Beverage

Beverage Consumers expect their beverages to look good, smell good and taste good. This is the basis of beverage quality, the major determining factor for beverage sales. Activated carbon is an agent for keeping things clean such as removing unwanted contaminants from fruit juices, juice concentrates, wine, malt beverages, and distilled liquor. Dedicated products ensure that essential ingredients such as water, CO2 and sugar are purified to fulfill the most stringent quality criteria. Activated carbon can be used for everything from the removal of bad tastes and odors to the provision of long term color stability to the removal of disinfectants and their degradation products from water.

The technology behind a myriad of drinks

The results for you?
With Norit activated carbon you will find the best fit for your purification needs and overall improvement in the efficiency of your operation and in the final quality of your product.

Beverage

Safety and Purity

Norit represents safety and consistent quality. Our activated carbons have a reputation that dates back more than 90 years. This reputation is underlined by the fact that all our manufacturing and reactivation facilities are ISO certified. Quality assurance is built into the stringent quality processes for manufacturing and handling from raw materials, entirely of vegetable origin, to safe means of

Worldwide
activation to product delivery and dosing Norit food grade products are regularly tested against standards including the U.S. Food Chemicals Codex. For the food industry, HACCP (Hazard Analysis and Critical Control Points) is a key factor to the quality and safety of our products. The principles of HACCP are implemented for the production and supply of our food grade activated carbons. They are produced entirely from raw materials of vegetable origin at our plants around the world.

Target Impurities
Activated carbons are used in a wide range of processes, to remove widely differing impurities, mostly of organic nature. The optimal treatment technology for your process depends on the nature and concentration of the impurities to be removed. For effective adsorption, the pore size must roughly match the size of the molecules of the impurities. Knowing what impurities have to be removed is the key to selecting the optimal activated carbon grades with proven ability to adsorb identical or similar compounds. Thus, activated carbon actually removes the impurity, unlike oxidative bleaching operations in which the colored impurity is only changed to colorless products. In the case of reducing disinfectants in water, such as chlorine and ozone by GAC, other physical properties such as particle size, shape and hardness are of major importance for the selection. When both adsorption of organic matter and de-chlorination/de-ozonation of feed water is required, a good balance between both adsorptive and other important physical properties must be achieved.

PROTEINS

Usually very large, found in many natural products

DARK COLORANTS (TYPICALLY DARK BROWN) MEDIUM SIZE COLORANTS (TYPICALLY LIGHT BROWN/GOLDEN) NATURAL PIGMENTS

Present initially or formed during processing Present initially or formed during processing

Responsible for many color impurities

OFF-TASTE

Present initially or formed during processing

How does activated carbon work?

Purification by activated carbon is a proven, modern, state-of-the-art technology for a multitude of purification needs. Nevertheless, the principles behind activated carbon have a rich history. The ancient Greeks described the use of charcoal to reduce the effects of food poisoning. And at the time of Columbus, sailors used to blacken the insides of water barrels with fire. They had learned that the water would stay fresh much longer by doing so. The beneficial behavior of carbonized materials is caused by the phenomenon that contaminants, organic compounds in most cases, tend to accumulate on surfaces - a process commonly referred to as adsorption. The purifying function of activated carbon is based upon the same principle of adsorption onto carbonized materials. It is the nature of the surface that makes adsorption occur but, in activated carbon, it is the sheer size of surface that makes it so highly effective - the size of the surface activates the carbon. The surface area of activated carbon is impressive, ranging from 500 to 1500 m2/g or even more. This means a teaspoon of activated carbon easily equals the surface area of a soccer field. The surface area is created during the activation process. The most common process is steam activation. At around 1000 C steam molecules selectively burn holes into the carbonized raw material, thus creating a multitude of pores inside the carbonaceous matrix. In chemical activation, phosphoric acid is used to build up such a porous system at a lower temperature. The prime application of activated carbon is in purification. It is the vast porous structure in a carbonaceous matrix that allows activated carbon to adsorb unwanted contaminants from liquid and gas flows, in a cost-effective way. Next to adsorption, activated carbon acts as an active reagent in the presence of oxidative disinfectants such as chlorine and ozone when percolated with water. Under such circumstances, the oxidants are reduced at the activated carbon.

LIGHT COLORANTS (TYPICALLY YELLOW) COLOR PRECURSORS

Present initially or formed during processing Responsible for color re-appearance during storage of finished products

MYCOTOxINS (E.G. PATULIN)

Formed by blue mold rot of apples

ODOR COMPOUNDS

Small, relatively volatile compounds

TRIHALOMETHANES (THM)

Very small degradation products from disinfection of water using chlorine

OH

H C C C C C O F F F CI

H C CI CI

C O

Patulin
C C C O OH O C C C C C NH C

THM
OH O

C C C C C C

O C C CH3

Ochtratoxin-A

CI

Beverage

PAC or GAC?
Two types of activated carbon are used in basic treatment technology: (1) Powdered Activated Carbon (PAC) and (2) Granular Activated Carbon (GAC). The type you select (sometimes you use both) depends on the answers to questions such as: Does the purification plant run continuously? Are there feasible possibilities for regenerating spent carbon? Does the process require a typical batch purification? and odor improvements. You never need to force fit a Norit product! GAC, particle size 0.54 mm, is typically used in processes running continuously. The process can be designed on an optimum service life basis for which downtime can be eliminated during change-out or regeneration. The regeneration option is one of the key benefits of GAC as, following regeneration, the GAC can be re-used in its original application. The regeneration process is either in situ or off-site; In situ: in specific cases, the exhausted GAC is regener ated in situ with steam or caustic soda; further, some large volume industries have in-situ thermal reactivation plants Off-site: the exhausted GAC is regenerated by thermal reactivation; Norit Activated Carbon provides this service from a network of dedicated plants in Europe Contact us for further information on carbon regeneration.

Purity of activated carbon

Activated carbon is used to purify a process flow not to add impurities so a carbon of the purity required has to be selected. Norit products are produced from raw materials of vegetable origin. It thus contains trace levels of some impurities typically originating in these raw materials (e.g. wood contains calcium, coal contains iron) or from the activation agents used in chemical activation processes. Because the purity of your beverage product is of utmost importance, the activated carbon you use should not leach any metals into your product that could be potentially hazardous or reduce the stability of the treated product. Norit offers a number of grades certified for very low levels of extractable minerals. For final purification (polishing) of sensitive beverage products, very pure carbons manufactured by steam activation are recommended. Where a strong decolorizing carbon is required to upgrade your beverage, Norit advises the use of carbons manufactured by the phosphoric acid activation process rather than activated by the zinc chloride activation process because of purity related standards in the food and beverage industries. The Codex Oenologique International (published by the Office International de la Vigne et du Vin) cautions against the use of carbons activated with metals.

The answers to these questions lead to the initial selection: PAC or GAC
PAC, particle size 1-150 m, is the best solution for batch processes. Dosage can be adjusted easily to ensure consistent purity requirements from a variable process flow. Norit offers a wide array of PAC grades for food applications. They range from micro-porous to meso-porous to macro-porous, from acid to neutral to alkaline reacting, from fast adsorbing to fast filterable. PAC is suitable for many purification processes in the food industry, from bulk decolorization to final taste

Beverage

Main applications
Below is a selection of main applications where Norit products have been established for purification of beverages and their ingredients. The selection suggests the diversity of tasks for which you can use safe and cost effective solutions.

Wine, vermouth
White and red wine are sometimes treated with PAC for color and taste correction. The purpose for decolorization can vary from slight color correction to complete decolorization, for example during the production of vermouth. Quality, dosing rates and treatment conditions are extensively described in various directives such as the Codex Oenologique International. The presence of the mycotoxin Ochratoxin A in wine might require a Norit Activated Carbon product in order to comply with the regulations. Water dispersible granulated products are available to simplify direct dosing of smaller quantities into treatment tanks with a minimum of carbon dust release.

Beer, malternatives
During the production of malt-beer, a very fine GAC is sometimes added to the wort to remove the straw-taste and is removed with the sediments afterwards. Today, another established application is the use of beer as basis for so-called malternatives (malt based alcoholic drinks with a low alcohol content). The beer, for this purpose, is completely decolorized by PAC or GAC and may require taste correction established by PAC. Occasionally, PAC is used to correct beer to remove foaming inhibitors such as traces of proteins or to slightly correct taste and color variances.

Liquid sugar
In the sugar and beverage industries activated carbon is used for decolorization and improvement of the sensory characteristics of sugar syrup.Depending on the origin of the sugar and the type of beverage to be produced, dedicated PAC grades can be used to meet the high standards for color and sensory characteristics required for soft drinks, alcoholic beverages, etc. It is common practice that e.g. soft drink producers demand certification of the activated carbon quality showing compliance of the activated carbon grade with the stringent purity requirements specified for liquid sugar, water or CO2 purification. Norit is able to provide the relevant documents upon request to meet the quality assurance requirements .

Rum, vodka, whisky

Norit products are used to decolorize rum, to prevent turbidity during ageing of whisky or to remove unwanted congeners such as fusel oils and aldehydes that influence the sensory character (taste/odor). For occasional purification needs PAC grades are used and for continuous processes GAC grades are used. The spent GAC bed is sometimes regenerated in-situ with steam.

Fruit juices
Norit offers dedicated decolorizing carbon grades which are able to remove colorants such as polyphenols and melanoidins from fruit juices such as apple juice and grape juice. A special product enables maximum throughput and minimizes membrane damage when PAC is used in conjunction with membranes. Other products might be appropriate to remove undesirable taste compounds and color precursors created during fruit juice processing. The same carbons are suitable to remove traces of pesticides and fungicide residues such as the mycotoxin Patulin to meet international health standards.

Water
Water is the basis for most beverages. For the production of beer and soft drinks, tap or well water is used. A disinfectant such as chlorine, ozone or chloramines is added to the water to inhibit microbial activity. This treatment is followed by percolation over a GAC bed in order to eliminate the residual disinfectant, possible reaction products such as trihalomethanes (THM), and eventually other organic contaminants.

Norit has its roots in sugar treatment. The companys founders invented activated carbon for sugar purification!

Beverage

Carbon dioxide gas (CO2)

CO2 is the sparkling element in soft drinks and beer. The CO2 used in the beverage industry usually comes from two sources:

Norit
Norit leading in purification develops and applies state-of-the-art purification technologies to help society, through our clients, meet environmental, health, and safety challenges, and work towards a sustainable future. The Norit Group, headquartered in The Netherlands, supplies consumables, components, systems, and solutions, based on proprietary technology in every step of the water and beverage value chains. More than 8 percent of the worlds population - over half a billion people - already consumes water purified by Norit! Norits activated carbon, membranes, pumps, aseptic and hygienic valves, carbon dioxide systems, and quality control equipment rank among the worlds best. Norit offers global coverage with research and development, engineering, and manufacturing facilities in seven countries. A network of dedicated Norit sales and service centers, business partners, and distributors serves customers in more than 150 countries around the world.

Breweries
In breweries, CO2 recovered during the fermentation process can be used in many ways. It may be added to the beer, or provide a protective atmosphere during bottling, canning or transporting the beer. In addition, excess CO2 may be sold as an end product for various applications in other industries. To enable this use of CO2, it must be purified by GAC to remove taste and odor causing compounds including H2S and mercaptanes, and other organic compounds.

External sources
It is common practice that this sourced CO2 is treated by GAC in safety filters before it is used as an additive in order to assure that traces of taste and odor causing compounds, as well as traces of aromatic hydrocarbons, are completely eliminated.

No following. Norit. Just leading.

More than one billion people consume drinks purified by Norit activated carbon

Beverage

Beverage
All over the world you will find companies using Norit products. We supply these products from a number of plants around the world. Wherever the carbon is produced, the products have one important feature in
Rum, vodka, whisky Beer, malternatives

Main Norit products

The table shows a selection of beverage applications and the standard products. In cases where customers have special processes or quality demands, other products may be recommended.

common: they are all produced under

Liquid sugar

Fruit juices

stringent quality control as reflected by our ISO 9001:2000 system.

Carbon grade

Wine, vermouth

Water

PAC Norit CAP SUPER-WJ Norit CASPF Norit CA UF Norit CA 1 Norit SX PLUS Norit DX 4 PT Norit DX 10 Norit PN 2 Darco S-51HF GAC Norit C GRAN Norit PK 1-3 Norit GAC 1240 EN / W Norit GCN 1240 Norit GAC 1240 PLUS (-N) Norit GCN 830 PLUS Norit ROW 0.8 SUPRA Norit RB 3 Bentonorit

CO2

Technical Documentation
Norit Infosheet 20-02: Liquid sugar Norit Infosheet 23-01: Potable alcohol Norit Infosheet 23-02: Fruit juices Norit Infosheet 23-03: Wine Norit Infosheet 29-01: Aqueous solutions Norit TB 058: Dechlorination of water with Norit Activated Carbon grades Norit TB 063: Purification of carbon dioxide in the soft drink industry and breweries Norit TB 72: Evaluation of activated carbon in liquid phase applications, Summary of laboratory test procedures Norit TB 72A: Evaluation of activated carbon in liquid phase applications, Preparation of isotherms Norit TB 72B: Evaluation of activated carbon in liquid phase applications, Pilot column tests with granular carbon Norit TB 72C: Evaluation of activated carbon in liquid phase applications, The Norit GPU (GAC pilot unit) Brochure on Norit in the food industry industry Furthermore the extensive Norit library provides information available for you upon request with subjects such as - Transport and handling of PAC and GAC - Filtration behaviour of PAC - Mobile GAC filter units and much more

Evaluating activated carbon

When evaluating the cost effectiveness of activated carbon for your purification process you need to take into account, the laboratory test results, price, specific process conditions, the final product requirements, and food safety aspects involved with the carbon grade and its manufacturing process.

The added value of working with Norit in the evaluation process is that you receive more than just samples and quotations. Norit provides dedicated technical support to enable testing and evaluation of activated carbon in the best possible way. Activated carbon evaluations often require assistance from application specialists to support the process design or process optimization. In addition to an R&D department with application laboratories, we have GAC pilot column equipment available for rental to support your GAC evaluation with guidance of Norit technical specialists. You are encouraged to make use of our technical support capabilities when appropriate to assure that highest performance is obtained with the Norit product to be applied in your process.

Immediate suspension of Bentonorit in aqueous solution.

Norit Nederland BV
Beverage S/E 1-2009

P.O. Box 105 3800 AC Amersfoort The Netherlands T +31 33 46 48 911 F +31 33 46 17 429 E [email protected] I www.norit-ac.com
Please visit our website to obtain information about your local supplier.

Norit Nederland BV reserves the right to make changes in the technical specifications at any time.

Norit Nederland BV
Beverage B/E 1-2009

P.O. Box 105 3800 AC Amersfoort The Netherlands T +31 33 46 48 911 F +31 33 46 17 429 E [email protected] I www.norit-ac.com
Please visit our website to obtain information about your local supplier.

Norit Nederland BV reserves the right to make changes in the technical specifications at any time.