SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006 (REACH) Article 31, Annex II as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name: MARINE RENOLIT CXI 2

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses: Lubricating grease

Uses advised against: No uses advised against identified.

1.3 Details of the supplier of the safety data sheet

Manufacturer / Supplier Fuchs Schmierstoffe GmbH

Friesenheimer Str. 19
68169 Mannheim

Telephone: +49 621 3701-0 (ZENTRALE)

Fax: +49 621 3701-570

Contact Person: Fuchs Schmierstoffe GmbH Abteilung Produktsicherheit

Telephone: +49 621 3701-1333
Fax: +49 621 3701-7303
E-mail: [email protected]

1.4 Emergency telephone number: +49 621 3701-1333 / +49 621 3701-0 (Mo-Do 8-17, Fr 8-16)

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

The product has been classified and labelled as hazardous according to regulation (EU) 1272/2008 (CLP).

Classification according to Regulation (EC) No 1272/2008 as amended.

Health Hazards
Serious eye damage Category 1 H318: Causes serious eye damage.
Environmental Hazards
Chronic hazards to the aquatic Category 3 H412: Harmful to aquatic life with long lasting
environment effects.

Hazard summary
Physical Hazards: No data available.

2.2 Label Elements

Contains: Ca-sulfonate

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Product name: MARINE RENOLIT CXI 2

Signal Words: Danger

Hazard Statement(s): H318: Causes serious eye damage.

H412: Harmful to aquatic life with long lasting effects.

Precautionary Statements

Prevention: P273: Avoid release to the environment.

P280: Wear protective gloves/protective clothing/eye protection/face
protection.

Response: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several

minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
P310: Immediately call a POISON CENTER/doctor.

Supplemental label information

EUH208: Contains: Calcium Sulfonate, Calcium Sulfonate, Ca Sulfonate.
May produce an allergic reaction.

2.3 Other hazards: By handling of mineral oil products and chemical products no particular
hazard is known when normal precautions (item 7) and personal protective
equipment (item 8) are kept. The product may not be released into the
environment without control.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

General information: Lubricating grease: Thickener system and additives in solvent refined
mineral oil.

Chemical name Identifier Concentration * REACH Registration Notes

No.
Calcium Sulfonate EINECS: 271-529-4 5,00 - <10,00% 01-2119492627-25
Ca-sulfonate EC: 932-231-6 3,00 - <5,00% 01-2119560592-37
Calcium Sulfonate EINECS: 263-093-9 1,00 - <5,00% 01-2119488992-18
Ca Sulfonate EINECS: 274-263-7 1,00 - <5,00% 01-2119492616-28
phenolic antioxidant EINECS: 204-881-4 0,25 - <1,00% 01-2119565113-46
Triphenyl phosphate EINECS: 204-112-2 0,25 - <1,00% 01-2119457432-41
* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.
PBT: persistent, bioaccumulative and toxic substance.
vPvB: very persistent and very bioaccumulative substance.

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Classification

Chemical name Identifier Classification

Calcium Sulfonate EINECS: 271-529-4 CLP: Skin Sens. 1B;H317
Ca-sulfonate EC: 932-231-6 CLP: Eye Dam. 1;H318, Skin Irrit. 2;H315, Aquatic
Chronic 3;H412
Calcium Sulfonate EINECS: 263-093-9 CLP: Skin Sens. 1B;H317
Ca Sulfonate EINECS: 274-263-7 CLP: Skin Sens. 1B;H317
phenolic antioxidant EINECS: 204-881-4 CLP: Aquatic Acute 1;H400, Aquatic Chronic 1;H410
Triphenyl phosphate EINECS: 204-112-2 CLP: , Aquatic Acute 1;H400, Aquatic Chronic 2;H411; M-
Factor (aquatic acute): 1
CLP: Regulation No. 1272/2008.

For the wording of the listed hazard statements refer to section 16.

Please note that the mineral oils and petroleum distillates used in our products are severely refined and have a
DMSO extract < 3% as measured by method IP 346 and are not classified as carcinogenic according to Note L
of Annex VI of Regulation EC 1272/2008."

SECTION 4: First aid measures

General: Instantly remove any clothing soiled by the product.

4.1 Description of first aid measures

Inhalation: Supply fresh air; consult doctor in case of symptoms.

Eye contact: Immediately flush with plenty of water for at least 15 minutes. If easy to do,
remove contact lenses. Get medical attention.

Skin Contact: Wash with soap and water.

Ingestion: Rinse mouth thoroughly.

4.2 Most important symptoms Risk of serious damage to eyes.

and effects, both acute and
delayed:

4.3 Indication of any immediate Get medical attention if symptoms occur.

medical attention and
special treatment needed

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing CO2, fire extinguishing powder or fog like water spraying. Extinguish larger
media: fires with alcohol resistant foam or spray water with suitable surfactant
added

Unsuitable extinguishing Water with a full water jet.

media:

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5.2 Special hazards arising During fire, gases hazardous to health may be formed.
from the substance or
mixture:

5.3 Advice for firefighters

Special fire fighting Move container from fire area if it can be done without risk. Dispose of fire
procedures: debris and contaminated fire fighting water inaccordance with official
regulations. Collect contaminated fire fighting water separately. It must not
enter drains.

Special protective Self-contained breathing apparatus and full protective clothing must be
equipment for fire-fighters: worn in case of fire.

SECTION 6: Accidental release measures

6.1 Personal precautions, Not required.

protective equipment and
emergency procedures:

6.2 Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe
to do so.

6.3 Methods and material for Scrape up spillage or absorb with absorbing material. Dispose of the
containment and cleaning material collected according to regulations. Stop the flow of material, if this
up: is without risk.

6.4 Reference to other See Section 8 of the SDS for Personal Protective Equipment. See Section
sections: 7 for information on safe handling See Section 13 for information on
disposal.

Dike for later disposal. Prevent entry into waterways, sewer, basements or
confined areas. Stop the flow of material, if this is without risk.

SECTION 7: Handling and storage:

7.1 Precautions for safe Provide adequate ventilation. Observe good industrial hygiene practices.
handling: Do not eat, drink or smoke when working with the product. Take usual
precautions when handling mineral oil products or chemical products.

7.2 Conditions for safe storage, Local regulations concerning handling and storage of waterpolluting
including any products have to be followed.
incompatibilities:

7.3 Specific end use(s): Not applicable

Storage Class: 11, Combustible solids

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SECTION 8: Exposure controls/personal protection

8.1 Control Parameters

Occupational Exposure Limits
None of the components have assigned exposure limits.

8.2 Exposure controls

Appropriate engineering Provide adequate ventilation. Ventilation rates should be matched to
controls: conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below
recommended exposure limits. If exposure limits have not been
established, maintain airborne levels to an acceptable level.

Individual protection measures, such as personal protective equipment

General information: Wash hands before breaks and after work. Use personal protective
equipment as required. Personal protection equipment should be chosen
according to the CEN standards and in discussion with the supplier of the
personal protective equipment. The usual precautionary measures should
be adhered to inhandling the chemicals or the mineral oil products.

Eye/face protection: Safety glasses (EN 166) recommended during refilling. Avoid contact with
eyes. Wear closed protection glasses.

Skin protection
Hand Protection: Material: Nitrile-butadiene rubber (NBR).
Min. Breakthrough time: >= 480 min
Recommended thickness of the material: >= 0,38 mm

Avoid long-term and repeated skin contact. Suitable gloves can be

recommended by the glove supplier. Use skin protection cream for
preventive skin protection. Protective gloves, where permitted in acc. to
safety directions. The exact break through time has to be found out by the
manufacturer of the protective gloves and has to be observed.

Other: Do not carry cleaning cloths impregnated with the product in trouser
pockets. Wear suitable protective clothing.

Respiratory Protection: Not relevant, due to the form of the product.

Thermal hazards: Not known.

Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated
footwear that cannot be cleaned.

Environmental Controls: No data available.

SECTION 9: Physical and chemical properties

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Product name: MARINE RENOLIT CXI 2
9.1 Information on basic physical and chemical properties
Appearance
Physical state: solid
Form: Paste
Color: Light brown
Odor: Characteristic
Odor Threshold: Not applicable for mixtures
pH: Not applicable
Melting Point: Not applicable for mixtures
Boiling Point: Value not relevant for classification
Flash Point: Not applicable
Evaporation Rate: Not applicable for mixtures
Flammability (solid, gas): Value not relevant for classification
Flammability Limit - Upper (%)–: Not applicable for mixtures
Flammability Limit - Lower (%)–: Not applicable for mixtures
Vapor pressure: Not applicable for mixtures
Vapor density (air=1): Not applicable for mixtures
Density: 1,05 g/ml (25,00 °C)
Solubility(ies)
Solubility in Water: Insoluble in water
Solubility (other): No data available.
Partition coefficient (n-octanol/water): Not applicable for mixtures
Autoignition Temperature: Value not relevant for classification
Decomposition Temperature: Value not relevant for classification
NLGI: 2
Explosive properties: Value not relevant for classification
Oxidizing properties: Value not relevant for classification
9.2 Other information No data available.

SECTION 10: Stability and reactivity

10.1 Reactivity: Stable under normal use conditions.

10.2 Chemical Stability: Stable under normal use conditions.

10.3 Possibility of hazardous Stable under normal use conditions.

reactions:

10.4 Conditions to avoid: Stable under normal use conditions.

10.5 Incompatible Materials: Strong oxidizing substances. Strong acids. Strong bases.

10.6 Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and
Products: other toxic gases or vapors.

SECTION 11: Toxicological information

Information on likely routes of exposure

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Product name: MARINE RENOLIT CXI 2
Inhalation: No data available.

Ingestion: No data available.

Skin Contact: No data available.

Eye contact: Causes serious eye damage.

11.1 Information on toxicological effects

Acute toxicity

Oral
Product: ATEmix: 174.600 mg/kg
Specified substance(s)
Calcium Sulfonate LD 50 (Rat): > 16.000 mg/kg

phenolic antioxidant LD 50 (Rat): 2.930 mg/kg (OECD 401)

Triphenyl phosphate LD 50 (Rat): > 20.000 mg/kg (OECD 401)

Dermal
Product: ATEmix: 110.000 mg/kg
Specified substance(s)
Ca-sulfonate (OECD 402)
Based on available data, the classification criteria are not met.

phenolic antioxidant LD 50 (Rat): > 5.000 mg/kg (OECD 402)

Triphenyl phosphate LD 50 (Rabbit): > 10.000 mg/kg (OECD 402)

Inhalation
Product:
Not classified for acute toxicity based on available data.
Specified substance(s)
Ca-sulfonate
No data available.

Skin Corrosion/Irritation:
Product: Based on available data, the classification criteria are not met.
Specified substance(s)
Ca-sulfonate OECD 404
Slightly irritating.

Calcium Sulfonate OECD 404 (Rabbit):

Not irritant.

Triphenyl phosphate OECD 404 (Rabbit, 72 h):

Not irritant.

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Serious Eye Damage/Eye Irritation:
Product: Based on available data, the classification criteria are met.
Specified substance(s)
Ca-sulfonate OECD 405
May cause burns.

Calcium Sulfonate OECD 405 (Rabbit):

Not irritant.

Triphenyl phosphate OECD 405 (Rabbit, 72 h):

Not irritant.

Respiratory or Skin Sensitization:

Product:
Experimental data has shown that the concentration of potentially
sensitizing components present in this product does not induce skin
sensitization.
Specified substance(s)
Ca-sulfonate , OECD 406-1 (Guinea Pig)
Based on available data, the classification criteria are not met.

phenolic antioxidant
No sensitizing effect (guinea pig); OECD 406

Germ Cell Mutagenicity

Product: Based on available data, the classification criteria are not met.
In vitro
Specified substance(s)
Ca-sulfonate (OECD 471)
Based on available data, the classification criteria are not met.

Carcinogenicity
Product: Based on available data, the classification criteria are not met.

Reproductive toxicity
Product: Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity - Single Exposure

Product: Based on available data, the classification criteria are not met.

Specific Target Organ Toxicity - Repeated Exposure

Product: Based on available data, the classification criteria are not met.

Aspiration Hazard
Product: Based on available data, the classification criteria are not met.

Other adverse effects: No data available.

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SECTION 12: Ecological information

12.1 Toxicity

Acute toxicity
Product: Based on available data, the classification criteria are not met.

Fish
Specified substance(s)
Ca-sulfonate LL 50 (Fish, 96 h): > 1 mg/l (OECD 203)
LL 50 (Fish, 96 h): < 10 mg/l (OECD 203)

Calcium Sulfonate LC 50 (Fish, 96 h): > 10.000 mg/l (OECD 203)

Ca Sulfonate LC 50 (Fish, 96 h): > 1.001 mg/l

Triphenyl phosphate LC 50 (Oncorhynchus mykiss, 96 h): 0,4 mg/l

Aquatic Invertebrates
Specified substance(s)
Ca-sulfonate LL 50 (Water Flea, 48 h): 2,9 mg/l (OECD 202)

Calcium Sulfonate EC 50 (Water flea (Simocephalus vetulus), 48 h): > 100 mg/l (OECD 202)

Ca Sulfonate EC 50 (Water Flea, 48 h): > 1.001 mg/l

Triphenyl phosphate EC 50 (Water Flea, 48 h): 1 mg/l

Chronic ToxicityProduct: Based on available data, the classification criteria are met.

Aquatic Invertebrates
Specified substance(s)
phenolic antioxidant NOEC (Water Flea, 21 d): > 0,39 mg/l

Triphenyl phosphate NOEC (Water Flea, 21 d): 0,254 mg/l (OECD 211)

Toxicity to Aquatic Plants

Specified substance(s)
Ca-sulfonate EC 50 (Alga, 96 h): 29 mg/l

12.2 Persistence and Degradability

Biodegradation
Product: Not applicable for mixtures
Specified substance(s)
Ca-sulfonate (OECD 301B) Readily biodegradable

Calcium Sulfonate 8,6 % (28 d) Not easily biodegradable

phenolic antioxidant 30 % (OECD 302C)

Triphenyl phosphate 83 - 94 % (28 d, OECD 301C) Readily biodegradable

12.3 Bioaccumulative potential

Product: Not applicable for mixtures

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Specified substance(s)
phenolic antioxidant May be accumulated in organism

12.4 Mobility in soil:

Product: Not applicable for mixtures

12.5 Results of PBT and vPvB The product does not contain any substances fulfilling the PBT/vPvB criteria.
assessment:

12.6 Other adverse effects: Harmful to aquatic life with long lasting effects.

Water Hazard Class WGK 1: slightly water-endangering.

(WGK):

SECTION 13: Disposal considerations

13.1 Waste treatment methods

General information: Dispose in accordance with all applicable regulations.

Disposal methods: Discharge, treatment, or disposal may be subject to national, state, or local
laws.

European Waste Codes

12 01 12*: spent waxes and fats

SECTION 14: Transport information

ADR/RID
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
Hazard No. (ADR): –
Tunnel restriction code: –
14.4 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

ADN
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
14.3 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

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IMDG
14.1 UN Number: –
14.2 UN Proper Shipping Name: –
14.3 Transport Hazard Class(es)
Class: Non-dangerous goods
Label(s): –
EmS No.: –
14.3 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

IATA
14.1 UN Number: –
14.2 Proper Shipping Name: –
14.3 Transport Hazard Class(es):
Class: Non-dangerous goods
Label(s): –
14.4 Packing Group: –
14.5 Environmental hazards: –
14.6 Special precautions for user: –

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code: Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

EU Regulations

Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer: none

Regulation (EC) No. 850/2004 on persistent organic pollutants: none

National Regulations

Water Hazard Class WGK 1: slightly water-endangering.

(WGK):

15.2 Chemical safety No Chemical Safety Assessment has been carried out.
assessment:

SECTION 16: Other information

Revision Information: Vertical lines in the margin indicate an amendment.

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Wording of the H-statements in section 2 and 3

H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

Other information: The classification complies with the current EU lists; however, it has been
supplemented with expert literature information and information provided
by/about our company. It was derived from the test data and/or the
application of the conventional method.

Revision Date: 15.11.2018

Disclaimer: The data contained in this safety data sheet are based on our current
knowledge and experience and are given to the best of our knowledge and
belief. It characterizes the product only with regard to safety requirements for
handling, transport and disposal. The data do not describe the product's
properties (tech. product specification). Neither should any agreed property
nor the suitability of the product for any specific technical application be
deduced from the data contained in this safety data sheet. Modifications on
this document are not allowed. The data are not transferable to other
products. In the case of mixing the product with other products or in the case
of processing, the data in this safety data sheet are not necessarily valid for
the new-made material. It is the responsibility of the recipient of the product to
observe federal, state and local law. Please contact us to obtain up-to-date
safety data sheets. This document was issued electronically and has no
signature.

Issue Date: 30.10.2013

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