PC110 Instruction Manual GZ0000427799B

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Instruction Manual

pH/ORP/Conductivity Meter
LAQUAact-PC110

Portable pH・Water Quality Meter


■ Preface
This manual describes the operation of the following instrument.
Brand (pet name): LAQUAact
Series name: Portable pH Water Quality Meter
Model: LAQUAact-PC110
Model description: pH/ORP/Conductivity Meter
Be sure to read this manual before using the product to ensure proper and safe
operation of the product. Also safely store the manual so it is readily available whenever
necessary.
Product specifications and appearance, as well as the contents of this manual are
subject to change without notice.

● Warranty and responsibility


HORIBA Advanced Techno Co., Ltd. warrants that the Product shall be free from defects
in material and workmanship and agrees to repair or replace free of charge, at option of
HORIBA Advanced Techno Co., Ltd., any malfunctioned or damaged Product
attributable to responsibility of HORIBA Advanced Techno Co., Ltd. for a period of Two
(2) years from the delivery unless otherwise agreed with a written agreement. In any one
of the following cases, none of the warranties set forth herein shall be extended;

・ Any malfunction or damage attributable to improper operation


・ Any malfunction attributable to repair or modification by any person not authorized
by HORIBA Advanced Techno Co., Ltd.
・ Any malfunction or damage attributable to the use in an environment not specified in
this manual
・ Any malfunction or damage attributable to violation of the instructions in this manual
or operations in the manner not specified in this manual
・ Any malfunction or damage attributable to any cause or causes beyond the
reasonable control of HORIBA Advanced Techno Co., Ltd. such as natural disasters
・ Any deterioration in appearance attributable to corrosion, rust, and so on
・ Replacement of consumables

HORIBA Advanced Techno Co., Ltd. SHALL NOT BE LIABLE FOR ANY DAMAGES
RESULTING FROM ANY MALFUNCTIONS OF THE PRODUCT, ANY ERASURE OF
DATA, OR ANY OTHER USES OF THE PRODUCT.

● Trademarks
・ Microsoft, Windows, Windows Vista are registered trademarks or trademarks of
Microsoft Corporation in the United States and other countries.
Other company names and brand names are either registered trademarks or trademarks
of the respective companies. (R), (TM) symbols may be omitted in this manual.

CODE:GZ0000427799B
January, 2017      2017 HORIBA Advanced Techno Co., Ltd.

I
Regulations

■ Regulations
● EU regulations
●Conformable standards
This equipment conforms to the following standards:
EMC: EN61326-1
Class B, Basic electromagnetic environment
Safety: EN61010-1
RoHS: EN50581
9. Monitoring and control instruments

Warning: This product is not intended for use in industrial environments. In an


industrial environment, electromagnetic environmental effects may
cause the incorrect performance of the product in which case the
user may be required to take adequate measures.

●Installation environment
This product is designed for the following environment.
・Overvoltage category II
・Pollution degree 2

●Information on disposal of electrical and electronic equipment and


disposal of batteries and accumulators
The crossed out wheeled bin symbol with underbar shown on the product or
accompanying documents indicates the product requires appropriate treatment,
collection and recycle for waste electrical and electronic equipment (WEEE) under the
Directive 2012/19/EU, and/or waste batteries and accumulators under the Directive
2006/66/EC in the European Union.
The symbol might be put with one of the chemical symbols below. In this case, it satisfies
the requirements of the Directive 2006/66/EC for the object chemical.
This product should not be disposed of as unsorted household waste.
Your correct disposal of WEEE, waste batteries and accumulators will contribute to
reducing wasteful consumption of natural resources, and protecting human health and
the environment from potential negative effects caused by hazardous substance in
products.
Contact your supplier for information on applicable disposal methods.

●Authorised representative in EU
HORIBA UK Limited
2 Dalston Gardens, Stanmore, Middx HA7 1BQ, UK

II
Regulations

● FCC rules
Any changes or modifications not expressly approved by the party responsible for
compliance shall void the user's authority to operate the equipment.

●Warning
This equipment has been tested and found to comply with the limits for a Class A digital
device, pursuant to part 15 of the FCC Rules. These limits are designed to provide
reasonable protection against harmful interference when the equipment is operated in a
commercial environment. This equipment generates, uses, and can radiate radio
frequency energy and, if not installed and used in accordance with the instruction
manual, may cause harmful interference to radio communications.
Operation of this equipment in a residential area is likely to cause harmful interference in
which case the user will be required to correct the interference at his own expense.

● Korea certification

● Taiwan battery recycling mark

III
Regulations

● China regulation
ḽ䇦Ⲻᝅѿ
Meaning of Marking
䝬䞊䜽䛾ព࿡㻌

ᵢḽ䇦䘸⭞൞ѣ঄Ӱ≇ާૂള䬶୤⭫ಞ⭫ᆆӝ૷θḽ䇦ѣཤⲺᮦ
ᆍ㺞⽰⧥ູؓᣚֵ⭞ᵕ䲆ⲺᒪᮦȾ(уᱥ㺞⽰ӝ૷䍞䠅ؓ䇷ᵕ䰪Ⱦ)
ਠ㾷䚫ᆾ䘏Ѡӝ૷ᴿީⲺᆿ‫⌞⭞ֵૂޞ‬ᝅӁ亯θԄ࡬䙖ᰛᔶခ㇍
䎭൞䘏Ѡᒪ䲆޻θуՐ㔏⧥ູ⊗ḉȽӰ։ૂ䍘ӝᑜᶛћ䠃ⲺᖧଃȾ
䈭у㾷䳅ᝅᓕᔹᵢ⭫ಞ⭫ᆆӝ૷Ⱦ

This marking is applied to electric and electronic products sold


in the People's Republic of China. The figure at the center of
the marking indicates the environmental protection use period
in years. (It does not indicate a product guarantee period.) It
guarantees that the product will not cause environment
pollution nor serious influence on human body and property
within the period of the indicated years which is counted from
the date of manufacture as far as the safety and usage
precautions for the product are observed. Do not throw away
this product without any good reason.

ᮏ䝬䞊䜽䛿䚸୰⳹ேẸඹ࿴ᅜ䛷㈍኎䛥䜜䜛㟁Ẽ㟁Ꮚ〇ရ䛻㐺⏝䛥
䜜䚸䝬䞊䜽䛾୰ኸ䛾ᩘᏐ䛿⎔ቃಖㆤ౑⏝ᮇ㝈䛾ᖺᩘ䜢ព࿡䛧䜎䛩
䠄〇ရ䛾ရ㉁ಖドᮇ㛫䜢♧䛩䜒䛾䛷䛿䛒䜚䜎䛫䜣䠅䚹䛣䛾〇ရ䛻㛵
䛩䜛Ᏻ඲䜔౑⏝ୖ䛾ὀព䜢䛚Ᏺ䜚㡬䛟㝈䜚䚸〇㐀᪥䛛䜙㉳⟬䛩䜛䛣
䛾ᖺ㝈ෆ䛷䛿䚸⎔ቃởᰁ䜔ேయ䜔㈈⏘䛻῝้䛺ᙳ㡪䜢ཬ䜌䛩䛣䛸
䛿䛒䜚䜎䛫䜣䚹ᮏ〇ရ䜢䜏䛰䜚䛻ᗫᲠ䛧䛺䛔䛷䛟䛰䛥䛔䚹

IV
Regulations

ӝ૷ѣᴿᇩ⢟䍞Ⲻ੃〦਀੡䠅
Name and amount of hazardous substance used in a product
ᴿᇩ⢟䍞
Hazardous substance
‫ޣ‬ԭ䬢 ཐ⓪ӂ㤥䟐
ཐ⓪㚊㤥
䜞Ԭ੃〦 ⊔ 䭿 Hexa- Poly
䫻 Poly
Unit name Mer Cad- valent bromo-
Lead bromo-
cury mium㻌 chrom- diphenyl
(Pb) biphenyl
(Hg) (Cd) ium㻌 ether
(PBB)
(Cr (VI)) (PBDE)
ᵢ։ 
™ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
Main unit
⭫⊖ 
™ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
Battery
AC䘸䞃ಞ
*1, *2 ™ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
AC adapter
⭫㔼 
*2 ™ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
Cable
᭥ᷬ 
*2 ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
Stand
ᢉদᵰ
*2 ™ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
Printer
⭫ᶷ
*2 ™ ‫ۑ‬ ™ ‫ۑ‬ ‫ۑ‬ ‫ۑ‬
Electrode

ᵢ㺞Ṳ‫ᦤד‬SJ/T 11364Ⲻ㿺ᇐ㕌࡬Ⱦ
This form is prepared in accordance with SJ/T 11364.
‫ۑ‬: 㺞⽰䈛ᴿᇩ⢟䍞൞䈛䜞Ԭᡶᴿൽ䍞ᶆᯏѣⲺ੡䠅ൽ൞ GB/T 26572 㿺ᇐⲺ䲆䠅㾷
≸ԛсȾ
Denotes that the amount of the hazardous substance contained in all of the
homogeneous materials used in the component is below the limit on the
acceptable amount stipulated in the GB/T 26572.
h: 㺞⽰䈛ᴿᇩ⢟䍞㠩ቇ൞䈛䜞ԬⲺḆжൽ䍞ᶆᯏѣⲺ੡䠅䎻࠰GB/T 26572 㿺ᇐⲺ
䲆䠅㾷≸Ⱦ
Denotes that the amount of the hazardous substance contained in any of the
homogeneous materials used in the component is above the limit on the
acceptable amount stipulated in the GB/T 26572.
*1: ᵢ䜞ԬⲺ⧥ֵؓ⭞ᵕ䲆Ѱ10ᒪȾ㻌 The environmental protection use period
of this product is 10 years.
*2: 䘿䞃Ԭ Optional products

V
For Your Safety

■ For Your Safety


● Hazard classification and warning symbols
Warning messages are described in the following manner. Read the messages and
follow the instructions carefully.

●Hazard classification
This indicates an imminently hazardous situation which, if
not avoided, will result in death or serious injury. This is to
be limited to the most extreme situations.

This indicates a potentially hazardous situation which, if


not avoided, could result in death or serious injury.

This indicates a potentially hazardous situation which, if


not avoided, may result in minor or moderate injury. It may
also be used to alert against unsafe practices.

●Warning symbols

Description of what should be done, or what should be followed

Description of what should never be done, or what is prohibited

● [DEU] Sicherheitsinformation
Lesen Sie vor der Verwendung des Produkts unbedingt diese Anleitung, um den ord-
nungsgemäßen und sicheren Betrieb des Produkts zu gewährleisten. Bewahren Sie die
Anleitung sicher auf, damit sie bei Bedarf jederzeit zur Hand ist.
Die Inhalt dieser Anleitung können ohne Vorankündigung geändert werden.

●Installationsumgebung
Dieses Produkt ist nicht zum Gebrauch in industriellen Umgebungen, wie in EN61326-1
definiert, vorgesehen.
In einer industriellen Umgebung können die elektromagnetischen Störungen eventuell
zu Produktfehlfunktionen führen. Um dieses Produkt unter solchen Umständen verwen-
den zu können, muss der Benutzer ggf. angemessene Maßnahmen ergreifen.
Das Produkt ist gemäß EN61010-1 für die folgende Umgebung vorgesehen.
- Überspannungskategorie II
- Verschmutzungsgrad 2

VI
For Your Safety

● [FRA] Informations de sécurité


Veillez à lire le présent manuel avant d’utiliser le produit de manière à garantir son utili-
sation correcte et sûre. De même, rangez le manuel dans un lieu sûr de manière à pou-
voir vous y reporter lorsque cela est nécessaire.
Le contenu du présent manuel peut être modifié sans notification préalable.

●Environnement d’installation
Ce produit n'est pas destinés à une utilisation dans des environnements industriels, tels
que définis dans la norme EN61326-1.
Dans un environnement industriel, les interférences électromagnétiques peuvent entraî-
ner un dysfonctionnement du produit. Pour utiliser le produit dans ce type d’environne-
ments, l’utilisateur peut avoir à prendre des mesures appropriées.
Le produit est conçu pour l’environnement suivant, tel que défini dans la norme
EN61010-1.
- Catégorie de surtension II
- Degré de pollution 2

● [ITA] Informazioni sulla sicurezza


Leggere attentamente questo manuale prima di utilizzare il prodotto al fine di utilizzarlo
in modo sicuro e adeguato. Inoltre, conservare in un luogo sicuro il manuale per poterlo
consultare se necessario.
Le contenuti di questo manuale sono soggetti a modifiche senza preavviso.

●Ambiente di installazione
Questo prodotto non è stati progettati per essere utilizzati in ambienti industriali, secondo
la norma EN61326-1.
In un ambiente industriale, le interferenze elettromagnetiche potrebbero causare un mal-
funzionamento del prodotto. Per utilizzare il prodotto in tali ambienti, all'utente potrebbe
essere richiesto di adottare le contromisure necessarie.
Il prodotto è designato per il seguente ambiente, definito nello standard EN61010-1.
- Categoria di sovratensione II
- Livello di inquinamento 2

● [SWE] Säkerhetsinformation
Se till att du läser denna handbok innan du börjar använda produkten för en korrekt och
säker användning av den. Spara sedan handboken på en säker och lättåtkomlig plats så
att du kan konsultera den när så behövs.
Innehållet i denna handbok kan komma att ändras utan föregående meddelande därom.

●Installationsmiljö
Detta produkten är ej avsedda för användning i industriella miljöer enligt riktlinjerna i
EN61326-1.
Om den används i industrimiljöer kan de elektromagnetiska störningarna orsaka tek-
niska fel hos produkten. Om produkten ska användas i sådana miljöer kan användaren
behöva vidta lämpliga åtgärder för att lösa dessa problem.
Produkten är utformad för användning i följande miljöer, i enlighet med SS-EN 61010-1.
- Överspänningskategori II
- Föroreningsgrad 2

VII
For Your Safety

● [SPA] Información de seguridad


Asegúrese de leer este manual antes de utilizar el producto para garantizar un uso
correcto y seguro del mismo. Asimismo, guarde de forma segura el manual para que
esté disponible siempre que sea necesario.
El contenido de este manual están sujetos a cambios sin previo aviso.

●Entorno de instalación
Este producto está diseñado para su uso en entornos industriales, tal y como se define
en EN61326-1.
En un entorno industrial, las interferencias electromagnéticas pueden provocar un fun-
cionamiento incorrecto del producto. Para usar el producto en tales entornos, el usuario
debe tomar las medidas adecuadas.
El producto se ha diseñado para el siguiente entorno, definido en EN61010-1.
- Categoría de sobretensión II
- Nivel de contaminación 2

● [POL] Informacje dotyczące bezpieczeństwa


Przed przystąpieniem do użytkowania tego produktu należy dokładnie zapoznać się z
niniejszą instrukcją, aby zapewniona była prawidłowa i bezpieczna eksploatacja pro-
duktu. Instrukcję przechowywać w bezpiecznym miejscu, aby w razie potrzeby była
zawsze dostępna.
Treść niniejszej instrukcji może ulec zmianie bez wcześniejszego powiadomienia.

●Środowisko instalacji
Ten produkt nie są przeznaczone do użytkowania w środowisku przemysłowym, zgodnie
z definicją określoną w normie EN61326-1.
W środowisku przemysłowym zakłócenia elektromagnetyczne mogą powodować niepra-
widłowe działanie produktów. Możliwe, że aby użytkować produkt w takich środowi-
skach, użytkownik będzie musiał podjąć stosowne środki zaradcze.
Produkt jest przeznaczony do użycia w poniższym środowisku zdefiniowanym w normie
EN61010-1.
- Kategoria przepięciowa II
- Stopień zanieczyszczenia 2

VIII
For Your Safety

● [NLD] Veiligheidsinformatie
Lees deze handleiding voordat u dit product gebruikt zodat u het op de juiste manier en
veilig kunt gebruiken. Bewaar de handleiding goed zodat u hem wanneer nodig kunt
raadplegen.
De inhoud van deze handleiding kunnen zonder voorafgaande kennisgeving worden
gewijzigd.

●Installatieomgeving
Dit product is niet bedoeld voor gebruik in een industriële omgeving zoals gedefinieerd in
EN 61326-1.
In een industriële omgeving kan de elektromagnetische interferentie de werking van dit
product storen. Voor gebruik van het product in een dergelijke omgeving moet de gebrui-
ker mogelijk maatregelen treffen om de storing te verhelpen.
Het product is ontworpen voor de volgende omgeving, gedefinieerd in EN 61010-1.
- Overspanningscategorie II
- Vervuilingsgraad 2

● [JPN] 安全情報
ご使用にな る前に、 本書を必ずお読み く だ さ い。 お読みにな っ た後は必要な と き にす ぐ
に取 り 出せる よ う に大切に保管 し て く だ さ い。
本書に記載 さ れている内容は予告な く 変更 さ れる場合があ り ます。 あ らか じ めご了承 く
だ さ い。
●設置環境
本製品は、EN61326-1 で定義 さ れる工業環境で使用する こ と を想定 し た製品ではあ り ま
せん。
工業環境においては、 電磁妨害の影響を受ける可能性があ り 、 その場合には使用者が適
切な対策を講ずる こ と が必要 と な る こ と があ り ます。
本製品は、 EN61010-1 で定義 さ れる以下の環境用に設計 さ れています。
- 過電圧カ テ ゴ リ ー II
- 汚染度 2

IX
For Your Safety

● Safety precautions
This section provides precautions for using the product safely and correctly and to
prevent injury and damage. The terms of DANGER, WARNING, and CAUTION indicate
the degree of imminency and hazardous situation. Read the precautions carefully as it
contains important safety messages.

●Instrument and electrode

WARNING

Do not use an unspecified AC adapter.


Otherwise, it may heat up or be ignited resulting in a fire or an accident.
Do not disassemble or modify the instrument.
Otherwise, it may heat up or be ignited resulting in a fire or an accident.

CAUTION

Harmful chemicals
The internal solution of a pH electrode is highly concentrated potassium
chloride (3.33 mol/L KCl). If the internal solution comes in contact with the
skin, wash it off immediately. If it gets into the eyes, flush with plenty of water
and then consult a doctor.

Broken glass
Broken glass may cause injury. The outer tube and tip of an electrode are
made of glass. Handle them with care.
Do not use the RS-232C communication and the AC adapter under wet or
humid conditions. Otherwise, it may cause a fire, electric shock, or
breakage.

X
For Your Safety
●Battery

CAUTION

Keep batteries out of reach of children. If someone accidentally swallows a


battery, consult a doctor immediately.
If alkaline fluid from a battery gets into the eyes, do not rub the eyes, rinse
with clean water immediately and then consult a doctor.
Contact with alkaline fluid could cause blindness.
Do not put batteries in a fire, expose to heat, disassemble or remodel.
Doing so could case fluid leakage, overheating or explosion.

CAUTION

Do not remove or scratch the external label of the battery.


Doing so could cause injury to hands and fingers.

XI
Product Handling Information

■ Product Handling Information


● Operational precautions (instrument)
・Only use the product including accessories for their intended purpose.

・Do not drop, crash, or give any physical impact on the instrument.

・The instrument is made of solvent-resistant materials but that does not mean it is
resistant to all chemicals. Do not dip the instrument in strong acid or alkali solution, or
wipe with such solution.

・If the instrument is dropped into water or gets wet, wipe it using soft cloth. Do not heat
to dry it with a hair-dryer (or the like).

・The instrument has a dust-proof and waterproof structure. Waterproof performance is


following specification: the instrument does not malfunction even when immersed in
water of 1 m depth for 30 minutes.
This does not mean to guarantee non-destructive, trouble-free, dust-proof, and
waterproof performance in all situations. If the instrument is correctly handled
according to the descriptions in this manual, the instrument provides dust-proof and
waterproof performance.

・When replacing the batteries with an AC adapter or a serial cable connected the
instrument does not have the dust-proof and waterproof performance. The dust-proof
and waterproof performance is maintained only when the covers are attached
correctly.

・After replacing the batteries with an AC adapter or a serial cable connected make sure
that the waterproof packing attached to each cover is not deformed or discolored, or
has foreign matter adhering to it. If the waterproof packing is deformed, discolored or
has foreign matter adhering to it, or dust could get inside, water leaks could occur that
could lead to instrument malfunction.

・To disconnect an electrode, AC adapter cable or serial cable, hold the connector and
pull it off. If you pull at the cable, it may cause a breakage.

・The RS-232C communication between the instrument and a personal computer


(referred to as PC in the rest of this document) may fail because of environmental
conditions, such as (radio/electromagnetic) noise.

・Do not replace the batteries in a dusty place or with wet hands while an AC adapter or
a serial cable is connected. Dust or moisture could get inside the instrument, possibly
causing instrument malfunction.

・Do not use the tip of a nail or an object with a sharp end to press the keys.

・If the power supply is interrupted while measurement data is being saved in the
instrument, the data could be corrupted.

XII
Product Handling Information
・A NiMH rechargeable battery can be used in this instrument, but the battery used in
the instrument cannot be charged using the AC adapter.

● Operational precautions (battery)


・Do not short-circuit a battery.

・Set the  and  side of the battery correctly.

・When the battery has run out or the instrument will not be used for a long time, remove
the batteries.

・Of the specified battery types, make sure to use two batteries of the same type.

・Do not use a new battery together with a used battery.

・Do not use a fully charged nickel-metal hydride battery together with a partially
charged battery.

・Do not attempt to charge a non-rechargeable battery.

● Environmental conditions for use and storage


・Temperature: 0°C to 45°C

・Humidity: under 80% in relative humidity and free from condensation

Avoid the following conditions.


・Strong vibration
・Direct sunlight
・Corrosive gas environment
・Close to an air-conditioner
・Direct wind

● Transportation
When transporting the instrument, repackage it in the original package box. Otherwise, it
may cause instrument breakage.

● Disposal
・Standard solution used for the calibration must be under neutralized before the
disposal.

・When disposing of the product, follow the related laws and/or regulations of your
country for disposal of the product.

XIII
Manual Information

■ Manual Information
● Description in this manual

Note
This interprets the necessary points for correct operation and notifies the important
points for handling the product.

Reference
This indicates the part where to refer for information.

Tip
This indicates reference information.

XIV
Contents

■ Preface...................................................................................I
■ Regulations ..........................................................................II
■ For Your Safety.................................................................. VI
■ Product Handling Information......................................... XII
■ Manual Information ......................................................... XIV
Part Names and Basic Operation ....................................... 1
■ Names of each part .............................................................2
● Instrument....................................................................................2
● Identification of manufacturing date .........................................3
● Display .........................................................................................4
● Operation key ..............................................................................6
■ Basic operation....................................................................7
● Function layer..............................................................................7
● Changing the operation mode .................................................11
● Switching the displays .............................................................12
● Changing the measurement parameter ..................................13
● Using the backlight ...................................................................14
● Entering numeric values ..........................................................15
● Saving measurement data in the internal memory ................16
Measurement ...................................................................... 17
■ Preparation.........................................................................18
● Confirmation before starting measurement ...........................18
● Turning ON the instrument ......................................................19
● Connecting an electrode ..........................................................22
■ pH measurement ...............................................................23
● Setting the instrument ..............................................................23
● Performing calibration..............................................................27

XV
Contents

● Performing measurement ........................................................ 35


● Saving measured value............................................................ 36
■ mV, ORP measurement .....................................................37
● Switching between absolute value and relative value .......... 37
● Performing measurement ........................................................ 38
● Saving measured value............................................................ 39
■ Conductivity measurement...............................................40
● Setting the instrument.............................................................. 41
● Performing conductivity calibration ....................................... 57
● Performing measurement ....................................................... 61
● Saving measured values.......................................................... 62
Using Various Functions................................................... 63
■ Data functions....................................................................64
● Displaying saved data .............................................................. 64
● Using the automatic data save ................................................ 65
● Deleting all saved data ............................................................. 68
■ Measurement setting.........................................................70
● Displaying the latest calibration and inspection data........... 70
● Changing the calibration method............................................ 73
● Using the calibration interval alarm (default: OFF) ............... 74
● Deleting calibration data .......................................................... 75
■ Temperature settings ........................................................77
● Calibrating temperature sensor .............................................. 77
■ General settings.................................................................79
● Setting the auto stability and auto hold function .................. 79
● Changing the automatic power off setting (default: 30 min) 81
● Resetting to factory default settings ...................................... 83
● Setting the date and time ......................................................... 85

XVI
Contents

● Performing test printing of the printer unit ............................87


■ Other settings ....................................................................89
● Printing measured values and calibration data .....................89
● Transferring saved data to a PC ..............................................93
● Operating the instrument from an external device ................94
Maintenance ....................................................................... 95
● Contact for maintenance ..........................................................95
● Maintenance and storage of the instrument...........................95
● Environmental conditions for storage ....................................95
● Maintenance and storage of the pH electrode .......................96
● Maintenance and storage of the ORP electrode ....................97
● Checking the state of the ORP electrode................................98
● Maintenance and storage of the conductivity cell .................99
How to Resolve Errors or Troubles................................ 101
■ When an error message appears ...................................101
● ERR No.0001   Memory error .................................................101
● ERR No.0002   Empty battery level .......................................102
● ERR No.0004   Asymmetric potential error ..........................102
● ERR No.0005   Electrode sensitivity error............................103
● ERR No.0006   Maximum calibration points exceeded .......103
● ERR No.0007   Cannot identify standard solution...............103
● ERR No.0008   Calibration interval error ..............................104
● ERR No.0009   Printer error ...................................................104
● ERR No.0010   Memory full ....................................................104
● ERR No.0011   Cell constant is out of range........................104
■ Troubleshooting ..............................................................105
● The indicated value fluctuates...............................................105
● The response is slow..............................................................106

XVII
Contents

● The indicated value does not change/No response ............ 106


● The measured value is out of the measurement range....... 107
● Repeatability of the measured value is poor ....................... 107
● Nothing appears when the power is turned ON................... 108
● Swelling of operation key sheet ............................................ 108
● Part of the display is missing ................................................ 108
Appendix........................................................................... 109
■ Main specifications..........................................................109
● Table of conductivity cell range ............................................ 111
● Table of conductivity cell range (resistivity range) ............. 112
■ Instrument default settings.............................................113
■ Technical note..................................................................114
● pH standard solutions at various temperatures .................. 114
● Conductivity standard values at various temperatures...... 115
■ Options .............................................................................116

XVIII
Part Names and Basic Operation
This section describes the name of each part and the main role, function, and basic
operation method of each part.

■ Names of each part...................................................................... 2


● Instrument.............................................................................................. 2
● Identification of manufacturing date ................................................... 3
● Display.................................................................................................... 4
● Operation key ........................................................................................ 6

■ Basic operation ............................................................................ 7


● Function layer........................................................................................ 7
● Changing the operation mode ........................................................... 11
● Switching the displays........................................................................ 12
● Changing the measurement parameter............................................. 13
● Using the backlight ............................................................................. 14
● Entering numeric values..................................................................... 15
● Saving measurement data in the internal memory .......................... 16

1
Names of each part

■ Names of each part


● Instrument

No. Name Function


1 Display Displays the measured value and set value and so on.
2 Operation keys Used for instrument operation.
3 Electrode connector Connects the BNC connector of the electrode.
Temperature Connects the temperature connector (T)
4
connector (T) of the electrode.
5 Battery cover Set batteries inside.
Electrode hook
6 Attach the electrode hook to carry with instrument.
attachment section
7 Strap attachment section Attach a strap.
8 Serial connector Connects the serial cable and printer cable.
9 AC adapter jack Connects an optional AC adapter.

2
Names of each part

● Identification of manufacturing date


Manufacturing date can be identified from MFG No. described in the ID label on the
backside of the instrument.
Third number from the left in the MFG No. indicates manufacturing year.
Forth alphabet from the left in the MFG No. indicates manufacturing month.
The alphabet is assigned to month according to the table below.

Ex.: ID: AA6A0000 means the device manufactured in 2016 January.

JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC
A B C D E F G H J K L M

3
Names of each part

● Display
Two electrodes can be connected to measure two parameters at the same time with this
instrument. The display is divided into the main screen and the sub screen, and you can
select the channel displayed on the main screen. The selected channel can be identified
with an icon.

1
2 3
4
5 11
6
7 10
8
9
12
Main screen
2 2

13 14

6 11
10
12 14 Sub screen
8

No. Name Function


Displays the current operation mode, electrode
1 Status icon status, printer or PC connection status, and
remaining battery level.
2 Direction key icon Displays the currently available direction key.
Date and time, set item Displays the current date and time and the set
3
display area items.
4 ERR No. icon Displays an error No.
5 Data No. icon Displays the data No.
Displays the currently set measurement parameter.
Measurement parameter
6 This is displayed in the main screen and the sub
display area
screen, respectively.
7 Main screen channel icon Displays the channel of the main screen.
Lights when the measured value display is fixed in
auto hold mode.
8 HOLD icon
This is displayed in the main screen and the sub
screen, respectively.
9 SET icon Lights when numerical values are entered.
Displays the measured and the set temperature.
10 Temperature display area This is displayed in the main screen and the sub
screen, respectively.
Lights when the temperature setting is MTC
(optional temperature setting).
11 MTC icon
This is displayed in the main screen and the sub
screen, respectively.

4
Names of each part

No. Name Function


Displays the measured value and the set value.
Measured value, set item
12 This is displayed in the main screen and the sub
display area
screen, respectively.
Standard solution When calibrating pH or conductivity standard
13
calibration history icon solution, the corresponding icon lights.
Displays the unit for the measurement parameter
and the display item.
14 Unit display area
This is displayed in the main screen and the sub
screen, respectively.

•Battery level display

Battery level is high.

Battery level is a little lower.

Battery level is low.


The backlight may become unavailable.
Battery has run out. Replace the batteries or use AC adapter
(option).
"ERR No. 0002" is displayed and operation is disabled.

5
Names of each part

● Operation key

Key Name Function


Changes the operation mode to the measurement mode
during operation in a different mode.
MEAS key
Releases the fixed measurement value mode in the auto
hold mode.
Changes from the measurement mode to the calibration
CAL key mode.
Start calibration in the calibration mode.
DATA key Changes from the measurement mode to the data mode.

Changes from the measurement mode to the setting mode.


SET key
Starts repeatability inspection after calibration is complete.

POWER key Turns ON/OFF the power of instrument.

In the measurement mode, changes measurement


MODE key
parameters.

LIGHT key Turns on/off the backlight.

Determines the selection or setting.


ENTER key
Prints data in measurement, the calibration and data mode.
In the measurement mode, switches the display between
UP key the main screen and the sub screen.
Changes the selected item.
DOWN key Changes the number of the selected digit when entering
numbers.
LEFT key
Changes the selected item.
Changes the selected digit when entering numbers.
RIGHT key

6
Basic operation

■ Basic operation
● Function layer
The function layer of the data mode and setting mode is shown as below.
"dX" and "PXX" indicates the program number which is shown in the screen of the
instrument.
• Data mode

Screen Layer Description


d1: DATA OUT Saved data display

d2: AUT LOG Automatic data save setting

d3: DATA CLR Deletion of saved data

7
Basic operation

• Setting mode
<Channel 1>

Screen Layer Description


P1: PH pH measurement settings
P11: BUF Selection of standard solution
type for calibration:
USA, NIST, CUST
P12: CAL DATA Calibration data display
P13: CAL ALR Calibration alarm setting:
1 day to 400 days
P14: CAL CLR Deletion of calibration data

P2: TEMP Temperature setting


Selection of temperature
conversion or display
: ATC, MTC

P3: GEN General settings


P31: MEAS Selection of auto hold type:
auto stability, auto hold
P32: AUTO OFF Automatic power off setting:
0 min to 30 min
P33: RESET Initialization of settings
P34: DATE Date and time setting
P35: PRINT Test print

8
Basic operation

<Channel 2>

Screen Layer Description


P1: COND Conductivity measurement
settings
P11: CELL Cell constant setting
P12: UNIT Selection of unit:
S/cm, S/m, mS/cm FIX
P13: CAL DATA Calibration data display
P14: AUTO CAL Selection of auto calibration,
manual calibration
P15: CAL CLR Deletion of calibration data
P16: TEMP CF Temperature conversion setting:
0.00%/°C to 10.00%/°C
P17: TEMP REF Reference temperature setting:
15°C to 30°C
P2: TDS TDS measurement settings
P21: TDS TYPE Selection of TDS calculation
method: Linear, 442, En27888,
NaCl

P3: SALT Salinity measurement settings


P31: UNIT Selection of unit: ppt, %
P32: SALT TYP Selection of salinity calculation
method: NaCl, Sea water

P4: TEMP Temperature settings


Selection of temperature
conversion: ATC, MTC

9
Basic operation

Screen Layer Description


P5: GEN General settings
P51: MEAS Selection of auto hold type:
auto stability, auto hold
P52: AUTO OFF Automatic power off setting:
0 min to 30 min
P53: RESET Initialization of settings
P54: DATE Date and time setting
P55: PRINT Test print

10
Basic operation

● Changing the operation mode


Change the operation mode from four available modes depending on the purpose of use.
The status icon indicates the current mode.
You can change the operation mode using the corresponding key. However changing to
the calibration mode, data mode, or setting mode is possible only from the measurement
mode. When changing to a different mode, first change to the measurement mode and
then change to the desired mode.

Status icon

Icon Name Function


Measurement mode Performs measurement.
Calibration mode Performs calibration.
Performs data settings.
Data mode
Displays the saved data.
Setting mode Performs various settings.

Measurement mode

key key or key

key key

key key or
key

Calibration mode Data mode Setting mode

11
Basic operation

● Switching the displays


Switch the channel between the main screen and the sub screen.
In the measurement mode, pressing the keys can switch the channels between the
main screen and the sub screen.
When performing calibration or setting, switch the display to show the desired channel
(measurement parameter) on the main screen.

key

12
Basic operation

● Changing the measurement parameter


This instrument can measure multiple parameters. For measurement, an electrode
corresponding to the measurement parameter is required. In the measurement mode,
the measurement parameter can be changed by pressing the key.
This operation is available for the channel that is shown on the main screen.

< Channel 1 >

key

< Channel 2 >

key

key key

key

13
Basic operation

● Using the backlight


When it is difficult to see the screen in a dark location, you can turn on the backlight by
pressing the key. If the backlight is not operated for 5 minutes, it automatically turns
off. To turn it off manually, press the key again while the backlight is on.

key

Note
・ Turning on the backlight consumes energy and shortens battery life.
・ The backlight becomes unavailable when the battery level becomes low.

14
Basic operation

● Entering numeric values


When entering numeric values to make various settings and set a calibration value,
change the selected digit using the keys and increment or decrement the value (0
to 9) using the keys.

key

key

15
Basic operation

● Saving measurement data in the internal memory


Up to 1000 data items measured by the instrument can be stored in the internal memory.
Saving the measurement data is possible only when the instrument is in the
measurement mode.

1. Press the key while the data to save is displayed.


The saved data is displayed for two seconds and then the display returns to the
previous screen automatically.

key

Note
If the data saved reaches 1000 data items, an error occurs and "ERR No. 0010" is
displayed. Copy or transfer necessary data to a PC and delete the data from the memory
("Deleting all saved data" (page 68)).

16
Measurement
This section describes the basic measuring method of each measurement parameter.

■ Preparation ................................................................................. 18
● Confirmation before starting measurement ..................................... 18
● Turning ON the instrument................................................................. 19
● Connecting an electrode .................................................................... 22

■ pH measurement........................................................................ 23
● Setting the instrument ........................................................................ 23
● Performing calibration ........................................................................ 27
● Performing measurement................................................................... 35
● Saving measured value ...................................................................... 36

■ mV, ORP measurement ............................................................. 37


● Switching between absolute value and relative value..................... 37
● Performing measurement................................................................... 38
● Saving measured value ...................................................................... 39

■ Conductivity measurement....................................................... 40
● Setting the instrument ........................................................................ 41
● Performing conductivity calibration.................................................. 57
● Performing measurement .................................................................. 61
● Saving measured values .................................................................... 62

17
Preparation

■ Preparation
● Confirmation before starting measurement
・ Have you prepared the appropriate electrode for the measurement parameter?
⇒ If not, purchase the appropriate electrode.

・ Is the prepared electrode in good condition?


⇒ If the responsive part is stained or damaged, it may not be possible to obtain
    accurate values.

・ Have you prepared the appropriate standard solution for the measurement parameter?
⇒ If not, prepare the standard solution according to your applications.

・ Are there any items that should not be wet or stained around the instrument?
⇒Depending on the operation during measurement, items around the instrument could
  get wet or stained. Secure sufficient space around the instrument and perform
  measurement while always paying attention to safety.

・ Are there any devices that can be a source of noise?


⇒ Measured values could be affected. Do not use the instrument near such devices.
  Always ground devices operated by AC power.

18
Preparation

● Turning ON the instrument


• Inserting the batteries
This instrument is operated by batteries. You can use AAA alkaline batteries or AAA Ni-
MH rechargeable batteries. Perform the following procedure to insert batteries in the
instrument.

1. Turn the knob on the battery cover on the back of


the instrument counterclockwise to unlock the
battery cover.

2. Remove the battery cover and set the batteries


inside.

3. Put the battery cover back in.

4. Turn the knob on the battery cover on the back of


the instrument clockwise to lock the battery cover.

Note
・ Do not replace the batteries in a dusty place or with wet hands. Dust or moisture could get
inside the instrument, possibly causing instrument malfunction.
・ Do not short-circuit a battery.
・ Set the + and  side of the battery correctly.
・When the battery has run out or the instrument will not be used for a long time, remove the
batteries.
・ Of the specified battery types, make sure to use two batteries of the same type.
・ Do not use a new battery together with a used battery.
・ When using the Ni-MH batteries, do not use a fully charged battery together with an
insufficiently-charged battery.

19
Preparation

• Using the AC adapter (option)


It is possible to use the AC adapter to operate the instrument.
Perform the following procedure to connect AC adapter to the instrument.
The AC adapter is an option. To purchase it, contact your dealer. (Refer to "Options"
(page 116).)

1. Open the AC adapter cover of the


instrument.
2. Insert the AC adapter cable by
fitting with the AC adapter jack of in
the instrument.
3. Insert AC adapter into the electrical
socket.

AC adapter jack

Note
・ Do not insert the cable with force when the connector does not match the jack.
・ When not using the AC adapter, close the AC adapter connector cover.
・ While the AC adapter is connected, the instrument does not have the dust-proof and
waterproof performance. Dust or moisture could get inside the instrument, possibly
causing instrument malfunction.

20
Preparation

• Pressing the POWER key


After setting the batteries or connecting the AC adapter, press the key over one
second. The LCD is fully displayed for one second, and the screen displays the version
number of software and the model, and then displays the measurement mode.

key

Note
• Do not hold down the key after the power of the instrument is turned ON.
• Do not use the tip of nail or an object with a sharp end to press keys.
• "VER" indicates the version of the software. It may be revised when the software is
updated.

21
Preparation

● Connecting an electrode
To perform measurement, it is necessary use the appropriate electrode for measurement
parameters. Recommended electrodes for each measured sample are listed in our
product catalog and on our website. Refer to them when preparing electrodes. Use the
following procedure to correctly connect the electrode to the instrument.

1. Insert the electrode connector


by fitting its groove with the
connector pin of the instrument.

2. Turn the electrode connector


clockwise by following the
groove.
Electrode connector

3. Put the connector cover on the


connector.

4. When using a combination


electrode equipped with a
temperature sensor, insert the
temperature connector (T) into
the jack of the temperature Temperature connector (T)
connector (T).

Tip
If the temperature connector (T) is unconnected or connection is wrong, temperature
selected for MTC (manual temperature compensation) is displayed as the sample
temperature.

Preparation for measurement is complete.


For details of the measurement operation, refer to the following pages.

22
pH measurement

■ pH measurement
You can measure the pH of the sample with a pH electrode.
Use a combination electrode incorporating a glass electrode and a reference electrode
for measurement. A single glass electrode cannot be used with this instrument.
pH can be measured using channel 1 of the instrument.

● Setting the instrument


• Setting temperature compensation
Automatic temperature compensation function can be used by using a combination
electrode equipped with a temperature sensor or connecting a temperature
compensation electrode. By measuring temperature during calibration of the pH
standard solution and compensating for the change in pH value of the standard solution
due to its temperature changes, you can perform calibration using the value matched to
the standard solution temperature (only when the standard solution setting is NIST and
USA). However, the function does not convert the pH value according to the temperature
characteristics of each sample, and you must record the obtained value together with the
sample temperature value. The variation of pH value accompanying the temperature
change differs depending on the sample.
If you do not use the automatic temperature compensation function, match the
temperature setting of the instrument to the temperature of the standard solution during
calibration and match the sample temperature to the temperature setting of the
instrument in measurement. By doing so, you can obtain the correct measurement value
without being affected by sensitivity variation caused by temperature.

1. Press the key to enter the setting mode.


2. Press the keys to select "TEMP" (temperature setting) and then press the
key.
If the temperature connector (T) is connected, "ATC" (automatic temperature
compensation) appears. If the temperature connector (T) is not connected, "MTC"
(manual temperature compensation) appears.

23
pH measurement

In the case of "ATC", you can calibrate the temperature sensor (refer to "Calibrating
temperature sensor" (page 77)).

key key

key

3. In the case of "MTC", enter the temperature to be compensated for and press
the key to confirm.

Enter a
key number

key

To return to the measurement mode, press the key.

24
pH measurement

• Setting the standard solution used for calibration (default: USA)


Set the standard solution used for calibration. With this instrument, you can choose from
3 types, USA, NIST, and CUST (the standard solution other than USA and NIST).
Set according to the standard solution to be used.

1. Press the key to enter the setting mode.


2. Press the keys to select "pH" (pH setting) and then press the key.
3. Select "BUF" (pH standard solution setting) and then press the key.

key key

25
pH measurement

4. Press the keys to select "USA", "NIST", or "CUST" according to the


standard solution to be used and then press the key to confirm selection.

key

key key

key

Select "USA"
and press the
key

(Ex.: "USA" is selected)

To return to the measurement mode, press the key.

• Standard solution type


Standard solution type Description
Set to use the standard solution of the USA specification.
USA Standard solution icon
(USA specification)
1.68 4.01 7.00 10.01 12.45
Set to use the standard solution of the NIST specification.
NIST Standard solution icon
(NIST specification)
1.68 4.01 6.86 9.18 12.45
CUST Set to use the standard solution of an optional specification.
(custom specification) Standard solution icon

26
pH measurement

● Performing calibration
Calibration is necessary to measure pH accurately.
We recommend performing calibration once a day, before the first measurement.
According to the following procedure, perform calibration accurately.
Note
・ Perform two-point calibration using pH 7 and pH 4 when you know that the sample is
acidic; pH 7 and pH 10 when you know that the sample is alkaline.
・Perform three-point calibration using pH 4, pH 7, and pH 10 when the sample is unknown.
・ You can confirm the current calibration data in the setting mode and delete the calibration
data in the setting mode. (Refer to "Displaying the latest calibration and inspection data"
(page 70), "Deleting calibration data" (page 75).)

• pH standard solution setting is USA or NIST


This section describes the procedure for two-point calibration of USA standard, pH 4 and
7, as an example of general calibration.

1. Clean the pH electrode with pure water (or


deionized water) and wipe it with filter paper
or tissue paper.

2. Open the internal solution filler port of the pH


electrode.
If calibration is performed with the port closed,
the internal solution does not flow and the
measurement value is not stable. Make sure to
keep the port open during calibration.

3. Perform the 1st point calibration. Immerse at


least 3 cm from the tip of the pH electrode in
the pH 7 standard solution.
In order for the internal solution to flow into the
standard solution, make sure to immerse the
liquid junction in the standard solution surely.
4. Press the key to enter the calibration
mode.
Stability judgment automatically starts and the pH icon blinks until the measured
value stabilizes. When the measured value stabilizes, the pH icon changes from the
blinking state to the lit state.
Tip
The standard solution type for the calibration is shown on the upper right screen.

27
pH measurement

5. Press the key or the key.


Calibration to the standard solution value at the measured temperature is performed.
The 1st point calibration ends and "7" calibration history icon lights, indicating that pH
7 calibration is complete.
The display automatically returns to the measurement screen.

key Stabilized

key or
key

6. Perform the 2nd point calibration. As with the step 1., clean the pH electrode
and immerse it in the pH 4 standard solution. As with the step 3., immerse at
least 3 cm from the tip of the pH electrode.
7. Press the key to enter the calibration mode.
Stability judgment automatically starts and the pH icon blinks until the measured
value stabilizes. When the measured value stabilizes, the pH icon changes from the
blinking state to the lit state.
8. Then press the key or the key.
Calibration to the standard solution value at the measured temperature is performed.
The 2nd point calibration ends and "4" calibration history icon lights, indicating that
pH 4 calibration is complete.

Stabilized
key

28
pH measurement

key or
key

Two-point calibration is complete.


When calibrating three points or more, use the same procedure to continue calibrating
the 3rd and subsequent points after the 2nd point calibration. You can calibrate up to five
points. Also, you can inspect repeatability using the pH 7 standard solution. About the
repeatability inspection procedure, refer to "Inspecting repeatability" (page 30).

Tip
The order of calibration of the standard solution is optional.
In the above example, you can calibrate pH 4 first and then pH 7.

Note
• If calibration of any standard solution is performed again, only the value of calibrated
solution is updated. If calibration is repeated, only the calibration value of used standard
solution is updated. The calibration values are retained until next calibration is performed,
the data is deleted or buffer setting is changed. For the procedure for deleting the
calibration data, refer to "Deleting calibration data" (page 75).
• It is recommended that you should clear the previous calibration data before the
calibration in order to perform more accurate calibration.

•Check of the pH electrode status


After calibration is complete, the current pH electrode status is diagnosed from the
calibration result. Refer to the following table for maintenance of the electrode.

Display Description Reference


Both and ERR No. Electrode sensitivity: 85% to 100%
Good condition. -
are not displayed
ERR No.0004 Asymmetry potential: less than 45 mV or excess 45
mV P. 102
blinks Maintain or replace the electrode.
ERR No.0005 Sensitivity: less than 85% or excess 105%
P. 103
blinks Maintain or replace the electrode.

29
pH measurement

• Inspecting repeatability
You can inspect repeatability using the pH 7 standard solution by returning to the
calibration screen after calibration and ends and pressing the key. Measure the pH 7
standard solution by using the calibrated electrode to display the absolute value of the
difference between the measured value and standard solution value.
In order to inspect repeatability, you need to perform calibration of the pH 7 standard
solution with either "USA" or "NIST" set as the standard solution.

1. Clean the calibrated pH electrode with pure


water (or deionized water) and wipe it with
filter paper or tissue paper.

2. Open the internal solution filler port of the pH


electrode.
If calibration is performed with the port closed,
the internal solution does not flow and the
measurement value is not stable. Make sure to
keep the port open during calibration.

3. Perform the 1st point calibration. Immerse at


least 3 cm from the tip of the pH electrode in
the pH 7 standard solution.
In order for the internal solution to flow into the
standard solution, make sure to immerse the
liquid junction in the standard solution surely.

4. Press the key to enter the calibration mode.

5. Make sure that the pH icon lights while the pH electrode is immersed in the
standard solution.
Stability judgment starts and the pH icon blinks. When the value is stabilized, the pH
icon changes from the blinking state to the lit state and the display is fixed to the
measured value at the stable time.

30
pH measurement

6. Press the key to start inspection.


"REP" (repeatability) is shown and display changes to the measurement mode.

Stabilized
key

key

31
pH measurement

• pH standard solution setting is CUST


This section describes the procedure for two-point calibration.

1. Clean the pH electrode with pure water (or


deionized water) and wipe it with filter paper
or tissue paper.

2. Open the internal solution filler port of the pH


electrode.
If calibration is performed with the port closed,
the internal solution does not flow and the
measurement value is not stable. Make sure to
keep the port open during calibration.

3. Perform the 1st point calibration. Immerse at


least 3 cm from the tip of the pH electrode in
standard solution.
In order for the internal solution to flow into the
standard solution, make sure to immerse the
liquid junction in the standard solution surely.

4. Press the key to enter the calibration mode.


Stability judgment automatically starts and the pH icon blinks until the measured
value stabilizes. When the measured value stabilizes, the pH icon changes from the
blinking state to the lit state.
5. Enter the standard solution value and press the key or the key.
Calibration to the set standard solution value is performed. The 1st point calibration
ends and the "1" calibration history icon lights, indicating that 1st point calibration is
complete.
The display returns to the measurement screen.

key Stabilized

key

32
pH measurement

key or
Enter a
number key

6. Perform the 2nd point calibration. As with the


step 1., clean the pH electrode and immerse it
in the 2nd standard solution. As with the step
3., immerse at least 3 cm from the tip of the
pH electrode.
7. Press the key to enter the calibration
mode.
Stability judgment automatically starts and the pH icon blinks until the measured
value stabilizes. When the measured value stabilizes, the pH icon changes from the
blinking state to the lit state.
8. Enter the standard solution value for the second point and press the key or
the key.
Calibration to the set standard solution value is performed. The 2nd point calibration
ends and the "2" calibration history icon lights, indicating that 2nd point calibration is
complete.

key Stabilized

key

33
pH measurement

key or
Enter a
number key

Two-point calibration is complete.


When calibrating three points or more, use the same procedure to continue calibrating
the 3rd and subsequent points after the 2nd calibration. You can calibrate up to five
points.

Note
• If calibration of any standard solution is performed again, only the value of calibrated
solution is updated. If calibration is repeated, only the calibration value of used standard
solution is updated. The calibration values are retained until next calibration is performed
or the data is deleted. For the procedure for deleting the calibration data, refer to "Delet-
ing calibration data" (page 75).
• It is recommended that you should clear the previous calibration data before the
calibration in order to perform more accurate calibration.

•Check of the pH electrode status


After calibration is complete, the current pH electrode status is diagnosed from the
calibration result. Refer to the following table for maintenance of the electrode.

Display Description Reference


Both and ERR No. Electrode sensitivity: 85% to 100%
Good condition. -
are not displayed
ERR No.0004 Asymmetry potential: less than 45 mV or excess 45
mV P. 102
blinks Maintain or replace the electrode.
ERR No.0005 Sensitivity: less than 85% or excess 105%
P. 103
blinks Maintain or replace the electrode.

34
pH measurement

● Performing measurement
You can perform measurement in the measurement mode by immersing the pH
electrode in the sample. You can use the automatic hold function to judge the stability of
the measured value. The automatic hold function has two modes, the auto stability mode
and the auto hold mode. For the instruction to set the mode, refer to "Setting the auto
stability and auto hold function" (page 79).

1. Clean the pH electrode with pure water (or


deionized water) and wipe it with filter paper
or tissue paper.

2. Open the internal solution filler port of the pH


electrode.
If calibration is performed with the port closed,
the internal solution does not flow and the
measurement value is not stable. Make sure to
keep the port open during calibration.

3. Immerse at least 3 cm from the tip of the pH


electrode in the sample solution.
In order for the internal solution to flow into the
sample solution, make sure to immerse the liquid
junction in the sample solution surely.
Stability judgment automatically starts and the pH
icon blinks until the measured value stabilizes.
When the measured value stabilizes, the pH icon
changes from the blinking state to the lit state
and the display is fixed to the stabilized
measured value.

35
pH measurement

• Auto stability mode


If the measurement pH value does not fulfill the stability condition, the fixed value is
released. When the measured value fulfills the stability condition again, the
measured value is fixed.

• Auto hold mode


Press the key to release the fixed measured value. When the measured value
fulfills stability condition again, the measured value is fixed.

Stabilized

Note
・ The criteria of stability judgment in the auto hold measurement are as follows.
  Potential variation for 10 seconds is less than 1 mV (0.015 pH equivalent) and
  temperature variation is less than 2.0°C
・ If the measured value is below the display range, "Ur" (under) appears. If the measured
value is above the display range, "Or" (over) appears. For details on the action to take,
refer to "The measured value is out of the measurement range" (page 107).

● Saving measured value


To save the measurement data, press the key in the screen that you want to save.
For details, refer to "Saving measurement data in the internal memory" (page 16).

36
mV, ORP measurement

■ mV, ORP measurement


You can measure the electromotive force between the electrode and the sample by
using a pH electrode. The mV value can be used to understand the status of the
electrode in the mV measurement.
You can measure the ORP (oxidation-reduction potential) of the sample by using an
ORP electrode in the ORP measurement.
In the measurement mode, press the key to change the measurement parameter to
"mV".
mV and ORP can be measured using channel 1 of the instrument.

● Switching between absolute value and relative value


There are two types of measurement mode for the mV and ORP measurement, the
absolute value measurement and the relative value measurement.
• Absolute value measurement mode
The measured value of electromotive force is displayed.
• Relative value measurement mode
The measured value of electromotive force of a sample is corrected to 0 mV and set as
a relative value. When the electromotive force of another sample is measured, the
difference value between the relative value and the measured value is displayed.

The default mode is the absolute value measurement mode. Pressing the key
switches to the relative value measurement mode. Pressing the key again returns to
the absolute value measurement mode.

key

37
mV, ORP measurement

● Performing measurement
You can perform measurement in the measurement mode by immersing the pH
electrode in the sample. Also, you can use the automatic hold function to judge the
stability of the measured value. The automatic hold function has two modes, the auto
stability mode and the auto hold mode. For how to set the mode, refer to "Setting the
auto stability and auto hold function" (page 79).

1. Clean the electrode with pure water (or


deionized water) and wipe it with filter paper
or tissue paper.

2. Open the internal solution filler port of the


electrode.
If calibration is performed with the port closed,
the internal solution does not flow and the
measurement value is not stable. Make sure to
keep the port open during calibration.

3. Immerse at least 3 cm from the tip of the


electrode in the sample solution.
In order for the internal solution to flow into the
sample solution, make sure to immerse the liquid
junction in the sample solution surely.
Stability judgment automatically starts and the
mV icon blinks until the measured value
stabilizes. When the measured value stabilizes,
the mV icon changes from the blinking state to
the lit state, and the display is fixed to the
stabilized measured value.

Stabilized

38
mV, ORP measurement

Note
• The criteria of stability judgment in the automatic hold measurement are as follows.
Potential variation for 10 seconds is less than 1 mV and temperature variation is less than
2.0°C
• If the measured value is below the display range, "Ur" (under) appears. If the measured
value is above the display range, "Or" (over) appears. For details on the action to take,
refer to "The measured value is out of the measurement range" (page 107).
• Note that when measuring the ORP of a sample solution that has extremely low
concentrations of oxidants and reductants (such as tap water, well water, or water treated
with purifying equipment), there may be less responsiveness and repeatability in general.
• If alkaline water is left, its ORP value changes considerably. Always measure alkaline Ion
water promptly.

● Saving measured value


To save the measurement data, press the key in the screen that you want to save.
For details, refer to "Saving measurement data in the internal memory" (page 16).

39
Conductivity measurement

■ Conductivity measurement
The conductivity cell can be used to measure the conductivity, salinity, TDS, and
resistivity of a sample. Salinity, TDS, and resistivity are calculated from the measured
value of conductivity.
Press the key to select the measurement parameter (refer to "Changing the
measurement parameter" (page 13)).

Conductivity can be measured using channel 2 of the instrument. Press the keys to
set the main screen to channel 2.

The basic steps are the same for all measurement parameters, however, some settings
and operations are only valid for specific measurement parameters. Select the settings
and perform the steps that show the mark of the parameter you want to measure.

< Examples >

: Conductivity measurement
: Salinity measurement
: Total dissolved solids measurement
: Resistivity measurement
: All measurement parameters

40
Conductivity measurement

● Setting the instrument


• Setting the temperature display
When a conductivity cell with a temperature sensor is used, or a conductivity cell without
a temperature sensor is used with a temperature electrode, the automatic temperature
measurement function can be used. During measurement, the temperature sensor
measures the temperature of the sample and displays the result on the instrument. If
automatic temperature measurement function is not used, or the temperature connector
is not connected to the instrument, the temperature set in the instrument is displayed.

1. Press the key to enter the setting mode.


2. Press the keys to select "TEMP" (temperature setting) and then press the
key.
If the temperature connector (T) is connected, "ATC" (automatic temperature
compensation) appears. If the temperature connector (T) is not connected, "MTC"
(manual temperature compensation) appears.
In the case of "ATC", the temperature sensor can be calibrated (refer to "Calibrating
temperature sensor" (page 77)).

key key

key

41
Conductivity measurement

3. In the case of "MTC", enter the temperature to be compensated for and press
the key to confirm.

key

Enter a
number key

To return to the measurement mode, press the key.

42
Conductivity measurement

• Setting the conductivity unit (default: S/cm)


Select the conductivity unit from three options, S/cm, S/m, mS/cm FIX (fixed at mS/cm)
depending on your application.
When measuring resistivity, these units correspond to Ω·cm, Ω·m, Ω·cm (for mS/cm
FIX).

1. Press the key to enter the setting mode.


2. Press the keys to select "COND" (conductivity setting) and then press
the key.
3. Press the keys to select "UNIT" (unit setting) and then press the key.

key key

key key

43
Conductivity measurement

4. Press the keys to select the unit and press the key to confirm selection.

key key

key

Select "S/cm"
and press the
key

(Ex.: "S/cm" is selected)

To return to the measurement mode, press the key.

44
Conductivity measurement

• Setting the salinity unit (default: PPT)


Select the salinity unit from % or PPT depending on your application.

1. Press the key to enter the setting mode.


2. Press the keys to select "SALT" (conductivity setting) and then press the
key.
3. Press the keys to select "UNIT" (unit setting) and then press the key.

key key

key key

45
Conductivity measurement

4. Press the keys to select the unit and then press the key to confirm
selection.

key

key

(Ex.: "%" is selected)

To return to the measurement mode, press the key.

46
Conductivity measurement

• Setting the cell constant (default: 1.000×1.0 cm-1)


A cell constant is unique for each conductivity cell. To measure conductivity correctly, the
cell constant of the conductivity cell must be set in the instrument.

1. Press the key to enter the setting mode.


2. Press the keys to select "COND" (conductivity setting) and then press
the key.
3. Press the keys to select "CELL" (cell constant setting) and then press the
key.

key key

47
Conductivity measurement

4. Press the keys to select the digit number of the cell constant of the
conductivity cell and then press the key.

key

key key

key

Select "1.0"
and press the
key

(Ex.: "1.0" is selected)


5. Press the keys to enter the cell constant value of the conductivity cell
and then press the key to confirm.

Enter a
number key

To return to the measurement mode, press the key.

48
Conductivity measurement

Note
・ The unit used for the cell constant corresponds to the unit set in "Setting the conductivity
unit (default: S/cm)" (page 43).
・ When the cell constant is changed through the cell constant setting, all the previous
calibration data is deleted.
・ Match the unit indicated on the conductivity cell to the unit set in the instrument.
        10 m-1 ⇔ 0.1 cm-1     100 m-1 ⇔ 1 cm-1     1000 m-1 ⇔ 10 cm-1

49
Conductivity measurement

• Setting the temperature conversion (Default: ON, 2.00%/°C)


The measured value of a sample that is not at 25°C can be converted to a value at the
selected temperature. To use the temperature conversion function correctly, temperature
coefficient (the rate of change per 1°C of the conductivity) must be set for each sample.
The setting of "Setting the temperature display" (page 41) is applied to the sample
temperature before the conversion.

1. Press the key to enter the setting mode.


2. Press the keys to select "COND" (conductivity setting) and then press
the key.
3. Press the keys to select "TEMP CF" (temperature conversion setting) and
then press the key.

key key

key key

4. Press the keys to enter the temperature coefficient and then press the
key to confirm.

Enter a
key
number

To return to the measurement mode, press the key.

50
Conductivity measurement

Note
・ The temperature coefficient varies by sample. Before using the temperature conversion
function, always check the temperature coefficient of the sample and set it in the
instrument.
・ When the temperature conversion function is used with automatic temperature
measurement (ATC), deviations may occur within the accuracy of the temperature sensor.
For more accurate measurement, set the temperature setting to manual temperature
display (MTC), and measure using a temperature controlled bath.

51
Conductivity measurement

• Setting the reference temperature (Default: 25°C)


Temperature to be converted can be selected from 15°C to 30°C.

1. Press the key to enter the setting mode.


2. Press the keys to select "COND" (conductivity setting) and then press the
key.
3. Press the keys to select "TEMP REF" (reference temperature setting) and
then press the key.

key

key key key

4. Press the keys to enter the reference temperature and then press the
key to confirm.
Temperature can be selected from 15°C to 30°C.

Enter a
key
number

To return to the measurement mode, press the key.

52
Conductivity measurement

• Setting the TDS method


TDS is calculated from the measured conductivity value. The available calibration
methods are "LINEAR": KCl with factor adjustable from 0.4 to 1.0 (default: 0.5), "442":
Myron L 442 non-linear standard curve, "EN27888": European environmental standard
non-linear curve, and "NACL": non-linear salinity curve.

1. Press the key to enter the setting mode.


2. Press the keys to select "TDS" (total dissolved solid setting) and then
press the key.
3. Press the keys to select "TDS TYPE" (TDS method setting) and then
press the key.

key key

key key

53
Conductivity measurement

4. Press the keys to select the TDS method and then press the key.
5. When selecting "LINEAR", enter the factor and then press the key to
confirm.

key

key key

key

Selected
"LINEAR"
and press Enter a
the key number

key

To return to the measurement mode, press the key.

54
Conductivity measurement

• Setting the salinity method


Salinity is calculated from the measured conductivity value. The available calibration
methods are "NACL" and "SEAWTR" (sea water).

1. Press the key to enter the setting mode.


2. Press the keys to select "SALT" (salinity setting) and then press the
key.
3. Press the keys to select "SALT TYP" (salinity calculation method setting)
and then press the key.

key key

key key key

55
Conductivity measurement

4. Press the keys to select the salinity calculation method and then press
the key to confirm.

key

key

To return to the measurement mode, press the key.

56
Conductivity measurement

● Performing conductivity calibration


The factory-certified cell constant is indicated on the label on the electrical conductivity
cell. Cell constant may change depending on the usage condition. In such case, the
conductivity cell can be calibrated automatically or manually.
You can select calibration method. For how to set the mode, refer to "Changing the
calibration method" (page 73).

•Automatic calibration
1. Clean the conductivity cell with pure water (or
deionized water) and wipe it with filter paper
or tissue paper.
Do not touch the black electrode part.
Refer to the instruction manual of the conductivity
cell for how to clean the conductivity cell.
2. Immerse the conductivity cell in the standard
solution.
Make sure the hole at the upper part of the cell is
immersed.
3. Press the key to enter the calibration
mode.
Stability judgment starts and the COND icon
blinks. When the measured value stabilizes, the
COND icon changes from the blinking state to
the lit state.
4. Press the key or the key.
The 1st point calibration ends and the calibration history icon corresponding to the
calibration range lights, indicating that 1st point calibration is complete.
The display returns to the measurement screen.

key Stabilized

key or
key

For multiple point calibration, repeat the steps 1. to 4.

57
Conductivity measurement

Note
In automatic calibration, the measured value of a standard solution that is not at 25°C is
always converted to 25°C with 2.00%/°C temperature coefficient.

58
Conductivity measurement

•Manual calibration
1. Clean the conductivity cell with pure water (or
deionized water) and wipe it with filter paper
or tissue paper.
Do not touch the black electrode part.
Refer to the instruction manual of the conductivity
cell for how to clean the conductivity cell.
2. Immerse the conductivity cell in the standard
solution.
Make sure the hole at the upper part of the cell is
immersed.
3. Press the key to enter the calibration
mode.
Stability judgment starts and the COND icon
blinks. When the measured value stabilizes, the
COND icon changes from the blinking state to
the lit state.
4. Press the keys to enter the electrical conductivity value of the
standard solution used for calibration at the measured temperature.
5. Press the key or the key.
Calibration to the set standard solution value at the measured temperature is
performed. The 1st point calibration ends and the calibration history icon
corresponding to the calibration range lights, indicating that 1st point calibration is
complete.
The display returns to the measurement screen.

59
Conductivity measurement

key Stabilized

Enter a
key number

key

For multiple point calibration, repeat the steps 1. to 5.


The calibration points are up to 5 points.

Note
The calibration for TDS, salinity, and resistivity is performed with the result of the calibration
of conductivity. When pressing the key to enter the calibration mode for TDS, salinity,
and resistivity, "CAL in COND" is displayed. It indicates that performing conductivity
calibration is recommended.

60
Conductivity measurement

● Performing measurement
Immerse the conductivity cell in a sample to perform measurement. Auto stability mode
and auto hold mode are available to judge the stability of the measurement value.
For details of settings, refer to "Setting the auto stability and auto hold function" (page
79).

1. Press the key to change to the


measurement parameter to measure.
2. Clean the conductivity cell with pure water (or
deionized water) and wipe it with filter paper
or tissue paper.
Do not touch the black electrode part.
Refer to the instruction manual of the conductivity
cell for how to clean the conductivity cell.

3. Immerse the conductivity cell in the sample


solution.
Make sure the hole at the upper part of the cell is
immersed.
Stability judgment starts and the measurement
item icon blinks. When the measured value
stabilizes, the measurement item icon changes
from the blinking state to the lit state, and the
display is fixed to the stabilized measured value.

Stabilized

Note
・ The criteria of stability judgment in the auto stability mode and auto hold mode are as
follows.
  Conductivity: Display value change for 10 seconds is less than 3 digit and temperature
change is less than 2.0°C.
  Salinity: Display value change for 10 seconds is less than 1.0 PPT (0.1%) and
temperature change is less than 2.0°C.
  TDS: Display value change for 10 seconds is less than 30 mg/L and
temperature change is less than 2.0°C.
  Resistivity: Display value change for 10 seconds is less than 3 digit and temperature
change is less than 2.0°C.
・ If the measured value is above the display range, "Or" (over) appears. For details on the
action to take, refer to "The measured value is out of the measurement range" (page 107).

61
Conductivity measurement

● Saving measured values


To save the measurement data, press the key in the screen that you want to save. For
details, refer to "Saving measurement data in the internal memory" (page 16).

62
Using Various Functions
This section describes functions available in this instrument.

■ Data functions.......................................................... 64
● Displaying saved data......................................................................... 64
● Using the automatic data save........................................................... 65
● Deleting all saved data........................................................................ 68

■ Measurement setting............................................... 70
● Displaying the latest calibration and inspection data ..................... 70
● Changing the calibration method ...................................................... 73
● Using the calibration interval alarm (default: OFF) .......................... 74
● Deleting calibration data..................................................................... 75

■ Temperature settings .............................................. 77


● Calibrating temperature sensor ......................................................... 77

■ General settings....................................................... 79
● Setting the auto stability and auto hold function ............................. 79
● Changing the automatic power off setting (default: 30 min)........... 81
● Resetting to factory default settings ................................................. 83
● Setting the date and time.................................................................... 85
● Performing test printing of the printer unit....................................... 87

■ Other settings .......................................................... 89


● Printing measured values and calibration data................................ 89
● Transferring saved data to a PC ........................................................ 93
● Operating the instrument from an external device .......................... 94

63
Data functions

■ Data functions
● Displaying saved data
You can display the data saved in the internal memory.

1. Press the key to enter the data mode.


2. Press the keys to select "DATA OUT" (display saved data) and then press
the key.
Press the keys to change the measurement data and press the keys to
change the display between date and data number.

key

key key

key

key

To return to the measurement mode, press the key and then press the key.

64
Data functions

● Using the automatic data save


This function saves the data in the internal memory of the instrument at the specified
interval automatically.
While using this function, auto stability and hold mode are not available and the
automatic power off setting is disabled.
If the batteries run out while using the automatic data save function, the data saved until
just before the batteries run out. Replace the batteries and check the data.

1. Press the key to enter the setting mode.


2. Press the keys to select "AUT LOG" (automatic data save) and then press
the key.

key key

65
Data functions

3. Enter the interval of saving in seconds and press the key.


An interval from 0, 2 s to 3600 s can be set.
When "0" is entered, this function is set to OFF.
4. Enter the period of saving in minutes and press the key.
A period from 0 min to 3600 min can be set.
"0" indicates no period.

Enter a
key number

Enter a
key number

key

5. Press the key to return the measurement mode.

66
Data functions

6. Pressing the key starts saving the data (when the setting is "ON").
Pressing the key again stops the data saving process. During automatic data
saving measurement, data is displayed for one second each time a measurement
takes place. When more than 1000 data items are saved, "ERR No. 0010" is
displayed and data saving is stopped. When you delete the data, the error is cleared
(refer to "Deleting all saved data" (page 68)).

When data is
key saved

67
Data functions

● Deleting all saved data


Delete all data saved in the internal memory. Data cannot be deleted selectively. Copy or
transfer the data to a PC for storage if necessary.

1. Press the key to enter the data mode.

key

2. Press the keys to select "DATA CLR" (delete saved data) and then press
the key to confirm.

68
Data functions

3. Select "YES" to delete the saved data, or select "NO" to cancel deleting it. And
then press the key to confirm.
When "YES" is selected, "END" appears after deletion is complete.

key key

Select "YES"
and press the
key

To return to the measurement mode, press the key.

69
Measurement setting

■ Measurement setting
● Displaying the latest calibration and inspection data
You can display the latest calibration data and repeatability inspection data.

• In the case of displaying the latest pH calibration data and repeatability


inspection data
1. Press the key to enter the data mode when "pH" icon is shown on the main
screen.
2. Press the keys to select "pH" and then press the key.

key key

70
Measurement setting

3. Press the keys to select "CAL DATA" (display calibration data) and then
press the key.
The electrode status based on the calibration result is displayed. You can change the
display item among "OFS" (asymmetry potential) to SLP (sensitivity) to REP
(repeatability) by pressing the keys.

key

key

key

key

Asymmetry potential display

key

Repeatability display Sensitivity display

To return to the measurement mode, press the key and then press the key.
Tip
• The asymmetry potential can be displayed only for pH calibration data.
• When multiple point calibration (more than two points) is performed, the results of multiple
point calibration are displayed.

・ Electrode status based on calibration result

Display Description Reference


Electrode sensitivity: 85% to 105%
GOOD -
Good condition.

71
Measurement setting

• In the case of displaying the latest conductivity calibration data


1. Press the key to enter the setting mode when "COND" icon is shown on the
main screen.
2. Press the keys to select "COND" (conductivity setting) and then press the
key.
3. Press the keys to select "CAL DATA" (display calibration data) and then
press the key.
The cell constants determined by calibration are displayed. Press the key to
show the cell constants in order of ranges.

key

key key

key

To return to the measurement mode, press the key and then press the key.

72
Measurement setting

● Changing the calibration method


Select automatic calibration or manual calibration for the conductivity calibration method.

1. Press the key to enter the setting mode when "COND" icon is shown on the
main screen.
2. Press the keys to select "COND" (conductivity setting) and then press the
key.
3. Press the keys to select "AUTO CAL" (automatic calibration setting) and
then press the key.
4. Select "ON" to set the automatic calibration, or select "OFF" to set the manual
calibration. And then press the key to confirm.

key key

key key key

Select "ON"
and press the
key

To return to the measurement mode, press the key.


Note
When the setting of calibration method (auto or manual) is changed, the cell constant is
initialized. Make sure to enter the cell constant or to perform calibration again.

73
Measurement setting

● Using the calibration interval alarm (default: OFF)


If calibration has not been performed for set period of time after last calibration is
performed, "ERR No. 0008" is displayed to prevent forgetting to perform calibration.
When the error is displayed, performing calibration clears the error.

1. Press the key to enter the setting mode when "pH" icon is shown on the
main screen.
2. Press the keys to select "pH" (pH setting) and then press the key.
3. Press the key to select "CAL ALR" (calibration alarm setting) and then
press the key.

key key

key key

4. Enter the setting period of the calibration interval alarm and then press the
key.
The setting range is 1 day to 400 days.

Enter a
number key

To return to the measurement mode, press the key.

74
Measurement setting

● Deleting calibration data


Delete the calibration data set in the instrument.

1. Press the key to enter the setting mode.


2. Press the key to select the component to delete the data from "pH" or
"COND" and then press the key.
3. Press the keys to select "CAL CLR" (delete calibration data) and then
press the key.

key key

key key

(Ex.: "pH" is selected)

75
Measurement setting

4. Select "YES" to delete the calibration data, or select "NO" to cancel deleting it.
And then press the key to confirm selection.
When "YES" is selected and is pressed, "END" appears after deletion is
complete.

key

Select "YES"
and press the
key

To return to the measurement mode, press the key.


Tip
When the key is pressed for more than three seconds in the measurement mode,
"CALCLR" screen appears, and the calibration data can be deleted.

76
Temperature settings

■ Temperature settings
● Calibrating temperature sensor
The temperature sensor or temperature compensation electrode in the combination
electrode has ±1°C accuracy without calibration. You can use a known temperature
solution to calibrate the temperature sensor.

1. Insert the temperature connector into the jack of temperature connector (T) on
the instrument.
2. Immerse the electrode into the solution until the temperature sensor is
immersed.
3. Press the key to enter the setting mode when the channel which is
connected to the temperature sensor to calibrate is active.
4. Press the keys to select "TEMP" (temperature calibration setting) and
then press the key.

key key

5. Make sure that "ATC" is displayed, and press the key.


The temperature setting screen is displayed.
6. Enter the set temperature and press the key to confirm.
The temperature sensor is calibrated.

77
Temperature settings

key

Enter a
number key

To return to the measurement mode, press the key.

Note
When initializing temperature calibration data, all settings need to be initialized. Perform
initialization by referring to "Resetting to factory default settings" (page 83). When
initialization is performed, all saved data is deleted. Copy or transfer necessary data to a
PC for storage.

78
General settings

■ General settings
● Setting the auto stability and auto hold function
This instrument has auto stability mode and auto hold mode.

• Auto stability mode (displayed as AS)


When the criterion for stability judgment is fulfilled during measurement, the component
icon lights and the measured value is fixed. Once the value deviates from the stability
judgment criterion, the measured value is released and displays instantaneous value.

• Auto hold mode (displayed as AH)


When the criterion for stability judgment is fulfilled during measurement, the component
icon and the HOLD icon light and the measured value is fixed. To release the measured
value, press the key. Once a measured value is fixed, the measured value is not
released automatically even when the state deviates from the stability judgment criterion.

• Setting procedure
1. Press the key to enter the setting mode.
2. Press the keys to select "GEN" (general setting) and then press the
key.
3. Press the keys to select "MEAS" (measurement setting) and then press
the key.

key key

key key

Note
The general setting is common in both CH1 and CH2.

79
General settings

4. Select "AS" to set the auto stability, or select "AH" to set the auto hold. And
then press the key to confirm selection.

Select "AS"
and press
key key

To return to the measurement mode, press the key.


Note
In the calibration mode, the auto stability mode always works.

Tip
The stability judgment criteria are the same for both the auto stability mode and the auto
hold mode.

80
General settings

● Changing the automatic power off setting (default: 30 min)


You can set the instrument to automatically turn OFF when there is no key operation for
a certain period of time.
This function is disabled during automatic data memory saving or remote operation using
an external device.

1. Press the key to enter the setting mode.


2. Press the keys to select "GEN" (general setting) and then press the
key.

key key

key key

3. Press the keys to select "AUTO OFF" (automatic power off setting) and
then press the key.

81
General settings

4. Enter the automatic power off time and press the key.
The setting range is 0 min to 30 min.
"0" indicates the automatic power off is "OFF."

Enter a
key number

key

To return to the measurement mode, press the key.

82
General settings

● Resetting to factory default settings


The instrument settings can be reset to the factory default settings. The calibration data
is deleted but the data of date and time, and the saved data are not deleted. Make sure
there will be no problems before using this function. When this function is used, the
temperature calibration data is also initialized.

1. Press the key to enter the setting mode.


2. Press the keys to select "GEN" (general setting) and then press the
key.

key key

key key

3. Press the keys to select "RESET" (initialize) and then press the key.

83
General settings

4. Select "YES" to initialize the settings to the factory default settings, or select
"NO" to cancel initialization. And then press the key to confirm selection.
When "YES" is selected, "END" appears after the settings are initialized and then the
instrument is automatically powered OFF.

key key

Select "YES"
and press the
key

Power OFF

84
General settings

● Setting the date and time


When using the instrument for the first time or after replacing the batteries, set the date
and time. After setting, the date and time data is displayed correctly when saving data in
the internal memory. If the setting is incorrect, the date and time of saved data becomes
incorrect.

1. Press the key to enter the setting mode.


2. Press the keys to select "GEN" (general setting) and then press the
key.

key key

key key

85
General settings

3. Press the keys to select "DATE" (date and time setting) and then press
the key.
4. Enter "YEAR" (current year) and press the key.
5. In the same way, set "MONTH" (month), "DAY" (date) and "TIME" (hour and
minute), in that order.
6. Press ● key to confirm.

key key

Enter a Enter a
number and number and
press key press key

Enter a Enter a
number and number and
press key press key

To return to the setting mode, press the key.

86
General settings

● Performing test printing of the printer unit


In order to check whether the printer unit is operating correctly or there is a printer
communication problem, you can perform test printing.
Connect the instrument and a printer correctly and perform the following procedure for
test printing. As a result of test printing, if the printout is as shown below, the printer unit
is operating correctly.

1. Press the key to enter the setting mode.


2. Press the keys to select "GEN" (general setting) and then press the
key.

key key

key key

87
General settings

3. Press the keys to select "PRINT" (test print) and then press the key.
Printing starts automatically. When printing ends, the printer icon lights and "END"
appears. Press the key or the key.

key Printed

key or
key

To return to the measurement mode, press the key.

88
Other settings

■ Other settings
● Printing measured values and calibration data
Print out the measured value or calibrated value displayed on the instrument, or the
measurement data or the calibration data saved in the instrument. If the repeatability is
inspected, the inspection data is printed out with the calibration data.
Pressing the key starts printing during displaying the data you want to print. Use the
printer cable to connect the printer unit with the instrument beforehand. If the automatic
data memory is set to "ON", you cannot print out in the measurement mode.

Reference
For details of how to display measurement data and calibration data, refer to the respective
section.
  "Displaying saved data" (page 64)
  "Displaying the latest calibration and inspection data" (page 70)

Refer to the following table for the pH (two point calibration) and conductivity.

89
Other settings

< The data saved in internal memory >

Printout format Description


Memory Num : 0001 Data number
Date : 2016/01/01 Measurement date
Time : 09:00 Measurement time
Channel :1 Measurement Channel
Measured value
Out of measure range
pH : 5.22
Over: OR
Under: UR
Temperature value and temperature setting
Out of measure range
Temperature : 25.0°C MTC
Over: OR
Under: UR
Inst. model : LAQUAact-PC110 Instrument model
Inst. SN : KL1TSN20 Instrument serial number
Elect. status : GOOD Electrode status based on calibration result
Memory Num : 0001 Data number
Date : 2016/01/01 Measurement date
Time : 09:00 Measurement time
Channel :2 Measurement Channel
COND : 1.121 mS/m Measured value
Temperature : 25.0°C MTC Temperature value and temperature setting
Inst. model : LAQUAact-PC110 Instrument model
Inst. SN : KL1TSN20 Instrument serial number

90
Other settings

< Calibration data (pH, inspection was performed) >

Printout format Description


Inst. model : LAQUAact-PC110 Instrument model
Inst. SN : KL1TSN20 Instrument serial number
Elect. status : GOOD Electrode status based on calibration result
Offset : 0.7 mV Asymmetry potential of calibration data
Sensitivity Sensitivity of calibration data
pH 4.01 - 6.86 : 98.9%
Repeatability : 0.01 Repeatability of calibration data
Calibration data
Date : 2016/01/01 Calibration date
Time : 09:00 Calibration time
pH 4.01 : 176.9 mV Measurement potential
: 25.0°C ATC Temperature value and temperature setting
pH 6.86 : 7.6 mV Measurement potential
: 25.0°C ATC Temperature value and temperature setting
Inspection before use
Measurement potential at time of
pH 6.85 : 7.8 mV
repeatability inspection
: 25.0°C ATC Temperature value and temperature setting

< Calibration data (pH, inspection was not performed) >

Printout format Description


Inst. model : LAQUAact-PC110 Instrument model
Inst. SN : KL1TSN20 Instrument serial number
Elect. status : GOOD Electrode status based on calibration result
Offset : 0.7 mV Asymmetry potential of calibration data
Sensitivity Sensitivity of calibration data
pH 4.01 - 6.86 : 98.9%
Calibration data
Date : 2016/01/01 Calibration date
Time : 09:00 Calibration time
pH 4.01 : 176.9 mV Measurement potential
: 25.0°C ATC Temperature value and temperature setting
pH 6.86 : 7.6 mV Measurement potential
: 25.0°C ATC Temperature value and temperature setting

91
Other settings

< Calibration data (conductivity) >

Printout format Description


Inst. model : LAQUAact-PC110 Instrument model
Inst. SN : KL1TSN20 Instrument serial number
CELL : Cell constant
R1 (0.00-19.99 μS/cm) Measurement range (range 1)
1.000×1 cm-1 Cell constant (range 1)
R2 (18.0-199.9 μS/cm) Measurement range (range 2)
1.000×1 cm-1 Cell constant (range 2)
R3 (180-1999 μS/cm) Measurement range (range 3)
1.000×1 cm-1 Cell constant (range 3)
R4 (1.80-19.99 mS/cm) Measurement range (range 4)
1.000×1 cm-1 Cell constant (range 4)
R5 (18.0-200.0 mS/cm) Measurement range (range 5)
1.000×1 cm-1 Cell constant (range 5)
Calibration data
Date : 2016/01/01 Calibration date
Time : 09:00 Calibration time
1413 S/cm : Calibration value
Calibration Temperature and temperature
: 25.0°C ATC
setting
111.8 mS/cm : Standard value
Calibration Temperature and temperature
: 25.0°C ATC
setting

Tip
The conductivity range marked with "0" (Ex. oR1) indicates calibrated conductivity range.

92
Other settings

● Transferring saved data to a PC


By using a serial cable to connect the instrument to a PC, you can transfer the saved
data to the PC and edit it. Connect the RS-232C connector at the instrument side to the
serial port on the PC.
To save and edit data, please download the software "FD-70" from our website after the
registration.
For details of how to use the "FD-70", refer to the "FD-70" instruction manual, which you
can download from our website as well.
The required PC specifications and recommended PC specifications for using the "FD-
70" are shown in the following table.

Item Required PC specifications Recommended PC specifications


32 bit: 1 GB or more
Memory
64 bit: 2 GB or more
CPU 1 GHz or more
HDD free space 5 GB or more 10 GB or more
OS Windows 7, Windows 8 (8.1), or Windows 10
Display Super VGA (800 × 600) or more
Connector Serial connector (D-Sub 9 pin)

Note
・ If you are not using the RS-232C communication, close the connector cover tightly.
・ While using the RS-232C communication, the instrument is not dust-proof or waterproof.
Do not use the RS-232C communication in a dusty place or with wet hands.

93
Other settings

● Operating the instrument from an external device


You can remotely operate the instrument from an external device (such as PC) via the
RS-232C communication. Use the serial cable to connect the serial connector on the
instrument side and the serial port on the PC.

When using this function, pay attention to the following points.

・ Use the optional serial cable to connect the unit to a PC.

・ Make sure that the transfer formats used in the instrument and a PC are the same.
When different transfer formats are used, a communication error occurs and the
online mode does not start up, and as a result RS-232C communication cannot be
performed. Also, when the transfer format is changed, turn OFF the power of the
instrument and PC and then reboot them.

The transfer format of the instrument is as follows.


  ・ Baud rate: 2400 bps
  ・ Character length: 8 bits
  ・ Parity: None
  ・ Stop bit: 1 bit

You can download a list of communication commands from our website.


In order to download the list, you need to complete user registration.

Note
・ If you are not using the RS-232C communication, close the connector cover tightly.
・ While using the RS-232C communication, the instrument is not dust-proof or waterproof.
Do not use the RS-232C communication in a dusty place or with wet hands.

94
Maintenance

Maintenance
This section describes maintenance of the instrument and the electrodes that are used
with the instrument. To use them for a long period, perform the described maintenance
procedures appropriately.

● Contact for maintenance


Please contact your dealer for the product maintenance.

● Maintenance and storage of the instrument


・ If the instrument becomes dirty, wipe it gently with a soft dry cloth. If it is difficult to
remove the dirt, wipe it gently with a cloth moistened with alcohol.

・ The instrument is made of solvent resistant materials but that does not mean it is
resistant to all chemicals. Do not dip the instrument in strong acid or alkali solution, or
wipe it with such solution.

・ Do not wipe the instrument with a polishing powder or other abrasive compound.

● Environmental conditions for storage


  Temperature: 0°C to 45°C
  Humidity: under 80% in relative humidity and free from condensation

Avoid the following conditions.


  ・ Dusty place
  ・ Strong vibration
  ・ Direct sunlight
  ・ Corrosive gas environment
  ・ Close to an air-conditioner
  ・ Direct wind

95
Maintenance

● Maintenance and storage of the pH electrode


For the detailed procedures for maintaining and storing electrodes, refer to the
instruction manual for each electrode. This section describes an overview of the
procedures for maintenance and storage to be performed as part of daily use.

• How to clean the electrode


When the tip of an electrode (responsive membrane and liquid junction) becomes dirty,
the response speed may become slow or an error may occur in the measurement
results. To avoid such error, clean the electrode. For dirt that cannot be removed by pure
water (or deionized water), use the cleaning solution indicated below depending on the
type of dirt. After cleaning, rinse the electrode with pure water (or deionized water).

Type of dirt Cleaning solution


General Diluted neutral cleaning solution
Oil Alcohol, or diluted neutral cleaning solution
Inorganic substance 1 mol/L HCl or electrode cleaning solution (model 220)
Cleaning solution including protein-removing enzyme (model
Protein
250)
Immerse 1 mol/L HCl or electrode cleaning solution (model 220)
alkali
in 1 h to 2 h

• Daily storage of the electrode


If the electrode becomes dry, the response will become slow. Store in a moist
atmosphere. Follow the steps below to properly store the electrode.

1. Clean the electrode well with pure water (or deionized water) to remove sample
completely, and close the internal solution filler port.
2. Clean inside of the protective cap with pure water (or deionized water), then
add enough pure water (or deionized water) to soak the sponge.
3. Attach the protective cap.

• When the electrode will not be used for a long period


To store the electrode for a long period, follow the electrode storage procedure above,
and in addition, use a dropper or similar tool to replace the reference electrode internal
solution (model 300) with new solution. Replace the internal solution once every three to
six months.

96
Maintenance

● Maintenance and storage of the ORP electrode


For the detailed procedures for maintaining and storing electrodes, refer to the
instruction manual for each electrode. This section describes an overview of the
procedures for maintenance and storage to be performed as part of daily use.

• How to clean the electrode


When the tip of an electrode (responsive membrane and liquid junction) becomes dirty,
the response speed may become slow or an error may occur in the measurement
results. To avoid such error, clean the electrode. For dirt that cannot be removed by pure
water (or deionized water), use the cleaning solution indicated below depending on the
type of dirt. After cleaning, rinse the electrode with pure water (or deionized water).

Type of dirt Cleaning solution


General
Diluted neutral cleaning solution
Oil
Inorganic substance Immerse dilute nitric acid (1:1 nitric acid)

• Daily storage of the electrode


If the electrode becomes dry, the response will become slow. Store in a moist
atmosphere. Follow the steps below to properly store the electrode.

1. Clean the electrode well with pure water (or deionized water) to remove sample
completely, and close the internal solution filler port.
2. Clean inside of the protective cap with pure water (or deionized water), then
add enough pure water (or deionized water) to soak the sponge.
3. Attach the protective cap.

• When the electrode will not be used for a long period


To store the electrode for a long period, follow the electrode storage procedure above,
and in addition, use a dropper or similar tool to replace the reference electrode internal
solution (model 300) with new solution. Replace the internal solution once every three to
six months.

97
Maintenance

● Checking the state of the ORP electrode


ORP standard solution can be used to check the state of the ORP electrode.
This solution is only used to check the state of the ORP electrode; it is not used to
calibrate the instrument. The procedure for checking the electrode using HORIBA ORP
standard solution powder 160-22 or 160-51 is explained below.

1. Add one bag of 160-22 or 160-51 standard solution powder to 250 mL of


deionized water and mix thoroughly.
When mixing, the excess quinhydrone (a black powder) will float to the surface of the
solution.
2. Immerse a washed and dried ORP electrode in the prepared standard solution
and measure the mV value.
If the electrode and the instrument are working properly, numerical values within ±15
mV of those indicated below should be obtained.
The ORP value varies by temperature. Check the appropriate ORP value for the
temperature of the standard solution.
3. If the ORP value is not within ±15 mV, replace the reference electrode internal
solution.
If the surface of the metal electrode is dirty, wipe it gently with a soft material such as
absorbent cotton moistened with alcohol or a neutral cleaning solution, or immerse in
dilute nitric acid (1:1 nitric acid) to remove the dirt.
4. Repeat the measurement.
If the ORP value is within ±15 mV, the electrode is normal.
If not within ±15 mV, the electrode may have failed. Replace the electrode.
Note
・ If the prepared standard solution is left out in air for one hour or more, that the ORP value
might change. Do not use the ORP standard solution that was prepared more than an hour
before.
・ When measuring a solution that has low concentrations of oxidants and reductants after
conducting an operational check using a standard substance, the measured values may not
stabilize or the repeatability might be poor. If this is the case, use the ORP electrode after
immersing it in the solution again and mixing it thoroughly.

• ORP value based on the temperature of ORP standard solution

Temp. 160-22 160-51


Phthalic-acid chloride + quinhydrone Neutral phosphate + quinhydrone
(°C) (mV) (mV)
5 274.2 111.9
10 270.9 106.9
15 266.8 101.0
20 262.5 95.0
25 257.6 89.0
30 253.5 82.7
35 248.6 76.2
40 243.6 69.0

98
Maintenance

● Maintenance and storage of the conductivity cell


For the detailed procedures for maintaining and storing cells, refer to the instruction
manual for each cell. This section describes an overview of the procedures for
maintenance and storage to be performed as part of daily use.

• How to clean the cell


Always wash the cell in pure water (or deionized water) after every measurement. When
the response is slow or residue from the sample adheres to the cell, use the appropriate
method below to clean the cell, and then wash again with pure water (or deionized
water).

Type of dirt Cleaning solution


General Diluted neutral cleaning solution
Inorganic substance Ethanol (keep the ethanol away from plastic parts)
A commercially available scale remover (neutral cleansing
solution for kitchen use, etc.) diluted by a factor of 100. If this
Scale that formed during
does not remove the scale, use diluted solution that contains
long term storage
oxygen bleach (sodium percarbonate) or chlorine bleach
(sodium hypochlorite).

• Daily storage of the cell


If the cell is stored in a dry state, the cell constant will change. Store with the black
electrode part immersed in pure water (or deionized water), or with the protective cap
filled with pure water (or deionized water) and attached to the cell.

• When the electrode will not be used for a long period


To store the cell for a long period, wash it well and attach the protective cap filled with
pure water (or deionized water).

99
MEMO
When an error message appears

How to Resolve Errors or Troubles


This section describes the causes of typical problems and the actions to be taken,
including questions frequently asked by customers. Check these before contacting us.

■ When an error message appears


If "ERR No.00XX" is displayed while you are using the instrument, check the error in the
error list below, and check the cause and action to be taken.

ERR No. Description Definition of error


Data cannot be read from or written to the internal
0001 Memory error
memory.
0002 Empty battery level The battery level is empty.
Asymmetric potential The asymmetric potential of the electrode is out of
0004
error the range of ±45 mV.
Electrode sensitivity The electrode sensitivity is either 105% or more or
0005
error 85% or less than the theoretical sensitivity.
Maximum calibration
0006 6th point calibration is attempted.
points exceeded
Cannot identify The instrument cannot identify the standard
0007
standard solution solution.
Calibration interval
0008 Exceeds the calibration interval setting.
error
0009 Printer error There is a problem with the printer.
The number of the data saved has exceeded the
0010 Memory full
specified number of items.
Cell constant is out of
0011 Cell constant is out of automatic calculation range.
range

● ERR No.0001   Memory error


Data cannot be read from or written to the internal memory.

Cause How to solve problem


The instrument does not start Remove the batteries, disconnect the AC adapter, and
properly due to noise or other at
power ON. then press the key.
The defect of the internal IC Contact your dealer for repair.

101
When an error message appears

● ERR No.0002   Empty battery level


The instrument cannot operate properly because the battery level is empty.

Cause How to solve problem


The battery level is empty. Replace the batteries or connect the AC adapter (option).

● ERR No.0004   Asymmetric potential error


Detected that the asymmetric potential of the electrode is out of the setting range that
allows proper measurement.

Cause How to solve problem


The electrode is dirty. Clean the electrode.
The electrode is cracked. Replace the electrode.
The standard solution
Replace the internal solution in the reference electrode.
concentration is fluctuating.
The electrode is not connected
Connect the electrode correctly.
correctly.
The electrode must be immersed up to the liquid junction.
Electrode is not immersed
As a guide, immerse to at least 3 cm from the tip of the
enough to cover liquid junction.
electrode.
There is a problem with the
Use new standard solution.
standard solution.

102
When an error message appears

● ERR No.0005   Electrode sensitivity error


Detected that the electrode sensitivity is out of the setting range that allows proper
measurement.

Cause How to solve problem


The electrode is dirty. Clean the electrode.
The electrode is cracked. Replace the electrode.
Calibration was not performed
Perform calibration correctly.
correctly.
The electrode is not connected
Connect the electrode correctly.
correctly.
The electrode must be immersed up to the liquid junction.
Electrode is not immersed
As a guide, immerse to at least 3 cm from the tip of the
enough to cover liquid junction.
electrode.
There is a problem with the
Use new standard solution.
standard solution.

● ERR No.0006   Maximum calibration points exceeded


Attempted to perform 6th point calibration during pH calibration.

Cause How to solve problem


6th point calibration is
Up to five points can be calibrated.
attempted.

● ERR No.0007   Cannot identify standard solution


Unable to automatically detect the standard solution during pH calibration.

Cause How to solve problem


There is a problem with the
Use new standard solution.
standard solution.
Settings about the standard
Check if the instrument settings and the specifications of
solution do not match the
the standard solution are compatible.
instrument.
The electrode is dirty. Clean the electrode.
The electrode is cracked. Replace the electrode.
The standard solution
Replace the internal solution in the reference electrode.
concentration is fluctuating.
The electrode must be immersed up to the liquid junction.
Electrode is not immersed
As a guide, immerse to at least 3 cm from the tip of the
enough to cover liquid junction.
electrode.

103
When an error message appears

● ERR No.0008   Calibration interval error


・ More than the set number of days has elapsed since calibration was last performed.
・ The calibration interval alarm is "ON" and calibration has not been performed.

Cause How to solve problem


Calibration has not been
performed for the set number of
Perform calibration.
days of the calibration interval or
longer.
The calibration interval alarm is
"ON" and calibration has not Perform calibration.
been performed.

● ERR No.0009   Printer error


An error occurred during printer communication.

Cause How to solve problem


There is a problem with the Check the printer connection, and connect the instrument
printer unit connection. and printer again.
The defect of the printer Consult your dealer.

● ERR No.0010   Memory full


Attempted to save more than the specified number of items.

Cause How to solve problem


The maximum number of savable items of data is 1000.
Saving more than specified Copy or transfer necessary data to a PC and delete the
number of items. data from the memory ("Deleting all saved data" (page
68)).

● ERR No.0011   Cell constant is out of range


Cell constant is out of setting range.

Cause How to solve problem


End of cell life Replace the conductivity cell.
There is a problem with the
Use new standard solution.
standard solution

104
Troubleshooting

■ Troubleshooting
This section describes causes and actions to take for problems that customers
frequently ask us.

● The indicated value fluctuates

< Problem with the electrode >

Cause How to solve problem


The electrode is dirty. Clean the electrode.
The electrode is cracked. Replace the electrode.
The wrong internal solution is
Use the correct internal solution.
being used.
There are air bubbles on the
Shake the electrode to remove the air bubbles.
electrode.
The level of internal solution in Replenish the internal solution of the reference electrode
reference electrode is low. until it is higher than the level of the sample.

< Problem with the instrument >

Cause How to solve problem


There is a motor or other device Measure at a place where no influence from induction is
causing electrical interference. given. Ground all AC-powered equipment.
The electrode is not connected
Connect the electrode correctly.
correctly.

< Problem with the sample >

Cause How to solve problem


The electrode must be immersed up to the liquid junction.
Electrode is not immersed
As a guide, immerse to at least 3 cm from the tip of the
enough to cover liquid junction.
electrode.
It is important to select an electrode that is appropriate
for the sample. Consult your dealer. To confirm an
The stability of electrode is
electrode that is appropriate for the sample, check the pH
affected by the sample solution.
electrode selection guide in our catalogue, or refer to our
website.

105
Troubleshooting

● The response is slow

Cause How to solve problem


The electrode is dirty. Clean the electrode.
The electrode is cracked. Replace the electrode.
The wrong internal solution is
Use the correct internal solution.
being used.
It is important to select an electrode that is appropriate
for the sample. Consult your dealer. To confirm an
The response of electrode is
electrode that is appropriate for the sample, check the pH
affected by the sample solution.
electrode selection guide in our catalogue, or refer to our
website.

● The indicated value does not change/No response

Cause How to solve problem


The electrode is cracked. Replace the electrode.
The electrode is not connected
Connect the electrode correctly.
correctly.
Turn OFF the power, remove the batteries, and then turn
Keys are locked.
ON the power again.
The instrument is in HOLD state. Cancel the HOLD state.
Instrument defect Consult your dealer.

106
Troubleshooting

● The measured value is out of the measurement range


When the measured value is below the display range, "Ur" appears. When the measured
value is over the display range, "Or" appears.

Cause How to solve problem


Sample is out of the
Use a sample within the measurement range.
measurement range.
The electrode must be immersed up to the liquid junction.
Electrode is not immersed
As a guide, immerse to at least 3 cm from the tip of the
enough to cover liquid junction.
electrode.
The electrode cable is broken. Replace the electrode.
Calibration is not performed or
Perform calibration correctly.
performed incorrectly.
Instrument defect Check as explained below.

• How to check for instrument defect


Short the metal part of the outer tube to the center pin of the electrode
connector of the corresponding channel of the instrument. If "Ur" or "Or"
appears in this condition, consult your dealer.

● Repeatability of the measured value is poor

Cause How to solve problem


Repeatability becomes poor when the pH of the sample
Effect of the sample solution
changes over time.
Clean the electrode. (Electrode cleaning solution 220 or
The electrode is dirty.
250 is recommended.)
The electrode is cracked. Replace the electrode.
The internal solution of the
electrode runs out or Replace the internal solution with new one.
contaminated.
The level of internal solution in Replenish the internal solution of the reference electrode
reference electrode is low. until it is higher than the level of the sample.

107
Troubleshooting

● Nothing appears when the power is turned ON

Cause How to solve problem


Power is not supplied. Insert batteries or connect the AC adapter (option).
Battery polarity (+, ) is Insert the batteries with the polarity (+, ) correctly
reversed. oriented.
Battery life is low. Replace the batteries or connect the AC adapter (option).
Instrument defect Consult your dealer.

● Swelling of operation key sheet

Cause How to solve problem


Using the instrument at high To eliminate the pressure difference between the inside
elevation or other location where and outside of the instrument, briefly open and then close
the air pressure is different from the AC adapter cover. After opening, correctly close the
sea level. cover to maintain dust and water proofing.
Instrument defect Consult your dealer.

● Part of the display is missing

Cause How to solve problem


Check the display in full screen state when turning ON
Instrument defect
the power of the instrument.

108
Main specifications

Appendix
This section describes the specifications of the instrument, default settings,
measurement principles, and other technical information.
Options for the instrument are also described.

■ Main specifications

Item Description
Model LAQUAact-PC110
Brand (pet name) LAQUAact
Series name Portable pH Water Quality Meter
Model description pH/ORP/Conductivity Meter
Measurement
pH, mV (ORP), conductivity, salinity, TDS, resistivity, temperature
parameters
Operating ambient 0°C to 45°C
temperature, humidity 80% or less in relative humidity (no condensation)
AAA alkaline batteries (LR03) or AAA Ni-MH rechargeable
Power batteries × 2
AC adapter 100 V to 240 V, 50/60 Hz, 0.37 A (option)
Approx. 67 [80] (W) × 170 (D) × 28 [42] (H) mm
Dimensions
(The figures in square bracket are maximum thicknesses.)
Mass Approx. 285 g (without batteries)

・ Specification of each measurement parameter

Measurement
Item Description
parameter
Measuring principle Glass electrode
Display range pH 2.00 to pH 16.00
pH Measuring range pH 0.00 to pH 14.00
Resolution 0.01 pH
Accuracy ±0.01 pH
Measuring range ±2000 mV
Resolution 1 mV
mV (ORP)
1 mV or 1% of the read value,
Accuracy
whichever is greater
Measuring principle Thermistor method
Display range 30.0°C to 130.0°C
Temperature Measuring range 0.0°C to 100.0°C
Resolution 0.1°C
Accuracy ±0.4°C

109
Main specifications

Measurement
Item Description
parameter
Measuring principle 2 AC bipolar method
Cell constant 1 cm-1: 0.00 S/cm to 200.0 mS/cm
Measuring range
(Display range) Cell constant 0.1 cm-1: 0.000 S/cm to 20.00 mS/cm
Cell constant 10 cm-1: 0.0 S/cm to 2.000 S/cm
Conductivity
Resolution 0.05% of full scale
±0.6% of full scale
Accuracy
(18.0 mS/cm to 200.0 mS/cm: ±1.5% of full scale)
Repeatability ±0.6% of full scale
Measuring principle Conversion from conductivity value
Measuring range 0.00% to 10.00%
Salinity (Display range) (0.0 ppt to 100.0 ppt)
Accuracy ±0.2% of full scale
Resolution 0.01% (0.1 ppt)
Measuring principle Conversion from conductivity value
Measuring range 0.00 mg/L to 100 g/L
TDS (Display range) TDS factor: 0.40 to 1.00
Accuracy ±0.1% of full scale
Resolution 0.01 mg/L
Measuring principle Conversion from conductivity value
Cell constant 1 cm-1: 0.000 kΩ·cm to 20.00 MΩ·cm
Measuring range
(Display range) Cell constant 0.1 cm-1: 0.00 kΩ·cm to 200.0 MΩ·cm
Cell constant 10 cm-1: 0.0 Ω·cm to 2.000 MΩ·cm
Resistivity
Resolution 0.05% of full scale
±0.6% of full scale
Accuracy
(1.80 MΩ·cm to 20.00 MΩ·cm: ±1.5% of full scale)
Repeatability ±0.5% of full scale ±1 digit

Tip
Accuracy is the difference between the measured value and the simulation value when the
simulation value is inputted to the instrument.

110
Main specifications

● Table of conductivity cell range


・ Unit: S/m

Cell constant
Range
1000 m-1 100 m-1 10 m-1
20.0 to 200.0 S/m
2.00 to 19.99 S/m
0.200 to 1.999 S/m
20.0 to 199.9 mS/m
2.00 (0.00) to 19.99 mS/m
0.200 (0.000) to 1.999 mS/m
0.0 to 199.9 µS/m

・ Unit: S/cm

Cell constant
Range
10 cm-1 1 cm-1 0.1 cm-1
0.200 to 2.000 S/cm
20.0 to 199.9 mS/cm
2.00 to 19.99 mS/cm
200 to 1999 µS/cm
20.0 (0.0) to 199.9 µS/cm
2.00 (0.00) to 19.99 µS/cm
0.000 to 1.999 µS/cm

・ Unit: mS/cm FIX

Cell constant
Range
10 cm-1 1 cm-1 0.1 cm-1
200.0 to 2000 mS/cm
20.00 to 199.9 mS/cm
2.000 to 19.99 mS/cm
0.200 (0.000) to 1.999 mS/cm
0.020 (0.000) to 0.199 mS/cm
0.002 to 0.019 mS/cm
0.000 to 0.002 mS/cm

111
Main specifications

● Table of conductivity cell range (resistivity range)


・ Unit: Ω·m

Cell constant
Range
10 m-1 100 m-1 1000 m-1
0.200 to 2.000 MΩ·m
20.0 to 199.9 kΩ·m
2.00 to 19.99 kΩ·m
0.200 to 1.999 kΩ·m
20.0 (0.0) to 199.9 Ω·m
2.00 (0.00) to 19.99 Ω·m
0.000 to 1.999 Ω·m

・ Unit: Ω·cm

Cell constant
Range
0.1 cm-1 1 cm-1 10 cm-1
20.0 to 199.9 MΩ·cm
2.00 to 19.99 MΩ·cm
0.200 to 1.999 MΩ·cm
20.0 to 199.9 kΩ·cm
2.00 (0.00) to 19.99 kΩ·cm
0.200 (0.000) to 1.999 kΩ·cm
0.0 to 199.9 Ω·cm

112
Instrument default settings

■ Instrument default settings

Measurement Selection item/Setting


Item Default values
parameter range
Auto hold AS/AH AS
Temperature input value 0.0°C to 100.0°C 25.0°C
Auto power off time 0 min to 30 min *1 30 min
Common
Auto data memory time 0, 2 s to 3600 s *2 0s
Auto data memory
0 min to 3600 min 0 min
period
Standard solution USA/NIST/CUST USA
pH
Calibration interval 0 day to 400 days *3 0 day
0.700 to 1.300
1.000
Cell constant (0.1 cm-1, 1 cm-1,
(1 cm-1)
10 cm-1)
Conductivity Temperature coefficient 0.00%/°C to 10.00%/°C 2.00%/°C
Unit S/cm, S/m, mS/cm FIX S/cm
Calibration method Auto/Manual Auto
Reference temperature 15°C to 30°C 25°C
Unit PPT, % PPT
Salinity
Calculation method NaCl/Sea water NaCl
Linear/442/En27888/
TDS Calculation method Linear
NaCl

*1: When 0 is inputted, auto power OFF is OFF.


*2: When 0 is inputted, auto data memory is OFF.
*3: When 0 is inputted, calibration alarm interval is OFF.

113
Technical note

■ Technical note
● pH standard solutions at various temperatures

< USA >


pH 12
pH 7
Temp. pH 2 pH 4 pH 10 Saturated calcium
Neutral
(°C) Oxalate Phthalate Carbonate hydroxide
phosphate
solution
0 1.666 4.003 7.119 10.318 13.423
5 1.668 3.999 7.086 10.245 13.207
10 1.670 3.998 7.058 10.178 13.003
15 1.672 3.999 7.035 10.117 12.810
20 1.675 4.002 7.015 10.061 12.627
25 1.679 4.008 7.000 10.011 12.454
30 1.683 4.015 6.988 9.965 12.289
35 1.688 4.024 6.979 9.925 12.133
40 1.694 4.035 6.973 9.888 11.984
45 1.700 4.047 6.969 9.856 11.841

< NIST (pH 2, 4, 12 are common) >


pH 7
Temp. pH 9
Neutral
(°C) Borate
phosphate
0 6.984 9.464
5 6.951 9.395
10 6.923 9.332
15 6.900 9.276
20 6.881 9.225
25 6.865 9.180
30 6.853 9.139
35 6.844 9.102
40 6.838 9.068
45 6.834 9.038

Tip
The differences between NIST and USA standard solutions are a different pH7 value, and
the use of pH10 standard solution instead of pH9 standard solution in USA.

Note
Calibration is performed using Nernst's equation with the above values.

114
Technical note

● Conductivity standard values at various temperatures


Temp. Conductivity value at 25°C
(°C) 84.00 (S/cm) 1413 (S/cm) 12.88 (mS/cm) 111.8 (mS/cm)
0 64.01 776 7.15 65.4
5 65.00 896 8.22 74.1
10 67.00 1020 9.33 83.2
15 68.00 1147 10.48 92.5
16 70.00 1173 10.72 94.4
17 71.00 1199 10.95 96.3
18 73.00 1225 11.19 98.2
19 74.00 1251 11.43 100.2
20 76.00 1278 11.67 102.1
21 78.00 1305 11.91 104.0
22 79.00 1332 12.15 105.9
23 81.00 1359 12.39 107.9
24 82.00 1386 12.64 109.8
25 84.00 1413 12.88 111.8
26 86.00 1440 13.13 113.8
27 87.00 1467 13.37 115.7
28 89.00 1494 13.62 117.7
29 90.00 1521 13.87 119.7
30 92.00 1548 14.12 121.8
31 94.00 1575 14.37 123.9

115
Options

■ Options
A wide variety of electrodes and options are available for use with the instrument. You
can select the optimum electrode and options for your application and objectives.
These options can be purchased from your nearest agency. Please provide the part
name and part number to the representative.
With regard to electrodes, it is important to select the optimum electrode for the sample
you want to measure. For details, refer to the catalogue or our website, or contact your
dealer.

Part name Part number Remarks


Printer (USA, 120 V) 3014030146
Printer cable sold separately
Printer (EU, 230 V) 3014030147
Plain paper
Printer cable 3014030148 1.5 m
printer
Roll paper 3014030149 20 rolls/set
Ink ribbon 3014030150 5 pcs/set
Serial cable 3014030151 1.5 m
AC adapter* 3200647413 With 6 plug adapters

*: The AC adapter includes 6 plug adapters.


Referring to the following table, attach the appropriate plug adapter to the AC
adapter depending on the country to be used.

⑤ U.K., ⑥ USA,
① Australia ② China ③ Europe ④ Korea
Singapore Canada, Taiwan

116
31, Miyanonishi-cho, Kisshoin Minami-ku, Kyoto 601-8306, Japan
http://www.horiba-adt.jp

For any questions regarding this product, please contact your local agency, or inquire from the
following website.
http://global.horiba.com/contact_e/index.htm

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