Safewing TKS 406B

SAFETY DATA SHEET
Safewing TKS 406B Page 1
Substance key: KFTKS406B Revision Date: 08/14/2018

Version : 2 - 2 / USA Date of printing :08/16/2019
SECTION 1. IDENTIFICATION
Identification of the Clariant Corporation

company: 4000 Monroe Road
Charlotte, NC, 28205
Telephone No.: +1 704-331-7000
Information of the substance/preparation:

BU Industrial & Consumer Specialties
Product Stewardship, +1-704-331-7710
Emergency tel. number: +1 800-424-9300(CHEMTRE C)
Trade name: Safewing TKS 406B

Material number: 288910
Primary product use: Aircraft de-icing
SECTION 2. HAZARDS IDENTIFICATION
GHS classification in accordance with 29 CFR 1910.1200

Flammable liquids : Category 3
Acute toxicity (Oral) : Category 4
Eye irritation : Category 2A
Specific target organ toxicity : Category 2 (Kidney)

- repeated exposure (Oral)
GHS label elements

Hazard pictograms :
Signal word : Warning
Hazard statements : H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H373 May cause damage to organs (Kidney) through prolonged
or repeated exposure if swallowed.
Precautionary statements :
Prevention:
P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
SAFETY DATA SHEET

P233 Keep container tightly closed.

P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P301 + P312 + P330 IF SWALLOWED: Call a POISON
CENTER/doctor if you feel unwell. Rinse mouth.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical name CAS-No. Concentration (% w/w)
Ethanol 64-17-5 1-5
Methanol 67-56-1 < 0.5
Ethanediol 107-21-1 60 - 100
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
SECTION 4. FIRST AID MEASURES
General advice : Remove/Take off immediately all contaminated clothing.
If inhaled : Move the victim to fresh air.

SAFETY DATA SHEET

Give oxygen or artificial respiration if needed.

Get immediate medical advice/ attention.
Never give anything by mouth to an unconscious person.
In case of skin contact : Immediately flush skin under running water for at least fifteen
minutes. Seek medical attention if irritation or chemical burn is
present.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Get medical attention immediately if irritation develops and
persists.
If swallowed : IF SWALLOWED: Immediately call a POISON

CENTER/doctor.
Most important symptoms : The possible symptoms known are those derived from the
and effects, both acute and labelling (see section 2).
delayed No additional symptoms are known.
Notes to physician : None known.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Unsuitable extinguishing : High volume water jet

media
Specific hazards during : Hazardous decomposition products:

firefighting Carbon monoxide and carbon dioxide
In case of fires, hazardous combustion gases are formed:

Carbon monoxide (CO)
Burning produces noxious and toxic fumes.
Further information : Wear full protective clothing and self-contained breathing

apparatus.
Remove product from areas of fire, or otherwise cool
containers with water in order to avoid pressure being build up
due to heat.
Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Wear positive pressure self-contained breathing apparatus

(SCBA) and full protective equipment.
Special protective equipment : Self-contained breathing apparatus

for firefighters
SAFETY DATA SHEET

SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Wear suitable protective equipment.

protective equipment and Only trained personnel should be involved in spill operations.
emergency procedures Wear suitable protective equipment. Ensure adequate
ventilation. Remove all ignition sources. Contain spill and
pump into proper containers using explosion-proof equipment.
Smaller spills may be recovered using an inert non-
combustible absorbent material (sand, kieselguhr) and
collected into suitable containers. Do not use organic
absorbent material. Containers in which spilt substance has
been collected must be properly labelled. Spill may be
covered with an appropriate foam to hinder the formation of
explosive vapours. Wash spill area. Do not allow to enter
sewers, storm drains, surface waters or the soil.
Formation of explosive gas/air mixtures.
Wearing appropriate personal protective equipment, contain
spill, collect onto inert absorbent, and place in a suitable
container.
Contain spill and pump into proper containers using
compatible equipment. Smaller spills may be recovered using
inert absorbent material. Wash spill area. Wear prescribed
protective gear.
Environmental precautions : Do not allow to enter drains or waterways
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
Can be landfilled or incinerated, when in compliance with local

regulations.
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion
Advice on safe handling : Avoid contact with skin, eyes and clothing.
Use only with adequate ventilation and proper protective
eyewear, gloves, and clothing.
Avoid contact with skin and eyes.
Technical : Keep containers tightly closed in a cool, well-ventilated place.

measures/Precautions
Keep containers tightly closed in a cool, well-ventilated place.

Handle and open container with care.
SAFETY DATA SHEET

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Ethanol 64-17-5 STEL 1,000 ppm ACGIH
TWA 1,000 ppm NIOSH REL
1,900 mg/m3
TWA 1,000 ppm OSHA Z-1
1,900 mg/m3
TWA 1,000 ppm OSHA P0
1,900 mg/m3
Methanol 67-56-1 TWA 200 ppm ACGIH
STEL 250 ppm ACGIH
TWA 200 ppm NIOSH REL
260 mg/m3
ST 250 ppm NIOSH REL
325 mg/m3
TWA 200 ppm OSHA Z-1
260 mg/m3
STEL 250 ppm OSHA P0
325 mg/m3
TWA 200 ppm OSHA P0
260 mg/m3
Ethanediol 107-21-1 C 50 ppm OSHA P0
125 mg/m3
TWA 25 ppm ACGIH
(Vapour)
STEL 50 ppm ACGIH
(Vapour)
STEL 10 mg/m3 ACGIH
(Inhalable
fraction,
Aerosol only)
Engineering measures : Local ventilation recommended - mechanical ventilation may
be used.
Personal protective equipment

Respiratory protection : Wear an approved respirator when exposed to vapours or to
mists beyond the TLV. Use appropriate filters. Do not exceed
filters limitations. TLV = Threshold Limit Value
If airborne concentrations pose a health hazard, become

irritating or exceed recommended limits, use a NIOSH
approved respirator in accordance with OSHA respiratory
protection requirements under 29 CFR 1910.134
Wear an approved respirator when exposed to vapours or to

SAFETY DATA SHEET

mists beyond the TLV. Use appropriate filters. Do not exceed

filters limitations. TLV = Threshold Limit Value
Hand protection
Material : Impervious gloves
Remarks : Impervious gloves
Butyl Rubber, PVC Or Neoprene.
Eye protection : Safety goggles

Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary,
face shield.)
Safety goggles
Skin and body protection : Wear suitable protective clothing.

Protective clothing to minimize skin contact should be worn.
Chemically resistant safety shoes. Wash contaminated
clothing with soap and water and dry before reuse. Safety
showers and eyewash stations should be provided in all
areas where this material is handled.
Wear suitable protective clothing.
Protective measures : Avoid contact with skin and eyes.
Hygiene measures : Keep away from food and drink.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Colour : colourless, clear
Odour : odourless
none
Odour Threshold : not tested.
pH : not tested.
Freezing point : -60 °C
Boiling point : 120 °C

(1,013.25 hPa)
Flash point : 54 °C
Method: closed cup
Evaporation rate : not tested.

SAFETY DATA SHEET

Flammability (solid, gas) : Not applicable
Self-ignition : The substance or mixture is not classified as self heating.
Burning number : Not applicable
Upper explosion limit / upper : not tested.

flammability limit
Lower explosion limit / Lower : not tested.

flammability limit
Vapour pressure : 9.33 hPa (0 °C)
Relative vapour density : 2
Density : 1.092 - 1.097 g/cm3 (20 °C)
Bulk density : Not applicable
Solubility(ies)
Water solubility : completely miscible (20 °C)
Solubility in other solvents : not tested.
Partition coefficient: n- : Not applicable

octanol/water
Auto-ignition temperature : 365 °C
Decomposition temperature : No decomposition if used as directed.
not available
Viscosity
Viscosity, dynamic : not tested.
Viscosity, kinematic : 11 - 13 mm2/s (20 °C)
Explosive properties : no data available
Oxidizing properties : Not applicable
Metal corrosion rate : < 6.25 mm/a
Minimum ignition energy : not tested.
Particle size : Not applicable
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.

SAFETY DATA SHEET

Chemical stability : Stable
Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions Stable
Conditions to avoid : Strong oxidizers and strong acids. Heated surfaces, sparks,
open flames and other sources of ignition.
None known.
Incompatible materials : Strong acids and oxidizing agents
Hazardous decomposition : Hazardous decomposition products:

products Carbon monoxide and carbon dioxide
When handled and stored appropriately, no dangerous

decomposition products are known
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure

None known.
Acute toxicity
Product:
Acute oral toxicity : LC50 (Rat): 8,000 mg/kg
Acute toxicity estimate: 606.43 mg/kg

Method: Calculation method
Acute inhalation toxicity : LC50: 200 mg/l
Acute toxicity estimate: > 40 mg/l

Exposure time: 4 h
Test atmosphere: vapour
Acute dermal toxicity : Acute toxicity estimate: 120,000 mg/kg

Acute toxicity estimate: 4,084 mg/kg

Components:
Ethanol:
Acute oral toxicity : LD50 (Rat, male and female): 10,470 mg/kg
Method: OECD Test Guideline 401
GLP: no
SAFETY DATA SHEET

Acute inhalation toxicity : LC50 (Rat, male and female): 124.7 mg/l
Exposure time: 4 h
GLP: no
Acute dermal toxicity : LD50 (Rabbit): > 2,000 mg/kg

Methanol:
Acute oral toxicity : LD50 (Rat, male and female): 1,187 - 2,769 mg/kg
Method: BASF test
GLP: no
Assessment: The component/mixture is toxic after single
ingestion.
Acute inhalation toxicity : LC50 (Rat, male and female): 87.5 mg/l
Exposure time: 6 h
Method: BASF test
GLP: no
Assessment: The component/mixture is toxic after short term
inhalation.
Acute dermal toxicity : Assessment: The component/mixture is toxic after single

contact with skin.
Ethanediol:
Acute oral toxicity : LD50 (Rat, male and female): 22,000 mg/kg
Method: Other
GLP: no
Acute inhalation toxicity : LC50 (Rat, male and female): > 2.5 mg/l
Exposure time: 6 h
Test atmosphere: dust/mist
Method: Other
GLP: yes
Acute dermal toxicity : LD50 (Mouse, male and female): > 3,500 mg/kg
Method: Other
GLP: yes
Skin corrosion/irritation
Product:
Result: Repeated exposure may cause skin dryness or cracking.
Components:
Ethanol:
SAFETY DATA SHEET

Species: Rabbit
Exposure time: 24 h
Result: No skin irritation
GLP: yes
Methanol:
Species: Rabbit
Exposure time: <= 20 h
Method: Other
GLP: no
Ethanediol:
Species: Rabbit
Exposure time: 20 h
Method: Other
GLP: no
Serious eye damage/eye irritation

Product:
Result: irritating
Components:
Ethanol:
Species: Rabbit
Result: Irritating to eyes.
GLP: No information available.
Methanol:
Species: Rabbit
Result: No eye irritation
Method: Other
GLP: no
Ethanediol:
Species: Rabbit
Result: No eye irritation
Exposure time: 24 h
Method: Other
GLP: no
SAFETY DATA SHEET

Respiratory or skin sensitisation

Product:
Remarks: not tested.
Components:
Ethanol:
Exposure routes: Dermal
Species: Mouse
Method: Other
Result: Not a skin sensitizer.
Methanol:
Test Type: Maximisation Test
Species: Guinea pig
GLP: no
Assessment: Toxic if swallowed, in contact with skin or if inhaled.
Ethanediol:
Test Type: Maximisation Test
Species: Guinea pig
GLP: yes
Assessment: Harmful if swallowed.
Germ cell mutagenicity

Product:
Germ cell mutagenicity - : No information available.
Assessment
Components:
Ethanol:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Metabolic activation: with and without metabolic activation
Result: negative
Test Type: In vitro mammalian cell gene mutation test

SAFETY DATA SHEET

Test system: mouse lymphoma cells

Result: negative
Test Type: Chromosome aberration test in vitro

Test system: Human lymphocytes
Metabolic activation: without
Result: negative
Genotoxicity in vivo : Test Type: In vivo micronucleus test

Species: Rat (male)
Strain: Other
Cell type: Bone marrow
Application Route: Drinking water
Result: negative
Germ cell mutagenicity - : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.
Methanol:
Genotoxicity in vitro : Test Type: Micronucleus test
Test system: Chinese hamster lung cells
Concentration: 40 mg/ml
Metabolic activation: without
Method: Other
Result: negative
Test Type: HGPRT assay

Test system: Chinese hamster lung cells
Concentration: 15,8 - 63,3 mg/ml
Result: negative
Test Type: In vitro gene mutation study in bacteria

Concentration: 5 - 5000 µg/plate
Result: negative
Genotoxicity in vivo : Test Type: Chromosome Aberration Test

Species: Mouse (male)
Strain: C57BL/6 x DBA/2
SAFETY DATA SHEET

Cell type: Erythrocytes

Application Route: Inhalation
Exposure time: 5 d, 6 h/day
Dose: 1,04 - 5,3 mg/l
Method: Other
Result: negative
Ethanediol:
Genotoxicity in vitro : Test Type: Ames test
Result: negative
GLP: yes
Test Type: Ames test

Test system: Escherichia coli
Result: negative
GLP: yes
Test Type: Chromosome aberration test in vitro

Test system: Chinese hamster ovary cells
Method: Other
Result: negative
GLP: yes
Test Type: In vitro mammalian cell gene mutation test

Test system: mouse lymphoma cells
Result: negative
GLP: yes
Genotoxicity in vivo : Test Type: Dominant lethal assay

Species: Rat (male and female)
Strain: Fischer F344
Application Route: oral (feed)
Exposure time: 3 generation
Dose: 40 - 200 - 1000 mg/kg
Method: Other
Result: negative
GLP: no
SAFETY DATA SHEET

Carcinogenicity
Product:
Carcinogenicity - : No information available.
Assessment
Components:
Ethanol:
Species: Mouse, (female)
Exposure time: 105 weeks
Dose: 0, 2.5 and 5% in drinking wate
Group: yes
4,400 mg/kg bw/day
Method: OPPTS 870.4200
GLP: yes
Carcinogenicity - : Not classifiable as a human carcinogen.

Assessment
Methanol:
Species: Rat, (male and female)
Exposure time: 24
Dose: 0,013 - 0,13 - 1,3 mg/l
Group: yes
Frequency of Treatment: 20 h/day
NOAEL: >= 1.3 mg/l

Assessment
Ethanediol:
Species: Mouse, (male and female)
Exposure time: 2 a
Dose: 6250-12500-25000-50000 ppm
Group: yes
Frequency of Treatment: daily
NOAEL: 1,500 mg/kg bw/day
Method: Other
GLP: yes

Assessment
SAFETY DATA SHEET

IARC Not listed
OSHA Not listed
NTP Not listed
Reproductive toxicity
Product:
Reproductive toxicity - : No information available.
Assessment
No information available.
Components:
Ethanol:
Effects on fertility : Test Type: Two-generation study
Species: Mouse, male and female
Strain: CD1
Dose: 5, 10 and 15% v/v in water
Duration of Single Treatment: 126 d
General Toxicity - Parent: NOAEL: 15 %
General Toxicity F1: NOAEL: 10 %
General Toxicity F2: NOAEL: < 15 %
Effects on foetal : Test Type: Pre-natal

development Species: Rat, female
Strain: Sprague-Dawley
Dose: 10000, 16000, 20000 ppm nom.
Frequency of Treatment: 1 daily
General Toxicity Maternal: NOAEL: 16,000 ppm
Teratogenicity: NOAEL: 20,000 ppm
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
Methanol:
Effects on fertility : Test Type: Two-generation study
Species: Rat, male and female
Dose: 0,013 - 0,13 - 1,3 mg/l
Duration of Single Treatment: 20 h
General Toxicity - Parent: NOAEC: 1.3 mg/l
SAFETY DATA SHEET

General Toxicity F1: NOAEC: 0.13 mg/l

General Toxicity F2: NOAEC: 0.13 mg/l
Effects on foetal : Test Type: Pre-natal

Dose: 0,27 - 1,33 - 6,65 mg/l
Duration of Single Treatment: 22.7 h
General Toxicity Maternal: NOAEC: 1.33 mg/l
Teratogenicity: NOAEC F1: 1.33 mg/l
Test Type: Pre-natal

Species: Rat
Strain: Long-Evans
Application Route: oral (gavage)
Dose: 1027 - 2054 - 4108 mg/kg
Frequency of Treatment: 1
General Toxicity Maternal: LOAEL: 1,027 mg/kg body weight
Teratogenicity: LOAEL F1: 1,027 mg/kg body weight

Ethanediol:
Effects on fertility : Test Type: Three-generation study
Strain: Fischer F344
Dose: 40 - 200 - 1000
General Toxicity - Parent: NOAEL: > 1,000 mg/kg body weight
General Toxicity F1: NOAEL: > 1,000 mg/kg body weight
General Toxicity F2: NOAEL: > 1,000 mg/kg body weight
Method: Other
GLP: no
Effects on foetal : Test Type: reproductive and developmental toxicity study

Dose: 150 - 500 - 1000 - 2500 mg/kg
General Toxicity Maternal: NOEL: 1,500 mg/kg body weight
Teratogenicity: NOEL: 150 mg/kg body weight
Method: Other
GLP: yes
SAFETY DATA SHEET


STOT - single exposure

Product:
Components:
Ethanol:
Assessment: The substance or mixture is not classified as specific target organ toxicant, single
exposure.
Methanol:
Target Organs: Eyes, Central nervous system
Assessment: Causes damage to organs.
Ethanediol:
Assessment: The substance or mixture is not classified as specific target organ toxicant, single
exposure.
STOT - repeated exposure

Components:
Ethanol:
Remarks: no data available
Methanol:
Assessment: The substance or mixture is not classified as specific target organ toxicant,
repeated exposure.
Ethanediol:
Target Organs: Kidney
Assessment: May cause damage to organs through prolonged or repeated exposure.
Repeated dose toxicity

Product:
Components:
Ethanol:
LOAEL: ca. 3200 mg/kg
Exposure time: 7 weeks or 14 weeks
SAFETY DATA SHEET

Number of exposures: twice daily, 7 days a week

Dose: 5, 10, 20 ml/kg
Group: yes
Species: Rat, male

NOEL: > 20 mg/l
Application Route: inhalation (vapour)
Exposure time: 3, 6, 9, 26 day groups
Number of exposures: continuous
Dose: 20 mg/l
Group: yes
Method: Other
Methanol:
Species: Monkey, male
LOAEL: 2,340 mg/kg
Exposure time: 3 d
Number of exposures: daily
Dose: 2340 mg/kg
Group: no data available
Method: Other
Remarks: Significant toxicity observed in testing

NOEL: 0.13 mg/l
LOAEL: 1.3 mg/l
Exposure time: 12 m
Number of exposures: 20 h/day
Dose: 0,013 - 0,13 - 1,3 mg/l
Group: yes

NOAEL: 6.66 mg/l
Exposure time: 4 w
Number of exposures: 6 h/d, 5 d/wk
Dose: 0,663 - 2,65 - 6,63 mg/l
Group: yes
Application Route: Skin contact

SAFETY DATA SHEET

Repeated dose toxicity - : Toxic if swallowed, in contact with skin or if inhaled.

Assessment
Ethanediol:
Species: Rat, male
NOAEL: 150 mg/kg bw/day
Exposure time: 16 w
Dose: 50 - 150 - 500 - 1000 mg/kg
Group: yes
Species: Dog, male

NOAEL: 2.200 - 4.400 mg/kg bw/day
Application Route: Dermal
Exposure time: 4 w
Dose: 2 - 4 mL/kg bw
Group: yes
GLP: yes
Repeated dose toxicity - : Harmful if swallowed.

Assessment
Aspiration toxicity
Product:
no data available
Components:
Ethanol:
No aspiration toxicity classification
Methanol:
Ethanediol:
Experience with human exposure

Product:
General Information : The possible symptoms known are those derived from the
labelling (see section 2).
SAFETY DATA SHEET

SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish :
Remarks: not available
Components:
Ethanol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 15,300 mg/l
End point: mortality
Exposure time: 96 h
Test Type: flow-through test
Analytical monitoring: yes
Method: Other
LC50 (Oncorhynchus mykiss (rainbow trout)): 11,200 mg/l

Exposure time: 24 h
Analytical monitoring: no
Method: Other
Toxicity to daphnia and other : LC50 (Ceriodaphnia dubia (water flea)): 5,012 mg/l
aquatic invertebrates End point: mortality
Exposure time: 48 h
Test Type: static test
Method: Other
EC50 (Daphnia magna (Water flea)): > 10,000 mg/l

End point: Immobilization
Exposure time: 48 h
Method: DIN 38412
GLP: no
Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l
Exposure time: 72 h
EC10 (Chlorella vulgaris (Fresh water algae)): 11.5 mg/l

Exposure time: 72 h
Toxicity to fish (Chronic : NOEC (Danio rerio (zebra fish)): 250 mg/l
toxicity) End point: Other
SAFETY DATA SHEET

Exposure time: 120 h

Test Type: semi-static test
Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates
(Chronic toxicity)
Toxicity to microorganisms : EC50 (Natural microorganism): 5,800 mg/l

Exposure time: 4 h
Toxicity to soil dwelling : Remarks: Not applicable

organisms
Plant toxicity : Remarks: Not applicable
Sediment toxicity : Remarks: Not applicable
Toxicity to terrestrial : Remarks: Not applicable

organisms
Methanol:
Toxicity to fish : LC50 (Lepomis macrochirus (Bluegill sunfish)): 15,400 mg/l
Exposure time: 96 h
Method: EPA
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 18,260 mg/l
aquatic invertebrates End point: Immobilization
Exposure time: 96 h
Analytical monitoring: no data available
Remarks: The details of the toxic effect relate to the nominal
concentration.
Toxicity to algae : ErC50 (Pseudokirchneriella subcapitata (microalgae)): ca.

22,000 mg/l
End point: Growth rate
Exposure time: 96 h
Toxicity to fish (Chronic : NOEC (Pimephales promelas (fathead minnow)): 446.7 mg/l
toxicity) Exposure time: 28 d
SAFETY DATA SHEET

Method: Other
GLP: no
Remarks: The value is given based on a SAR/AAR approach
using OECD Toolbox, DEREK, VEGA QSAR models
(CAESAR models), etc.
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 208 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 21 d
Method: calculated
GLP: no
Toxicity to microorganisms : IC50 (activated sludge): > 1,000 mg/l

End point: Bacteria toxicity (growth inhibition)
Exposure time: 3 h
Test Type: aquatic
Toxicity to soil dwelling : Test Type: filter paper

organisms LC50 (Eisenia fetida (earthworms)): > 1 mg/cm2
Exposure time: 48 h
Test Type: Other

NOEC (Folsomia candida): 10000 mg/kg dry weight (d.w.)
Exposure time: 28 d
Method: Other
Plant toxicity : IC50 (Lactuca sativa (lettuce)): ca. 41,000 mg/l

Exposure time: 3 d
End point: emergence
Method: Other
GLP: no
Sediment toxicity : Remarks: Not applicable
Ethanediol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 72,860 mg/l
Exposure time: 96 h
Method: EPA
GLP: no
SAFETY DATA SHEET


concentration.
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 100 mg/l
aquatic invertebrates Exposure time: 48 h
GLP: yes
Toxicity to algae : EC50 (Pseudokirchneriella subcapitata (green algae)): 6,500 -

13,000 mg/l
End point: Growth rate
Exposure time: 7 d
Method: EPA
Toxicity to fish (Chronic : Chronic Toxicity Value (Fish): 2,629 mg/l

toxicity) End point: Other
Exposure time: 30 d
Method: Other
GLP: no
Toxicity to daphnia and other : NOEC (Ceriodaphnia spec.): 8,590 mg/l

aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 7 d
Method: Other
concentration.
Toxicity to microorganisms : EC20 (activated sludge, domestic): > 1,995 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 0.5 h
Method: ISO 8192
GLP: no
Persistence and degradability

Product:
Biodegradability : Remarks: Expected to be biodegradable
Biochemical Oxygen : Remarks: not tested.

SAFETY DATA SHEET

Demand (BOD)
Components:
Ethanol:
Biodegradability : aerobic
Result: Readily biodegradable.
Biodegradation: 84 %
Exposure time: 20 d
Methanol:
Inoculum: activated sludge, domestic, non-adapted
Concentration: 3 - 10 mg/l
BOD in % of theoretical OD
Biodegradation: 95 %
Exposure time: 20 d
Method: Closed Bottle test
GLP: no
aerobic
Inoculum: domestic sewage
Concentration: 4 - 200 g/l
BOD in % of theoretical OD
Biodegradation: 82.7 %
Exposure time: 5 d
Method: Respirometertest
GLP: no
Photodegradation : Rate constant: 9.32E-13 cm3/s

Degradation (indirect photolysis): 50 % Degradation half life:
17.2 d
Method: other (measured)
GLP: no
Ethanediol:
Inoculum: activated sludge
Concentration: 53 mg/l
Dissolved organic carbon (DOC)
Biodegradation: 90 - 100 %
Exposure time: 10 d
Method: OECD Test Guideline 301A
GLP: yes
SAFETY DATA SHEET

Bioaccumulative potential
Product:
Bioaccumulation : Remarks: not tested.
Components:
Ethanol:
Bioaccumulation : Bioconcentration factor (BCF): 0.66
Method: calculated
Remarks: Does not bioaccumulate.
Partition coefficient: n- : log Pow: -0.35 (24 °C)

octanol/water pH: 7.4
Methanol:
Bioaccumulation : Species: Leuciscus idus (Golden orfe)
Bioconcentration factor (BCF): < 10
Exposure time: 72 h
Method: Other
Partition coefficient: n- : log Pow: -0.77

octanol/water Method: No information available.
Ethanediol:
Bioaccumulation : Remarks: Due to the low logPow bioaccumulation is not
expected
Partition coefficient: n- : log Pow: -1.36

octanol/water Method: estimated
GLP: no
Mobility in soil
Product:
Distribution among : Remarks: not tested.
environmental compartments
Components:
Ethanol:
Distribution among : adsorption
environmental compartments Medium: water - soil
Remarks: Not expected to adsorb on soil.
Methanol:
Distribution among : Adsorption/Soil
SAFETY DATA SHEET


Koc: 1
Method: other (calculated)
Ethanediol:
Distribution among : Adsorption/Soil
log Koc: 0
Method: other (calculated)
Other adverse effects

Product:
Environmental fate and : Remarks: no data available
pathways
Results of PBT and vPvB : Remarks: no data available

assessment
Additional ecological : Biologically degradable, when diluted may be degraded in

information biological purification plants
Harmful effects to fish and bacteria: not harmful
Components:
Ethanol:
Results of PBT and vPvB : This substance is not considered to be persistent,
assessment bioaccumulating and toxic (PBT).
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
Methanol:
Environmental fate and : not available
pathways

Additional ecological : Do not allow to enter ground water, waterways or waste water.
information
Ethanediol:
Environmental fate and : not available
pathways

SAFETY DATA SHEET

Additional ecological : Do not allow to enter ground water, waterways or waste water.
information
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
RCRA - Resource : No -- Not as sold.
Conservation and Recovery
Authorization Act
Waste Code : NONE
Waste from residues : In accordance with local authority regulations, take to

chemical/physical treatment plant
Must be incinerated in a suitable incineration plant holding a

permit delivered by the competent authorities.
Contaminated packaging : Packaging that cannot be cleaned should be disposed of as

product waste
SECTION 14. TRANSPORT INFORMATION
DOT Regulation:
Proper shipping name: Combustible liquid, n.o.s.
Hazard class: C
Packing group: III
UN/NA-number: NA 1993
Technical Name: Ethanol
Methanol
Emergency Response 128
Guide:
Reportable Quantity: 2,835.000 kg Ethylene Glycol
IATA
Proper shipping name: Flammable liquid, n.o.s.
Class: 3
Packing group: III
UN/ID number: UN 1993
Primary risk: 3
Remarks: Shipment permitted
Hazard inducer(s): Ethanol
Methanol
IMDG
Proper shipping name: Flammable liquid, n.o.s.
Class: 3
Packing group: III
UN no.: UN 1993
Primary risk: 3
SAFETY DATA SHEET

Hazard inducer(s): Ethanol

Methanol
EmS: F-E S-E
Further information:
Not regulated for surface transportation in non-bulk containers under 119gallons.
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act

CERCLA Reportable Quantity
Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Ethanediol 107-21-1 5000 6250
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 302 Extremely Hazardous Substances Threshold Planning Quantity
This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)
Acute toxicity (any route of exposure)
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
SARA 313 : The following components are subject to reporting levels

established by SARA Title III, Section 313:
Methanol 67-56-1 < 0.5 %
Ethanediol 107-21-1 60 - 100 %
Clean Water Act

Contains no known priority pollutants at concentrations greater than 0.1%.
The components of this product are reported in the following inventories:
TSCA : All components of this product are listed or excluded from
listing on the United States Environmental Protection Agency
Toxic Substances Control Act (TSCA) Inventory.
SAFETY DATA SHEET

SECTION 16. OTHER INFORMATION
Further information
NFPA:
Flammability
2
Instability
Health
1 0
Special hazard.
Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA P0 : USA. OSHA - TABLE Z-1 Limits for Air Contaminants -
1910.1000
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1
Limits for Air Contaminants
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA P0 / TWA : 8-hour time weighted average
OSHA P0 / STEL : Short-term exposure limit
OSHA P0 / C : Ceiling limit
OSHA Z-1 / TWA : 8-hour time weighted average
AICS - Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response,
Compensation, and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN -
Standard of the German Institute for Standardisation; DOT - Department of Transportation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response; EHS -
Extremely Hazardous Substance; ELx - Loading rate associated with x% response; EmS -
Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; ERG - Emergency Response Guide;
GHS - Globally Harmonized System; GLP - Good Laboratory Practice; HMIS - Hazardous
Materials Identification System; IARC - International Agency for Research on Cancer; IATA -
International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
SAFETY DATA SHEET

- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test

population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; MSHA - Mine Safety and Health Administration; n.o.s. - Not Otherwise
Specified; NFPA - National Fire Protection Association; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NTP - National Toxicology Program; NZIoC - New Zealand Inventory of Chemicals;
OECD - Organization for Economic Co-operation and Development; OPPTS - Office of Chemical
Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS
- Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure
Activity Relationship; RCRA - Resource Conservation and Recovery Act; REACH - Regulation
(EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self-
Accelerating Decomposition Temperature; SARA - Superfund Amendments and Reauthorization
Act; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations
Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very
Bioaccumulative
Observe national and local legal requirements

None known.
Revision Date : 08/14/2018
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information’s accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application. NO
EXPRESS OR IMPLIED WARRANTY IS MADE OF THE MERCHANTABILITY, SUITABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OTHERWISE OF ANY PRODUCT OR
SERVICE. Nothing included in this information waives any of Clariant’s General Terms and
Conditions of Sale, which control unless it agrees ot herwise in writing. Any existing
intellectual/industrial property rights must be observed. Due to possible changes in our products
and applicable national and international regulations and laws, the status of our products could
change. Material Safety Data Sheets providing safety precautions, that should be observed when
handling or storing Clariant products, are available upon request and are provided in compliance
with applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
US / EN

Safewing TKS 406B

Uploaded by

Copyright:

Available Formats

Safewing TKS 406B

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Safewing TKS 406B

Uploaded by

Copyright:

Available Formats

SAFETY DATA SHEET

Safewing TKS 406B Page 1

Substance key: KFTKS406B Revision Date: 08/14/2018

Identification of the Clariant Corporation

Information of the substance/preparation:

Trade name: Safewing TKS 406B

Primary product use: Aircraft de-icing

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200

Acute toxicity (Oral) : Category 4

Eye irritation : Category 2A

Specific target organ toxicity : Category 2 (Kidney)

GHS label elements

Signal word : Warning

Hazard statements : H226 Flammable liquid and vapour.

Safewing TKS 406B Page 2

Substance key: KFTKS406B Revision Date: 08/14/2018

P233 Keep container tightly closed.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

SECTION 4. FIRST AID MEASURES

General advice : Remove/Take off immediately all contaminated clothing.

If inhaled : Move the victim to fresh air.

Safewing TKS 406B Page 3

Substance key: KFTKS406B Revision Date: 08/14/2018

Give oxygen or artificial respiration if needed.

If swallowed : IF SWALLOWED: Immediately call a POISON

Notes to physician : None known.

SECTION 5. FIREFIGHTING MEASURES

Unsuitable extinguishing : High volume water jet

Specific hazards during : Hazardous decomposition products:

In case of fires, hazardous combustion gases are formed:

Burning produces noxious and toxic fumes.

Further information : Wear full protective clothing and self-contained breathing

Wear positive pressure self-contained breathing apparatus

Special protective equipment : Self-contained breathing apparatus

Safewing TKS 406B Page 4

Substance key: KFTKS406B Revision Date: 08/14/2018

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Wear suitable protective equipment.

Environmental precautions : Do not allow to enter drains or waterways

Can be landfilled or incinerated, when in compliance with local

SECTION 7. HANDLING AND STORAGE

Avoid contact with skin and eyes.

Technical : Keep containers tightly closed in a cool, well-ventilated place.

Keep containers tightly closed in a cool, well-ventilated place.

Safewing TKS 406B Page 5

Substance key: KFTKS406B Revision Date: 08/14/2018

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Personal protective equipment

If airborne concentrations pose a health hazard, become

Wear an approved respirator when exposed to vapours or to

Safewing TKS 406B Page 6

Substance key: KFTKS406B Revision Date: 08/14/2018

mists beyond the TLV. Use appropriate filters. Do not exceed

Butyl Rubber, PVC Or Neoprene.

Eye protection : Safety goggles

Skin and body protection : Wear suitable protective clothing.