GCSE Science Chemistry

Contents
Atomic Structure 2
Isotopes 4
The Alkali Metals (Group 1) 5
The Halogens (Group 7) 7
Flame Test / Silver Nitrate Test 8
Ionic Bonding 10
Covalent Bonding 13
Structures 15
Giant Covalent Structures 16
Metallic Bonding 17
Smart Materials 19
Rates of Reaction 22
Fractional Distillation 26
Alkanes and Alkenes 28
Addition Polymerisation 29
Types of plastic 31
Calculations – Energy in Reactions 32
Calculating Mr and % composition 33
Calculating Reacting Masses 34
Calculating simplest formula 35
Calculating % yield 36
Water 37
Dehalination / Distillation 39
Chromatography 40
Types of Drinking Water 42
Solubility Curves 46
www.bangor.ac.uk GCSE Science: Chemistry 2 1

Atomic Structure
Atoms contain a nucleus and electrons
The small central nucleus is made from protons and neutrons.
Around these are orbits (shells) of electrons.
Here is a diagram showing an atom of Lithium

Electron
Nucleus
Shell
Proton
Neutron
This diagram shows that a piece of Potassium is made up of millions of the

same atom.
A piece of
potassium Formed from
metal atoms
Potassium atom
A nucleus of Orbit of
protons and electrons
electrons
Atoms of different elements are different.
The number of protons is always different with different elements.
Element Lithium Potassium

Protons 3 19
Neutrons 4 20
Electrons 3 19
Neutron number for some elements are the same.

Electron number can be the same when the atoms have bonded.
2 GCSE Science: Chemistry 2 www.bangor.ac.uk

Atomic Structure
Atoms have no charge.
The number of protons (in the nucleus) is always the same as the number of
electrons (in shells)
Protons are positively charged. (+)

Electrons are negatively charged (-)
Neutrons do not have a charge (0)
Every electron has a charge of -1
Every proton has a charge of +1
Neutrons have no charge
Therefore an atom of lithium has no charge :- +3p + -3e = 0 no charge
Ion has uneven number of protons and electrons
This happens when an electron is lost
Or when an electron is gained
The proton number does not change.
Mass and Charge of atoms
Here are the relative mass of each particle and their electric charge.
mass charge
proton 1 +1
electron 0 -1
neutron 1 0
Protons and neutrons have similar mass.

Electrons have no mass, or extremely little amount.

Atomic Structure
Atomic Number 7
3 Li
Number on the bottom which means the number of protons or electrons
The number increases across the periodic table
Mass Number 7
3 Li
Number on the top which means the number of protons and neutrons in
the nucleus.
Neutron Number
The number of neutrons in an atom is worked out by subtracting the

number of protons (Atomic number) from the Mass number.
Neutron= mass number –atomic

number
7-3 = 4 neutron Mass number
Proton + Neutron
Atomic number
Proton or Electron
Isotopes The same element (as it has the same number of protons) but with different
number of neutrons (making the mass number different). Hydrogen
1H 2H 3H
1 1 1
Proton =
Electron =
Neutron =
Proton number = 1 Proton number = 1 Proton number = 1

Neutron number = 0 Neutron number = 1 Neutron number = 2

Metals Physical Properties Non-Metals
Does not
Conduct conduct
Electricity Electricity
Conduct Does not

Heat conduct
heat
High Low
Melting point Melting point
Boiling point Boiling point
Malleable Can be hammered into sheets Not malleable
Ductile Can be pulled into wires Not ductile
Group 1 Alkali Metals 1 electron on the outer shell Physical Properties
All metals look dull on the outside.
Over a short period of time a layer of oxide makes the metal look dull.
The inside of every metal is shiny
It is possible to cut every metal with a knife
They are kept in oil to prevent them from reacting with oxygen and
moisture in the air.
Their density is low therefore most float
The boiling point and melting point are lower than many other metals

Group 1 Alkali Metals Chemical Properties
They react with oxygen and water.
Alkali metals with oxygen and water
Oxygen causes the surface of the metal to turn dull by

forming a layer of oxide
eg. potassium + oxygen potassium oxide
4K(s) + O2 (g) 2K2O(s)
The oxide layer forms quicker as we go down the group
Alkali metals with water
The metal creates alkali as it reacts water (purple with

universal indicator)
The metal with water creates hydrogen
The metal floats, moves and fizzes.
eg. lithium + water lithium hydroxide + hydrogen
2Li(s) + 2H2O (l) 2LiOH (aq)+ H2 (g)
Sodium In addition this Potassium In addition it

moves quicker moves quickly
and has a ball and has a lilac
shape. flame.
Safety Precautions Use safety goggles

Use a small piece of metal in the water
Use tongs to hold the metal

Group 7 Halogens Physical Properties
They react with group 1 metals and salts
7 electrons on the outer shell State and appearance
Poisonous
Vapours
Chlorine Yellow Green Gas
Bromine
Bromine Orange Red Liquid Orange gas
e
Iodine
Iodine Shiny Grey Solid Purple gas
Vapours
With colour
Halogen with group 1 metals

Least reactive
They create white solids.
The halogens become less reactive down the

group
eg. potassium + chlorine potassium chloride
2K(s) + Cl2(g) 2KCl (s)
Most reactive
Safety Precautions Use safety goggles

Use a fume cupboard
Use plastic gloves

Group 7 The Halogens Identifying compounds
Metal Flame test Non- Silver

metal Nitrate test
Lithium Red Chloride white
Sodium Yellow-orange Bromide cream
Potassium Lilac Iodide yellow
Flame Test Silver Nitrate Test

(to identify the metal) (to identify non metal ions)
Examples
Lithium Red White precipitate

Chloride due to lithiwm due to chloride ions
Sodium Yellow-orange Yellow precipitate

Iodide due to sodium due to iodide ions
Potassium Lilac Cream precipitate

Bromide due to potassium Due to bromide ions
Higher Tier: Silver Nitrate ionic equation:

e.e. Ag+ (aq) + Cl- (aq) AgCl (s)
Atomic Spectroscopy (Higher Tier): This method is used to identify and

show the amount (concentration) of specific atoms/ions present in the
sample.

Higher Tier
Alkali Metals Group 1 metals become more reactive down the group.

MORE reactive
Group 1 metals react by losing 1 electron


There are more orbits as you go down the group.

The outer electron becomes further from the nucleus.
Due to less attraction it is easier to lose an electron.
The Halogens Group 7 non-metals become less reactive down the group.
 Group 7 non-metals react by gaining 1 electron

LESS reactive
 As you go down the group there are more orbits, because of

this it is harder to attract an electron, they become less
reactive
Displacement reactions
down the group
The reactions become less reactive
This reaction shows the trend in

reactivity down the group
Chlorine
Sodium Sodium
Bromine Bromide Chloride Bromine
Sodium Sodium
Iodide Bromide Iodine
Cl2(g) + 2NaBr(aq) 2NaCl (aq) + Br2(aq)

Materials and Bonding
Bonding and Structure
When a chemical reaction occurs new bonds are formed. The can form by the
transfer of electrons or by the sharing of electrons.
Ionic Bonding
Charged particles called ions are formed when electrons are transferred
between atoms during chemical bonding.
e.g.
When sodium chloride (NaCl) forms, one electron is transferred to chlorine.
This will form a full stable outer shell (like noble gasses) for the two particles
(‘atom’).
Electron
Transfer
Before bonding
Na Cl
After bonding
One electron One electron

lost gained
Proton(+) = 11 Proton(+) = 17
Electron(-) = 10 Electron(-) = 18
Charge = +1 Charge = -1
POSITIVE ION NEGATIVE ION
Strong Electrostatic
attraction between
2,8 the two ions 2,8,8
Covalent Bond
When hydrogen gas(H2) forms electrons are shared between two atoms to
form a molecule. There is no charge on molecules.
Electrons share to
form a full outer shell

Ionic Bonding
Here is the information needed to draw ionic bonding diagrams.
Check the ionic charges by using the ions table at the back of the examination
paper.
Sodium Chloride (NaCl) Group 1 with Group 7
Electron
Before Bonding Transfer
After bonding
Strong electrostatic
charge between the ions
cryf rhwng y ddau ion
Magnesium oxide (MgO) Group 2 with Group 6
Before Bonding Electron

Transfer
After bonding
MgO has a higher

melting point than
Strong electrostatic NaCl as the charges
charge between the ions are greater – there is
cryf rhwng y ddau ion more attraction
between ions

Materials and bonding
Lithium Oxide (Li2O) Group 1 with Group 6
Before Bonding
Electronic
Transfer
After bonding
Magnesium Chloride (MgCl2) Group 2 with Group 7
Before Bonding Electronic

Transfer
After bonding

Covalent Bonds
Hydrogen (H2)
Electrons share to
Chlorine (Cl2)
Electrons share to
Water (H2O)
Electrons share to
Hydrogen Chloride (HCl)
Electrons share to

Covalent Bonding
Ammonia (NH3)
Methane (CH4)
Covalent examples with double bonds (Higher Tier)
Oxygen (O2) Carbon Dioxide (CO2)
Ethene (C2H4)

Simple and Giant structures
Giant ionic structure(e.g. sodium chloride, magnesium oxide),
High Melting and Boiling points

Solubility = Dissolved in water
Simple molecular structure (e.g. carbon dioxide, water)
Low Melting and Boiling points

Solubility = Dissolved in water
CO2 H2O (water) CH4 (methane)
As the forces between molecules are weak the melting and boiling points are
low
Giant covalent structure (e.g. diamond, graphite),

Very High Melting and Boiling points
Solubility = Does not dissolve in water
Diamond Graphite

Diamond and Graphite Carbon atoms linked

covalently to three
Carbon atoms
other carbon atoms
Carbon atoms linked
covalently to four
other carbon atoms
Diamond Graphite
Sea of free moving

electrons because
Properties related to uses the fourth electron is
unbonded.
Graphite
Appearance Grey/black shiny solid

Hardness very soft
Conductivity Conducts electricity
Melting point Very high over 3600ºC
Uses Pensil lubricants
Diamond
Uses
Appearance Transparent/crystalline Gemstones
Hardness very hard Glass cutting, Drill bits
Conductivity Electrical insulator
Melting point Very high over 3500ºC
Carbon nanotubes
 They are roles of carbon

hexagons similar to graphite.
They conduct electricity / used

in semi-conductors
The have a very small
diameter which is about
10,000 times less than a

human hair.

They are extremely strong.

Very low density
They are proposed to be used
in small electronic circuits

Materials
The uses of everyday materials depends on their properties.
Aluminium Ceramic Diamond
Low density Hardness, strength Hardness, lusture
Aluminium Oxide Teflon Glass
Low friction and wear Low friction high Mpt Hardness transmits light
The properties of all materials, are determined by:-
the types of atoms present,

the types of bonding between the atoms,
and the way the atoms are packed together
Metals are giant structures with free electrons
Metallic bonds are strong, so metals can maintain a regular structure and
usually have high melting and boiling points.
Outer shell electrons of metals are free to move.
The strength of bond in a metal is the force of attraction between the metal
ions and free moving electrons.
More free electrons and more protons in the ions increase the strength of a
metal.

Metallic bonding
Free electrons allow electricity to be carried as well as heat energy.
Sodium metal
Outer electron
free to move
These electrons allow metals to conduct electricity and conduct heat.
Metals are also malleable (hit into shape) and ductile (drawn into wires)
because the free electrons allow the metal atoms to slide over each other.
Having more free electrons in the outer shell e.g. Aluminium compared to
sodium above and more protons in each nucleus the forces of attraction for
the free electrons is greater. This makes the metal stronger.
Aluminium metal
More outer
electron free
to move.
More protons in
each ion
attracting more
electrons

Smart Materials
Smart Materials
The term smart material has been given to a range of modern materials.
A variety of smart materials exist which can change shape and colour, retain
shape after bending and can expand greatly with different liquids.
This means that their properties change.
The materials properties change with a change in the surroundings, such as

changes in temperature, light, pH.
Thermochromic Paint
This smart material has the ability to change colour with a change in
temperature.
The boat seen in this t shirt appears because

thermochromic paint has been used. Under cold
conditions the pigments are white, but when heated
in warm weather, or if the person becomes warmer
the pigments change colour to reviles a picture of a
boat.
Photochromic Paint
This material has the ability to change colour with a change in the light
strength.
The sunglass lenses become darker when exposed

to strong light and become lighter in weak light

Smart Materials
Shape memory alloy
This smart material is a mixture of metals (alloy) that retains its original shape
when heated
A mixture of nickel and titanium make up the alloy

called NiTi or nitinol.
This metal can be bent into any shape at low

temperature, but when heated it can remember its
original shape so it bends back very quickly. It can
be used as a coffeepot thermostat.
Stents are metal structures that can be inserted in

veins to prevent them from sticking together. The
stents are cooled to below 37C so they change
shape and become thinner, when inserted into the
vein it warms up to body temperature and changes
shape to open the vein.
This alloy can also be used in super elastic

spectacle frames. These retain their original shape
after bending them.
Shape memory polymer
This smart material is a form of plastic that can retain its original shape when
heated. These could be used for:-
Surgical stutures are threads of smart polymer that

can tighten to the right tension automatically when
heated.
Car bumpers could be made from this material. If

the car body such as bumpers were dented, on
heating they would regain their original shape.

Smart Materials
Polymer gels
This smart material is a form of plastic with cross linkage (see diagram below)
that can swell or shrink with different liquids.
No cross linkage across polymer Cross linkage across polymer
These gels can swell to 1000 times their volume depending on the
temperature or pH.
Artificial snow – this smart material expands

greatly by adding water. It can also shrink by
heating.
Nappies – this smart material is similar to

artificial snow and expands greatly when it
becomes wet.
Contact Lens – within these lenses there is a

smart material which prevents them from drying
up. They can then be used for weeks instead of
days.
Artificial muscles – gels can be used to swell

and shrink creating an artificial muscle.
Robot actuators – gels can be used to swell and

shrink creating movement.
Toxic Chemical absorber – gels can be used to

block dangerous chemicals in the body.

Rates of Reactions It means the speed of a reaction
There are four ways 2 increase the rate of the

reaction on the right..
1. change concentration of the acid (acid strength)
2. change temperature of the acid Magnesium Hydrogen
3. change surface area of the magnesium (crush into
powder) Hydrochloric
4. use a catalyst Acid
magnesium + hydrochloric acid magnesium chloride + hydrogen
Reactants Products
The substances that react together. The substances that are produced.
Mass Mg
Hydrogen
Time Time
The reactants are used up The products form
Collision Theory: Particles must collide with enough energy – these are called
successful collisions
Change concentration Strong acid

More H2
forms
If the strength of the acid is weak,

it will take more time for the
hydrogen to be produced. Weak acid
Less H2
forms
Time sec
Acid particles
Weak acid
Strong acid
Mg particles
As there are less acid particles in weak acid the chance of them colliding with
magnesium successfully is lower.

Rates of Reaction It means the speed of a reaction
Change temperature Higher

temperature
– less time to
create H2
If the temperature of the acid is
higher, it will take less time for
hydrogen to be produced
Lower
temperature
– more time
to create H2
Time sec
More energy
Cold acid Hot acid

Less energy
When the temperature is higher the particles have more energy. As a result the
particles collide more frequently. The collisions have more energy – there are more
successful collisions.
Change Surface Area Large

Surface Area
– less time to
create H2
Hydrogen
Small Surface
Area – more
time to create
magnesium
H2
broken up.
Time sec
If magnesium is cut into little There is more chance for the particles to
pieces, there will be more surface collide successfully if the surface area is
area for the acid to react large.
Small pieces
of
magnesium.
Small Surface area Large Surface area

Rates of Reaction It means the speed of a reaction
Using a Catalyst
If a catalyst (e.g. iron) is added to the acid

and magnesium the reaction will be faster.
catalyst
e.g. iron.
Catalyst
a substance that speeds up a reaction but is not used up

(e.g. if 1g of catalyst is used, there will be 1g of catalyst left)
A catalyst can be reused over and over.
Different catalysts are used for different reactions. e.g. manganese oxide is a catalyst
which is used to create oxygen quickly from hydrogen peroxide.
The development of better catalysts is extremely important as it can lead to new ways of
making materials that may use less energy, use renewable raw materials or use fewer
steps.
.
.
Using Sensors
30ºC
Advantages of using sensors
Recording advantages
A number of results per second
can be collected
Acid and
Instant showing of results magnesium
Screen to show results instantly .
Long term collection of

results Types of sensors
(Can collect results day and night
without a break)
Light sensors
Temperature sensors
pH sensors
Gas sensors

Reaction rates Higher Tier
Calculating rate of reaction
Concentration
By drawing a tangent to the curve
y
we can calculate the rate at any
point, the steeper the tangent the
x
faster the reaction.
Rate = y / x
Time
More about temperature
The energy of a collision is very important, only those collisions that have enough
energy lead to reaction (these are known as successful collisions). The minimum
energy required for a reaction to take place is called the Activation energy.
More about Catalysts

Activation Energy
Reaction without a catalyst

A catalyst reduces the activation
energy, it provides an alternative
pathway for the reaction Reaction with a catalyst
Reactants
Products

Fractional Distillation
Crude oil is a mixture of different substances, most of them being hydrocarbons
H H H H
Example of a H C C C C H
hydrocarbon H H H H
Some other
substances
S
Hydrocarbons are molecules which contain the elements hydrogen and carbon only.
Fractional Distillation – it is possible to separate hydrocarbons by fractional distillation

because hydrocarbons boil at different temperature ranges
Fractional Distillation in a laboratory
The reaction is carried out in a fume cupboard as poisonous gases such as sulphur
dioxide can form.
Condenser
Fractionating
column
Fraction
Heat
As some of the hydrocarbons have similar boiling points a group of them will collect
together. Fraction is the name given to a group of hydrocarbons that collect this way.
The hydrocarbon boiling point increases with the size of the carbon chain.
In the industrial process the crude oil is vaporized. The vapour is let into the column
where it is hot at the bottom an cools up the column. The fractions with shorter chains
have lower boiling points and can condense higher up the column. The longer
hydrocarbons condense at a lower level in the column.

Fractional Distillation
Crude oil is separated into fractions The process is called Fractional Distillation
Number of
Fractionating Boiling point Use
Fraction carbon atoms in
column range / ˚C
a chain
Gas 1–4 -160 to 25 Fuel
Petrol 4 – 12 40 to 100 Car fuel
Naphtha 7 – 14 100 to 150 Chemicals
Kerosene 11 – 15 150 to 250 Jet fuel
Diesel oil 15 – 19 250 to 350 Heating fuel
Lubricating oil 20 – 30 over 350 Car oil
Bitumen C30 – above over 400 Road pitch
Heated
Crude oil
Crude oil is separated into less complex mixtures, these are called fractions. Fractions
contain hydrocarbons with boiling points in the same range, e.g. the petrol fraction has
hydrocarbons with boiling points in the range 40-100 ˚C
Long chain hydrocarbons are at the bottom of the column as they do not boil until a
very high temperature.
Some of the fractions are used as fuels (e.g. kerosine – aeroplane fuel) others are further
processed by cracking.
Properties of the fractions
As the length of the chain increases:
1. The colour of the fraction turns

from colourless – yellow - brown.
2. They are harder to ignite.
3. They burn dirtier.
4. They get more viscous
Short Long
chain chain

Basic Organic Chemistry
Alkanes These are hydrocarbons with single covalent bonds between the
carbon atoms. They are referred to as saturated hydrocarbon for this
reason. Alkanes have the general formula CnH2n+2
Name Formula Structural Formula
Methane CH4
Ethane C2H6 Single bond
Propane C3H8
Butane C4H10
Pentane C5H12
Alkanes are fairly unreactive, they combust well only.
Alkenes When there are double bonds between two carbon atoms the name
given to the group is alkenes. For this reason they are described as
unsaturated molecules. Alkenes have the general formula CnH2n
Name Formula Structural formula
Ethene C2H4
Propene
C3H6
As a result of the double bond the alkenes are very reactive molecules, the double
bond can be broken to form single bonds with other atoms (addition reaction).

Alkenes – Addition Reactions
Reaction with Hydrogen (Hydrogenation) (Higher Tier) Can you write the
equation for
H H propene?
H H Nickel catalyst
C C + H2 H C C H
High pressure
H H
H H
ethene hydrogen
ethane
Reaction with Bromine Water (Higher Tier)
H H
H H
+ Br2 dibromoethane
C C H C C H
H H
ethene bromine Br Br
This reaction is a way of identifying

alkenes. Brown bromine water turns
colourless
Addition Polymerisation
Creating Plastics
When small reactive molecules such as ethene react together in a chemical

reaction a long chain molecule is formed called a polymer.
Monomer is the name given to small reactive organic molecule
monomer
polymer
The process whereby monomers link to create a polymer is polymerisation.
The type of polymerisation that happen here is addition polymerisation as

there is only one product formed

Addition Polymerisation
The process of making poly(ethene) is an example of addition polymerisation. The

unsaturated monomers used are ethene.
ethene polythene
n(H2C=CH2) ( CH2 CH2 ) n
PTFE / Poly(tetrafluoroethene) /Teflon
F F F F
n
F F
F F n
Tetrafluoroethene Poly(tetrafluoroethene)
n(F2C=CF2) ( CF2 CF2 ) n
Polyvinyl chloride (PVC)
n
Cl Cl n
Vinyl chloride Polyvinylchloride
n(H2C=CHCl) ( CH2 CHCl ) n
Polypropene
n
CH3 CH3 n
propene Polypropene
n(H2C=CHCH3) ( CH2 CHCH3 ) n

Types of Plastics
Plastics are classed on the basis of their reaction on heating, there are 2 types
Thermoplastics – when these are heated they lose their shape. This is
because the hydrocarbon chains are not linked together, as they are heated
the chains slide over each other causing the plastic to melt. Poly(ethene),
polypropylene, PTFE and PVC are examples
heat
e.g. plastic bags, home containers e.g. domestos bottle
Thermoset – these have strong covalent bonds between chains. The cross
linkages make the structure rigid, because of this they do not melt upon
heating. They can only be heated once into shape Bakelite and melamine are
examples
Cross linkages
E.g. saucepan handles, Electrical light fittings;

Energy in reactions
Changes in temperature happen often during chemical reactions.
Exothermic reactions Endothermic Reaction
A reaction where
A reaction where temperature falls.
temperature rises. e.g. ammonium nitrate
e.g. magnesium and acid and acid
Here is a reaction for making ammonia
Hydrogen + Nitrogen Ammonia
3 H2(g) + N2(g) 2 NH3(g)
To create the product ammonia its is necessary to break bonds between hydrogen and
nitrogen (the reactants).
To break bonds energy in required. Creating bonds releases energy.
388 kJ
436kJ
388 kJ
436kJ
388 kJ
388 kJ
944kJ
388 kJ
388 kJ
436kJ
Bonds Broken Bonds Made

436 + 436 + 436 + 944 = 2252kJ 388 x 6 = 2328kJ
Overall Energy Change = Bonds broken – Bonds made

Exothermic Reaction
In an endothermic - Because energy is
reaction the number 2252 - 2328 = -76kJ released (negative
would be positive. number)

Chemical Calculations
Every atom has different mass. This is determined by the number of protons
and neutrons in the nucleus.
A lithium atom has a mass of 7.
3 protons and 4 neutrons
Relative atomic mass (Ar) is a way of saying how heavy different atoms are
compared to each other.
The Ar of Lithium is 7 and that of Carbon is 12. We use the top number to
determine this; this is called the mass number
Relative formula mass or relative molecular mass (Mr) is the mass for a
compound (e.g. MgCl2) so the masses for each element are
Mg Cl Cl
Mass numbers 24 + 35 + 35 = 94
What is the molecular mass of ammonium sulphate (NH4) 2SO4?

(N=14, S=32, O=16, H=1)
Calculate (NH4) 2 first = 14+1+1+1+1 = 18 x 2 = 36
S= 32
4 oxygen atoms 16 x 4 = 64
Mr= 132
Calculating % composition
After calculating Mr it is possible to calculate % composition, this shows how

much of a specific element is in a compound in percentage form
e.g. % Mg in MgCl2 = total Mr of Mg in MgCl2 x 100

Mr MgCl2
24 x 100 = 25.5 %
94

Calculating Reacting Masses
By using relative atomic masses and (Ar) and relative molecular masses (Mr)
it is possible to calculate how much of a product is produced or how much
reactants are needed.
e.g. (product calculation)
What is the mass of magnesium oxide is produced when 60g of magnesium

is burned in air?
Symbol Equation
2Mg + O2  2MgO
Mr = 224 2 (24+16)
48 80
Therefore 48g (or tonnes) will produce 80g
1g 80  48 = 1.67g
60g will produce 60  1.67 = 100.2g
e.g. (reactant calculation)
What is the mass of magnesium needed to produce 90g of magnesium

oxide?
2Mg + O2  2MgO
Mr = 224 2 (24+16)
48 80
Therefore 48g (or tonnes) will produce 80g
Or 80g of MgO will be produced with 48g of Mg
1g 4880=0.6g
90g will produce 90  0.6 = 54g

Calculations
Determining the formula of a compound from experimental data
When 4 g of copper oxide is reduced in a steam of hydrogen, 3.2 g of copper

remains.
1. Work out how much oxygen was contained in the compound
4 – 3.2 = 0.8 g
Cu O
3.2 0.8
Divide with Ar 64 16
0.05 0.05
Divide with smallest 0.05 0.05
Whole number 1 1
1 Cu 1O
Formula = CuO
Example 2
Find the formula of iron oxide produced when 44.8g of iron react with 19.2g of
oxygen. (Ar Fe = 56 and O = 16)
Fe O
Mass 44.8 19.2
Divide with Ar 44.856 19.216
0.8 1.2
Divide with the smallest value 0.80.8 1.2 0.8
1 1.5
A formula must have whole numbers therefore
2 3
Formula = Fe2O3

Calculating reactants or product masses
Reactants Products
NaOH + HCl NaCl + H2O
23+16 + 1 1 + 35 23+35 1+1+16
40 36 58 18
76 76
Units g / tones g / tones
Calculating the percentage yield
When we want to create a chemical, the aim is to work carefully and to

produce the maximum amount possible.
The amount formed or yield is calculated in percentage. It is very unlikely that

100% yield will be achieved e.g. some might be stuck in filter paper,
evaporating dish, the product might react with the air.
Example
Magnesium metal dissolves in hydrochloric acid to form magnesium chloride.
Mg(s) + 2HCl(aq) MgCl2(aq) + H2(g)
24g 95g
(24 + 35.5 + 35.5)
(a) What is the maximum theoretical mass of magnesium chloride which
can be made from 12g of magnesium?
12g 95/2 = 47.5g
(b) If only 47.0g of purified magnesium chloride was obtained after

crystallising the salt from the solution, what is the % yield of the salt
preparation?
actual amount obtained x 100
% yield = maximum possible
% yield = 47.0 x 100 = 98.9% (to 1 decimal place)

47.5

Water
Water
Water is necessary for life to exist. The quality of life depends on the
availability of clean water. Water in this country is made drinkable by treating
rainwater.
Here are the steps involved in making water drinkable.
Groundwater, rivers
provide water to
reservoir
Water stored in
reservoir. Solids settle
to bottom
Small particles are

removed by filtration
Chlorination – to kill
bacteria
Clean water stored in

tanks and water tower
Water passed along

pipes to households
Fluoride ions are added to water to strengthen children’s teeth in some areas.
Fluoride is not added to water supplies in Wales.

Water
Water Preservation
Although there is ample water on Earth, only a very small fraction is safe for
drinking. With an increasing population and developing industry our need for
water is larger than ever.
The need for water
Water is needed in factories Hygiene – We need water to

for cooling machinery keep clean and wash clothes
Water is needed on farms to

grow food We need drinking water
We use 150 litres of water each on average every day. The water comes from
natural underwater storage, rivers and different reservoirs. During dry
conditions when there is not enough rain there is a strain on the water supply
– areas will experience drought.
Shortage of water problems arise when there is more demand than supply of
water, which is a threat to life and the environment. Water cost may increase
if future climate changes cause shortage of water in the UK. Using less water
in the future is very important.
Here are some ways of decreasing our use of water.


Use washing machines and dish washers only when they are full.

Having a shower instead of a bath.

Use waste water for plants and to wash the car.

Repair dripping taps.
Do not allow the water to run excessively (e.g. when brushing teeth)

Water
Desalination - It is possible to desalinate sea water to supply drinking

water.
To desalinate sea water distillation of sea water by boiling is used. Boiling

uses large amounts of energy which is costly. Due to this the process is not
viable in many parts of the world.
If a country is to use desaliantion they need to

ensure
• a renewable means of creating heat

energy where no carbon dioxde is created
(greenhouse effect)
• sea nearby.
Distillation – Separating water and miscible liquids.
Pure liquids have specific boiling points, e.g. water boils ar 100°C. Ethanol
boils at 78°C. Water and ethanol are miscible (when two liquids mix together
easily without separating into layers.)
thermometer
condenser
Water out
Distillation flask
Cold water in receiving

flask
Bunsen Burner
distillate
If a mixture of miscible liquids exist it is possible to separate them by

distilation. In a mixture of ethanol and water, the ethanol would boil and
evaporate first (as it has the lower boiling point) leaving the water behind. The
ethanol would condense on the cold wall of the condeser.

Water
Chromatography
Pigments in ink can be separated using paper chromatography.
The most soluble substance will be transported furthest by the solvent.

Water
Chromatography
The distance that a substance travels allows scientists to recognise a

substance. Am Rf value is calculated
Rf Value= distance the substance has traveled

distance the solvent has traveled
e.g. The Rf value for ink B = 4/8 = 0.5
Gas Chromatography (Higher Tier)

This method is very useful as it gives quantitative information -
that is the amount of substance present. Chemical analysts use the method to
identify e.g. the amount of a pollutant in water or air, it is also used to identify
the amount of an illegal drug in blood.

Water
Types of drinking water.
Depending on the type of rocks a region has, water can be of two types :-
Hard water and Soft water
Hard Water
If rainwater passes along limestone (calcium carbonate) rocks on its way to a

reservoir, calcium ions Ca2+ will collect in the water. Other ions such as
magnesium ions Mg2+can also collect in water. These additional ions make
the water hard.
Soap in hard water does not readily lather, scum is formed
Hardness in water is defined as difficulty in producing a lather with

soap.
There are two types of hard water:
Temporary hard water and permanently hard water

Water
Temporary hard water
Calcium and Magnesium

hydrogen carbonates form
temporary hard water because
when this water is boiled,
hardness is removed.
Hydrogen carbonates are

decomposed.
Lime scale furring up a kettle element
Magnesium and Calcium become
magnesium carbonate and calcium carbonate which are insoluble. This lime
scale collects on kettles as ‘fur’.
Permanently hard water
When insoluble calcium and magnesium sulfates or

carbonate exists in water it is called permanently
hard water.
Lime scale clogs up
hot water pipe
Treating permanently hard water.
1. Adding sodium carbonate (washing soda).
sodium + calcium calcium sodium

+
carbonate sulfate carbonate sulfate
Calcium ions are

removed as solid
Calcium
carbonate
making the water
softer

Water
2. Ion exchange column
When hard water is passed along negatively charged particles within a

container, the positive ions of magnesium and calcium in hard water
are attracted and held there, they are replaced with sodium ions. Water
leaves the container soft.
Advantages and Disadvantages of hard water
Advantages
1. Strengthens teeth
2. Reduces the risk of heart disease
3. Some people prefer the taste of hard water
Disadvantages
1. Lime scale on kettles make them less efficient at boiling water and
therefore waste energy. Hot water pipes can also block up with lime
scale.
2. Removing scale can be expensive.
3. More soap is needed with hard water.
4. Ion exchange water softeners release sodium ions which can be

unsuitable for some uses.
5. Ion exchange units need to be ‘cleaned’ out of magnesium and calcium

ions when it has filled up (usually with sodium chloride (salt))

Water
Experiments to determine the amount of hardness of water.
A buret is the apparatus used to measure the amount of soap solution

needed.
The amount of water to be tested is kept the same in the conical flask.
Buret – filled with

soap solution
Conical flask with known

volume of water e.g. hard
water
Soap solution is added every 1 cm3 to the water and the flask shaken to try
and form lather (bubbles). When lather starts to form the soap solution is
added every 0.5 cm3 until it stays permanently. The amount of soap solution
can be determined using the buret.
Soft water lathers easily therefore little amount of soap solution is used.
Hard water lathers slowly therefore more soap solution is needed.
Experiment to determine if water is permanently hard or temporarily

hard.
If two samples of water seem to be hard water from the above experiment,
samples of both types of water could be boiled.
The same experiment as above could then be undertaken.
If the water is still difficult to lather then the water is permanently hard.

Water
Solubility curves
Soluble solids dissolve more readily when heated.
Every solid has a different rate of solubility. The diagram below shows that
potassium nitrate dissolved more readily than copper sulphate at any
temperature above 0ºC.
e.g.
3
The amount of copper sulphate that dissolves at 40ºC is 24 g in 100 cm water.
3
The amount of potassium nitrate that dissolves at 40ºC is 60 g in 100 cm water.
Notice that the standard amount of water used is 100 cm 3 or 100 g.
This graph shows the maximum amount of solid that will dissolve at any
temperature.
A saturated solution is the maximum amount of solid that will dissolve at a

particular temperature.
3
The amount of copper sulphate that dissolves at 60ºC is 107 g in 100 cm water.
If a saturated solution of copper sulphate at 60ºC was to cool down to 40ºC

not as much solid would be able to dissolve.
It is possible to work out how much less would dissolve by subtracting:
107 g – 60 g = 47 g of solid would appear on the bottom of the beaker.

FORMULAE FOR SOME COMMON IONS
POSITIVE IONS NEGATIVE IONS
Name Formula Name Formula
Aluminium Al3+ Bromide Br–

Ammonium NH 4+ Carbonate CO32–
Barium Ba2+ Chloride Cl –
Calcium Ca2+ Fluoride F–
Copper(II) Cu2+ Hydroxide OH –
Hydrogen H+ Iodide I–
Iron(II) Fe2+ Nitrate NO3–
Iron(III) Fe3+ Oxide O2–
Lithium Li+ Sulphate SO42–
Magnesium Mg2+
Nickel Ni2+
Potassium K+
Silver Ag+
Sodium Na+

48
PERIODIC TABLE OF ELEMENTS
1 2 Group 3 4 5 6 7 0
1 4
1 H 2 He
Hydrogen Helium
7 9 11 12 14 16 19 20
3 Li 4 Be 5 B 6 C 7 N 8 O 9 F 10 Ne
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
23 24 27 28 31 32 35 40
11 Na 12 Mg 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar
Sodium Magnesium Aluminium Silicon Phosphorus Sulphur Chlorine Argon
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
GCSE Science: Chemistry 2
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
86 88 89 91 93 96 99 101 103 106 108 112 115 119 122 128 127 131
37 Rb 38 Sr 39 Y 40 Zr 41 Nb 42 Mo 43 Tc 44 Ru 45 Rh 46 Pd 47 Ag 48 Cd 49 In 50 Sn 51 Sb 52 Te 53 I 54 Xe
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
133 137 139 179 181 184 186 190 192 195 197 201 204 207 209 210 210 222
55 Cs 56 Ba 57 La 72 Hf 73 Ta 74 W 75 Re 76 Os 77 Ir 78 Pt 79 Au 80 Hg 81 Tl 82 Pb 83 Bi 84 Po 85 At 86 Rn
Caesium Barium Lanthanum Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon
223 226 227
87 Fr 88 Ra 89 Ac
www.bangor.ac.uk
Francium Radium Actinium Key:
Mass number A
X Element Symbol
Atomic number Z
Name

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Contents

www.bangor.ac.uk GCSE Science: Chemistry 2 1

Atoms contain a nucleus and electrons

The small central nucleus is made from protons and neutrons.

Around these are orbits (shells) of electrons.

Here is a diagram showing an atom of Lithium

This diagram shows that a piece of Potassium is made up of millions of the

Atoms of different elements are different.

The number of protons is always different with different elements.

Element Lithium Potassium

Neutron number for some elements are the same.

2 GCSE Science: Chemistry 2 www.bangor.ac.uk

Atoms have no charge.

Protons are positively charged. (+)

Every electron has a charge of -1

Every proton has a charge of +1

Neutrons have no charge

Therefore an atom of lithium has no charge :- +3p + -3e = 0 no charge

Ion has uneven number of protons and electrons

This happens when an electron is lost

Or when an electron is gained

The proton number does not change.

Mass and Charge of atoms

Protons and neutrons have similar mass.

www.bangor.ac.uk GCSE Science: Chemistry 2 3

The number increases across the periodic table

The number of neutrons in an atom is worked out by subtracting the

Neutron= mass number –atomic

Proton number = 1 Proton number = 1 Proton number = 1

4 GCSE Science: Chemistry 2 www.bangor.ac.uk

Conduct Does not

Malleable Can be hammered into sheets Not malleable

Ductile Can be pulled into wires Not ductile

Group 1 Alkali Metals 1 electron on the outer shell Physical Properties

All metals look dull on the outside.

The inside of every metal is shiny

It is possible to cut every metal with a knife

Their density is low therefore most float

www.bangor.ac.uk GCSE Science: Chemistry 2 5

They react with oxygen and water.

Alkali metals with oxygen and water

Oxygen causes the surface of the metal to turn dull by

eg. potassium + oxygen potassium oxide

4K(s) + O2 (g) 2K2O(s)

The oxide layer forms quicker as we go down the group

Alkali metals with water

The metal creates alkali as it reacts water (purple with

The metal with water creates hydrogen

The metal floats, moves and fizzes.

eg. lithium + water lithium hydroxide + hydrogen

2Li(s) + 2H2O (l) 2LiOH (aq)+ H2 (g)

Sodium In addition this Potassium In addition it

Safety Precautions Use safety goggles

6 GCSE Science: Chemistry 2 www.bangor.ac.uk

They react with group 1 metals and salts

7 electrons on the outer shell State and appearance

Halogen with group 1 metals