Capsule For Low Achievers
Capsule For Low Achievers
Capsule For Low Achievers
SOLUTION
Concentration of Solutions:-
Molarity [M]: No. of moles of solute present per liter of solution in called ‘molarity of solution’. . It is
temperature dependent. M= No. of Moles of solute / Volume of solution in litre
Molality [m]: No. of moles of solute present per kg. of solvent is called molality. It is temperature
independent. m= No. of Moles of solute / Mass of Solvent in Kg
Mole Fraction: Ratio of moles of components to total no. of moles of all the components of solution
is called mole fraction (x) of the component.
Henry’s law :- “The partial pressure of the gas in vapour phase p is proportional to the mole fraction of
the gas x in the solution.” P=KH x
Applications of Henery Law(1) In Packing of soda/ Soft drinks(2) In Deep see diving( He = 11.7 % , N2 =
56.2 % and O2 =32.1% ) (3) Functions of lungs (4)At high altitudes pressure is low there for breathing
problems lead to ANOXIA (unable to think and weak)
Vapour Pressure: The pressure exerted by vapours over the liquid surface at equilibrium is called vapour
pressure of the liquid.
Raoult’s Law:“The V.P. of any volatile component in the solution is directly proportional to its mole fraction”.
Raoult’s Law for Solutions Containing Non-Volatile Solute Raoult’s Law for Solution Containing Volatile Solute
Osmosis:- The phenomenon of the passage of pure solven from a region of lower concentration (of
the solution) to a region of its higher concentration through a semi-permeable membrane.
Osmotic Pressure: Excess pressure which must be applied to a solution in order to prevent flow of
solvent into the solution through the semi-permeable membrane.
Reverse Osmosis: If pressure greater than osmotic pressure is applied then, flow of solvent
molecules is reversed, i.e. from a higher concentration solution to lower concentrated solution. This
phenomenon is called “Reverse Osmosis”. It is used in water purification and desalination of
water.
UNIT-3 ELECTROCHEMISTRY
SrNo Terminology
1.
2
3
.Units of k1 = s-1EXAMPLES
Unit of rate constant = mol litre-1s-1
Examples:
Enzyme catalyzed reactions
Half Life: Time required to consume the half of initial Half Life:Time required to consume the half of initial
concentration of reactant is called half life period. concentration of reactant is called half life period.At t =
At t = t1/2[A] = [A0]/2 t1/2[A] = [A0]/2
K0t1/2 = [A]0-[A0]/2 t1/2 = [A]0/2k k1=( 2.303/ t1/2 )log ([A]0 / [A0/2]) t1/2 = 0.693/k1
Half life is directly proportion of the initial concentration Half-life is independent of the initial concentration of the
of the reactant for a zero order reaction. reactant for a first order reaction
The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume. SO2Cl2 (g) →
SO2(g) + Cl2(g). Calculate the rate constant.
THRESHOLD ENERGY The Minimum extra amt of energy which the reactants molecules
must have sothat reactant molecule reacts and overcome the
energy barriers and converts into products.
ACTIVATION ENERGY The Minimum extra amt of energy absorbed by the reactant
molecule so that their energy becomes equal to threshold energy.
d and f- BLOCK ELEMENTS (By Dr M R CHOUDHARY 846913570)
1 d-block elements are called transition elements incomplete d-orbitals in neutral or most stable oxidation state.
2 Zn, Hg, Cd, are not included as transition as they have filled d-orbitals in neutral and most stable +2
elements and why? oxidation state.
3 Sc3+ has d0 configuration but it is transition metal Because of partially filled d1 configuration of Sc
4 First series transition elements shows irregular Due to shielding effect of inner 3d electrons which overcome
trend of atomic radii ENC.
5 Atomic radii of Zr to Hf are almost same. due to Lanthenoid Contraction.
6 First series transition elements shows irregular It is because of mutual exchange of energy between d and f
trend of IE orbitals after removal of one electron.
7 Transition metals have high enthalpy of due to presence of unpaired electrons form strong metallic
atomization and melting point. bonding
8 Zn, Cd, Hg are not very hard and have low M.P. Due to presence of all paired electrons they have least enthalpy
and B.P. of atomization, very weak metallic bond & are not very hard
with low M.P. and B.P.
9 d-block elements shows a large no. of oxidation due to presence of unpaired electrons or partially filled d-
state orbitals.
10 Which first series transition metal shows highest Mn shows highest number of oxidation state due presence of
number of oxidation states and why? highest number of unpaired electrons.
11 Which first series transition metal do not show Sc , due to achieving noble gas configuration in +3 O.S
variable oxidation states and why?
12 Cr3+ is more stable as compared to Cr2+ due to stable half filled t2g3 configuration.
13 Cu2+ is more stable in solution than Cu+ due to high hydration enthalpy of Cu2+ ion in solution.
14 Which first series transition metal shows +1 Cu shows +1 oxidation state in gaseous form due to stable full
oxidation states and why? filled 3d10 configuration.
15 Higher oxidation states of transition metals because higher oxidation states stabilized by highly
found in their oxides and fluorides electronegative elements such as O and F
16 higher oxidation states are more common in due to formation of dπ-pπ bond between metal and oxygen.
oxides rather than fluorides of transition metals.
17 +2 O.S becomes more stable in first series as number of unpaired electrons decreases.
transition elements moving from left to right
18 Write oxoanions of first series transition metals MnO4-, Cr2O72-, VO3-, CrO42-
in which group number and O.N. of transition
metal are same-
19 Moving from left to right E0 for M2+/M becomes trends due to irregular variation of IE1 + IE2.
less negative but it shows irregular trend
20 For copper E0 Cu2+/Cu is +ve (+0.34 V) it is due to low hydration enthalpy of Cu2+ which cannot
compensate ∆subH0 + IE1 + IE2.
21 For Mn , E0 Mn3+/Mn2+ is +ve because by converting into Mn2+ it achieves half filled
configuration.
22 For Cr , E Cr /Cr is −ve
0 3+ 2+ because Cr3+ is more stable due to half filled t2g configuration.
23 Most of the compounds of transition metal are It is due to d-d transition
coloured in solid state as well as in their solution
24 (Sc3+, Ti4+) does not exhibit any colour Due to absent of unpaired e- as d-d transition is not possible
25 (Zn2+, Cu+) does not exhibit any colour full filled d-orbitals (d10) as d-d transition is not possible
26 Transition metals or ions are paramagnetic in Due to presence of unpaired electrons (d1-9)
nature
27 Transition metal form large number of High charge by mass ratio, availability of vacant d-orbital &
coordination complexes Variable oxidation state
28 What are Interstitial compounds? Compounds in which small elements like H, B, C, N trapped in
the interstitial space of metal lattice.
29 Transition metals form Interstitial compounds. due to availability of interstitial space in metal lattice.
30 Why interstitial compounds are found to be more These compounds have high M.P as compared to pure metals.
useful than pure metal? These are very hard and are Chemically inert.
31 Transition metals and their compounds are Due to large surface area, variable oxidation state & Availability
widely used as catalyst of vacant d-orbitals
32 transition metals form alloy. Due to comparable metallic radii
33 Why oxides of Higher oxidation states of Higher oxidation states are more polarizing in nature . hence
transition metals are acidic in nature whereas are acidic in nature whereas lower O.S. are less polarizing
lower O.S. are basic in nature? hence are basic in nature.
34 Actinoids shows greater number of oxidation Due to comparable energy of 5f, 6d, and 7s orbitals.
states then lanthanoids
35 It is difficult to study chemistry of actinoids. Due to radio active nature and small half life
36 Ce(IV) is a good oxidizing agent in aq. soln because in aq. solution its E0Ce4+/ Ce3+ is +1.74 V
37 Actinoid contraction is greater from element to because of poor shielding by 5f orbitals due to its superficial
element as compared to lanthanoids . position.
Potassium Dichromate [K2Cr2O7] Potassium Permanganate [KMnO4]
Preparation: Preparation: from pyrolucite ore [MnO2]
It is prepared from chromite ore : FeCr2O4/ FeO Cr2O3 Step 1:
Step 1: 2MnO2 (Black)+4KOH+O2 2K2MnO4 (Green)+ 2H2O
4FeCr2O4 + 8Na2CO3 +7O2 8Na2CrO4 + 2Fe2O3 + 8CO2 Step 2:
Step 2: 2Na2CrO4 (Yellow)+ H2SO4 3MnO42- (Green)+4H+ 2MnO4-( Purple)+MnO2+ 2H2O
Na2Cr2O7(Orange)+ Na2SO4 + H2O Oxidizing Character: (Oxidation in acidic medium)
Step 3: Na2Cr2O7 + 2KCl K2Cr2O7 + 2NaCl MnO4- + 8H+ + 5e- Mn2+ + 4H2O
Orange Orange Eq. mass of KMnO4 = 158/5 = 31.6
Effect of pH: MnO4-+5Fe2++8H+ Mn2++5Fe3++ 4H2O
Cr2O72- (Orange) + 2OH- 2CrO42- (Yellow) + H2O 2MnO4- + 10Cl- + 16H+ 2Mn2+ + 8H2O + 5Cl2
2CrO42- (Yellow) + 2H+ Cr2O72- (Orange) + H2O 2MnO4- +5C2O42-+ 16H+ 2Mn2++10CO2+ 8H2O
Oxidizing Character: Dichromate ion acts as strong 2MnO4-+5SO32-+6H+ 2Mn2+ + 5SO42- + 3H2O
oxidizing agent in acidic medium. 2MnO4 +5NO2 +6H
- - + 2Mn2+ + 5NO3- + 3H2O
Cr2O72- + 14H+ + 6e- 2Cr3+ + 7H2O 2MnO4-+5S2-+16H+ 2Mn2+ + 5S + 8H2O
Cr2O72- + 14H+ + 6I- 2Cr3+ + 7H2O + 3I2 2MnO4- +3H2O+ I- 2MnO2 +IO3- + 2OH-
Cr2O7 + 14H + 6Fe
2- + 2+ 2Cr3+ 7H2O + 6Fe3+ 8MnO4 +3S2O3 +H2O
- 2- 8MnO2 + 6SO42- + 2OH-
Cr2O72- + 14H+ + 3Sn2+ 2Cr3+ 7H2O + 3Sn4+ 2MnO4- +3 Mn2++2 H2O 5MnO2 +4H+
Cr2O72- + 8H+ + 3H2S 2Cr3+ + 7H2O + 3S
f-Block Elements Consequences: 1. Resemblance in the properties of second and
General configuration (n – 2) f 1-14 (n – 1)d 0-1 ns2 third transition series from Zr & Hf) atomic size of 2nd and 3rd
57La [Xe] 5d1 6s2 89Ac [Rn] 6d1 7s2 - transition series become same.
58Ce [Xe] 4f1 5d1 6s2 91Pa [Rn] 5f2 6d1 7s2 2. Similarity in the properties of Lanthanoids:- The decrease in
63Eu [Xe] 4f7 5d0 6s2 92U [Rn] 5f3 6d1 7s2 atomic radii from Lanthenoid to Lanthenoid is very less hence
64Gd [Xe] 4f 5d 6s
7 1 2
94Pu [Rn] 5f6 6d0 7s2 it is very difficult to separate these elements in pure state.
70Yb [Xe] 4f14 5d0 6s2 3. Basic strength of hydroxides of Lanthanoids decreases from
Lanthanoid Contraction- Regular decrease in atomic Lanthenium (La) to Lutesium (Lu).
or ionic radii of Lanthenoid with increase in atomic Misch Metal – It is alloy of Lanthanoids(95%) with iron
number is called Lanthenoid contraction. (5%)and Trace of S, C, Al ,Ca Lanthenoid – 95% Metal + Trace
Cause: It is due to imperfect shielding of one 4f orbital of S, C, Al ,Ca + Iron – 5%
by another 4f orbital due to which ENC regularly Uses- making bullet shells and flinter of lighters.
increases with increase in atomic number.
Lanthanoids Actinoids
Last electron enters in 4f orbital Last electron enters in 5f orbital
Are natural elements and non radioactive in nature Are radioactive in nature and after Np they are synthetic
elements
Shows less number of oxidation states [+2,+3,+4] Shows greater number of oxidation states [+3,+4,+5,+6,+7]
Element to element lanthanoid contraction is less Element to element actinoid contraction is more
Coordination Compounds
Ligand: Provide pair of electron for formation of Coordination Number: Number of coordinate bonds
coordinate bond to central metal atom is called ligand. formed by ligands with central metal atom in the complex
(Lewis Base) is called coordination number of complex.
Types of ligands:- eg. - [Mg(EDTA)]2- [Fe(CN)6]4- [Co(en)3]3+
(a) Monodentate :-One donar atom
(b) Bidentate :- Two donar atom C.N. 6 6 6
(c) Ambidentate:- Two donar atom but at a time 5) Homoleptic and Hetroleptic Complexes:
form only one bond Eg: SCN- and NCS- A complex with same type of ligands surrounding central
F -Fluorido, Cl- - Chlorido, Br- -Bromido
- metal atom is called homoleptic complex. E.g.-
I- - Iodido, H- -Hydrido, OH- - Hydroxido [Cu(NH3)4]2+, [Pt(NH3)4]2+
CN- -Cyanido, SCN- - Thiocyanato A complex with different types of ligands surrounding
NCS- - Isothiocyanato, CH3COO- -Acetato central metal atom is called hetroleptic complex. E.g.
SO42- - Sulphato, CO32- - Carbonato [Pt(NH3)2 Cl2]
(COO-)2 or C2O42- - Oxalato (ox), NO3- - Nitrato 6. Coordination Polyhedron: Spatial arrangement of
NO2- - Nitrito(N), PO43- - Phosphato ligands around central metal atom or ion is called
Neutral ligands- H2O- Aqua , NH3 - Ammine coordination polyhedron.
R NH2 -Alkanamine, CO –Carbonyl, Writing Formula of Coordination Complex:
H2NCH2CH2NH2 - ethane-1,2–diamine 1. Cation is written first followed by anion.
Ethylenediaminetetraacetate ion (EDTA4–) 2. In coordination sphere central metal atom is written
Ligand which has two different donor atoms and first followed by ligands.
either of the two ligetes in the complex is called 3. If more than one type of ligands are present then
ambidentate ligand. Examples NO2 – and SCN– alphabet is followed. Na2[Fe(H2O)4 (NO) Br]
Swarts reaction Heating of alkyl chloride/bromide in the R – X AgF, Hg 2F2 , CoF2 or SbF3
R–F
presence of a metallic fluoride such as AgF,Hg2F2, CoF2 or CH3 –Br + AgF CH3 –F + AgBr
SbF3 to give alkyl fluorides
12. ALCOHOLS,PHENOLS AND ETHERS
Hydroboration –oxidation reaction : The alcohol CH3-CH=CH2(
i ) B2 H 6 ( ii ) H2O2/O H
CH3-CH2-CH2-OH
obtained through anti- Markownikov ’s addition of H2O
Reimer-Tiemann reaction-
Phenol reacts with chloroform and NaOH to give
salicylaldehyde
Kolbe’s reaction:-
Phenol reacts with NaOH followed by CO2 in acidic
mediumto give salicylaldehyde
Williamson’s synthesis :In this method an primary CH3Cl + CH3 ONa → CH3OCH3 + NaCl
alkyl halide reacts with a sodium alkoxide to form
symmetrical or unsymmetrical ethers.
12. ALDEHYDES, KETONES AND CARBOXYLIC ACID
Aldol Condensation : Aldehydes and ketones having at
least one α – hydrogen undergo a condensation
reaction in the presence of dilute alkali (NaOH ,KOH
etc.)as catalyst to form β- hydroxyaldehyde (aldol)or β –
hydroxyketone (ketol) respectively
Cross Aldol Condensation: When aldol condensation is carried out between two different aldehydesand / or ketones, it
is called cross aldol condensation. If both of them contain α-hydrogen atoms, it gives a mixture of four products.
hydrochloric acid.(Conc.HCl)
Wolf Kishner Reaction:- reaction used to convert
carbonyl group (-CO-) into methylene groups through
reaction with hydrazine and KOH- ethylene glycol
Rosenmund Reaction: Acyl chloride (acid chloride) is
hydrogenated over catalyst, palladium on BaSO4
5 Why haloarenes are less reactive than haloalkanes In haloarenes C—X bond acquires a partial double
towards nucleophilic substitution reactions bond character due to resonance
6 Which compound in each of the following pairs will (i) iodine is a better leaving group because of its larger
react faster in SN2 reaction? Why? size. (ii) three bulky methyl group hinder the
(i) CH3Br or CH3I (ii) (CH3)3C-Cl or CH3-Cl approaching nucleophile
7 Compound (I) reacts faster in SN1 reaction as it is a 2°
alkyl halide
8 A solution of KOH hydrolyses CH3CH(Cl)CH2CH3 and CH3CH2ClCHCH3 more easily hydrolysed as it forms 20
CH3CH2CH2CH2Cl. Which one of these is more easily carbocation which is more stable than 10 carbocation
hydrolysed and why?
9 State one use each of DDT and iodoform DDT: It is used as insecticide Iodoform: Iodoform is
used as an antiseptic.
10 What is known as a racemic mixture? Give an An equi-molar mixture of d- and l- isomers(50:50 d+l)
example. For example, butan-2-ol. A racemic mixture is optically
inactive due to external compensation
11 Although chlorine is an electron withdrawing Through resonance effect, chlorine tends to stabilize
group, yet it is ortho-, para-directing in the carbocation and the effect is onlyapplicable at
electrophilic aromatic substitution reactions. ortho and para-positions.
Explain why it is so?
12 Grignard’s reagents should be prepared under This is because Grignard reagent forms alkanes by
anhydrous conditions, why? reacting with moisture.
13 the dipole moment of Chlorobenzene is lower than due to resonance ,Chlorobenzene shorter C—Cl
that of Cyclohexyl chloride bond(sp2)than cyclohexyl chloride C—Cl bond(sp3)
14 Chloroform is stored in closed dark brown bottles chloroform is slowly oxidised by air in the presence of
light to form poisonous gas phosgene.COCl2
11. ALCOHOL, PHENOL AND ETHER
1 p-nitro phenol is more acidic than p-methyl phenol Due to –I/–R effect of –NO2 group & +I /+R effect of CH3
2 p-nitrophenol is more acidic than o-nitrophenol OR p-nitro phenol has intermolecular H-bond while o-nitro
O-nitrophenol is steam volatile ,not p-nitrophenol phenol has intramolecular H-bond.
3 Phenol is more acidic than ethanol. phenoxide ion stabilised by resonance)
4 Boiling point of ethanol is higher in comparison to Because of hydrogen bonding in ethanol
methoxymethane.
5 The C – O – H bond angle in alcohols is slightly less Due to lone pair- lone pair repulsion on oxygen
than the tetrahedral angle (109o28’).
6 Although phenoxide ion has more number of carboxylate ion stabilized through equivalent resonance
resonating structures than carboxylate ion, whereas phenoxide ion through non equivalent
carboxylic acid is a stronger acid than phenol. resonance
12. ALDEHYDES KETONES AND CARBOXYLIC ACIDS
Step II: The carbocation at once combines with the nucleophile to form final
product (racemic mixture)
2. SN2 mechanism
It is One step reaction
4. Mechanism for the acidic Dehydration of alcohols to give alkenes (At 443 K)
Step 1: Formation of protonated alcohol.
5. Mechanism for the acidic Dehydration of alcohols to give ethers (At 413K)
Reactions of Glucose
Reactions that prove cyclic i. Aldehyde group present but glucose does not react with NaHSO3& NH3.
structure of Glucose ii. Glucose does not give the Schiff’s Test & 2,4-DNP test for aldehyde.
iii. Glucose penta-acetate does not react hydroxyl amine, which shows that
aldehyde group is absent in glucose.
iv. Glucose exist in two stereo-isomeric forms ( &).
All observations indicate that free aldehydic group is not present in glucose.
Cyclic Structure of Glucose
Structure of Nucleotide