Q1: At 35oC, the vapour pressure of CS2 is 512 mm Hg and that of acetone is 344 mm Hg.

A
solution of CS2 in acetone has a total vapour pressure of 600 mm Hg. The false statement
amongst the following is :
(A) CS2 and acetone are less attracted to each other than to themselves

(B) heat must be absorbed in order to produce the solution at 35oC

(C) Raoult’s law is not obeyed by this system

(D) a mixture of 100 mL CS2 and 100 mL acetone has a volume < 200 mL
Q1: At 35oC, the vapour pressure of CS2 is 512 mm Hg and that of acetone is 344 mm Hg. A
solution of CS2 in acetone has a total vapour pressure of 600 mm Hg. The false statement
amongst the following is :
(A) CS2 and acetone are less attracted to each other than to themselves

(B) heat must be absorbed in order to produce the solution at 35oC

(C) Raoult’s law is not obeyed by this system

(D) a mixture of 100 mL CS2 and 100 mL acetone has a volume < 200 mL

Solution:

The maximum value XA can hold is 1, and hence the maximum value of PT should come out to be 512 mm of Hg, which is
less than the value of PT observed (600 mm of Hg). Therefore, positive deviation from Raoult’s law that is observed. This
implies that A-A interactions and B-B interactions are stronger than A-B interactions. As we know, for a system not obeying
Raoult’s law and showing positive deviation, ΔVmix>0, ΔHmix>0 .
Q2: Two open beakers one containing a solvent and the other containing a mixture of that
solvent with a non-volatile solute are together sealed in a container for over time:
(A) the volume of the solution and the solvent does not change

(B) the volume of the solution increases and the volume of the solvent decreases

(C) the volume of the solution decreases and the volume of the solvent increases

(D) the volume of the solution does not change and the volume of the solvent decreases
Q2: Two open beakers one containing a solvent and the other containing a mixture of that
solvent with a non-volatile solute are together sealed in a container for over time:
(A) the volume of the solution and the solvent does not change

(B) the volume of the solution increases and the volume of the solvent decreases

(C) the volume of the solution decreases and the volume of the solvent increases

(D) the volume of the solution does not change and the volume of the solvent decreases

Solution:

Consider beaker I contains the solvent and beaker 2 contains the solution. Let the vapour pressure of the beaker I be Po and
the vapour pressure of beaker II be Ps . According to Raoult’s law, the vapour pressure of the solvent (Po) is greater than the
vapour pressure of the solution (Ps)

(Po > Ps)

Due to a higher vapour pressure, the solvent flows into the solution. So volume of beaker II would increase.

In a closed beaker, both the liquids on attaining equilibrium with the vapour phase will end up having the same vapour
pressure. Beaker II attains equilibrium at a lower vapour pressure and so in its case, condensation will occur so as to negate
the increased vapour pressure from beaker I, which results in an increase in its volume.

On the contrary, since particles are condensing from the vapour phase in beaker II, the vapour pressure will decrease. Since
beaker I at equilibrium attains a higher vapour pressure evaporation will be favoured more so as to compensate for the
decreased vapour pressure, as mentioned in the previous statement.
Q3: A graph of vapour pressure and temperature for three different liquids X, Y and Z is
shown below:

The following inferences are made:

(A) X has higher intermolecular interactions compared to Y

(B) X has lower intermolecular interactions compared to Y

(C) Z has lower intermolecular interactions compared to Y

The correct inference(s) is/are:

(A) C

(B) A

(C) B

(D) A and C
Q3: A graph of vapour pressure and temperature for three different liquids X, Y and Z is
shown below:

The following inferences are made:

(A) X has higher intermolecular interactions compared to Y

(B) X has lower intermolecular interactions compared to Y

(C) Z has lower intermolecular interactions compared to Y

The correct inference(s) is/are:

(A) C

(B) A

(C) B

(D) A and C
Solution:

As shown in the plot below, for the same T, the vapour pressure of X is the highest and of Z is the lowest. Now, that means
with the same average K.E. of X, Y and Z molecules, the X molecules are able to compensate their respective intermolecular
forces better. So, X molecules have the highest vapour pressure. Which implies that the intermolecular forces in X are the
weakest among the three. The opposite could be said for Z as well.

Q4: The size of a raw mango shrinks to a much smaller size when kept in a concentrated salt
solution. Which one of the following process can explain this ?
(A) Diffusion

(B) Osmosis

(C) Reverse osmosis

(D) Dialysis
Q4: The size of a raw mango shrinks to a much smaller size when kept in a concentrated salt
solution. Which one of the following process can explain this ?
(A) Diffusion

(B) Osmosis

(C) Reverse osmosis

(D) Dialysis

Solution:

Raw mango shrink in salt solution due to net transfer of water molecules from mango to salt solution due to phenomenon of
osmosis.

Hence option (b) is correct

Q5: A solution of two components containing n1 moles of the 1st component and n2 moles of
the 2nd component is prepared. M1 and M2 are the molecular weights of component 1 and 2
respectively. If d is the density of the solution in g mL-1, C2 is the molarity and x2 is the mole
fraction of the 2nd component, then C2 can be expressed as :
(A)

(B)

(C)

(D)
Q5: A solution of two components containing n1 moles of the 1st component and n2 moles of
the 2nd component is prepared. M1 and M2 are the molecular weights of component 1 and 2
respectively. If d is the density of the solution in g mL-1, C2 is the molarity and x2 is the mole
fraction of the 2nd component, then C2 can be expressed as :
(A)

(B)

(C)

(D)

Solution:

Q6: A set of solution is prepared using 180g of water as a solvent and 10g of different non-
volatile solutes A, B and C. The relative lowering of vapour pressure in the presence of these
solutes are in the order [Given, molar mass of A = 100g mol-1 ; B =200g mol-1 ; C = 10,000g
mol-1]
(A) A>C>B

(B) B>C>A

(C) C>B>A

(D) A>B>C
Q6: A set of solution is prepared using 180g of water as a solvent and 10g of different non-
volatile solutes A, B and C. The relative lowering of vapour pressure in the presence of these
solutes are in the order [Given, molar mass of A = 100g mol-1 ; B =200g mol-1 ; C = 10,000g
mol-1]
(A) A>C>B

(B) B>C>A

(C) C>B>A

(D) A>B>C

Solution:

Relative lowering of V.P. =  = xsolute

Q7: Given below are two statements :

Statement I : A mixture of chloroform and aniline can be separated by simple distillation.

Statement II : When separating aniline from a mixture of aniline and water by steam
distillation aniline boils below its boiling point.

In the light of the above statements, choose the most appropriate answer from the options
given below :
(A) Both statement I and statement II are true

(B) Both Statement I and Statement II are false

(C) Statement I is false but Statement II is true

(D) Statement I is true but Statement II is false

Q7: Given below are two statements :

Statement I : A mixture of chloroform and aniline can be separated by simple distillation.

Statement II : When separating aniline from a mixture of aniline and water by steam
distillation aniline boils below its boiling point.

In the light of the above statements, choose the most appropriate answer from the options
given below :
(A) Both statement I and statement II are true

(B) Both Statement I and Statement II are false

(C) Statement I is false but Statement II is true

(D) Statement I is true but Statement II is false

Solution:

Simple distillation method is used to separate

(i) volatile liquids from nonvolatile impurities.
(ii) the liquids having sufficient difference in their boiling points.
Liquids having different boiling points vaporise at different temperatures.
The vapours are cooled and the liquids so formed are collected separately.
Chloroform (b.p 334 K) and aniline (b.p. 457 K) are easily separated by the technique of distillation.
Steam Distillation: This technique is
applied to separate substances which are
 steam volatile and are immiscible with
water.

if one of the substances in the mixture is water and the other, a water insoluble substance,

then the mixture will boil close to but below, 373K. A mixture of water and the substance is

obtained which can be separated by using a separating funnel.

Aniline is separated by this technique from aniline – water mixture

Q8: The water having more dissolved is:
(A) boiling water

(B) water at

(C) polluted water

(D) water at
Q8: The water having more dissolved is:
(A) boiling water

(B) water at

(C) polluted water

(D) water at

Solution:

As the temperature increases, the solubility of gases in the liquid decreases. Thus, water at will have maximum dissolved
oxygen.

Polluted water has less oxygen concentration than normal water as a large population of bacteria decomposes organic matter
present in water. They consume oxygen dissolved in water.
Q9: Which one of the following 0.06 M aqueous solutions has lowest freezing point?
(A)

(B)

(C)

(D)
Q9: Which one of the following 0.06 M aqueous solutions has lowest freezing point?
(A)

(B)

(C)

(D)

Solution:

As the value of ∆Tf increases, the freezing point of the solution decreases. Since all the given solutions have the same
concentration, the one with maximum value of van’t hoff factor for the solute will have minimum freezing point. The values are
–

-5
- 1

- 2

- 3

Thus, among given solutes, aq. solution of will have lowest freezing point.
Q10: Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing
point depression?
(A) hydrazine

(B) glucose

(C) glycine

(D) KHSO4
Q10: Which one of the following 0.10 M aqueous solutions will exhibit the largest freezing
point depression?
(A) hydrazine

(B) glucose

(C) glycine

(D) KHSO4

Solution:

Since van't Hoff factor is highest for KHSO4, therefore colligative property (∆Tf ) will be highest for KHSO4.
Q11: Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water, it
depresses the freezing point by 0.2 oC. The percentage association of solute A in water is:

[Given: Molar mass of A = 93 g mol–1. Molal depression constant of water is 1.86 K kg mol–1.
(A) 50%

(B) 60%

(C) 70%

(D) 80%
Q11: Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water, it
depresses the freezing point by 0.2 oC. The percentage association of solute A in water is:

[Given: Molar mass of A = 93 g mol–1. Molal depression constant of water is 1.86 K kg mol–1.
(A) 50%

(B) 60%

(C) 70%

(D) 80%

Solution:

∆Tf = i Kf × m

0.2 = i × 1.86 × m

0.2 = i × 1.86 ×

i= = 0.61

i=1+

2A ⇌ A2

n = 2

i=1+

0.6 – 1 =

0.4 × 2 = α

α = 0.8 ⇒ 80%
Q12: The depression in freezing point observed for a formic acid solution of concentration 0.5
mL L–1 is 0.0405°C. Density of formic acid is 1.05 g mL–1. The Van't Hoff factor of the formic
acid solution is nearly: (Given for water kf = 1.86 K kg mol–1)
(A) 0.8

(B) 1.1

(C) 1.9

(D) 2.4
Q12: The depression in freezing point observed for a formic acid solution of concentration 0.5
mL L–1 is 0.0405°C. Density of formic acid is 1.05 g mL–1. The Van't Hoff factor of the formic
acid solution is nearly: (Given for water kf = 1.86 K kg mol–1)
(A) 0.8

(B) 1.1

(C) 1.9

(D) 2.4

Solution:

Concentration of formic acid solution = 0.5 mL L–1

(Mass of water = volume of water)

Molality of formic acid solution

∆Tf = iKfm

0.0405 = i × 1.86 × m

Q13: Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y.
respectively in 1 kg of water. The ratio of depression in freezing points for A and B is found to
be 1 : 4. The ratio of molar masses of X and Y is :
(A) 1:4

(B) 1 : 0.25

(C) 1 : 0.20

(D) 1:5
Q13: Two solutions A and B are prepared by dissolving 1 g of non-volatile solutes X and Y.
respectively in 1 kg of water. The ratio of depression in freezing points for A and B is found to
be 1 : 4. The ratio of molar masses of X and Y is :
(A) 1:4

(B) 1 : 0.25

(C) 1 : 0.20

(D) 1:5

Solution:
Q14: Boiling point of a 2% aqueous solution of a nonvolatile solute A is equal to the boiling
point of 8% aqueous solution of a non-volatile solute B. The relation between molecular
weights of A and B is
(A) MA = 4MB

(B) MB = 4MA

(C) MA = 8MB

(D) MB = 8MA
Q14: Boiling point of a 2% aqueous solution of a nonvolatile solute A is equal to the boiling
point of 8% aqueous solution of a non-volatile solute B. The relation between molecular
weights of A and B is
(A) MA = 4MB

(B) MB = 4MA

(C) MA = 8MB

(D) MB = 8MA

Solution:

Q15: Henry’s constant (in kbar) for four gases in water at 298 K is given
below :

50 2 2 × 10–5 0.5

(density of water = 103 kg m–3 at 298 K)

This table implies that :

(A) solubility of at 308 K is lower than at 298 K

(B) The pressure of a 55.5 molal solution of is 250 K bar

(C) has the highest solubility in water at a given pressure

(D) The pressure of a 55.5 molal solution of is 1 bar

Q15: Henry’s constant (in kbar) for four gases in water at 298 K is given
below :

50 2 2 × 10–5 0.5

(density of water = 103 kg m–3 at 298 K)

This table implies that :

(A) solubility of at 308 K is lower than at 298 K

(B) The pressure of a 55.5 molal solution of is 250 K bar

(C) has the highest solubility in water at a given pressure

(D) The pressure of a 55.5 molal solution of is 1 bar

Solution:

(a)On increasing temperature solubility of gases decreases

(b) Pδ = KHXδ

Pδ = 0.5 x  = 250 bar

(c) KH ↓ solubility ↑ and lowest KH  for 𝛾  

(d) P𝛾 = KHXY
P𝛾 = 2 x 10–5 x  = 1 x 10–5 K bar

     = 1 x 10–2 bar

Q16: Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount (in grams)
of the salt required to achieve 10 ppm of iron in 100 kg of wheat is

(Atomic weight: Fe = 56.00; S = 32.00; O = 16.00)

Q16: Ferrous sulphate heptahydrate is used to fortify foods with iron. The amount (in grams)
of the salt required to achieve 10 ppm of iron in 100 kg of wheat is

(Atomic weight: Fe = 56.00; S = 32.00; O = 16.00)

4.96

Solution:

10 ppm of Fe means 10g of Fe in 106 g of wheat. So, for 100 kg i.e., 105 g of wheat, Fe needed is 1 g. So, for 1 g of Fe, the
mass of FeSO4.7H2O required is .
Q17: The molarity of HNO3 in a sample which has density 1.4 g/mL and mass percentage of
63% is ----- (Molecular weight of HNO3 = 63).
Q17: The molarity of HNO3 in a sample which has density 1.4 g/mL and mass percentage of
63% is ----- (Molecular weight of HNO3 = 63).
14.00

Solution:

Q18: How much amount of NaCl should be added to 600 g of water (ρ = 1.00 g/mL) to
decrease the freezing point of water to -0.2°C?

(The freezing point depression constant for water = 2 K Kg mol–1)

Q18: How much amount of NaCl should be added to 600 g of water (ρ = 1.00 g/mL) to
decrease the freezing point of water to -0.2°C?

(The freezing point depression constant for water = 2 K Kg mol–1)

1.76

Solution:

NaCl is strong electrolyte and gives 2 ions in the solution. This implies, i = 2.

on solving we get,

w = 1.76 grams
Q19: A cylinder containing an ideal gas (0.1 mol of 1.0 dm3) is in thermal equilibrium with a
large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the
stoppers S1 and S2 (as shown in the figure) suddenly withdrawn, the volume of the gas in
liters after equilibrium is achieved will be -

(Given, Kf (water) = 2.0 K kg mol–1, R = 0.08 dm3 atm K–1 mol–1)

Q19: A cylinder containing an ideal gas (0.1 mol of 1.0 dm3) is in thermal equilibrium with a
large volume of 0.5 molal aqueous solution of ethylene glycol at its freezing point. If the
stoppers S1 and S2 (as shown in the figure) suddenly withdrawn, the volume of the gas in
liters after equilibrium is achieved will be -

(Given, Kf (water) = 2.0 K kg mol–1, R = 0.08 dm3 atm K–1 mol–1)

2.18
Solution:

Kf = 2

Molality, ‘m’ = 0.5

∆Tf = Kf .m

= (0.5 × 2) = 1

So, the initial temperature now becomes 272 K. Further using the given value of moles and initial volume of the gas and the
calculated initial temperature value, we can find out the initial pressure of the ideal gas contained inside the piston.

Pgas =

= (0.1) (0.08) (272) = 2.176 atm

Now, on releasing the piston against an external pressure of 1 atm, the gas will expand until the final pressure of the gas, i.e.
P2 becomes equal to 1 atm. During this expansion, since no reaction is happening and the temperature of the gas is not
changing as well, the boyle’s law relation can be applied.

P1V1 = P2V2

2.176 × 1 = 1 × V2
V2 = 2.18 dm3
Q20: One litre of sea water (d =1.03g/cm3) contains 10.3 mg of O2 gas. Determine the
concentration of O2 in ppm:
Q20: One litre of sea water (d =1.03g/cm3) contains 10.3 mg of O2 gas. Determine the
concentration of O2 in ppm:
10.00

Solution:

ppm × 100

Using the density of the solution and its volume (1L = 1000 mL = 1000 cm3), the weight of the solution can be calculated.

Wsolution = 1.03 × 1000 = 1030 g

Thus, ppm = × 106 

Q21: If 250 cm3 of an aqueous solution containing 0.73 g of a protein A is isotonic with one
litre of another aqueous solution containing 1.65 g of a protein B, at 298 K, the ratio of the
molecular masses of A and B is ……… × 10–2 (to the nearest integer).
Q21: If 250 cm3 of an aqueous solution containing 0.73 g of a protein A is isotonic with one
litre of another aqueous solution containing 1.65 g of a protein B, at 298 K, the ratio of the
molecular masses of A and B is ……… × 10–2 (to the nearest integer).
177.00

Solution:

Q22: 6.023 × 1022 molecules are present in 10 g of a substance ‘x’. The molarity of a solution
containing 5 g of substance ‘x’ in 2 L solution is ……… × 10–3.
Q22: 6.023 × 1022 molecules are present in 10 g of a substance ‘x’. The molarity of a solution
containing 5 g of substance ‘x’ in 2 L solution is ……… × 10–3.
25.00

Solution:

Mol. Wt of ‘x’

= 100 g/mol

Q23: At 300 K, the vapour pressure of a solution containing 1 mole of n-hexane and 3 moles
of n-heptane is 550 mm of Hg. At the same temperature, if one more mole of n-heptane is
added to this solution, the vapour pressure of the solution increases by 10 mm of Hg. What is
the vapour pressure in mm Hg of n-heptane in its pure state _____?
Q23: At 300 K, the vapour pressure of a solution containing 1 mole of n-hexane and 3 moles
of n-heptane is 550 mm of Hg. At the same temperature, if one more mole of n-heptane is
added to this solution, the vapour pressure of the solution increases by 10 mm of Hg. What is
the vapour pressure in mm Hg of n-heptane in its pure state _____?
600.00

Solution:

= 550 + 50 = 600 mm of Hg
Q24: The osmotic pressure of a solution of NaCl is 0.10 atm and that of a glucose solution is
0.20 atm. The osmotic pressure of a solution formed by mixing 1 L of the sodium chloride
solution with 2 L of the glucose solution is 10–3 atm. x is _______. (nearest integer)
Q24: The osmotic pressure of a solution of NaCl is 0.10 atm and that of a glucose solution is
0.20 atm. The osmotic pressure of a solution formed by mixing 1 L of the sodium chloride
solution with 2 L of the glucose solution is 10–3 atm. x is _______. (nearest integer)
167.00
Solution:

Osmotic pressure = π = i x C x RT
For NaCl i = 2 so
πNaCl = i x CNaCl x RT        CNaCl = conc. of NaCl
0.1 = 2 x CNaCl x RT

CNaCl =         Cglucose = conc. of glucose

For glucose i = 1 so

πGlucose = i x Cglucose x RT

0.2 = 1 x Cglucose x RT

Cglucose =       nNaCl = No. of moles of NaCl

nNaCl in 1 L = CNaCl x VLitre

=  nglucose = No. of moles glucose

nglucose in 2 L = Cglucose x VLitre = 

VTotal = 1 + 2 = 3L

so final conc. NaCl = 

Final conc. glucose =

πTotal = πNaCl + πglucose

= [i x CNaCl + Cglucose] x RT
= 

=  atm

= 0.1666 atm

= 166.6 x 10–3 atm

= 167.00 x 10–3 atm

so, x = 167.00
Q25: A 100 mL solution was made by adding 1.43 g of Na2CO3. xH2O. The normality of the
solution is 0.1 N. The value of x is ________. (The atomic mass of Na is 23 g/mol).
Q25: A 100 mL solution was made by adding 1.43 g of Na2CO3. xH2O. The normality of the
solution is 0.1 N. The value of x is ________. (The atomic mass of Na is 23 g/mol).
10.00
Solution:

Molar mass of Na2CO3 . xH2O

⇒ 23  2 + 12 + 48 + 18x

⇒ 46 + 12 + 48 + 18x

⇒ (106 + 18x)

Eqwt =  = (53 + 9x)

As nfactor in dossociaion will be determined from net cationic or anionic charge. which is 2 so

Eqwt = = 53 + 9x

Gmeq =  = 

Normality = 

Normality = 0.1 = 

As volume = 100 ml

= 0.1 Litre

So, 10–2 = 

53 + 9x = 143

9x = 90

x = 10.00
Q26: The elevation of boiling point of 0.10m aqueous CrCl3.xNH3 solution is two times that of
0.05 m aqueous CaCl2 solution. The value of x is ……………...

[Assume 100% ionisation of the complex and CaCl2, coordination number of Cr as 6, and that
all NH3 molecules are present inside the coordination sphere]
Q26: The elevation of boiling point of 0.10m aqueous CrCl3.xNH3 solution is two times that of
0.05 m aqueous CaCl2 solution. The value of x is ……………...

[Assume 100% ionisation of the complex and CaCl2, coordination number of Cr as 6, and that
all NH3 molecules are present inside the coordination sphere]
5.00

Solution:

Q27: 4.5 g of compound A (MW = 90) was used to make 250 mL of its aqueous solution. The
molarity of the solution in M is x × 10-1. The value of x is ________. (Rounded off to the
nearest integer)
Q27: 4.5 g of compound A (MW = 90) was used to make 250 mL of its aqueous solution. The
molarity of the solution in M is x × 10-1. The value of x is ________. (Rounded off to the
nearest integer)
2.00
Solution:
Q28: When 9.45 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by
0.5oC. The dissociation constant of ClCH2COOH is x × 10-3. The value of x is _____.
(Rounded off to the nearest integer)

Q28: When 9.45 g of ClCH2COOH is added to 500 mL of water, its freezing point drops by
0.5oC. The dissociation constant of ClCH2COOH is x × 10-3. The value of x is _____.
(Rounded off to the nearest integer)

36.00
Solution:
Q29: C6H6 freezes at 5.5°C. The temperature at which a solution of 10 g of C4H10 in 200 g of
C6H6 freeze is ____°C. (The molal freezing point depression constant of C6H6, is 5.12° C/m)
Q29: C6H6 freezes at 5.5°C. The temperature at which a solution of 10 g of C4H10 in 200 g of
C6H6 freeze is ____°C. (The molal freezing point depression constant of C6H6, is 5.12° C/m)
1.00

Solution:
Q30: 1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the
solution at 1 atm is ______ K. (Rounded-off to the nearest integer)

[Given Kbfor (H2O) = 0.52 K kg mol-1]

Q30: 1 molal aqueous solution of an electrolyte A2B3 is 60% ionised. The boiling point of the
solution at 1 atm is ______ K. (Rounded-off to the nearest integer)

[Given Kbfor (H2O) = 0.52 K kg mol-1]

375.00

Solution:
Q31: If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality
of the solution which shows a 2.5 K rise in the boiling point of the solution is ______ molal.
(Rounded-off to the nearest integer)

[Kb = 0.52 K kg mol-1]

Q31: If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality
of the solution which shows a 2.5 K rise in the boiling point of the solution is ______ molal.
(Rounded-off to the nearest integer)

[Kb = 0.52 K kg mol-1]

3.00

Solution:

So Ans. is 3
Q32: 224 mL of SO2(g) at 298 K and 1 atm is passed through 100 mL of 0.1 M NaOH solution
The non-volatile solute produced is dissolved in 36 g of water. The lowering of vapour
pressure of solution (assuming the solution is dilute)  is
the value of x is _______. (Integer answer)
Q32: 224 mL of SO2(g) at 298 K and 1 atm is passed through 100 mL of 0.1 M NaOH solution
The non-volatile solute produced is dissolved in 36 g of water. The lowering of vapour
pressure of solution (assuming the solution is dilute)  is
the value of x is _______. (Integer answer)
18.00
Solution:

Q33: When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution
was found to be -0.93oC(Kf(H2O) = 1.86 K kg mol-1). The number (n) of benzoic acid
molecules associated (assuming 100% association) is_______.
Q33: When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution
was found to be -0.93oC(Kf(H2O) = 1.86 K kg mol-1). The number (n) of benzoic acid
molecules associated (assuming 100% association) is_______.
2.00

Solution:

Now, if 'n' molecules of benzoic acid associated,

( for 100% association)

So n = 2
Q34: A 6.50 molal solution of KOH (aq.) has a density of 1.89 g cm-3. The molarity of the
solution is _______ mol dm-3. (Round off to the Nearest Integer).

[Atomic masses: K : 39.0 u; O : 16.0 u; H : 1.0 u]

Q34: A 6.50 molal solution of KOH (aq.) has a density of 1.89 g cm-3. The molarity of the
solution is _______ mol dm-3. (Round off to the Nearest Integer).

[Atomic masses: K : 39.0 u; O : 16.0 u; H : 1.0 u]

9.00

Solution:

12285 – 364M = 1000 M

1364 M = 12285

M=9
Q35: AB2 is 10% dissociated in water to A2+ and B-. The boiling point of a 10.0 molal aqueous
solution of AB2 is _______ oC. (Round off to the Nearest Integer).

[Given: Molal elevation constant of water Kb = 0.5 K kg mol-1 boiling point of pure water =
100oC]
Q35: AB2 is 10% dissociated in water to A2+ and B-. The boiling point of a 10.0 molal aqueous
solution of AB2 is _______ oC. (Round off to the Nearest Integer).

[Given: Molal elevation constant of water Kb = 0.5 K kg mol-1 boiling point of pure water =
100oC]
106.00

Solution:

∆ Tb = iKbm

[AB2 ⇌ A2+ + 2B–]

i = 1.2

∆ Tb = 1.2 × 0.5 × 10 = 6

(Tb)solution = 106oC
Q36: At 363 K, the vapor pressure of A is 21 kPa and that of B is 18 kPa. One mole of A and
2 moles of B are mixed. Assuming that this solution is ideal, the vapor pressure of the mixture
is ____ kPa. (Round off to the Nearest Integer).
Q36: At 363 K, the vapor pressure of A is 21 kPa and that of B is 18 kPa. One mole of A and
2 moles of B are mixed. Assuming that this solution is ideal, the vapor pressure of the mixture
is ____ kPa. (Round off to the Nearest Integer).
19.00

Solution:

= 21 × + 18 ×

= 7 + 12

= 19 kPa
Q37: The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above
water. The molar solubility of oxygen in water is …………. × 10–5 mol dm–3.

(Round off to the Nearest Integer).

[Given: Henry’s law constant = KH = 8.0 × 104 kPa for O2.

Density of water with dissolved oxygen = 1.0 kg dm–3]

Q37: The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above
water. The molar solubility of oxygen in water is …………. × 10–5 mol dm–3.

(Round off to the Nearest Integer).

[Given: Henry’s law constant = KH = 8.0 × 104 kPa for O2.

Density of water with dissolved oxygen = 1.0 kg dm–3]

1388

Solution:

Solubility

Solubility

Thus, there are 0.00025 moles of oxygen dissolved in 1 mole water.

Mass of solution = 0.00025 32 + 1 18 = 18.008 g

Thus, volume of solution = 18.008 mL (density is given as 1 kg/L) = 0.018008 L

Thus, molar solubility = = 0.013882718 = 1388.27 10–5 M

Q38: The mole fraction of a solute in a 100 molal aqueous solution is ……….. × 10–2.

(Round off to the Nearest Integer).

[Given: Atomic masse: H : 1.0 u, O : 16.0 u]

Q38: The mole fraction of a solute in a 100 molal aqueous solution is ……….. × 10–2.

(Round off to the Nearest Integer).

[Given: Atomic masse: H : 1.0 u, O : 16.0 u]

64.00

Solution:

Let weight of

Moles of solute = 100

(mole)

Mole fraction of solute

Q39: A 1 molal solution has a degree of dissociation of 0.4. Its boiling point is
equal to that of another solution which contains 18.1 weight percent of a non electrolytic
solute A. The molar mass of A is ............... u. (Round off to the Nearest Integer).

[Density of water = 1.0 g cm–3]

Q39: A 1 molal solution has a degree of dissociation of 0.4. Its boiling point is
equal to that of another solution which contains 18.1 weight percent of a non electrolytic
solute A. The molar mass of A is ............... u. (Round off to the Nearest Integer).

[Density of water = 1.0 g cm–3]

85.00

Solution:

Since boiling point is same,

elevation in boiling point is also same for both solution.

Q40: 2 molal solution of a weak acid HA has a freezing point of –3.885ºC. The degree of
dissociation of this acid is .................. × 10–3. (Round off to the Nearest Integer).

[Given: Molal depression constant of water = 1.85 K kg mol–1

Freezing point of pure water = 0ºC]
Q40: 2 molal solution of a weak acid HA has a freezing point of –3.885ºC. The degree of
dissociation of this acid is .................. × 10–3. (Round off to the Nearest Integer).

[Given: Molal depression constant of water = 1.85 K kg mol–1

Freezing point of pure water = 0ºC]
50.00

Solution:

Tf  = –3.885°C

∆Tf = +3.885 = i × kf × m

3.885 = i × 1.85 × 2

i= = [1 + ∝]

∝= = 0.05 = 50 × 10–3

Answer is 50
Q41: A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100.52ºC.
The percentage association of A is ................... . (Round off to the Nearest Integer).

[Use: Kb for water = 0.52 K kg mol–1 Boiling point of water = 100ºC]

Q41: A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100.52ºC.
The percentage association of A is ................... . (Round off to the Nearest Integer).

[Use: Kb for water = 0.52 K kg mol–1 Boiling point of water = 100ºC]

100.00

Solution:

2A → A2

n=

molality = 2; Tb = 100.52

∆Tb = 0.52

= i × Kb × m

0.52 = i × 0.52 × 2

i= =1+ α

α=1
Q42: At , the vapour pressure of benzene is 70 torr and that of methyl benzene is 20
torr. The mole fraction of benzene in the vapour phase at above an equimolar mixture
of benzene and methyl benzene is . (Nearest integer)
Q42: At , the vapour pressure of benzene is 70 torr and that of methyl benzene is 20
torr. The mole fraction of benzene in the vapour phase at above an equimolar mixture
of benzene and methyl benzene is . (Nearest integer)
78.00

Solution:

Let benzene be A and methyl benzene be B. Since the mixture is equimolar, the mole fractions in the solution phase,

XA = XB = 0.5

Now, for mole fraction in vapour phase,

Q43: The vapour pressures of A and B at are 90 mm Hg and 15 mm Hg respectively. If

A and B are mixed such that the mole fraction of A in the mixture is 0.6, then the mole fraction
of B in the vapour phase is . The value of x is ___.

(Nearest integer)
Q43: The vapour pressures of A and B at are 90 mm Hg and 15 mm Hg respectively. If
A and B are mixed such that the mole fraction of A in the mixture is 0.6, then the mole fraction
of B in the vapour phase is . The value of x is ___.

(Nearest integer)
1.00

Solution:

Since XA + XB = 1 XB = 1 – 0.6 = 0.4

Now,
Q44: gas is bubbled through water during a soft drink manufacturing process at 298 K.
If exerts a partial pressure of 0.835 bar, then x mmol of would dissolve in 0.9 L of
water. The value of x is _____. (Nearest integer)

(Henry’s law constant for at 298 K is bar)

Q44: gas is bubbled through water during a soft drink manufacturing process at 298 K.
If exerts a partial pressure of 0.835 bar, then x mmol of would dissolve in 0.9 L of
water. The value of x is _____. (Nearest integer)

(Henry’s law constant for at 298 K is bar)

25.00

Solution:

0.9 L of water will weight 900 g.

Thus, moles of water =

Now, using Henry’s law -

Q45: When 3.00 g of a substance 'X' is dissolved in 100 g of CCl4, it raises the boiling point
by 0.60 K. The molar mass of the substance 'X' is ________ g mol–1. (Nearest integer).

[Given - Kb for CCl4 is 5.0 K kg mol-1]

Q45: When 3.00 g of a substance 'X' is dissolved in 100 g of CCl4, it raises the boiling point
by 0.60 K. The molar mass of the substance 'X' is ________ g mol–1. (Nearest integer).

[Given - Kb for CCl4 is 5.0 K kg mol-1]

250.00

Solution:
Q46: In a solvent 50% of an acid HA dimerizes and the rest dissociates. The van't Hoff factor
of the acid is _____ × 10–2. (Round off to the nearest integer)
Q46: In a solvent 50% of an acid HA dimerizes and the rest dissociates. The van't Hoff factor
of the acid is _____ × 10–2. (Round off to the nearest integer)
125.00

Solution:

Let there was one mole of HA initially.

(i) Dissociation of 0.5 mole HA will produce 0.5 moles of H+ and 0.5 moles of A–.

(ii) Dimerisation of 0.5 mole HA will produce moles of (HA)2

Thus, the total moles of particles after dissociation + association

Now,

Q47: 1.46 g of a biopolymer dissolved in a 100 mL water at 300 K exerted an osmotic

pressure of 2.42 × 10-3 bar. The molar mass of the biopolymer is ______× 104 g mol-1 (Round
off to the Nearest Integer)

[Use: R = 0.083 L bar mol-1 K-1]

Q47: 1.46 g of a biopolymer dissolved in a 100 mL water at 300 K exerted an osmotic
pressure of 2.42 × 10-3 bar. The molar mass of the biopolymer is ______× 104 g mol-1 (Round
off to the Nearest Integer)

[Use: R = 0.083 L bar mol-1 K-1]

15.00

Solution:

Q48: Of the following four aqueous solutions, total number of those solutions whose freezing
point is lower than that of 0.10 m C2H5OH is ______ (Integer answer)

(i) 0.10 m Ba3(PO4)2

(ii) 0.10 m Na2SO4

(iii) 0.10 m KCl

(iv) 0.10 m Li3PO4

Q48: Of the following four aqueous solutions, total number of those solutions whose freezing
point is lower than that of 0.10 m C2H5OH is ______ (Integer answer)

(i) 0.10 m Ba3(PO4)2

(ii) 0.10 m Na2SO4

(iii) 0.10 m KCl

(iv) 0.10 m Li3PO4

4.00

Solution:

As 0.1 M C2H5OH is non-dissociative (i = 1) and rest all salt given are dissociating electrolytes so in each case i > 1.

∆Tf = i × Kf × m

So, each will have lower freezing point.

Q49: An aqueous KCl solution of destiny 1.20 g mL-1 has a molality of 3.30 mol kg-1. The
molalrity of the solution in mol L–1 is ________ (Nearest integer)

[Molar mass of KCl = 74.5]

Q49: An aqueous KCl solution of destiny 1.20 g mL-1 has a molality of 3.30 mol kg-1. The
molalrity of the solution in mol L–1 is ________ (Nearest integer)

[Molar mass of KCl = 74.5]

3.00

Solution:

1000 g solvent has 3.3 moles of KCl

1000 g solvent → 3.3 × 74.5 g KCl → 245.85 g KCl

Weight of solution = 1245.85 g

Volume of solution = ml

So, molarity =
Q50: 83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is
_______K. (Nearest integer)

[Use: Molal Freezing point depression constant of water = 1.86 K kg mol–1, Freezing Point of
water = 273 K, Atomic masses: C - 12.0 u, O - 16.0 u, H - 1.0 u]
Q50: 83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is
_______K. (Nearest integer)

[Use: Molal Freezing point depression constant of water = 1.86 K kg mol–1, Freezing Point of
water = 273 K, Atomic masses: C - 12.0 u, O - 16.0 u, H - 1.0 u]
269.00

Solution:
Q51: 1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to –4°C before
freezing. The amount of ice (in g) that will be separated out is___________ . (Nearest integer)
[Given : Kf(H2O) = 1.86 K kg mol–1 ]
Q51: 1 kg of 0.75 molal aqueous solution of sucrose can be cooled up to –4°C before
freezing. The amount of ice (in g) that will be separated out is___________ . (Nearest integer)
[Given : Kf(H2O) = 1.86 K kg mol–1 ]
518.00

Solution:

Let mass of water initially present = x gm

Mass of sucrose = (1000 - x) gm

Moles of sucrose =

ice separated = (795.86 – 277.5) = 518.3 gm

Q52: 40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of
solution is _____ K. (Nearest integer)

[Given: Kf = 1.86 K kg mol–1; Density of water = 1.00 g cm–3; Freezing point of water = 273.15
K]
Q52: 40 g of glucose (Molar mass = 180) is mixed with 200 mL of water. The freezing point of
solution is _____ K. (Nearest integer)

[Given: Kf = 1.86 K kg mol–1; Density of water = 1.00 g cm–3; Freezing point of water = 273.15
K]
271.00

Solution:
Q53: 1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg
mol–1) and 100 g of acetone (Kb= 1.7 K kg mol–1). The acid is known to dimerize in benzene
but remain as a monomer in acetone. The boiling point of the solution in acetone increases by
0.17°C.The increase in boiling point of solution in benzene in °C is x × 10–2 . The value of x is
_______.(Nearest integer)

[Atomic mass: C = 12.0, H = 1.0, O= 16.0]

Q53: 1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg
mol–1) and 100 g of acetone (Kb= 1.7 K kg mol–1). The acid is known to dimerize in benzene
but remain as a monomer in acetone. The boiling point of the solution in acetone increases by
0.17°C.The increase in boiling point of solution in benzene in °C is x × 10–2 . The value of x is
_______.(Nearest integer)

[Atomic mass: C = 12.0, H = 1.0, O= 16.0]

13.00
Solution:

With benzene as solvent

With acetone as solvent

Dividing - (1) / (2)

Q54: A company dissolves ‘x’ amount of CO2 at 298 K in 1 litre of water to prepare soda
water. X = _____ × 10–3 g. (nearest integer)

(Given: partial pressure of CO2 at 298 K = 0.835 bar. Henry's law constant for CO2 at 298K =
1.67 kbar. Atomic mass of H, C and O is 1, 12, and 6 g mol–1, respectively)
Q54: A company dissolves ‘x’ amount of CO2 at 298 K in 1 litre of water to prepare soda
water. X = _____ × 10–3 g. (nearest integer)

(Given: partial pressure of CO2 at 298 K = 0.835 bar. Henry's law constant for CO2 at 298K =
1.67 kbar. Atomic mass of H, C and O is 1, 12, and 6 g mol–1, respectively)
1221.00

Solution:

 = 1.221 g = 1221 × 10–3 g

Q55: The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient
intravenously, it has to be isotonic with blood. The concentration of glucose solution in gL–1
is_____. (Molar mass of glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer)
Q55: The osmotic pressure of blood is 7.47 bar at 300 K. To inject glucose to a patient
intravenously, it has to be isotonic with blood. The concentration of glucose solution in gL–1
is_____. (Molar mass of glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer)
54.00

Solution:

= 0.3 moles glucose in 1 L

Strength of Glucose (g/L) = 0.3 x 180 = 54 g/L

Q56: A 0.5 percent solution of potassium chloride was found to freeze at –0.24oC. The
percentage dissociation of potassium chloride is_____. (Nearest integer)

(Molal depression constant for water is 1.80 K kg mol–1 and molar mass of KCl is 74.6 g mol–
1).
Q56: A 0.5 percent solution of potassium chloride was found to freeze at –0.24oC. The
percentage dissociation of potassium chloride is_____. (Nearest integer)

(Molal depression constant for water is 1.80 K kg mol–1 and molar mass of KCl is 74.6 g mol–
1).

98.00

Solution:

Total no. of moles

Q57: The osmotic pressure exerted by a solution prepared by dissolving 2.0 g of protein of
molar mass 60 kg mol–1 in 200 mL of water at 27°C is ______ Pa. [integer value]

(Use R = 0.083 L bar mol–1 K–1)

Q57: The osmotic pressure exerted by a solution prepared by dissolving 2.0 g of protein of
molar mass 60 kg mol–1 in 200 mL of water at 27°C is ______ Pa. [integer value]

(Use R = 0.083 L bar mol–1 K–1)

415

Solution:

0.00415 Bar

1 Bar = 105 Pa

0.00415 Bar = 415 Pa

Osmotic pressure = 415 Pa

Q58: A solution containing 2.5 x 10–3 kg of a solute dissolved in 75 x 10–3 kg of water boils at
373.535 K. The molar mass of the solute is _____ g mol–1. [nearest integer] (Given: Kb(H2O)
= 0.52 K kg mol–1 and boiling point of water = 373.15 K)
Q58: A solution containing 2.5 x 10–3 kg of a solute dissolved in 75 x 10–3 kg of water boils at
373.535 K. The molar mass of the solute is _____ g mol–1. [nearest integer] (Given: Kb(H2O)
= 0.52 K kg mol–1 and boiling point of water = 373.15 K)
45.00

Solution:

Molar mass = 45.02 g/mol

Molar mass of solute = 45 g/mol

Q59: 2 g of a non-volatile non-electrolyte solute is dissolved in 200 g of two different solvents
A and B whose ebullioscopic constants are in the ratio of 1 : 8. The elevation in boiling point
of A and B are in the ratio . The value of y is _____. (Nearest Integer)
Q59: 2 g of a non-volatile non-electrolyte solute is dissolved in 200 g of two different solvents
A and B whose ebullioscopic constants are in the ratio of 1 : 8. The elevation in boiling point
of A and B are in the ratio . The value of y is _____. (Nearest Integer)
8.00

Solution:

So y = 8
Q60: The vapour pressures of two volatile liquids A and B at 25 oC are 50 Torr and 100 Torr,
respectively. If the liquid mixture contains 0.3 mole fraction of A, then the mole fraction of
liquid B in the vapour phase is . The value of x is _____.
Q60: The vapour pressures of two volatile liquids A and B at 25 oC are 50 Torr and 100 Torr,
respectively. If the liquid mixture contains 0.3 mole fraction of A, then the mole fraction of
liquid B in the vapour phase is . The value of x is _____.
14.00

Solution:
Q61: 2.5 g of protein containing only glycine (C2H5NO2) is dissolved in water to make 500 mL
of solution. The osmotic pressure of this solution at 300 K is found to be 5.03 × 10–3 bar. The
total number of glycine units present in the protein is _____.

(Given: R= 0.083 L bar K–1 mol–1)

Q61: 2.5 g of protein containing only glycine (C2H5NO2) is dissolved in water to make 500 mL
of solution. The osmotic pressure of this solution at 300 K is found to be 5.03 × 10–3 bar. The
total number of glycine units present in the protein is _____.

(Given: R= 0.083 L bar K–1 mol–1)

330

Solution:

π = CRT

Number of glycine units in the protein = = 330

Q62: 1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in
freezing point observed for this strength of acid is 0.0198 oC. The percentage of dissociation
of the acid is_____. (Nearest integer)

[Given: Density of acetic acid is 1.02 g mL–1

Molar mass of acetic acid is 60 g mol–1

Kf(H2O) = 1.85 K kg mol–1]

Q62: 1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in
freezing point observed for this strength of acid is 0.0198 oC. The percentage of dissociation
of the acid is_____. (Nearest integer)

[Given: Density of acetic acid is 1.02 g mL–1

Molar mass of acetic acid is 60 g mol–1

Kf(H2O) = 1.85 K kg mol–1]

5.00

Solution:

(As moles of solute are very less, we can take molarity and molality same)

% =5%

Q63: Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The
depression in freezing point for 4.5 molal solution of glucose in water is 4 K. The ratio of molal
elevation constant to molal depression constant (Kb/Kf) is _____.
Q63: Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The
depression in freezing point for 4.5 molal solution of glucose in water is 4 K. The ratio of molal
elevation constant to molal depression constant (Kb/Kf) is _____.
3.00

Solution:

∆Tb = Kb m

Kb =

∆Tf = Kf m

Kf =

Q64: The elevation in boiling point for 1 molal solution of non-volatile solute A is 3 K. The
depression in freezing point for 2 molal solution of A in the same solvent is 6 K. The ratio of
Kb and Kf i.e., Kb/Kf is 1 : X. The value of X is [nearest integer]
Q64: The elevation in boiling point for 1 molal solution of non-volatile solute A is 3 K. The
depression in freezing point for 2 molal solution of A in the same solvent is 6 K. The ratio of
Kb and Kf i.e., Kb/Kf is 1 : X. The value of X is [nearest integer]
1.00

Solution:

Molality of a solution of non volatile solute (A) = 1

Elevation in boiling point is given by

                                                        ... (1)

Molality of (A) in the same solvent = 2

Depression in freezing point is given by

                                                      ... (2)

Dividing (1) by (2)

Q65: When a certain amount of solid A is dissolved in 100 g of water at 25°C to make a dilute
solution, the vapour pressure of the solution is reduced to one-half of that of pure water. The
vapour pressure of pure water is 23.76 mmHg. The number of moles of solute A added
is________. (Nearest Integer)
Q65: When a certain amount of solid A is dissolved in 100 g of water at 25°C to make a dilute
solution, the vapour pressure of the solution is reduced to one-half of that of pure water. The
vapour pressure of pure water is 23.76 mmHg. The number of moles of solute A added
is________. (Nearest Integer)
3.00

Solution:

Dilute solution given:

Q66: 150 g of acetic acid was contaminated with 10.2 g ascorbic acid (C6H8O6) to lower down
its freezing point by (x × 10–1)°C. The value of x is ________.

(Nearest integer) [Given Kf = 3.9 K kg mol–1; Molar mass of ascorbic acid = 176 g mol–1]
Q66: 150 g of acetic acid was contaminated with 10.2 g ascorbic acid (C6H8O6) to lower down
its freezing point by (x × 10–1)°C. The value of x is ________.

(Nearest integer) [Given Kf = 3.9 K kg mol–1; Molar mass of ascorbic acid = 176 g mol–1]
15

Solution:

150g CH3COOH

10.2g ascorbic acid ⇒ 0.058 moles

ΔTf = (x ✕ 10-1)oC

ΔTf =kf.Molarity

o
= 1.5 C

= 15 ✕ 10-1 oC
Q67: A gaseous mixture of two substances A and B, under a total pressure of 0.8 atm is in
equilibrium with an ideal liquid solution. The mole fraction of substance A is 0.5 in the vapour
phase and 0.2 in the liquid phase. The vapour pressure of pure liquid A is _______ atm.
(Nearest integer)
Q67: A gaseous mixture of two substances A and B, under a total pressure of 0.8 atm is in
equilibrium with an ideal liquid solution. The mole fraction of substance A is 0.5 in the vapour
phase and 0.2 in the liquid phase. The vapour pressure of pure liquid A is _______ atm.
(Nearest integer)
2.00

Solution:

Now,

Q68: If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that
dissolve in 1 litre of water is_______. (Nearest Integer)

(Given: Henry's Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920
bar) (Assume solubility of O2 in water is too small, nearly negligible)
Q68: If O2 gas is bubbled through water at 303 K, the number of millimoles of O2 gas that
dissolve in 1 litre of water is_______. (Nearest Integer)

(Given: Henry's Law constant for O2 at 303 K is 46.82 k bar and partial pressure of O2 = 0.920
bar) (Assume solubility of O2 in water is too small, nearly negligible)
1

Solution:

Q69: 1.80 g of solute A was dissolved in 62.5 cm3 of ethanol and freezing point of the solution
was found to be 155.1 K. The molar mass of solute A is __g mol–1.

[Given: Freezing point of ethanol is 156.0 K. Density of ethanol is 0.80 g cm–3.

Freezing point depression constant of ethanol is 2.00 K kg mol–1]

Q69: 1.80 g of solute A was dissolved in 62.5 cm3 of ethanol and freezing point of the solution
was found to be 155.1 K. The molar mass of solute A is __g mol–1.

[Given: Freezing point of ethanol is 156.0 K. Density of ethanol is 0.80 g cm–3.

Freezing point depression constant of ethanol is 2.00 K kg mol–1]

80.00

Solution:

Mass of solvent