1 s2.0 S0925838803007370 Main
1 s2.0 S0925838803007370 Main
1 s2.0 S0925838803007370 Main
Letter
Effect of Al content on the self-propagating high-temperature synthesis
reaction of Al–Ti–C system in molten magnesium
H.Y. Wang a , Q.C. Jiang a,∗ , X.L. Li b , F. Zhao a
a Department of Materials Science and Engineering, Jilin University, Nanling Campus, No. 142 Renmin Street, Changchun 130025, PR China
b The Key Laboratory of Automobile Materials, Jilin University, Ministry of Education, No. 142 Renmin Street, Changchun 130025, PR China
Received 8 May 2003; received in revised form 15 July 2003; accepted 15 July 2003
Abstract
The effect of Al content on the self-propagating high-temperature synthesis (SHS) reaction of the Al–Ti–C preform in molten magnesium
was investigated. As the Al content in the preforms was increased over the range of 20–40 wt.%, the TiC particulate sizes decreased from ∼5.0
to ∼1.0 m. Microstructural characterization of the TiC/Mg (AZ91D) composite showed relatively uniform distribution of TiC particulates
in the matrix material and the presence of minimal micro-porosity.
© 2003 Elsevier B.V. All rights reserved.
Keywords: Magnesium; Composites; In situ; Self-propagating high-temperature synthesis (SHS) reaction; Aluminum content
0925-8388/$ – see front matter © 2003 Elsevier B.V. All rights reserved.
doi:10.1016/S0925-8388(03)00737-0
L10 H.Y. Wang et al. / Journal of Alloys and Compounds 366 (2004) L9–L12
Fig. 1. Typical SEM microstructures of the water-quenched preforms fabricated by a SHS reaction in molten magnesium from the green preforms with
a Ti/C (molar ratio) = 1.0 mixed with (a) 10 wt.%, (b) 20 wt.%, (c) 30 wt.%, and (d) 40 wt.% Al.
H.Y. Wang et al. / Journal of Alloys and Compounds 366 (2004) L9–L12 L11
a Ti/C (molar ratio) = 1.0 mixed with 10–40 wt.% Al, re- Table 1
spectively. According to the XRD patterns, the quenched Effect of Al content in the Al–Ti–C system on the TiC particulate sizes
in the water-quenched preforms fabricated by SHS in molten magnesium
preform of 10 wt.% Al consists of Mg, TiAl, TiC, and resid-
ual Ti and C, as shown in Fig. 2(a). However, the preforms Al content in the Al–Ti–C system (wt.%) TiC particulate size (m)
of 20–40 wt.% Al consist of Mg, TiC and Al, as shown in 20 ∼5.0
Fig. 2(b)–(d). Based on the results, it is believed that the TiC 30 ∼2.5
formation reaction in the quenched preform did occur. The 40 ∼1.0
presence of Mg phase in the quenched Al–Ti–C preforms
is attributed to the infiltration and diffusion of the molten
magnesium into the preforms. because grain growth of TiC is an exponential function of the
According to [11,12], the addition of aluminum provides combustion temperature [6]. In addition, Al phase serves as
an easier route for the TiC formation in the Al–Ti–C pre- a diluent and might prevent the diffusion of carbon between
form. During the SHS process, the reactions between Al and TiC grains. It is reported that the grain growth of TiC in the
Ti to form TiAlx (TiAl, TiAl3 ) compounds occur initially, combustion reaction between Ti and C is controlled by the
which further react with C to form a more thermodynami- C diffusion through TiC [5,6,13].
cally stable TiC. In the present study, SEM and EDS results Although TiC is formed in the preforms of 20–40 wt.%
indicate that the surface of Ti in the quenched preform of Al, it should be noted that it is difficult for TiC synthesized
10 wt.% Al is coated with a thin TiAl layer; in this case, in the preform of 20 wt.% Al to disperse into the molten
a slight reaction between TiAl and C to form TiC occurs magnesium. The combustion temperature in the preform of
(identified by XRD result, shown in Fig. 2(a)). However, a 20 wt.% Al is higher than that in the preform of 30–40 wt.%
slight heat release by the reaction cannot further initiate the Al [5,6]; therefore, the TiC particulates formed in this case
SHS reaction and then dissipates into the molten magne- are more densified and even sintered together. When 5 wt.%
sium. As the Al content is increased to 20–40 wt.%, the heat Mg powder is added into the green preform with a Ti/C (mo-
release of reaction between Ti and Al per unit volume of the lar ratio) = 1.0 mixed with 20 wt.% Al, the generated TiC
preform is increased. When the rate of heat release exceeds particulates can easily disperse into the molten magnesium
the rate of heat dissipation, further reaction can occur, and alloy [11]. Because 5 wt.% Mg also serves as a diluent and
then the heat liberated by the reaction can further raise the assists the dispersion of the generated TiC particulates into
temperature, facilitating a faster and faster reaction. As the the molten magnesium.
Al content is further increased to 50 wt.%, the preform has Fig. 3(a) and (b) shows the SEM microstructure and XRD
dispersed into the molten magnesium before the exothermic pattern of the TiC (5 wt.%)/Mg (AZ91D) composite fabri-
reaction is initiated owing to the aluminum melting. XRD cated by the SHS reaction of the preforms with a Ti/C (molar
analysis shows that no TiAlx or TiC is found in the magne- ratio) = 1.0 mixed with 30 wt.% Al, respectively. The as-cast
sium alloy, which confirms that the reaction did not occur. microstructure of the in situ processed composite reveals
Table 1 shows the effect of Al content in the Al–Ti–C a relatively uniform distribution of TiC particulates with
system on the TiC particulate sizes in the water-quenched a spherical size of ∼2.5 m. Furthermore, microstructural
preforms fabricated by SHS in molten magnesium. The TiC characterization also shows the absence of macro-pores and
particulate sizes are decreased from ∼5.0 to ∼1.0 m when blowholes; however, the presence of minimal micro-porosity
Al content in the preforms ranges from 20 to 40 wt.%. This could be detected in the composite. It has been reported
is attributed to the decrease of the combustion temperature that the composite was successfully synthesized in molten
Fig. 3. Typical SEM microstructure of TiC/Mg (AZ91D) composite synthesized by a SHS reaction in molten magnesium for preforms with a Ti/C (molar
ratio) = 1.0 mixed with 30 wt.% Al.
L12 H.Y. Wang et al. / Journal of Alloys and Compounds 366 (2004) L9–L12
Acknowledgements
magnesium by the reaction of the preforms with a Ti/C (mo-
This work is supported by the National Natural Science
lar ratio) = 1.0 mixed with 40 wt.% Al [12].
Foundation of China (No. 50171029) and the Nanoscience
Hardness and wear rates of the as-cast unreinforced
Foundation of Jilin University (No. 2001NM004).
AZ91D alloy and TiC (5 wt.%)/AZ91D composite are listed
in Table 2. The sliding abrasive wear rates were tested
under loads of 5N using a pin-on-disc apparatus. Both the
References
unreinforced AZ91D alloy and the TiC (5 wt.%)/AZ91D
composite were used as pin materials with 6 mm diameter
[1] S.C. Tjong, Z.Y. Ma, Mater. Sci. Eng. (R) 29 (2000) 49–113.
and 12 mm height, and 1000 mesh SiC abrasive papers were [2] B.S.S. Daniel, V.S.R. Murthy, G.S. Murty, J. Mater. Process Technol.
used as the counterface. It is clear that the hardness and the 68 (1997) 132–155.
wear resistance of the TiC (5 wt.%)/AZ91D composite are [3] N. Tetsuya, C.F. Merton, Metall. Mater. Trans. 26A (1995) 1877–
higher than those of the unreinforced AZ91D alloy as ex- 1884.
[4] E. Zhang, S. Zeng, B. Yang, Q. Li, M. Ma, Metall. Mater. Trans.
pected. Improvement of the hardness and wear resistance of
30A (1999) 1147–1151.
the composite must from the presence of TiC particulates. [5] W.-C. Lee, S.-L. Chung, J. Am. Soc. 80 (1) (1997) 53–61.
[6] Y. Choi, S.-W. Thee, J. Mater. Sci. 28 (1993) 6669–6675.
[7] Z.H. Zhang, X.F. Bian, Z.Q. Wang, X.F. Liu, Y. Wang, J. Alloys
4. Conclusions Comp. 339 (2002) 180–188.
[8] Q.F. Guan, Q.C. Jiang, Y.Q. Zhao, C.H. Liu, ISIJ Int. 42 (2002)
673–675.
The effect of Al content on the self-propagating [9] Z.H. Zhang, X.F. Bian, Y. Wang, X.F. Liu, Z.Q. Wang, J. Alloys
high-temperature synthesis reaction of the Al–Ti–C pre- Comp. 339 (2003) 121–128.
forms in molten magnesium was investigated. The TiC par- [10] Q.C. Jiang, X.L. Li, H.Y. Wang, Scripta Mater. 48 (2003) 713–717.
ticulate sizes were decreased from ∼5.0 to ∼1.0 m when [11] Q.C. Jiang, H.Y. Wang, J.G. Wang, Q.F. Guan, C.L. Xu, Mater. Lett.
57 (2003) 2580–2583.
Al content in the preforms ranged from 20 to 40 wt.%. In
[12] H.Y. Wang, Q.C. Jiang, X.L. Li, J.G. Wang, Scripta Mater. 48 (2003)
situ formed TiC/Mg composite utilizing the SHS reaction of 1349–1354.
molten magnesium and Al–Ti–C preforms with a 30 wt.% [13] S.D. Dunmead, D.W. Readey, C.E. Semler, J. Am. Ceram. Soc.
Al content was synthesized successfully. Microstructural 72 (12) (1989) 2318–2324.