Eka-silicon are known as
(a) Gallium and germanium (b) Aluminium and silicon
(c) Iron and sulphur (d) Neutron and magnesium
6. Maximum bond angle is present in case of
(a) BBr3 (b) BCl3 (c) BF3 (d) Same in all
7. The correct order of hybridisation of the central atom in the following species: NH3, [PtCl4]2-, PCl5 and BCl3 is
(a) dsp², dsp³, sp² and sp³ (b) sp³, dsp², dsp³, sp²
(c) dsp², sp², sp³, dsp³ (d) dsp², sp³, sp², dsp³.
8. Which one of the following statement is false?
(a) Work is a state function
(b) Temperature is a state function
(c) Change in the state is completely defined when the initial final states are specified
(d) Work appears at the boundary of the system
9. An adiabatic’expansion of an ideal gas always has
(a) Decrease in temperature (b) q = 0 (c) W = 0 (d) ∆H = 0
10. For the reaction N2 + 3H2 ⇌ 2NH3 + heat
(a) Kp = K.(RT)2- (b) Kp = Kc (c) Kp = KcRT (d) Kp = Kc (RT)1-
11. Aluminium chloride is
(a) Bronsted Lowry acid (b) Arrhenius acid (c) Lewis acid (d) Lewis base
12. Rate of effusion of a gas is
(a) Directly proportional to its density
(b) Directly proportional to its molar mass
(c) Directly proportional to the square root of its mass
(d) Inversely proportional to the square root of its molar mass.
13. When temperature is increased, surface tension of water
(a) increases (b) decreases (c) remains constant (d) shows irregular behaviour
14. The C-H bond distance is longest in
(a) C2H2 (b) C2H4 (c) C2H6 (d) C2H2Br2
15. (a) if both assertion and reason are true and the reason is the correct explanation of the assertion.
(b) If both assertion and reason are true but the reason is not the correct explanation of the assertion.
(c) If the assertion is true but the reason is false.
(d) If the assertion is false but the reason is true.
Assertion: N2 + 3 H2 ⇌ NH3; ∆H = –92 kJ. High pressure favours the formation of ammonia.
Reason: An increase of external pressure on the above reaction at equilibrium favours the reaction in the direction
in which the number of moles decreases.
16. Assertion (A): All isotopes of a given element show the same type of chemical behaviour. Reason (R): The
chemical properties of an atom are controlled by the number of electrons in the atom.
(i) Both A and R are true and R is the correct explanation of A.
(ii)Both A and R are true but R is not the correct explanation of A.
(iii)A is true but R is false.
(iv)Both A and R are false.
17. Assertion (A): Generally, ionisation enthalpy increases from left to right in a period.
Reason (R): When successive electrons are added to the orbitals in the same principal
quantum level, the shielding effect of the inner core of electrons does not increase very much
to compensate for the increased attraction of the electron to the nucleus.
(i) Assertion is correct statement and reason is wrong statement.
(ii) Assertion and reason both are correct statements and reason is correct explanation of assertion.
(iii) Assertion and reason both are wrong statements.
(iv) Assertion is wrong statement and reason is correct statement.
18. Assertion (A): Sodium chloride formed by the action of chlorine gas on sodium metal is a stable compound.
Reason (R): This is because sodium and chloride ions acquire octet in sodium chloride formation.
(i) A and R both are correct, and R is the correct explanation of A.
(ii) A and R both are correct, but R is not the correct explanation of A.
(iii) A is true but R is false.
(iv) A and R both are false.
SECTION-B
19. Volume of a solution changes with change in temperature, then, will the molality solution be affected by
temperature? Give reason for your answer.1+1= 2
20. Why does a sharp glass edge become smooth on heating it up to its melting point In a flame? Explain which
property of muds is responsible for this phenomenon.1+1=2
21. Write Hund’s and Aufbau Principle with statements. 1+1=2
Or
Write Pauli’s Exclusion Principal and Heisenberg’s Uncertainity Principal. 1+1=2
22. Explain why the electron gain enthalpy of fluorine is less negative than that of chlorine. 2
23. At 298 K. Kp for the reaction N2O4 (g) ⇄ 2NO2 (g) is 0.98. Predict whether the reaction is spontaneous or not. [ ln
(0.98) = -0.02 ] 2
24. An ideal gas is allowed to expand against a constant pressure of 2 bar from 10 L to 50 L in one step. Calculate the
amount of work done by the gas. If the same expansion were carried out reversibly, will the work done be higher
or lower than the earlier case? (Given that 1 L bar = 100 J). 1+1=2
25. Write the Brownsted acid-base concept and The ionisation of hydrochloric in water is given below: HCI(aq) + H2O
(l) ⇋ H3O+ (aq) + CI– (aq)
Label two conjugate acid-base pairs in this ionisation. 1+1=2
SECTION-C
26. 45.4 L of dinitrogen reacted with 22.7 L of dioxygen and 45.4 L of nitrous oxide was formed. The reaction is given
below: 2N2(g) + O2(g) → 2N2O(g)
Which law is being obeyed in this experiment? Write the statement of the law. 1+1+1=3
27. An electron is in one of the 3d orbitals. Give the possible values of n, l and ml for this electron. 1+1+1=3
Or
What information provided by principal q.no. ,azimuthal q.no. and magnetic q.no. 1+1+1=3
28. What will be the pressure exerted by a mixture of 3.2g of methane and 4.4g of carbon dioxide contained in a 9
dm3 flask at 27 °C? 3
29. Predict the shapes of the following molecules on the basis of hybridization. 1+1+1=3
BCI3, CH4, CO2,
30. The solubility product of Al(OH)3 is 2.7 x 10-11. Calculate its solubility in g / L. (Atomic mass of Al = 27 u). 2+1=3
SECTION-D
31.Case Study 1:
The three-dimensional (3-D) structure of organic molecules can be represented on paper by using certain
conventions. For example, by using solid ( ) and dashed ( ) wedge formula, the 3-D image of a molecule from a
two-dimensional picture can be perceived. In these formulas the solid-wedge is used to indicate a bond
projecting out of the plane of paper, towards the observer. The dashed-wedge is used to depict the bond
projecting out of the plane of the paper and away from the observer. Wedges are shown in such a way that the
broad end of the wedge is towards the observer. The bonds lying in plane of the paper are depicted by using a
normal line (—).
Cyclic or closed chain or ring compounds
a) Alicyclic compounds Alicyclic (aliphatic cyclic) compounds contain carbon atoms joined in the form of a ring
(homocyclic).
These exhibit some of the properties similar to those of aliphatic compounds.
b) Aromatic compounds Aromatic compounds are special types of compounds. These include benzene and other
related ring compounds (benzenoid). Like alicyclic compounds, aromatic comounds may also have hetero atom in
the ring. Such compounds are called hetrocyclic aromatic compounds. Some of the examples of various types of
aromatic compounds are:
Benzenoid aromatic compounds .
Organic compounds can also be classified on the basis of functional groups, into families or homologous series.
Functional Group The functional group is an atom or a group of atoms joined to the carbon chain which is
responsible for the characteristic chemical properties of the organic compounds. The examples are hydroxyl
group (–OH), aldehyde group (–CHO) and carboxylic acid group (–COOH) etc.
Homologous Series A group or a series of organic compounds each containing a characteristic functional group
forms a homologous series and the members of the series are called homologues. The members of a homologous
series can be represented by general molecular formula and the successive members differ from each other in
molecular formula by a –CH2 unit. There are a number of homologous series of organic compounds. Some of
these are alkanes, alkenes, alkynes, haloalkanes, alkanols, alkanals, alkanones, alkanoic acids, amines etc. It is
also possible that a compound contains two or more identical or different functional groups. This gives rise to
polyfunctional compounds.
A systematic name of an organic compound is generally derived by identifying the parent hydrocarbon and the
functional group(s) attached to it. See the example given below.
By further using prefixes and suffixes, the parent name can be modified to obtain the actual name. Compounds
containing carbon and hydrogen only are called hydrocarbons. A hydrocarbon is termed saturated if it contains
only carbon-carbon single bonds.
The IUPAC name for a homologous series of such compounds is alkane. Paraffin (Latin: little affinity) was the
earlier name given to these compounds. Unsaturated hydrocarbons are those, which contain at least one carbon-
carbon double or triple bond. IUPAC Nomenclature of Alkanes Straight chain hydrocarbons: The names of such
compounds are based on their chain structure, and end with suffix ‘-ane’ and carry a prefix indicating the
number of carbon atoms present in the chain (except from CH4 to C4H10, where the prefixes are derived from
trivial names). The IUPAC names of some straight chain saturated hydrocarbons are given in Table. The alkanes in
table differ from each other by merely the number of – CH2 groups in the chain. They are homologues of alkane
series.
1) IUPAC is an acronym for …
a) International Union of Pure and Applied Chemistry
b) International units of proteins and carbohydrates
c) International understandings on physical aspects of chemistry
d) Iodine under packings
2) In homologous series, the successive members differ from each other in molecular formula by a … unit.
a) -CH3 b) -CH2- c) =CH- d) CH4
3) A hydrocarbon is termed saturated if it contains only carbon-carbon …bonds.
a) Triple b) Double c) Single d) Zero
4) From ….., where the prefixes are derived from… trivial names.
a) CH4 to C2H6 b) CH4 to C3H8c) CH4 to C6H14 d) CH4 to C4H10
Or
5) Molecular formula of octane is …
a) C4H10 b) C6H14 c) C2H6 d) C8H18
32. Case 2:
The French physicist, de Broglie, in 1924 proposed that matter, like radiation, shouldalso exhibit dual behaviour
i.e., both particleand wavelike properties.
where ∆x is the uncertainty in position and ∆p x(or ∆vx) is the uncertainty in momentum (orvelocity) of the
particle.
One of the important implications of theHeisenberg Uncertainty Principle is that itrules out existence of definite
paths ortrajectories of electrons and other similarparticles. The effect of Heisenberg Uncer tainty Principle is
significant only for motion of microscopic objects and is negligible for that of macroscopic objects. It, therefore,
means that theprecise statements of the position andmomentum of electrons have to bereplaced by the
statements of probability,that the electron has at a given positionand momentum. This is what happens inthe
quantum mechanical model of atom. In Bohr model, anelectron is regarded as a charged particlemovingin well
defined circular orbits aboutthe nucleus. The wave character of the electronis not considered in Bohr model.
Further, anorbit is a clearly defined path and this pathcan completely be defined only if both theposition and the
velocity of the electron areknown exactly at the same time.
When Schrödinger equation is solved forhydrogen atom, the solution gives the possibleenergy levels the electron
can occupy and thecorresponding wave function(s) (ψ) of theelectron associated with each energy level. A large
number of orbitals are possible in anatom. Qualitatively these orbitals can bedistinguished by their size, shape
andorientation. An orbital of smaller size meansthere is more chance of finding the electron nearthe nucleus.
Similarly shape and orientationmean that there is more probability of findingthe electron along certain directions
thanalong others. Atomic orbitals are preciselydistinguished by what are known as quantumnumbers. Each
orbital is designated by threequantum numbers labelled as n, l and m 1.
The principal quantum number ‘n’ isa positive integer with value of n = 1,2,3…….The principal quantum number
determines thesize and to large extent the energy of theorbital. Azimuthal quantum number. ‘l’ is alsoknown as
orbital angular momentum orsubsidiary quantum number. It defines thethree-dimensional shape of the orbital..
For agiven value of n, l can have n values rangingfrom 0 to n – 1, that is, for a given value of n,the possible value
of l are : l = 0, 1, 2, ……….(n–1)
Magnetic orbital quantum number. ‘mlgives information about the spatialorientation of the orbital with respect
tostandard set of co-ordinate axis. For anysub-shell (defined by ‘l’ value) 2l+1 valuesof ml are possible and these
values are givenbuy :ml = – l, – (l –1), – (l–2)… 0,1… (l –2), (l–1)..
These two orientations aredistinguished by the spin quantum numbersms which can take the values of +½ or –
½.These are called the two spin states of theelectron and are normally represented by twoarrows, ↑ (spin up)
and ↓ (spin down).the four quantum numbersprovide the following information :
i)n defines the shell, determines the size ofthe orbital and also to a large extent theenergy of the orbital.
ii)ii) There are n subshells in the n the shell. Lidentifies the subshell and determines the shape of the orbital (see
section 2.6.2).There are (2l+1) orbitals of each type in asubshell, that is, one s orbital (l = 0), threep orbitals (l = 1)
and five d orbitals (l = 2)per subshell. To some extent l alsodetermines the energy of the orbital in amulti-
electron atom.
iii)iii) ml designates the orientation of the orbital.For a given value of l, mlhas (2l+1) values,the same as the
number of orbitals persubshell. It means that the number oforbitals is equal to the number of ways inwhich t hey
are oriented.
iv)iv) ms refers to orientation of the spin of the electron.
1) Uncertainty principle was given by ..
(a) Werner Heisenberg (b) George Uhlenbeck
(c) Samuel Goudsmit (d) De Broglie
2) Quantum mechanics is a theoretical science that deals with the study of the motions of the ….. objects.
(a) Macroscopic (b) Microscopic
(c) Laparoscopic (d) All the above
3) The principal quantum number …
(a) l (b) m
(c) n (d) p
4) …is also known as orbital angular momentum or subsidiary quantum number.
(a) principal quantum number(b) electron spin quantum number
(c) Magnetic orbital quantum number. (d) Azimuthal quantum number
Or
5) George Uhlenbeck and Samuel Goudsmit proposed the presence of the fourth quantum number known as
the..
(a) principal quantum number(b) electron spin quantum number
(c) Magnetic orbital quantum number(d) Azimuthal quantum number
 SECTION-D
33. (a) Write structural formulae for compounds named as- 2+3=5
(i) 1-Bromoheptane (ii) 5-Bromoheptanoic acid
(b) Draw the resonance structures of the following compounds.

Or

(a) Name the compounds whose line formulae are given below : 2+3=5

(b) Which of the following compounds will not exist as a resonance hybrid. Give reason for your answer
(i) CH3OH (ii) R−CONH2 (iii) CH3CH=CHCH2NH2
34. (a) The pressure of a mixture of H2 and N2 in a container is 1200 torr. The partial pressure of nitrogen in the
mixture is 300 torr. What is the ratio of H2 and N2 molecules in the mixture? 3
(b) Explain the two factors which can affect the surface tension of a liquid. 2
OR
a) State and explain Boyle’s law. Represent the law graphically. 3
b) Give an expression for the van der Wools equation. What are units of a and b? 1+1=2
35. a) What do you understand by isoelectronic species? Name a species that will be iso electronic with each of the
following atoms or ions. (i) F– (ii) Ar (iii) Mg2+ (iv) Rb+ 1+2=3
b) Explain why cation are smaller and anions larger in radii than their parent atoms? 2