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02-Structure of Atom

The document provides a collection of questions related to the structure of atoms and quantum mechanics. Some questions ask about calculating quantities like the number of electrons or protons in atoms and molecules. Other questions ask about determining quantum numbers, orbital types, transition energies, and wavelengths associated with electron transitions between energy levels in hydrogen atoms.

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Priyansh
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© © All Rights Reserved
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126 views

02-Structure of Atom

The document provides a collection of questions related to the structure of atoms and quantum mechanics. Some questions ask about calculating quantities like the number of electrons or protons in atoms and molecules. Other questions ask about determining quantum numbers, orbital types, transition energies, and wavelengths associated with electron transitions between energy levels in hydrogen atoms.

Uploaded by

Priyansh
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Structure of Atom

NCERT Based Questions


Q. (i) Calculate the total number of electrons present in one mole of methane.
(ii) Find (a) the total number and (b) the total mass of neutrons in 7 mg of 14C.
(Assume that mass of a neutron = 1.675 × 10–27 kg).
(iii) Find (a) the total number and (b) the total mass of protons in 34 mg of NH3 at
STP. Will the answer change if the temperature and pressure are changed?
Q. A 25 watt bulb emits monochromatic yellow light of wavelength of 0.57μm.
Calculate the rate of emission of quanta per second.
Q. How much energy is required to ionise a H atom if the electron occupies n = 5 orbit?
Compare your answer with the ionization enthalpy of H atom (energy required to
remove the electron from n =1 orbit).
Q. What is the maximum number of emission lines when the excited electron of an H
atom in n = 6 drops to the ground state?
Q. (i) The energy associated with the first orbit in the hydrogen atom is
–2.18 × 10–18 J atom–1. What is the energy associated with the fifth orbit?
(ii) Calculate the radius of Bohr’s fifth orbit for hydrogen atom.
Q. The electron energy in hydrogen atom is given by En = (–2.18 × 10–18)/n2 J. Calculate
the energy required to remove an electron completely from the n = 2 orbit. What is
the longest wavelength of light in cm that can be used to cause this transition?
Q. An electron is in one of the 3d orbitals. Give the possible values of n, l and ml for this
electron.
Q. (i) An atomic orbital has n = 3. What are the possible values of l and ml ?
(ii) List the quantum numbers (ml and l) of electrons for 3d orbital.
(iii) Which of the following orbitals are possible? 1p, 2s, 2p and 3f
Q. Show that the circumference of the Bohr orbit for the hydrogen atom is an integral
multiple of the de Broglie wavelength associated with the electron revolving around
the orbit.
Q. What transition in the hydrogen spectrum would have the same wavelength as the
Balmer transition n = 4 to n = 2 of He+ spectrum?
Q. The quantum numbers of six electrons are given below. Arrange them in order of
increasing energies. If any of these combination(s) has/have the same energy lists:
1. n = 4, l = 2, ml = –2 , ms = –1/2
2. n = 3, l = 2, ml= 1 , ms = +1/2
3. n = 4, l = 1, ml = 0 , ms = +1/2
4. n = 3, l = 2, ml = –2 , ms = –1/2
5. n = 3, l = 1, ml = –1 , ms= +1/2
6. n = 4, l = 1, ml = 0 , ms = +1/2
Q. Among the following pairs of orbitals which orbital will experience the larger
effective nuclear charge? (i) 2s and 3s, (ii) 4d and 4f, (iii) 3d and 3p
Q. (a) How many sub-shells are associated with n = 4?
(b) How many electrons will be present in the sub-shells having ms value of –1/2
for n = 4?

Assignment from Outside NCERT

Q. Calculate and compare the energies of two radiations one with a wavelength of 800
nm and other with wavelength of 400 nm.
Q. A 100 watt bulb emits electro-magnetic light of wavelength 400 nm. Calculate the
number of photons emitted per second by the bulb.
Q. How many photons of light having a wavelength 400 nm are necessary to provide 1 J
of energy ?
Q. What is the wavelength of light emitted when the electron in hydrogen atom
undergoes transition from an energy level with n = 4 to an energy level with n = 2 ?
What is the colour of the radiation ?
Q. What are the frequency and wavelength of a photon emitted during a transition
from n = 5 to n = 2 state in the hydrogen atom?
Q. (i) The energy associated with the first orbit in the hydrogen atom is
–2.17 × 10–18 J atom–1.
What is the energy associated with the fifth orbit ?
(ii) Calculate the radius of Bohr’s fifth orbit for hydrogen atom.
Q. Calculate the ratio of the radius of 2nd orbit of H atom and that of 3rd orbit.
Q. What are the differences between Electromagnetic Waves and Matter Waves
Q. Calculate de-Broglie wavelength of an electron (mass = 9.1 × 10 –31 kg) moving at 1%
speed of light. (h = 6.63 × 10–34 kg m2 s–1)
Q. Calculate the wavelength of an electron moving with a velocity of 2.05 × 107 ms–1.
Q. Two particles A and B are in motion. If the wavelength associated with the particle A
is 5 × 10–8 m, calculate the wavelength of particle B if its momentum is half of A.
Q. Calculate the uncertainty in the velocity of a wagon of mass 2000 kg whose position
is known to an accuracy of ± 10 m.
Q. Calculate the uncertainty in the position of an electron if uncertainty in its velocity is
(i) 0.001%
(ii) zero.
(The mass of electron = 9.1 × 10–31 kg, velocity of electron = 300 m s–1).
Q. An electron has a speed of 500 m s–1 with uncertainty of 0.02%. What is the
uncertainty in locating its position ?
Q. A golf ball has a mass of 40 g and a speed of 45 m/s. If the speed can be measured
with accuracy of 2%, calculate the uncertainty in position.
Q. Give important differences between Orbit and Orbital
Q. Explain giving reasons, which of the following sets of quantum numbers are not
possible
(a) n = 0, l = 0, ml = 0, ms = + 1/2
(b) n = 1, l = 0, ml = 0, ms = – 1/2
(c) n = 1, l = 1, ml = –0, ms = + 1/2
(d) n = 2, l = 1, ml = 0, ms = – 1/2
(e) n = 3, l = 3, ml = –3, ms = + 1/2
(f) n = 3, l = 2, ml = 0, ms = +1/2
Q. (a) What subshells are possible in n = 3 energy level ?
(b) How many orbitals (of all kinds) are possible in this level ?
Q. How many unpaired electrons are present in the ground state of (i) P (Z = 15)
(ii) Fe2+ (Z = 26) (iii) Cl– (Z = 17) ?
Q. Give the symbol of the atom whose ground state corresponds to each of the
following configurations:
(i) 1s2 2s2 2p6
(ii) 1s2 2s2 2p6 3s2 3p6
Q Give two examples of negative and two positive ions corresponding to the above
configurations.

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