Worksheet LR - ER
Worksheet LR - ER
Worksheet LR - ER
2. Zinc and sulphur react to form zinc sulphide according to the equation.
Zn + S ---------> ZnS If 25.0 g of zinc and 30.0 g of sulphur are mixed,
a) Which chemical is the limiting reactant?
b) How many grams of ZnS will be formed?
c) How many grams of the excess reactant will remain after the reaction is over?
6. Silver nitrate, AgNO3, reacts with ferric chloride, FeCl 3, to give silver chloride,
AgCl, and ferric nitrate, Fe(NO 3)3. In a particular experiment, it was plannned to mix
a solution containing 25.0 g of AgNO 3 with another solution containing 45.0 grams of
FeCl3.
a) Write the chemical equation for the reaction.
b) Which reactant is the limiting reactant?
c) What is the maximum number of moles of AgCl that could be obtained from this
mixture?
d) What is the maximum number of grams of AgCl that could be obtained?
e) How many grams of the reactant in excess will remain after the reaction is over?
7. Solid calcium carbonate, CaCO 3, is able to remove sulphur dioxide from waste
gases by the reaction: CaCO3 + SO2 + other reactants ------> CaSO3 + other products
In a particular experiment, 255 g of CaCO 3 was exposed to 135 g of SO2 in the
presence of an excess amount of the other chemicals required for the reaction.
a) What is the theoretical yield of CaSO3?
b) If only 198 g of CaSO 3 was isolated from the products, what was the percentage
yield of CaSO3 in this experiment?
8. A research supervisor told a chemist to make 100 g of chlorobenzene from the
reaction of benzene with chlorine and to expect a yield no higher than 65%. What is
the minimum quantity of benzene that can give 100 g of chlorobenzene if the yield is
65%?
The equation for the reaction is:
C6H6 + Cl2 -----------> C6H5Cl + HCl
benzene chlorobenzene
9. Certain salts of benzoic acid have been used as food additives for decades. The
potassium salt of benzoic acid, potassium benzoate, can be made by the action of
potassium permanganate on toluene.
C7H8 + 2KMnO4 -------> KC7H5O2 + 2MnO2 + KOH + H2O
toluene potassium benzoate
11. Dimethylhydrazine, (CH3)2NNH2, was used as a fuel for the Apollo Lunar Descent
Module, with N2O4 being used as the oxidant. The products of the reaction are H 2O,
N2, and CO2.
i) Write a balanced chemical equation for the combustion reaction.
ii) If 150 kg of (CH 3)2NNH2 react with 460 kg of N 2O4, what is the theoretical yield of
N2?
iii) If a 30 kg yield of N2 gas represents a 68% yield, what mass of N 2O4 would have
been used up in the reaction?
12. Magnesium metal reacts quantitatively with oxygen to give magnesium oxide,
MgO. If 5.00 g of Mg and 5.00 g of O 2 are allowed to react, what weight of MgO is
formed, and what weight of which reactant is left in excess?
13. Adipic acid, C6H10O4, is a raw material for the making of nylon and it can be
prepared in the laboratory by the following reaction between cyclohexene, C 6H10, and
sodium dichromate, Na2Cr2O7 in sulphuric acid.
3C6H10(l) + 4Na2Cr2O7(aq) + 16H2SO4(aq) --------> 3C6H10O4(aq) +
4Cr2(SO4)3(aq) + 4Na2SO4(aq) + 16H2O
There are side reactions. These plus losses of product during its purification reduce
the overall yield. A typical yield of purified adipic acid is 68.6%.
(a) To prepare 12.5 grams of adipic acid in 68.6% yield requires how many grams of
cyclohexene?
(b) The only available supply of sodium dichromate is its dihydrate, Na 2Cr2O7 .2H2O.
(Since the reaction occurs in an aqueous medium, the water in the dihydrate causes
no problems, but it does contribute to the mass of what is taken of this reactant).
How many grams of this dihydrate are also required in the preparation of 12.5 grams
of adipic acid in a yield of 68.6%?