Chapter 2 CHM138
Chapter 2 CHM138
SUPPORT TEAM:
Norain Isa
Ainnie Rahayu Abdullah
Rohana Atan
2.1 Symbol, chemical formula and naming of
elements, molecules and compounds.
2.2 Definitions of atom, ion, molecule, compound,
atomic mass, formula mass.
2.3 Avogadro’s constant, mole concept, calculations of mass
- mole conversions.
2.4 Calculations on compositions, empirical and molecular
formulas.
2.5 Balancing chemical equations.
2.6 Stoichiometric calculations and Limiting reactants.
Lesson outcomes
At the end of this chapter, students will be able to:
Molecules
the smallest, discrete units that retain the
composition and chemical characteristics of an
element or compound.
• same element / different element combined
chemically.
• Example : hydrogen gas (H2), ozone (O3),
hydrochloric acid (HCl), methane (CH4).
Atom
• smallest particle of an element that gives the
characteristic properties of that element.
• Example :
Iron (Fe), Aluminium (Al), Sulphur (S)
Example:
Electrons < protons : cation (+ve charged ion)
Mg – 2e Mg 2+
Charges on ion +1 -2
Number of ions 2 1
Formula Na2CO3
b) Aluminium oxide
aluminium ion oxide ion
Al3+ O2-
Charges on ion +3 -2
Number of ions 2 3
Formula Al2O3
Ionic compounds:
Forming chemical formulas from valency
By knowing the valency of elements we can determine the
formula of compounds.
Example:
Give formulas & names: Ca & I, O & Mg, Na & S
Ca(OH)2
CuSO4
NH4NO3
Co2(CO3)3
Naming covalent compounds
1 mono -ide ending, each element has “prefix”
2 di • prefix refers to # of atoms - not valency
3 tri N2O4 = dinitrogen tetroxide
4 tetra • Exception: drop mono for first element
CO2 = carbon dioxide
5 penta
• The first vowel is often dropped to
6 hexa avoid the combination of “ao” or “oo”.
7 hepta CO = carbon monoxide (monooxide)
8 octa P4O10= tetraphosphorus decoxide
SO2= sulfur dioxide (doxide)
9 nona
• Example: Name the compounds:
10 deca CCl4, P2O3, IF7
Naming covalent compounds (contd):
further examples
CCl4
P2O3
IF7
Name these compounds:
Al2O3
CsF
K2O
Fe2O3
CuBr
SnO2
PbSO4
Mg3(PO4)2
KClO
Na2CrO4
N2O
SeBr4
B2O3
Atomic mass, molecular mass, molar
mass and formula mass
RMM =
Mass of 1 molecule/ formula unit of a compound
1/12 mass of one atom of carbon -12
Molar Mass (MM)
- The mass of 1 mole of substance in grams.
- The MM is always numerically equal to its formula
weight.
- MM CO2 = 44 g / mol
(a) Na2B4O7.10H2O
FORMULAS:
• Mol substance = Mass (gram) of substance
Molar mass of substance (g mol-1)
i) 13.5 g NH3
ii) 3.01 x 1023 molecules of S8
iii) 5.72 g oxygen gas
% Composition =
mass of the element in 1 mol of compound x 100
molar mass of compound
a) NaHCO3
b) P4O10
Chemical Formulas: Empirical & Molecular
Formulas
Chemical Formula
chemical composition that contains symbols of
elements in certain ratios.
Eg.
Empirical formula – formula which shows the
simplest possible whole number ratios of all
the atoms in a compound.
MASS PERCENT
OF ELEMENT
Assume 100g sample
CALCULATE THE
MASS OF EACH
CALCULATE THE
MOLES OF EACH
Calculate molar ratio
for each
Chemical reaction
• chemical changes whereby materials change from a
beginning mass to resulting substances. New
material(s) are made, along with the disappearance
of the mass that changed to make the new.
E.g. 4Fe + 3O2 2Fe2O3
Balancing chemical equations
1. Identify all reactants and products and write their
correct formula on the left side and right side of
equation.
2. Begin balancing the equation by trying suitable
coefficients that will give the same number of each
element on both sides of the equation.
3. Look for the elements that appear only once on each side
of the equation and with equal number of atoms on each
side – the formula containing these elements must have
the same coefficient.
4. Look for elements that appear only once on each side of
the equation but in unequal no of atoms. Balance these
elements. Next, balance elements that appear in two or
more formula on the same side of the equation. If a
reactant or product exists as a free elements, try
balancing that element last.
5. Check your balanced equation to be sure that you have
the same total number of each type of atom on both
sides of the equation.
Example
Balance the equations below:
a) Na + H2O NaOH + H2
-3
Concentration (g dm ) =
molarity (mol dm-3) x molar mass (g mol-1)
Answer: 0.6 M.
Example
How many grams of Mg(NO3)2 are required to prepare 50 cm3
of 0.55 M Mg(NO3)2 solution?
Answer: 4.07 g
Example
where:
M1 = Molarity (M) of the concentrated solution
M2 = Molarity (M) of the diluted solution
V1 = Volume (cm3 or dm3) of concentrated solution
V2 = Volume (cm3 or dm3) of diluted solution
Example
X = 0.48g
(b) How many moles of NO will be formed in
the above reaction?
Titration
procedure in which two reactants in a solution are made to
react in their stoichiometric proportions as indicated in a
balanced chemical equation.
Example:
VA cm3 of solution A of unknown concentration is transferred to a flask. A
solution B of known concentration, MB, is added carefully from a burette until
the reaction of A with B is just complete. This is called the equivalence point of
the titration.
Excess reagent
• other reactants, present in quantities greater than that
needed to react with the quantity of the limiting reagent
present in the reaction.
Percent Yield
Theoretical Yield
maximum amount of product that can be formed from calculated
stoichiometric relations in a chemical reaction.
Actual Yield
actual amount of product that can be obtained from a chemical
reaction.
A + B product
Mol A Mol
X Mol ratio of product / A = product The smallest
mol of product,
means, A or B
is the limiting
reactant.
Mol
Mol B X Mol ratio of product / B = product
Exercise
1) 15.00g aluminum sulfide and 10.00g water react
until the limiting reagent is used up. The balanced
equation for the reaction:
b) 500g
SUMMARY
Q & A SESSION
Thank you