CH Soln 1

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CHM152LL Solution Chemistry Worksheet

Many chemical reactions occur in solution. Solids are often dissolved in a solvent and mixed to
produce a chemical reaction that would not occur if the solids themselves were directly mixed
together. This worksheet will review the solution process, several different types of chemical
reactions in solution with focus on molecular-level pictures of the reactions, and end with a
review of calculations commonly used in the laboratory.
Solutions & Solubility Rules: When a solute is dissolved in a solvent we call the mixture
a solution. If the solvent is water, the mixture is an aqueous solution. The following solubility
rules are for ionic species in water as the solvent.
Solubility Rules for Ionic Compounds in Water
The compound is SOLUBLE if it has: The compound is INSOLUBLE if it has:
+ + +
1. Li , Na , K , NH4+ ions (ALWAYS!) 5. Carbonate ion, CO32–, but Rule 1 ions
2. Acetate ion, C2H3O2–, Nitrate ion, NO3– , or 6. Chromate ion, CrO42–, but Rule 1 ions
perchlorate ion ClO4– 7. Phosphate ion, PO43–, but Rule 1 ions
– –
3. Halide ions (X ): Chloride ion (Cl ), 8. Sulfide ion, S2–, but Rule 1 ions and
bromide ion (Br–), or iodide ion (I–), CaS, SrS, BaS are soluble
but AgX, PbX2, Hg2X2 are insoluble
9. Hydroxide ion, OH–, but Rule 1
4. Sulfate ion (SO42-),
but CaSO4, ions, Ca(OH)2, Sr(OH)2, Ba(OH)2
SrSO4, BaSO4 are insoluble are soluble
Watch the animations at the following links (sound is needed for the 2nd one) to answer the
following two questions:
1. http://www.northland.cc.mn.us/biology/Biology1111/animations/dissolve.html
2. http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/molvie1.swf
3. http://www.chem.iastate.edu/group/Greenbowe/sections/projectfolder/flashfiles/thermochem/solutionSalt.html
Question1: When sodium chloride dissolves in water explain how the water molecules arrange
themselves around the chloride ions. Draw a picture of a chloride ion surrounded by 2 water
molecules.
Question 2: Now explain why the water molecules arrange themselves like that. Discuss the
polarity of the water molecule in your answer.
GCC CHM 152LL: Solution Chemistry and Calculations Review page 1 of 6

Molecular-Level Representations of Ionic Solutions
For each ionic compound listed below write the chemical formula and draw a representation of
the compound in water. Do not show the water molecules. The first two have been completed
as examples.
1. potassium sulfate 2. calcium carbonate 3. lithium phosphate

formula___K2SO4______ formula___CaCO3____ formula________________
4. ammonium sulfide 5. silver iodide 6. barium hydroxide

formula________________ formula________________ formula________________
Chemical Reactions in Solution

Three common types of chemical reacitons that take place in solution are:
1. precipitations reactions (text section 4.4)
2. acid base neutralization reactions (text section 4.5)
3. single replacement reactions, a type of redox reaction (text section 4.6)
To review precipitation reactions watch the following animation:

http://preparatorychemistry.com/Bishop_precipitation_frames.htm
Question 1: What are the formulas for the four reactant ions involved in the above
animation?
Question 2: Why don’t the carbonate and nitrate ions “stick” together in the animation?
Question 3: Write the net ionic equation for the reaction in the animation.

Example: 1. calcium acetate and ammonium sulfate Reaction type: _precipitation__
Molecular: Ca(CH3COO)2(aq) + (NH4)2SO4(aq) J CaSO4(s) + 2 NH4CH3COO(aq)
Ionic: Ca2+(aq) + 2 CH3COO - (aq) + 2 NH4+(aq) + SO42- (aq) J CaSO4(s) + 2 CH3COO - (aq) + 2 NH4+(aq)
Net Ionic: Ca2+(aq) + SO42- (aq) J CaSO4(s)
We can write and balance these chemicals reactions using molecular equations, ionic
equations, and net ionic equations. (text section 4.3) For the following sets of reactants, write
and balance the molecular, ionic and net ionic equations (including all phases, using the
Solubility Rules on page 1) and draw a molecular-level representation of each reactant and the
products in the provided beakers (based on the ionic equation you wrote). Also indicate the
type of reaction; if there is no reaction write NR for the type but still complete the reactions and
molecular-level drawings. The first problem is already completed as an example. Draw the
water molecules if they are part of the reaction, but do not draw solvent water molecules.
2. hydrochloric acid and barium hydroxide Reaction type: ______________
Molecular:________________________________________________________________
Ionic:____________________________________________________________________
Net Ionic:_________________________________________________________________

4. aluminum and zinc nitrate – watch phases and oxidation numbers!!!
Reaction type: ______________
Molecular:________________________________________________________________
Ionic:____________________________________________________________________
Net Ionic:_________________________________________________________________
4. magnesium perchlorate and copper(II) chloride Reaction type: ______________
Molecular:________________________________________________________________
Ionic:____________________________________________________________________
Net Ionic:_________________________________________________________________

CHM 152LL: Review of Common Lab Calculations
A brief summary of some useful relationships is given below; if you need an in-depth review of these
relationships, refer to the McMurry Fay textbook sections listed in the margins. The review problems that follow
will give you practice on some of the types of calculations that are used in this lab course. Use the conversion-
factor method to solve these problems, and apply the rules for significant figures.
Sections 3.4: Molar Mass: the mass in grams of one mole of a substance; units = g/mol.
Example: Molar mass of NaOH = 40.0 g/mol; thus, 40.0 g NaOH = 1.00 mole NaOH
Sections 3.7: Molar Concentration: For a solution, molarity is the number of moles of solute per liter
of solution; that is, M = mol of solute/L of solution.
Example: For a 0.100 M NaOH solution, 0.100 mole NaOH is in 1.00 L of solution
Conversion factors can be constructed from these and other relations, and they can be “strung together” to solve a
problem. For example, to calculate the number of grams of HNO3 in 25.0 mL of 15.4 M HNO3 solution, the setup
and answer would be:
15.4 mol HNO3 63.0 g HNO3
g HNO3 = 25.0 mL HNO3 soln × × = 24.3 g HNO3
1000 mL HNO3 so ln 1 mol HNO3
Note: We substituted 1000mL for 1L so that mL would cancel out.
Ion Molarities: Soluble ionic compounds completely dissociate into ions in solution; to determine the
molarity of individual ions, we must consider the stoichiometric relationship between the ionic
compound and the number of ions formed in solution.
Example: What is the molarity of K+ ions in a 0.20 M K2CO3 solution?
K2CO3(s) → 2K+(aq) + CO32-(aq)
0.20 mol K 2 CO3 ⎛ 2 mol K + ⎞ 0.40 mol K +
⎜ ⎟ = = 0.40 M K+
1L ⎜ 1 mol K CO ⎟ 1L
⎝ 2 3 ⎠
Section 3.8: Diluting Solutions: Since only water is added during the dilution of aqueous
solutions, the moles of solute before dilution (Minit ⋅ Linit) equal the moles of solute after dilution (Mfin ⋅
Lfin) leading to Minit ⋅ Linit = Mfin ⋅ Lfin. To calculate the volume of water added, simply subtract the initial
number of liters from the final number of liters. Note that any unit of volume can be used in place of
liters. Hence, the following formula can be used to solve all dilution problems:
M1V1 = M2V2
Sections 3.9 & 10: Solution Stoichiometry: You must consider the balanced chemical reaction
and set up the appropriate conversion factors to solve solution stoichiometry and titration problems. Do
no use the dilution formula for these problems!
Example. How many L of 0.164 M Ca(OH)2 is needed to neutralize 25.00 mL of 0.458 M HCl
solution?
Ca(OH)2(aq) + 2 HCl(aq) → CaCl2(aq) + 2 H2O(l)
⎛ 1 L ⎞⎛ 0.458 moles HCl ⎞⎛ 1 mol Ca( OH )2 ⎞⎛ 1L ⎞
L Ca(OH)2 = 25.00 mL ⎜⎜ ⎟⎟⎜ ⎟⎜⎜ ⎟⎟⎜⎜ ⎟⎟
⎝ 1000 mL ⎠⎝ L ⎠⎝ 2 mol HCl ⎠⎝ 0.164 mol Ca( OH )2 ⎠
= 0.349 L Ca(OH)2

CHM 152LL: Lab Calculation Review Problems
1. Molar Mass: Calculate the number of moles in 75.0 g of lead(II) perchlorate trihydrate, Pb(ClO4)2 •
3H2O. For hydrates the water mass is added to the rest of the molecule’s mass to get the total molar
mass.
2. a) Ion Molarities: What is the molarity of Na+ ions in a 0.25 M solution of Na3PO4?
b) What is the molarity of PO 34− ions in this solution?
3. a) Dilution: How many mL of 6.00 M H2SO4 are needed to prepare 2.00 liters of 0.100 M H2SO4?
b) How much water is added to prepare this solution?
4. Molar Concentration: How many moles of HCl are there in 25.8 mL of 0.593 M HCl?
5. Molar Concentration: How many grams of solid NaOH are required to prepare 0.500 liters of 0.100
M NaOH solution?
6. Solution Stoichiometry: How many mL of 0.0500 M H2SO4 are necessary to precipitate all the Ba2+
in 15.0 mL of 0.0200 M BaCl2? (Write the balanced equation for the reaction, given BaSO4 (s) is
formed.)
7. Solution Stoichiometry: 60.0 mL of 0.100 M NaOH are required to neutralize 15.0 mL of H2SO4.
What is the molarity of the H2SO4? (Write the balanced equation for the reaction.)

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CHM152LL Solution Chemistry Worksheet

GCC CHM 152LL: Solution Chemistry and Calculations Review page 1 of 6

1. potassium sulfate 2. calcium carbonate 3. lithium phosphate

4. ammonium sulfide 5. silver iodide 6. barium hydroxide

Chemical Reactions in Solution

To review precipitation reactions watch the following animation:

GCC CHM 152LL: Solution Chemistry and Calculations Review page 2 of 6

Molecular: Ca(CH3COO)2(aq) + (NH4)2SO4(aq) J CaSO4(s) + 2 NH4CH3COO(aq)

Net Ionic: Ca2+(aq) + SO42- (aq) J CaSO4(s)

2. hydrochloric acid and barium hydroxide Reaction type: ______________

GCC CHM 152LL: Solution Chemistry and Calculations Review page 3 of 6

4. magnesium perchlorate and copper(II) chloride Reaction type: ______________

GCC CHM 152LL: Solution Chemistry and Calculations Review page 4 of 6

GCC CHM 152LL: Solution Chemistry and Calculations Review page 5 of 6

GCC CHM 152LL: Solution Chemistry and Calculations Review page 6 of 6

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