PC110 Instruction Manual GZ0000427799B
PC110 Instruction Manual GZ0000427799B
PC110 Instruction Manual GZ0000427799B
pH/ORP/Conductivity Meter
LAQUAact-PC110
HORIBA Advanced Techno Co., Ltd. SHALL NOT BE LIABLE FOR ANY DAMAGES
RESULTING FROM ANY MALFUNCTIONS OF THE PRODUCT, ANY ERASURE OF
DATA, OR ANY OTHER USES OF THE PRODUCT.
● Trademarks
・ Microsoft, Windows, Windows Vista are registered trademarks or trademarks of
Microsoft Corporation in the United States and other countries.
Other company names and brand names are either registered trademarks or trademarks
of the respective companies. (R), (TM) symbols may be omitted in this manual.
CODE:GZ0000427799B
January, 2017 2017 HORIBA Advanced Techno Co., Ltd.
I
Regulations
■ Regulations
● EU regulations
●Conformable standards
This equipment conforms to the following standards:
EMC: EN61326-1
Class B, Basic electromagnetic environment
Safety: EN61010-1
RoHS: EN50581
9. Monitoring and control instruments
●Installation environment
This product is designed for the following environment.
・Overvoltage category II
・Pollution degree 2
●Authorised representative in EU
HORIBA UK Limited
2 Dalston Gardens, Stanmore, Middx HA7 1BQ, UK
II
Regulations
● FCC rules
Any changes or modifications not expressly approved by the party responsible for
compliance shall void the user's authority to operate the equipment.
●Warning
This equipment has been tested and found to comply with the limits for a Class A digital
device, pursuant to part 15 of the FCC Rules. These limits are designed to provide
reasonable protection against harmful interference when the equipment is operated in a
commercial environment. This equipment generates, uses, and can radiate radio
frequency energy and, if not installed and used in accordance with the instruction
manual, may cause harmful interference to radio communications.
Operation of this equipment in a residential area is likely to cause harmful interference in
which case the user will be required to correct the interference at his own expense.
● Korea certification
●
III
Regulations
● China regulation
ḽ䇦Ⲻᝅѿ
Meaning of Marking
䝬䞊䜽䛾ព㻌
ᵢḽ䇦䘸⭞൞ѣӰ≇ާૂള䬶⭫ಞ⭫ᆆӝθḽ䇦ѣཤⲺᮦ
ᆍ㺞⽰⧥ູؓᣚֵ⭞ᵕ䲆ⲺᒪᮦȾ(уᱥ㺞⽰ӝ䍞䠅ؓ䇷ᵕ䰪Ⱦ)
ਠ㾷䚫ᆾ䘏ѠӝᴿީⲺᆿ⌞⭞ֵૂޞᝅӁ亯θԄ䙖ᰛᔶခ㇍
䎭൞䘏Ѡᒪ䲆θуՐ㔏⧥ູ⊗ḉȽӰ։ૂ䍘ӝᑜᶛћ䠃ⲺᖧଃȾ
䈭у㾷䳅ᝅᓕᔹᵢ⭫ಞ⭫ᆆӝȾ
ᮏ䝬䞊䜽䛿䚸୰⳹ேẸඹᅜ䛷㈍䛥䜜䜛㟁Ẽ㟁Ꮚ〇ရ䛻㐺⏝䛥
䜜䚸䝬䞊䜽䛾୰ኸ䛾ᩘᏐ䛿⎔ቃಖㆤ⏝ᮇ㝈䛾ᖺᩘ䜢ព䛧䜎䛩
䠄〇ရ䛾ရ㉁ಖドᮇ㛫䜢♧䛩䜒䛾䛷䛿䛒䜚䜎䛫䜣䠅䚹䛣䛾〇ရ䛻㛵
䛩䜛Ᏻ䜔⏝ୖ䛾ὀព䜢䛚Ᏺ䜚㡬䛟㝈䜚䚸〇㐀᪥䛛䜙㉳⟬䛩䜛䛣
䛾ᖺ㝈ෆ䛷䛿䚸⎔ቃởᰁ䜔ேయ䜔㈈⏘䛻῝้䛺ᙳ㡪䜢ཬ䜌䛩䛣䛸
䛿䛒䜚䜎䛫䜣䚹ᮏ〇ရ䜢䜏䛰䜚䛻ᗫᲠ䛧䛺䛔䛷䛟䛰䛥䛔䚹
IV
Regulations
ӝѣᴿᇩ⢟䍞Ⲻ〦䠅
Name and amount of hazardous substance used in a product
ᴿᇩ⢟䍞
Hazardous substance
ޣԭ䬢 ཐ⓪ӂ㤥䟐
ཐ⓪㚊㤥
䜞Ԭ〦 ⊔ 䭿 Hexa- Poly
䫻 Poly
Unit name Mer Cad- valent bromo-
Lead bromo-
cury mium㻌 chrom- diphenyl
(Pb) biphenyl
(Hg) (Cd) ium㻌 ether
(PBB)
(Cr (VI)) (PBDE)
ᵢ։
ۑ ۑ ۑ ۑ ۑ
Main unit
⭫⊖
ۑ ۑ ۑ ۑ ۑ
Battery
AC䘸䞃ಞ
*1, *2 ۑ ۑ ۑ ۑ ۑ
AC adapter
⭫㔼
*2 ۑ ۑ ۑ ۑ ۑ
Cable
᭥ᷬ
*2 ۑ ۑ ۑ ۑ ۑ ۑ
Stand
ᢉদᵰ
*2 ۑ ۑ ۑ ۑ ۑ
Printer
⭫ᶷ
*2 ۑ ۑ ۑ ۑ
Electrode
ᵢ㺞ṲᦤדSJ/T 11364Ⲻ㿺ᇐ㕌Ⱦ
This form is prepared in accordance with SJ/T 11364.
ۑ: 㺞⽰䈛ᴿᇩ⢟䍞൞䈛䜞Ԭᡶᴿൽ䍞ᶆᯏѣⲺ䠅ൽ൞ GB/T 26572 㿺ᇐⲺ䲆䠅㾷
≸ԛсȾ
Denotes that the amount of the hazardous substance contained in all of the
homogeneous materials used in the component is below the limit on the
acceptable amount stipulated in the GB/T 26572.
h: 㺞⽰䈛ᴿᇩ⢟䍞㠩ቇ൞䈛䜞ԬⲺḆжൽ䍞ᶆᯏѣⲺ䠅䎻࠰GB/T 26572 㿺ᇐⲺ
䲆䠅㾷≸Ⱦ
Denotes that the amount of the hazardous substance contained in any of the
homogeneous materials used in the component is above the limit on the
acceptable amount stipulated in the GB/T 26572.
*1: ᵢ䜞ԬⲺ⧥ֵؓ⭞ᵕ䲆Ѱ10ᒪȾ㻌 The environmental protection use period
of this product is 10 years.
*2: 䘿䞃Ԭ Optional products
V
For Your Safety
●Hazard classification
This indicates an imminently hazardous situation which, if
not avoided, will result in death or serious injury. This is to
be limited to the most extreme situations.
●Warning symbols
● [DEU] Sicherheitsinformation
Lesen Sie vor der Verwendung des Produkts unbedingt diese Anleitung, um den ord-
nungsgemäßen und sicheren Betrieb des Produkts zu gewährleisten. Bewahren Sie die
Anleitung sicher auf, damit sie bei Bedarf jederzeit zur Hand ist.
Die Inhalt dieser Anleitung können ohne Vorankündigung geändert werden.
●Installationsumgebung
Dieses Produkt ist nicht zum Gebrauch in industriellen Umgebungen, wie in EN61326-1
definiert, vorgesehen.
In einer industriellen Umgebung können die elektromagnetischen Störungen eventuell
zu Produktfehlfunktionen führen. Um dieses Produkt unter solchen Umständen verwen-
den zu können, muss der Benutzer ggf. angemessene Maßnahmen ergreifen.
Das Produkt ist gemäß EN61010-1 für die folgende Umgebung vorgesehen.
- Überspannungskategorie II
- Verschmutzungsgrad 2
VI
For Your Safety
●Environnement d’installation
Ce produit n'est pas destinés à une utilisation dans des environnements industriels, tels
que définis dans la norme EN61326-1.
Dans un environnement industriel, les interférences électromagnétiques peuvent entraî-
ner un dysfonctionnement du produit. Pour utiliser le produit dans ce type d’environne-
ments, l’utilisateur peut avoir à prendre des mesures appropriées.
Le produit est conçu pour l’environnement suivant, tel que défini dans la norme
EN61010-1.
- Catégorie de surtension II
- Degré de pollution 2
●Ambiente di installazione
Questo prodotto non è stati progettati per essere utilizzati in ambienti industriali, secondo
la norma EN61326-1.
In un ambiente industriale, le interferenze elettromagnetiche potrebbero causare un mal-
funzionamento del prodotto. Per utilizzare il prodotto in tali ambienti, all'utente potrebbe
essere richiesto di adottare le contromisure necessarie.
Il prodotto è designato per il seguente ambiente, definito nello standard EN61010-1.
- Categoria di sovratensione II
- Livello di inquinamento 2
● [SWE] Säkerhetsinformation
Se till att du läser denna handbok innan du börjar använda produkten för en korrekt och
säker användning av den. Spara sedan handboken på en säker och lättåtkomlig plats så
att du kan konsultera den när så behövs.
Innehållet i denna handbok kan komma att ändras utan föregående meddelande därom.
●Installationsmiljö
Detta produkten är ej avsedda för användning i industriella miljöer enligt riktlinjerna i
EN61326-1.
Om den används i industrimiljöer kan de elektromagnetiska störningarna orsaka tek-
niska fel hos produkten. Om produkten ska användas i sådana miljöer kan användaren
behöva vidta lämpliga åtgärder för att lösa dessa problem.
Produkten är utformad för användning i följande miljöer, i enlighet med SS-EN 61010-1.
- Överspänningskategori II
- Föroreningsgrad 2
VII
For Your Safety
●Entorno de instalación
Este producto está diseñado para su uso en entornos industriales, tal y como se define
en EN61326-1.
En un entorno industrial, las interferencias electromagnéticas pueden provocar un fun-
cionamiento incorrecto del producto. Para usar el producto en tales entornos, el usuario
debe tomar las medidas adecuadas.
El producto se ha diseñado para el siguiente entorno, definido en EN61010-1.
- Categoría de sobretensión II
- Nivel de contaminación 2
●Środowisko instalacji
Ten produkt nie są przeznaczone do użytkowania w środowisku przemysłowym, zgodnie
z definicją określoną w normie EN61326-1.
W środowisku przemysłowym zakłócenia elektromagnetyczne mogą powodować niepra-
widłowe działanie produktów. Możliwe, że aby użytkować produkt w takich środowi-
skach, użytkownik będzie musiał podjąć stosowne środki zaradcze.
Produkt jest przeznaczony do użycia w poniższym środowisku zdefiniowanym w normie
EN61010-1.
- Kategoria przepięciowa II
- Stopień zanieczyszczenia 2
VIII
For Your Safety
● [NLD] Veiligheidsinformatie
Lees deze handleiding voordat u dit product gebruikt zodat u het op de juiste manier en
veilig kunt gebruiken. Bewaar de handleiding goed zodat u hem wanneer nodig kunt
raadplegen.
De inhoud van deze handleiding kunnen zonder voorafgaande kennisgeving worden
gewijzigd.
●Installatieomgeving
Dit product is niet bedoeld voor gebruik in een industriële omgeving zoals gedefinieerd in
EN 61326-1.
In een industriële omgeving kan de elektromagnetische interferentie de werking van dit
product storen. Voor gebruik van het product in een dergelijke omgeving moet de gebrui-
ker mogelijk maatregelen treffen om de storing te verhelpen.
Het product is ontworpen voor de volgende omgeving, gedefinieerd in EN 61010-1.
- Overspanningscategorie II
- Vervuilingsgraad 2
● [JPN] 安全情報
ご使用にな る前に、 本書を必ずお読み く だ さ い。 お読みにな っ た後は必要な と き にす ぐ
に取 り 出せる よ う に大切に保管 し て く だ さ い。
本書に記載 さ れている内容は予告な く 変更 さ れる場合があ り ます。 あ らか じ めご了承 く
だ さ い。
●設置環境
本製品は、EN61326-1 で定義 さ れる工業環境で使用する こ と を想定 し た製品ではあ り ま
せん。
工業環境においては、 電磁妨害の影響を受ける可能性があ り 、 その場合には使用者が適
切な対策を講ずる こ と が必要 と な る こ と があ り ます。
本製品は、 EN61010-1 で定義 さ れる以下の環境用に設計 さ れています。
- 過電圧カ テ ゴ リ ー II
- 汚染度 2
IX
For Your Safety
● Safety precautions
This section provides precautions for using the product safely and correctly and to
prevent injury and damage. The terms of DANGER, WARNING, and CAUTION indicate
the degree of imminency and hazardous situation. Read the precautions carefully as it
contains important safety messages.
WARNING
CAUTION
Harmful chemicals
The internal solution of a pH electrode is highly concentrated potassium
chloride (3.33 mol/L KCl). If the internal solution comes in contact with the
skin, wash it off immediately. If it gets into the eyes, flush with plenty of water
and then consult a doctor.
Broken glass
Broken glass may cause injury. The outer tube and tip of an electrode are
made of glass. Handle them with care.
Do not use the RS-232C communication and the AC adapter under wet or
humid conditions. Otherwise, it may cause a fire, electric shock, or
breakage.
X
For Your Safety
●Battery
CAUTION
CAUTION
XI
Product Handling Information
・Do not drop, crash, or give any physical impact on the instrument.
・The instrument is made of solvent-resistant materials but that does not mean it is
resistant to all chemicals. Do not dip the instrument in strong acid or alkali solution, or
wipe with such solution.
・If the instrument is dropped into water or gets wet, wipe it using soft cloth. Do not heat
to dry it with a hair-dryer (or the like).
・When replacing the batteries with an AC adapter or a serial cable connected the
instrument does not have the dust-proof and waterproof performance. The dust-proof
and waterproof performance is maintained only when the covers are attached
correctly.
・After replacing the batteries with an AC adapter or a serial cable connected make sure
that the waterproof packing attached to each cover is not deformed or discolored, or
has foreign matter adhering to it. If the waterproof packing is deformed, discolored or
has foreign matter adhering to it, or dust could get inside, water leaks could occur that
could lead to instrument malfunction.
・To disconnect an electrode, AC adapter cable or serial cable, hold the connector and
pull it off. If you pull at the cable, it may cause a breakage.
・Do not replace the batteries in a dusty place or with wet hands while an AC adapter or
a serial cable is connected. Dust or moisture could get inside the instrument, possibly
causing instrument malfunction.
・Do not use the tip of a nail or an object with a sharp end to press the keys.
・If the power supply is interrupted while measurement data is being saved in the
instrument, the data could be corrupted.
XII
Product Handling Information
・A NiMH rechargeable battery can be used in this instrument, but the battery used in
the instrument cannot be charged using the AC adapter.
・When the battery has run out or the instrument will not be used for a long time, remove
the batteries.
・Of the specified battery types, make sure to use two batteries of the same type.
・Do not use a fully charged nickel-metal hydride battery together with a partially
charged battery.
● Transportation
When transporting the instrument, repackage it in the original package box. Otherwise, it
may cause instrument breakage.
● Disposal
・Standard solution used for the calibration must be under neutralized before the
disposal.
・When disposing of the product, follow the related laws and/or regulations of your
country for disposal of the product.
XIII
Manual Information
■ Manual Information
● Description in this manual
Note
This interprets the necessary points for correct operation and notifies the important
points for handling the product.
Reference
This indicates the part where to refer for information.
Tip
This indicates reference information.
XIV
Contents
■ Preface...................................................................................I
■ Regulations ..........................................................................II
■ For Your Safety.................................................................. VI
■ Product Handling Information......................................... XII
■ Manual Information ......................................................... XIV
Part Names and Basic Operation ....................................... 1
■ Names of each part .............................................................2
● Instrument....................................................................................2
● Identification of manufacturing date .........................................3
● Display .........................................................................................4
● Operation key ..............................................................................6
■ Basic operation....................................................................7
● Function layer..............................................................................7
● Changing the operation mode .................................................11
● Switching the displays .............................................................12
● Changing the measurement parameter ..................................13
● Using the backlight ...................................................................14
● Entering numeric values ..........................................................15
● Saving measurement data in the internal memory ................16
Measurement ...................................................................... 17
■ Preparation.........................................................................18
● Confirmation before starting measurement ...........................18
● Turning ON the instrument ......................................................19
● Connecting an electrode ..........................................................22
■ pH measurement ...............................................................23
● Setting the instrument ..............................................................23
● Performing calibration..............................................................27
XV
Contents
XVI
Contents
XVII
Contents
XVIII
Part Names and Basic Operation
This section describes the name of each part and the main role, function, and basic
operation method of each part.
1
Names of each part
2
Names of each part
JAN FEB MAR APR MAY JUN JUL AUG SEP OCT NOV DEC
A B C D E F G H J K L M
3
Names of each part
● Display
Two electrodes can be connected to measure two parameters at the same time with this
instrument. The display is divided into the main screen and the sub screen, and you can
select the channel displayed on the main screen. The selected channel can be identified
with an icon.
1
2 3
4
5 11
6
7 10
8
9
12
Main screen
2 2
13 14
6 11
10
12 14 Sub screen
8
4
Names of each part
5
Names of each part
● Operation key
6
Basic operation
■ Basic operation
● Function layer
The function layer of the data mode and setting mode is shown as below.
"dX" and "PXX" indicates the program number which is shown in the screen of the
instrument.
• Data mode
7
Basic operation
• Setting mode
<Channel 1>
8
Basic operation
<Channel 2>
9
Basic operation
10
Basic operation
Status icon
Measurement mode
key key
key key or
key
11
Basic operation
key
12
Basic operation
key
key
key key
key
13
Basic operation
key
Note
・ Turning on the backlight consumes energy and shortens battery life.
・ The backlight becomes unavailable when the battery level becomes low.
14
Basic operation
key
key
15
Basic operation
key
Note
If the data saved reaches 1000 data items, an error occurs and "ERR No. 0010" is
displayed. Copy or transfer necessary data to a PC and delete the data from the memory
("Deleting all saved data" (page 68)).
16
Measurement
This section describes the basic measuring method of each measurement parameter.
■ Preparation ................................................................................. 18
● Confirmation before starting measurement ..................................... 18
● Turning ON the instrument................................................................. 19
● Connecting an electrode .................................................................... 22
■ pH measurement........................................................................ 23
● Setting the instrument ........................................................................ 23
● Performing calibration ........................................................................ 27
● Performing measurement................................................................... 35
● Saving measured value ...................................................................... 36
■ Conductivity measurement....................................................... 40
● Setting the instrument ........................................................................ 41
● Performing conductivity calibration.................................................. 57
● Performing measurement .................................................................. 61
● Saving measured values .................................................................... 62
17
Preparation
■ Preparation
● Confirmation before starting measurement
・ Have you prepared the appropriate electrode for the measurement parameter?
⇒ If not, purchase the appropriate electrode.
・ Have you prepared the appropriate standard solution for the measurement parameter?
⇒ If not, prepare the standard solution according to your applications.
・ Are there any items that should not be wet or stained around the instrument?
⇒Depending on the operation during measurement, items around the instrument could
get wet or stained. Secure sufficient space around the instrument and perform
measurement while always paying attention to safety.
18
Preparation
Note
・ Do not replace the batteries in a dusty place or with wet hands. Dust or moisture could get
inside the instrument, possibly causing instrument malfunction.
・ Do not short-circuit a battery.
・ Set the + and side of the battery correctly.
・When the battery has run out or the instrument will not be used for a long time, remove the
batteries.
・ Of the specified battery types, make sure to use two batteries of the same type.
・ Do not use a new battery together with a used battery.
・ When using the Ni-MH batteries, do not use a fully charged battery together with an
insufficiently-charged battery.
19
Preparation
AC adapter jack
Note
・ Do not insert the cable with force when the connector does not match the jack.
・ When not using the AC adapter, close the AC adapter connector cover.
・ While the AC adapter is connected, the instrument does not have the dust-proof and
waterproof performance. Dust or moisture could get inside the instrument, possibly
causing instrument malfunction.
20
Preparation
key
Note
• Do not hold down the key after the power of the instrument is turned ON.
• Do not use the tip of nail or an object with a sharp end to press keys.
• "VER" indicates the version of the software. It may be revised when the software is
updated.
21
Preparation
● Connecting an electrode
To perform measurement, it is necessary use the appropriate electrode for measurement
parameters. Recommended electrodes for each measured sample are listed in our
product catalog and on our website. Refer to them when preparing electrodes. Use the
following procedure to correctly connect the electrode to the instrument.
Tip
If the temperature connector (T) is unconnected or connection is wrong, temperature
selected for MTC (manual temperature compensation) is displayed as the sample
temperature.
22
pH measurement
■ pH measurement
You can measure the pH of the sample with a pH electrode.
Use a combination electrode incorporating a glass electrode and a reference electrode
for measurement. A single glass electrode cannot be used with this instrument.
pH can be measured using channel 1 of the instrument.
23
pH measurement
In the case of "ATC", you can calibrate the temperature sensor (refer to "Calibrating
temperature sensor" (page 77)).
key key
key
3. In the case of "MTC", enter the temperature to be compensated for and press
the key to confirm.
Enter a
key number
key
24
pH measurement
key key
25
pH measurement
key
key key
key
Select "USA"
and press the
key
26
pH measurement
● Performing calibration
Calibration is necessary to measure pH accurately.
We recommend performing calibration once a day, before the first measurement.
According to the following procedure, perform calibration accurately.
Note
・ Perform two-point calibration using pH 7 and pH 4 when you know that the sample is
acidic; pH 7 and pH 10 when you know that the sample is alkaline.
・Perform three-point calibration using pH 4, pH 7, and pH 10 when the sample is unknown.
・ You can confirm the current calibration data in the setting mode and delete the calibration
data in the setting mode. (Refer to "Displaying the latest calibration and inspection data"
(page 70), "Deleting calibration data" (page 75).)
27
pH measurement
key Stabilized
key or
key
6. Perform the 2nd point calibration. As with the step 1., clean the pH electrode
and immerse it in the pH 4 standard solution. As with the step 3., immerse at
least 3 cm from the tip of the pH electrode.
7. Press the key to enter the calibration mode.
Stability judgment automatically starts and the pH icon blinks until the measured
value stabilizes. When the measured value stabilizes, the pH icon changes from the
blinking state to the lit state.
8. Then press the key or the key.
Calibration to the standard solution value at the measured temperature is performed.
The 2nd point calibration ends and "4" calibration history icon lights, indicating that
pH 4 calibration is complete.
Stabilized
key
28
pH measurement
key or
key
Tip
The order of calibration of the standard solution is optional.
In the above example, you can calibrate pH 4 first and then pH 7.
Note
• If calibration of any standard solution is performed again, only the value of calibrated
solution is updated. If calibration is repeated, only the calibration value of used standard
solution is updated. The calibration values are retained until next calibration is performed,
the data is deleted or buffer setting is changed. For the procedure for deleting the
calibration data, refer to "Deleting calibration data" (page 75).
• It is recommended that you should clear the previous calibration data before the
calibration in order to perform more accurate calibration.
29
pH measurement
• Inspecting repeatability
You can inspect repeatability using the pH 7 standard solution by returning to the
calibration screen after calibration and ends and pressing the key. Measure the pH 7
standard solution by using the calibrated electrode to display the absolute value of the
difference between the measured value and standard solution value.
In order to inspect repeatability, you need to perform calibration of the pH 7 standard
solution with either "USA" or "NIST" set as the standard solution.
5. Make sure that the pH icon lights while the pH electrode is immersed in the
standard solution.
Stability judgment starts and the pH icon blinks. When the value is stabilized, the pH
icon changes from the blinking state to the lit state and the display is fixed to the
measured value at the stable time.
30
pH measurement
Stabilized
key
key
31
pH measurement
key Stabilized
key
32
pH measurement
key or
Enter a
number key
key Stabilized
key
33
pH measurement
key or
Enter a
number key
Note
• If calibration of any standard solution is performed again, only the value of calibrated
solution is updated. If calibration is repeated, only the calibration value of used standard
solution is updated. The calibration values are retained until next calibration is performed
or the data is deleted. For the procedure for deleting the calibration data, refer to "Delet-
ing calibration data" (page 75).
• It is recommended that you should clear the previous calibration data before the
calibration in order to perform more accurate calibration.
34
pH measurement
● Performing measurement
You can perform measurement in the measurement mode by immersing the pH
electrode in the sample. You can use the automatic hold function to judge the stability of
the measured value. The automatic hold function has two modes, the auto stability mode
and the auto hold mode. For the instruction to set the mode, refer to "Setting the auto
stability and auto hold function" (page 79).
35
pH measurement
Stabilized
Note
・ The criteria of stability judgment in the auto hold measurement are as follows.
Potential variation for 10 seconds is less than 1 mV (0.015 pH equivalent) and
temperature variation is less than 2.0°C
・ If the measured value is below the display range, "Ur" (under) appears. If the measured
value is above the display range, "Or" (over) appears. For details on the action to take,
refer to "The measured value is out of the measurement range" (page 107).
36
mV, ORP measurement
The default mode is the absolute value measurement mode. Pressing the key
switches to the relative value measurement mode. Pressing the key again returns to
the absolute value measurement mode.
key
37
mV, ORP measurement
● Performing measurement
You can perform measurement in the measurement mode by immersing the pH
electrode in the sample. Also, you can use the automatic hold function to judge the
stability of the measured value. The automatic hold function has two modes, the auto
stability mode and the auto hold mode. For how to set the mode, refer to "Setting the
auto stability and auto hold function" (page 79).
Stabilized
38
mV, ORP measurement
Note
• The criteria of stability judgment in the automatic hold measurement are as follows.
Potential variation for 10 seconds is less than 1 mV and temperature variation is less than
2.0°C
• If the measured value is below the display range, "Ur" (under) appears. If the measured
value is above the display range, "Or" (over) appears. For details on the action to take,
refer to "The measured value is out of the measurement range" (page 107).
• Note that when measuring the ORP of a sample solution that has extremely low
concentrations of oxidants and reductants (such as tap water, well water, or water treated
with purifying equipment), there may be less responsiveness and repeatability in general.
• If alkaline water is left, its ORP value changes considerably. Always measure alkaline Ion
water promptly.
39
Conductivity measurement
■ Conductivity measurement
The conductivity cell can be used to measure the conductivity, salinity, TDS, and
resistivity of a sample. Salinity, TDS, and resistivity are calculated from the measured
value of conductivity.
Press the key to select the measurement parameter (refer to "Changing the
measurement parameter" (page 13)).
Conductivity can be measured using channel 2 of the instrument. Press the keys to
set the main screen to channel 2.
The basic steps are the same for all measurement parameters, however, some settings
and operations are only valid for specific measurement parameters. Select the settings
and perform the steps that show the mark of the parameter you want to measure.
: Conductivity measurement
: Salinity measurement
: Total dissolved solids measurement
: Resistivity measurement
: All measurement parameters
40
Conductivity measurement
key key
key
41
Conductivity measurement
3. In the case of "MTC", enter the temperature to be compensated for and press
the key to confirm.
key
Enter a
number key
42
Conductivity measurement
key key
key key
43
Conductivity measurement
4. Press the keys to select the unit and press the key to confirm selection.
key key
key
Select "S/cm"
and press the
key
44
Conductivity measurement
key key
key key
45
Conductivity measurement
4. Press the keys to select the unit and then press the key to confirm
selection.
key
key
46
Conductivity measurement
key key
47
Conductivity measurement
4. Press the keys to select the digit number of the cell constant of the
conductivity cell and then press the key.
key
key key
key
Select "1.0"
and press the
key
Enter a
number key
48
Conductivity measurement
Note
・ The unit used for the cell constant corresponds to the unit set in "Setting the conductivity
unit (default: S/cm)" (page 43).
・ When the cell constant is changed through the cell constant setting, all the previous
calibration data is deleted.
・ Match the unit indicated on the conductivity cell to the unit set in the instrument.
10 m-1 ⇔ 0.1 cm-1 100 m-1 ⇔ 1 cm-1 1000 m-1 ⇔ 10 cm-1
49
Conductivity measurement
key key
key key
4. Press the keys to enter the temperature coefficient and then press the
key to confirm.
Enter a
key
number
50
Conductivity measurement
Note
・ The temperature coefficient varies by sample. Before using the temperature conversion
function, always check the temperature coefficient of the sample and set it in the
instrument.
・ When the temperature conversion function is used with automatic temperature
measurement (ATC), deviations may occur within the accuracy of the temperature sensor.
For more accurate measurement, set the temperature setting to manual temperature
display (MTC), and measure using a temperature controlled bath.
51
Conductivity measurement
key
4. Press the keys to enter the reference temperature and then press the
key to confirm.
Temperature can be selected from 15°C to 30°C.
Enter a
key
number
52
Conductivity measurement
key key
key key
53
Conductivity measurement
4. Press the keys to select the TDS method and then press the key.
5. When selecting "LINEAR", enter the factor and then press the key to
confirm.
key
key key
key
Selected
"LINEAR"
and press Enter a
the key number
key
54
Conductivity measurement
key key
55
Conductivity measurement
4. Press the keys to select the salinity calculation method and then press
the key to confirm.
key
key
56
Conductivity measurement
•Automatic calibration
1. Clean the conductivity cell with pure water (or
deionized water) and wipe it with filter paper
or tissue paper.
Do not touch the black electrode part.
Refer to the instruction manual of the conductivity
cell for how to clean the conductivity cell.
2. Immerse the conductivity cell in the standard
solution.
Make sure the hole at the upper part of the cell is
immersed.
3. Press the key to enter the calibration
mode.
Stability judgment starts and the COND icon
blinks. When the measured value stabilizes, the
COND icon changes from the blinking state to
the lit state.
4. Press the key or the key.
The 1st point calibration ends and the calibration history icon corresponding to the
calibration range lights, indicating that 1st point calibration is complete.
The display returns to the measurement screen.
key Stabilized
key or
key
57
Conductivity measurement
Note
In automatic calibration, the measured value of a standard solution that is not at 25°C is
always converted to 25°C with 2.00%/°C temperature coefficient.
58
Conductivity measurement
•Manual calibration
1. Clean the conductivity cell with pure water (or
deionized water) and wipe it with filter paper
or tissue paper.
Do not touch the black electrode part.
Refer to the instruction manual of the conductivity
cell for how to clean the conductivity cell.
2. Immerse the conductivity cell in the standard
solution.
Make sure the hole at the upper part of the cell is
immersed.
3. Press the key to enter the calibration
mode.
Stability judgment starts and the COND icon
blinks. When the measured value stabilizes, the
COND icon changes from the blinking state to
the lit state.
4. Press the keys to enter the electrical conductivity value of the
standard solution used for calibration at the measured temperature.
5. Press the key or the key.
Calibration to the set standard solution value at the measured temperature is
performed. The 1st point calibration ends and the calibration history icon
corresponding to the calibration range lights, indicating that 1st point calibration is
complete.
The display returns to the measurement screen.
59
Conductivity measurement
key Stabilized
Enter a
key number
key
Note
The calibration for TDS, salinity, and resistivity is performed with the result of the calibration
of conductivity. When pressing the key to enter the calibration mode for TDS, salinity,
and resistivity, "CAL in COND" is displayed. It indicates that performing conductivity
calibration is recommended.
60
Conductivity measurement
● Performing measurement
Immerse the conductivity cell in a sample to perform measurement. Auto stability mode
and auto hold mode are available to judge the stability of the measurement value.
For details of settings, refer to "Setting the auto stability and auto hold function" (page
79).
Stabilized
Note
・ The criteria of stability judgment in the auto stability mode and auto hold mode are as
follows.
Conductivity: Display value change for 10 seconds is less than 3 digit and temperature
change is less than 2.0°C.
Salinity: Display value change for 10 seconds is less than 1.0 PPT (0.1%) and
temperature change is less than 2.0°C.
TDS: Display value change for 10 seconds is less than 30 mg/L and
temperature change is less than 2.0°C.
Resistivity: Display value change for 10 seconds is less than 3 digit and temperature
change is less than 2.0°C.
・ If the measured value is above the display range, "Or" (over) appears. For details on the
action to take, refer to "The measured value is out of the measurement range" (page 107).
61
Conductivity measurement
62
Using Various Functions
This section describes functions available in this instrument.
■ Data functions.......................................................... 64
● Displaying saved data......................................................................... 64
● Using the automatic data save........................................................... 65
● Deleting all saved data........................................................................ 68
■ Measurement setting............................................... 70
● Displaying the latest calibration and inspection data ..................... 70
● Changing the calibration method ...................................................... 73
● Using the calibration interval alarm (default: OFF) .......................... 74
● Deleting calibration data..................................................................... 75
■ General settings....................................................... 79
● Setting the auto stability and auto hold function ............................. 79
● Changing the automatic power off setting (default: 30 min)........... 81
● Resetting to factory default settings ................................................. 83
● Setting the date and time.................................................................... 85
● Performing test printing of the printer unit....................................... 87
63
Data functions
■ Data functions
● Displaying saved data
You can display the data saved in the internal memory.
key
key key
key
key
To return to the measurement mode, press the key and then press the key.
64
Data functions
key key
65
Data functions
Enter a
key number
Enter a
key number
key
66
Data functions
6. Pressing the key starts saving the data (when the setting is "ON").
Pressing the key again stops the data saving process. During automatic data
saving measurement, data is displayed for one second each time a measurement
takes place. When more than 1000 data items are saved, "ERR No. 0010" is
displayed and data saving is stopped. When you delete the data, the error is cleared
(refer to "Deleting all saved data" (page 68)).
When data is
key saved
67
Data functions
key
2. Press the keys to select "DATA CLR" (delete saved data) and then press
the key to confirm.
68
Data functions
3. Select "YES" to delete the saved data, or select "NO" to cancel deleting it. And
then press the key to confirm.
When "YES" is selected, "END" appears after deletion is complete.
key key
Select "YES"
and press the
key
69
Measurement setting
■ Measurement setting
● Displaying the latest calibration and inspection data
You can display the latest calibration data and repeatability inspection data.
key key
70
Measurement setting
3. Press the keys to select "CAL DATA" (display calibration data) and then
press the key.
The electrode status based on the calibration result is displayed. You can change the
display item among "OFS" (asymmetry potential) to SLP (sensitivity) to REP
(repeatability) by pressing the keys.
key
key
key
key
key
To return to the measurement mode, press the key and then press the key.
Tip
• The asymmetry potential can be displayed only for pH calibration data.
• When multiple point calibration (more than two points) is performed, the results of multiple
point calibration are displayed.
71
Measurement setting
key
key key
key
To return to the measurement mode, press the key and then press the key.
72
Measurement setting
1. Press the key to enter the setting mode when "COND" icon is shown on the
main screen.
2. Press the keys to select "COND" (conductivity setting) and then press the
key.
3. Press the keys to select "AUTO CAL" (automatic calibration setting) and
then press the key.
4. Select "ON" to set the automatic calibration, or select "OFF" to set the manual
calibration. And then press the key to confirm.
key key
Select "ON"
and press the
key
73
Measurement setting
1. Press the key to enter the setting mode when "pH" icon is shown on the
main screen.
2. Press the keys to select "pH" (pH setting) and then press the key.
3. Press the key to select "CAL ALR" (calibration alarm setting) and then
press the key.
key key
key key
4. Enter the setting period of the calibration interval alarm and then press the
key.
The setting range is 1 day to 400 days.
Enter a
number key
74
Measurement setting
key key
key key
75
Measurement setting
4. Select "YES" to delete the calibration data, or select "NO" to cancel deleting it.
And then press the key to confirm selection.
When "YES" is selected and is pressed, "END" appears after deletion is
complete.
key
Select "YES"
and press the
key
76
Temperature settings
■ Temperature settings
● Calibrating temperature sensor
The temperature sensor or temperature compensation electrode in the combination
electrode has ±1°C accuracy without calibration. You can use a known temperature
solution to calibrate the temperature sensor.
1. Insert the temperature connector into the jack of temperature connector (T) on
the instrument.
2. Immerse the electrode into the solution until the temperature sensor is
immersed.
3. Press the key to enter the setting mode when the channel which is
connected to the temperature sensor to calibrate is active.
4. Press the keys to select "TEMP" (temperature calibration setting) and
then press the key.
key key
77
Temperature settings
key
Enter a
number key
Note
When initializing temperature calibration data, all settings need to be initialized. Perform
initialization by referring to "Resetting to factory default settings" (page 83). When
initialization is performed, all saved data is deleted. Copy or transfer necessary data to a
PC for storage.
78
General settings
■ General settings
● Setting the auto stability and auto hold function
This instrument has auto stability mode and auto hold mode.
• Setting procedure
1. Press the key to enter the setting mode.
2. Press the keys to select "GEN" (general setting) and then press the
key.
3. Press the keys to select "MEAS" (measurement setting) and then press
the key.
key key
key key
Note
The general setting is common in both CH1 and CH2.
79
General settings
4. Select "AS" to set the auto stability, or select "AH" to set the auto hold. And
then press the key to confirm selection.
Select "AS"
and press
key key
Tip
The stability judgment criteria are the same for both the auto stability mode and the auto
hold mode.
80
General settings
key key
key key
3. Press the keys to select "AUTO OFF" (automatic power off setting) and
then press the key.
81
General settings
4. Enter the automatic power off time and press the key.
The setting range is 0 min to 30 min.
"0" indicates the automatic power off is "OFF."
Enter a
key number
key
82
General settings
key key
key key
3. Press the keys to select "RESET" (initialize) and then press the key.
83
General settings
4. Select "YES" to initialize the settings to the factory default settings, or select
"NO" to cancel initialization. And then press the key to confirm selection.
When "YES" is selected, "END" appears after the settings are initialized and then the
instrument is automatically powered OFF.
key key
Select "YES"
and press the
key
Power OFF
84
General settings
key key
key key
85
General settings
3. Press the keys to select "DATE" (date and time setting) and then press
the key.
4. Enter "YEAR" (current year) and press the key.
5. In the same way, set "MONTH" (month), "DAY" (date) and "TIME" (hour and
minute), in that order.
6. Press ● key to confirm.
key key
Enter a Enter a
number and number and
press key press key
Enter a Enter a
number and number and
press key press key
86
General settings
key key
key key
87
General settings
3. Press the keys to select "PRINT" (test print) and then press the key.
Printing starts automatically. When printing ends, the printer icon lights and "END"
appears. Press the key or the key.
key Printed
key or
key
88
Other settings
■ Other settings
● Printing measured values and calibration data
Print out the measured value or calibrated value displayed on the instrument, or the
measurement data or the calibration data saved in the instrument. If the repeatability is
inspected, the inspection data is printed out with the calibration data.
Pressing the key starts printing during displaying the data you want to print. Use the
printer cable to connect the printer unit with the instrument beforehand. If the automatic
data memory is set to "ON", you cannot print out in the measurement mode.
Reference
For details of how to display measurement data and calibration data, refer to the respective
section.
"Displaying saved data" (page 64)
"Displaying the latest calibration and inspection data" (page 70)
Refer to the following table for the pH (two point calibration) and conductivity.
89
Other settings
90
Other settings
91
Other settings
Tip
The conductivity range marked with "0" (Ex. oR1) indicates calibrated conductivity range.
92
Other settings
Note
・ If you are not using the RS-232C communication, close the connector cover tightly.
・ While using the RS-232C communication, the instrument is not dust-proof or waterproof.
Do not use the RS-232C communication in a dusty place or with wet hands.
93
Other settings
・ Make sure that the transfer formats used in the instrument and a PC are the same.
When different transfer formats are used, a communication error occurs and the
online mode does not start up, and as a result RS-232C communication cannot be
performed. Also, when the transfer format is changed, turn OFF the power of the
instrument and PC and then reboot them.
Note
・ If you are not using the RS-232C communication, close the connector cover tightly.
・ While using the RS-232C communication, the instrument is not dust-proof or waterproof.
Do not use the RS-232C communication in a dusty place or with wet hands.
94
Maintenance
Maintenance
This section describes maintenance of the instrument and the electrodes that are used
with the instrument. To use them for a long period, perform the described maintenance
procedures appropriately.
・ The instrument is made of solvent resistant materials but that does not mean it is
resistant to all chemicals. Do not dip the instrument in strong acid or alkali solution, or
wipe it with such solution.
・ Do not wipe the instrument with a polishing powder or other abrasive compound.
95
Maintenance
1. Clean the electrode well with pure water (or deionized water) to remove sample
completely, and close the internal solution filler port.
2. Clean inside of the protective cap with pure water (or deionized water), then
add enough pure water (or deionized water) to soak the sponge.
3. Attach the protective cap.
96
Maintenance
1. Clean the electrode well with pure water (or deionized water) to remove sample
completely, and close the internal solution filler port.
2. Clean inside of the protective cap with pure water (or deionized water), then
add enough pure water (or deionized water) to soak the sponge.
3. Attach the protective cap.
97
Maintenance
98
Maintenance
99
MEMO
When an error message appears
101
When an error message appears
102
When an error message appears
103
When an error message appears
104
Troubleshooting
■ Troubleshooting
This section describes causes and actions to take for problems that customers
frequently ask us.
105
Troubleshooting
106
Troubleshooting
107
Troubleshooting
108
Main specifications
Appendix
This section describes the specifications of the instrument, default settings,
measurement principles, and other technical information.
Options for the instrument are also described.
■ Main specifications
Item Description
Model LAQUAact-PC110
Brand (pet name) LAQUAact
Series name Portable pH Water Quality Meter
Model description pH/ORP/Conductivity Meter
Measurement
pH, mV (ORP), conductivity, salinity, TDS, resistivity, temperature
parameters
Operating ambient 0°C to 45°C
temperature, humidity 80% or less in relative humidity (no condensation)
AAA alkaline batteries (LR03) or AAA Ni-MH rechargeable
Power batteries × 2
AC adapter 100 V to 240 V, 50/60 Hz, 0.37 A (option)
Approx. 67 [80] (W) × 170 (D) × 28 [42] (H) mm
Dimensions
(The figures in square bracket are maximum thicknesses.)
Mass Approx. 285 g (without batteries)
Measurement
Item Description
parameter
Measuring principle Glass electrode
Display range pH 2.00 to pH 16.00
pH Measuring range pH 0.00 to pH 14.00
Resolution 0.01 pH
Accuracy ±0.01 pH
Measuring range ±2000 mV
Resolution 1 mV
mV (ORP)
1 mV or 1% of the read value,
Accuracy
whichever is greater
Measuring principle Thermistor method
Display range 30.0°C to 130.0°C
Temperature Measuring range 0.0°C to 100.0°C
Resolution 0.1°C
Accuracy ±0.4°C
109
Main specifications
Measurement
Item Description
parameter
Measuring principle 2 AC bipolar method
Cell constant 1 cm-1: 0.00 S/cm to 200.0 mS/cm
Measuring range
(Display range) Cell constant 0.1 cm-1: 0.000 S/cm to 20.00 mS/cm
Cell constant 10 cm-1: 0.0 S/cm to 2.000 S/cm
Conductivity
Resolution 0.05% of full scale
±0.6% of full scale
Accuracy
(18.0 mS/cm to 200.0 mS/cm: ±1.5% of full scale)
Repeatability ±0.6% of full scale
Measuring principle Conversion from conductivity value
Measuring range 0.00% to 10.00%
Salinity (Display range) (0.0 ppt to 100.0 ppt)
Accuracy ±0.2% of full scale
Resolution 0.01% (0.1 ppt)
Measuring principle Conversion from conductivity value
Measuring range 0.00 mg/L to 100 g/L
TDS (Display range) TDS factor: 0.40 to 1.00
Accuracy ±0.1% of full scale
Resolution 0.01 mg/L
Measuring principle Conversion from conductivity value
Cell constant 1 cm-1: 0.000 kΩ·cm to 20.00 MΩ·cm
Measuring range
(Display range) Cell constant 0.1 cm-1: 0.00 kΩ·cm to 200.0 MΩ·cm
Cell constant 10 cm-1: 0.0 Ω·cm to 2.000 MΩ·cm
Resistivity
Resolution 0.05% of full scale
±0.6% of full scale
Accuracy
(1.80 MΩ·cm to 20.00 MΩ·cm: ±1.5% of full scale)
Repeatability ±0.5% of full scale ±1 digit
Tip
Accuracy is the difference between the measured value and the simulation value when the
simulation value is inputted to the instrument.
110
Main specifications
Cell constant
Range
1000 m-1 100 m-1 10 m-1
20.0 to 200.0 S/m
2.00 to 19.99 S/m
0.200 to 1.999 S/m
20.0 to 199.9 mS/m
2.00 (0.00) to 19.99 mS/m
0.200 (0.000) to 1.999 mS/m
0.0 to 199.9 µS/m
・ Unit: S/cm
Cell constant
Range
10 cm-1 1 cm-1 0.1 cm-1
0.200 to 2.000 S/cm
20.0 to 199.9 mS/cm
2.00 to 19.99 mS/cm
200 to 1999 µS/cm
20.0 (0.0) to 199.9 µS/cm
2.00 (0.00) to 19.99 µS/cm
0.000 to 1.999 µS/cm
Cell constant
Range
10 cm-1 1 cm-1 0.1 cm-1
200.0 to 2000 mS/cm
20.00 to 199.9 mS/cm
2.000 to 19.99 mS/cm
0.200 (0.000) to 1.999 mS/cm
0.020 (0.000) to 0.199 mS/cm
0.002 to 0.019 mS/cm
0.000 to 0.002 mS/cm
111
Main specifications
Cell constant
Range
10 m-1 100 m-1 1000 m-1
0.200 to 2.000 MΩ·m
20.0 to 199.9 kΩ·m
2.00 to 19.99 kΩ·m
0.200 to 1.999 kΩ·m
20.0 (0.0) to 199.9 Ω·m
2.00 (0.00) to 19.99 Ω·m
0.000 to 1.999 Ω·m
・ Unit: Ω·cm
Cell constant
Range
0.1 cm-1 1 cm-1 10 cm-1
20.0 to 199.9 MΩ·cm
2.00 to 19.99 MΩ·cm
0.200 to 1.999 MΩ·cm
20.0 to 199.9 kΩ·cm
2.00 (0.00) to 19.99 kΩ·cm
0.200 (0.000) to 1.999 kΩ·cm
0.0 to 199.9 Ω·cm
112
Instrument default settings
113
Technical note
■ Technical note
● pH standard solutions at various temperatures
Tip
The differences between NIST and USA standard solutions are a different pH7 value, and
the use of pH10 standard solution instead of pH9 standard solution in USA.
Note
Calibration is performed using Nernst's equation with the above values.
114
Technical note
115
Options
■ Options
A wide variety of electrodes and options are available for use with the instrument. You
can select the optimum electrode and options for your application and objectives.
These options can be purchased from your nearest agency. Please provide the part
name and part number to the representative.
With regard to electrodes, it is important to select the optimum electrode for the sample
you want to measure. For details, refer to the catalogue or our website, or contact your
dealer.
⑤ U.K., ⑥ USA,
① Australia ② China ③ Europe ④ Korea
Singapore Canada, Taiwan
116
31, Miyanonishi-cho, Kisshoin Minami-ku, Kyoto 601-8306, Japan
http://www.horiba-adt.jp
For any questions regarding this product, please contact your local agency, or inquire from the
following website.
http://global.horiba.com/contact_e/index.htm