Safety data sheet

According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDENER

SPECIAL WHITE PART B 40%

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier: FGT EPOXY HARDENER SPECIAL WHITE PART B 40%

1.2 Relevant identified uses of the substance or mixture and uses advised against:
Relevant uses: Hardener for Epoxy Resin. For industrial user only.
Uses advised against: All uses not specified in this section or in section 7.3
1.3 Details of the supplier of the safety data sheet:
ROYAL SRL
VIA G. MARCONI 123/A
24020 RANICA (BG) ITALY
Phone.: +39 035 244941
[email protected]

1.4 Emergency telephone number: NHS Direct in England or Wales 0845 46 47

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture:

CLP Regulation (EC) No 1272/2008:
Classification of this product has been carried out in accordance with CLP Regulation (EC) No 1272/2008.
Acute Tox. 4: Acute toxicity, Category 4, H302+H312+H332
Aquatic Chronic 3: Hazardous to the aquatic environment, long-term hazard, Category 3, H412
Eye Dam. 1: Serious eye damage, Category 1, H318
Skin Corr. 1A: Skin corrosion, Category 1A, H314
Skin Sens. 1: Sensitisation, skin, Category 1, H317
2.2 Label elements:
CLP Regulation (EC) No 1272/2008:
Danger

Hazard statements:
Acute Tox. 4: H302+H312+H332 - Harmful if swallowed, in contact with skin or if inhaled
Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects
Skin Corr. 1A: H314 - Causes severe skin burns and eye damage
Skin Sens. 1: H317 - May cause an allergic skin reaction
Precautionary statements:
P271: Use only outdoors or in a well-ventilated area
P280: Wear protective gloves/protective clothing/eye protection/face protection
P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
P302+P352: IF ON SKIN: Wash with plenty of water
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing
P310: Immediately call a poison center/doctor
P501: Dispose of contents/container in accordance with regulations on hazardous waste or packaging and packaging
waste respectively
Substances that contribute to the classification
3-aminomethyl-3,5,5-trimethylcyclohexylamine (CAS: 2855-13-2); Benzyl alcohol (CAS: 100-51-6);
1,3-Cyclohexanedimethanamine (CAS: 2579-20-6)
2.3 Other hazards:
Product fails to meet PBT/vPvB criteria

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDENER

SPECIAL WHITE PART B 40%

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS (continued)

3.1 Substance:
Non-applicable
3.2 Mixture:
Chemical description: Solution composed of amines
Components:
In accordance with Annex II of Regulation (EC) No 1907/2006 (point 3), the product contains:
Identification Chemical name/Classification Concentratio
n
CAS: 2855-13-2 3-aminomethyl-3,5,5-trimethylcyclohexylamine⁽¹⁾ ATP CLP00
EC: 220-666-8 Regulation 1272/2008 Acute Tox. 4: H302+H312; Aquatic Chronic 3: H412; Skin Corr. 1B: H314; Skin Sens. 50 - <75
Index 612-067-00-9
1: H317 - Danger %
: 01-2119514687-32-
REAC XXXX
CAS: 100-51-6 Benzyl alcohol⁽¹⁾ ATP CLP00
EC: 202-859-9 Regulation 1272/2008 Acute Tox. 4: H302+H332 - Warning 25 - <50
Index 603-057-00-5
%
: 01-2119492630-38-
REAC XXXX
CAS: 2579-20-6 1,3-Cyclohexanedimethanamine⁽¹⁾ Self-classified
EC: 219-941-5 Regulation 1272/2008 Acute Tox. 4: H302+H312; Aquatic Chronic 3: H412; Skin Corr. 1A: H314 - Danger 10 - <25
Index Non-applicable
%
: 01-2119543741-41-
REAC XXXX

⁽¹⁾ Substances presenting a health or environmental hazard which meet criteria laid down in Regulation (EU) No. 2015/830
To obtain more information on the hazards of the substances consult sections 8, 11, 12, 15 and 16.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures:

Request medical assistance immediately, showing the SDS of this product.
By inhalation:
Remove the person affected from the area of exposure, provide with fresh air and keep at rest. In serious cases
such as cardiorespiratory failure, artificial resuscitation techniques will be necessary (mouth to mouth resuscitation,
cardiac massage, oxygen supply, etc.) requiring immediate medical assistance.
By skin contact:
Remove contaminated clothing and footwear, rinse skin or shower the person affected if appropriate with plenty of
cold water and neutral soap. In serious cases see a doctor. If the product causes burns or freezing, clothing should
not be removed as this could worsen the injury caused if it is stuck to the skin. If blisters form on the skin, these
should never be burst as this will increase the risk of infection.
By eye contact:
Rinse eyes thoroughly with lukewarm water for at least 15 minutes. Do not allow the person affected to rub or close
their eyes. If the injured person uses contact lenses, these should be removed unless they are stuck to the eyes, in
which case this could cause further damage. In all cases, after cleaning, a doctor should be consulted as quickly as
possible with the SDS of the product.
By ingestion/aspiration:
Request immediate medical assistance, showing the SDS of this product. Do not induce vomiting, because its
expulsion from the stomach can be hazardous to the mucus of the main digestive tract, and also risk damage to the
respiratory system through inhalation. Rinse out the mouth and throat, as they may have been affected during
ingestion. In the case of loss of consciousness do not administer anything orally unless supervised by a doctor. Keep
the person affected at rest.
4.2 Most important symptoms and effects, both acute and delayed:
Acute and delayed effects are indicated in sections 2 and 11.
4.3 Indication of any immediate medical attention and special treatment needed:
Non-applicable

SECTION 5: FIREFIGHTING MEASURES

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDENER

SPECIAL WHITE PART B 40%

SECTION 5: FIREFIGHTING MEASURES (continued)

5.1 Extinguishing media:

Product is non-flammable under normal conditions of storage, handling and use. In the case of combustion as a
result of improper handling, storage or use preferably use polyvalent powder extinguishers (ABC powder), in
accordance with the Regulation on fire protection systems. IT IS NOT RECOMMENDED to use tap water as an
extinguishing agent.
5.2 Special hazards arising from the substance or mixture:
As a result of combustion or thermal decomposition reactive sub-products are created that can become highly toxic
and, consequently, can present a serious health risk.
5.3 Advice for firefighters:
Depending on the magnitude of the fire it may be necessary to use full protective clothing and self-contained
breathing apparatus (SCBA). Minimum emergency facilities and equipment should be available (fire blankets,
portable first aid kit,...) in accordance with Directive 89/654/EC.
Additional provisions:
Act in accordance with the Internal Emergency Plan and the Information Sheets on actions to take after an accident
or other emergencies. Eliminate all sources of ignition. In case of fire, cool the storage containers and tanks for
products susceptible to combustion, explosion or BLEVE as a result of high temperatures. Avoid spillage of the
products used to extinguish the fire into an aqueous medium.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures:

Isolate leaks provided that there is no additional risk for the people performing this task. Personal protection
equipment must be used against potential contact with the spilt product (See section 8). Evacuate the area and keep
out those who do not have protection.
6.2 Environmental precautions:
Avoid at all cost any type of spillage into an aqueous medium. Contain the product absorbed appropriately in
hermetically sealed containers. Notify the relevant authority in case of exposure to the general public or the
environment.
6.3 Methods and material for containment and cleaning up:
It is recommended:
Absorb the spillage using sand or inert absorbent and move it to a safe place. Do not absorb in sawdust or other
combustible absorbents. For any concern related to disposal consult section 13.
6.4 Reference to other sections:
See sections 8 and 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling:

A.- Precautions for safe manipulation
Comply with the current legislation concerning the prevention of industrial risks. Keep containers hermetically
sealed. Control spills and residues, destroying them with safe methods (section 6). Avoid leakages from the
container. Maintain order and cleanliness where dangerous products are used.
B.- Technical recommendations for the prevention of fires and explosions
Product is non-flammable under normal conditions of storage, handling and use. It is recommended to transfer at
slow speeds to avoid the generation of electrostatic charges that can affect flammable products. Consult section
10 for information on conditions and materials that should be avoided.
C.- Technical recommendations to prevent ergonomic and toxicological risks
Do not eat or drink during the process, washing hands afterwards with suitable cleaning products.
D.-Technical recommendations to prevent environmental risks
Due to the danger of this product for the environment it is recommended to use it within an area containing
contamination control barriers in case of spillage, as well as having absorbent material in close proximity.
7.2 Conditions for safe storage, including any incompatibilities:
A.- Technical measures for storage

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDENER

SPECIAL WHITE PART B 40%

SECTION 7: HANDLING AND STORAGE (continued)

Minimum Temp.: 15 ºC
Maximum Temp.: 35 ºC
Maximum time: 12 Months
B.- General conditions for storage
Avoid sources of heat, radiation, static electricity and contact with food. For additional information see subsection
10.5
7.3 Specific end use(s):
Except for the instructions already specified it is not necessary to provide any special recommendation regarding the
uses of this product.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters:

Substances whose occupational exposure limits have to be monitored in the workplace
There are no occupational exposure limits for the substances contained in the product
DNEL (Workers):
Short exposure Long exposure

Identification Systemic Local Systemic Local

Benzyl alcohol Oral Non-applicable Non-applicable Non-applicable Non-applicable

CAS: 100-51-6 Dermal 47 mg/kg Non-applicable 9,5 mg/kg Non-applicable
EC: 202-859-9 Inhalation 450 mg/m³ Non-applicable 90 mg/m³ Non-applicable
1,3-Cyclohexanedimethanamine Oral Non-applicable Non-applicable Non-applicable Non-applicable
CAS: 2579-20-6 Dermal 6 mg/kg Non-applicable 0,2 mg/kg Non-applicable
EC: 219-941-5 Inhalation 21,2 mg/m³ Non-applicable 0,71 mg/m³ Non-applicable

DNEL (General population):

Short exposure Long exposure
Identification Systemic Local Systemic Local

3-aminomethyl-3,5,5-trimethylcyclohexylamine Oral Non-applicable Non-applicable 0,526 mg/kg Non-applicable

CAS: 2855-13-2 Dermal Non-applicable Non-applicable Non-applicable Non-applicable
EC: 220-666-8 Inhalation Non-applicable Non-applicable Non-applicable Non-applicable

Benzyl alcohol Oral 25 mg/kg Non-applicable 5 mg/kg Non-applicable

CAS: 100-51-6 Dermal 28,5 mg/kg Non-applicable 5,7 mg/kg Non-applicable
EC: 202-859-9 Inhalation 40,55 mg/m³ Non-applicable 8,11 mg/m³ Non-applicable
1,3-Cyclohexanedimethanamine Oral 3 mg/kg Non-applicable 0,1 mg/kg Non-applicable
CAS: 2579-20-6 Dermal 3 mg/kg Non-applicable 0,1 mg/kg Non-applicable
EC: 219-941-5 Inhalation 5,2 mg/m³ Non-applicable 0,17 mg/m³ Non-applicable

PNEC:
Identification

3-aminomethyl-3,5,5-trimethylcyclohexylamine STP 3,18 mg/L Fresh water 0,06 mg/L

CAS: 2855-13-2 Soil 1,121 mg/kg Marine water 0,006 mg/L
EC: 220-666-8 Intermittent 0,23 mg/L Sediment (Fresh water) 5,784 mg/kg
Oral Non-applicable Sediment (Marine water) 0,578 mg/kg
Benzyl alcohol STP 39 mg/L Fresh water 1 mg/L
CAS: 100-51-6 Soil 0,456 mg/kg Marine water 0,1 mg/L
EC: 202-859-9 Intermittent 2,3 mg/L Sediment (Fresh water) 5,27 mg/kg
Oral Non-applicable Sediment (Marine water) 0,527 mg/kg

1,3-Cyclohexanedimethanamine STP 10 mg/L Fresh water 0,0331 mg/L

CAS: 2579-20-6 Soil Non-applicable Marine water 0,00331 mg/L
EC: 219-941-5 Intermittent 0,331 mg/L Sediment (Fresh water) Non-applicable
Oral Non-applicable Sediment (Marine water) Non-applicable

8.2 Exposure controls:

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDENER

SPECIAL WHITE PART B 40%

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

A.- General security and hygiene measures in the work place

As a preventative measure it is recommended to use basic Personal Protective Equipment, with the corresponding
<<CE marking>> in accordance with Directive 89/686/EC. For more information on Personal Protective
Equipment (storage, use, cleaning, maintenance, class of protection,…) consult the information leaflet provided
by the manufacturer. For more information see subsection 7.1.
All information contained herein is a recommendation which needs some specification from the labour risk
prevention services as it is not known whether the company has additional measures at its disposal.
B.- Respiratory protection
Pictogram PPE Labelling CEN Standard Remarks

Filter mask for gases and EN 405:2001+A1:2009 Replace when there is a taste or smell of the
vapours contaminant inside the face mask. If the
contaminant comes with warnings it is
recommended to use isolation equipment.
Mandatory
respiratory tract
protection

C.- Specific protection for the hands

Pictogram PPE Labelling CEN Standard Remarks

NON-disposable chemical EN 374-1:2003 The Breakthrough Time indicated by the

protective gloves EN 374-3:2003/AC:2006 manufacturer must exceed the period during
EN 420:2003+A1:2009 which the product is being used. Do not use
protective creams after the product has come
into contact with skin.
Mandatory hand
protection

"As the product is a mixture of several substances, the resistance of the glove material can not be predicted in
advance with total reliability and has therefore to be checked prior to the application"
D.-Ocular and facial protection
Pictogram PPE Labelling CEN Standard Remarks

Face shield EN 166:2001 Clean daily and disinfect periodically

EN 167:2001 according to the manufacturer´s instructions.
EN 168:2001 Use if there is a risk of splashing.
EN ISO 4007:2012
Mandatory face
protection

E.- Body protection

Pictogram PPE Labelling CEN Standard Remarks

Disposable clothing for EN 13034:2005+A1:2009 For professional use only. Clean periodically
protection against EN 168:2001 according to the manufacturer´s instructions.
chemical risks EN ISO
13982-1:2004/A1:2010
EN ISO 6529:2001
Mandatory
complete body
EN ISO 6530:2005
protection EN 464:1994

Safety footwear for EN ISO 20345:2011 Replace boots at any sign of deterioration.
protection against EN 13832-1:2006
chemical risk

Mandatory foot
protection

F.- Additional emergency measures

Emergency measure Standards Emergency measure Standards

ANSI Z358-1 DIN 12 899

ISO 3864-1:2002 ISO 3864-1:2002

Emergency shower Eyewash stations

Environmental exposure controls:

In accordance with the community legislation for the protection of the environment it is recommended to avoid
environmental spillage of both the product and its container. For additional information see subsection 7.1.D
Volatile organic compounds:
With regard to Directive 2010/75/EU, this product has the following characteristics:
V.O.C. (Supply): 10 % weight

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDENER

SPECIAL WHITE PART B 40%

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (continued)

V.O.C. density at 20 ºC: 95,47 kg/m³ (95,47 g/L)

Average carbon number: 8
Average molecular weight: 140,23 g/mol

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties:

For complete information see the product datasheet.
Appearance:
Physical state at 20 ºC: Liquid
Appearance: Transparent
Colour: Colourless
Odour: Characteristic
Odour threshold: Non-applicable *
Volatility:
Boiling point at atmospheric pressure: 236 ºC
Vapour pressure at 20 ºC: 6 Pa
Vapour pressure at 50 ºC: 56 Pa (0 kPa)
Evaporation rate at 20 ºC: Non-applicable *
Product description:
Density at 20 ºC: 955 kg/m³
Relative density at 20 ºC: 0,955
Dynamic viscosity at 20 ºC: 2,59 cP
Kinematic viscosity at 20 ºC: 2,71 cSt
Kinematic viscosity at 40 ºC: Non-applicable *
Concentration: Non-applicable *
pH: Non-applicable *
Vapour density at 20 ºC: Non-applicable *
Partition coefficient n-octanol/water 20 ºC: Non-applicable *
Solubility in water at 20 ºC: Non-applicable *
Solubility properties: Non-applicable *
Decomposition temperature: Non-applicable *
Melting point/freezing point: Non-applicable *
Explosive properties: Non-applicable *
Oxidising properties: Non-applicable *
Flammability:
Flash Point: 107 ºC
Flammability (solid, gas): Non-applicable *
Autoignition temperature: 380 ºC
Lower flammability limit: Non-applicable *
Upper flammability limit: Non-applicable *
Explosive:
Lower explosive limit: Non-applicable *
Upper explosive limit: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDEBER

SPECIAL WHITE PART B 40%

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES (continued)

9.2 Other information:

Surface tension at 20 ºC: Non-applicable *
Refraction index: Non-applicable *
*Not relevant due to the nature of the product, not providing information property of its hazards.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity:
No hazardous reactions are expected because the product is stable under recommended storage conditions. See
section 7.
10.2 Chemical stability:
Chemically stable under the conditions of storage, handling and use.
10.3 Possibility of hazardous reactions:
Under the specified conditions, hazardous reactions that lead to excessive temperatures or pressure are not
expected.
10.4 Conditions to avoid:
Applicable for handling and storage at room temperature:
Shock and friction Contact with air Increase in temperature Sunlight Humidity
Not applicable Not applicable Not applicable Not applicable Not applicable

Avoid overheating. Avoid all sources of ignition.

Avoid non-intentional contacts with epoxy costituents/acids. May produce an exothermic reaction, forming phenolic
derivates, marbon monoxide and water.
10.5 Incompatible materials:
Acids Water Combustive materials Combustible materials Others
Avoid strong acids Not applicable Precaution Not applicable Avoid alkalis or strong
bases

Air. Oxidizing materials. Metals

10.6 Hazardous decomposition products:
In the event of thermal decomposition or fire, gases and vapours that are potentially dangerous to health may be
released, ammonia.
Nitrogen oxide may react with water vapor to form corrosive nitric acid.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects:

The experimental information related to the toxicological properties of the product itself is not available

Dangerous health implications:

In case of exposure that is repetitive, prolonged or at concentrations higher than the recommended occupational
exposure limits, adverse effects on health may result, depending on the means of exposure:
A- Ingestion (acute effect):

- Acute toxicity : The consumption of a considerable dose can cause irritation in the throat, abdominal pain,
nausea and vomiting.
- Corrosivity/Irritability: Corrosive product, if it is swallowed causes burns destroying the tissues. For more
information about secondary effects from skin contact see section 2.
B- Inhalation (acute effect):

- Acute toxicity : Exposure in high concentration can interfere with the central nervous system causing
headache, dizziness, vertigo, nausea, vomiting, confusion, and in serious cases, loss of consciousness.
- Corrosivity/Irritability: Prolonged inhalation of the product is corrosive to mucous membranes and the upper
respiratory tract
C- Contact with the skin and the eyes (acute effect):

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDEBER

SPECIAL WHITE PART B 40%

SECTION 11: TOXICOLOGICAL INFORMATION (continued)

- Contact with the skin: Above all, skin contact may occur as fabrics of all thicknesses can be destroyed,
resulting in burns. For more information on the secondary effects see section 2.
- Contact with the eyes: Produces serious eye damage after contact.
D- CMR effects (carcinogenicity, mutagenicity and toxicity to reproduction):

- Carcinogenicity: Based on available data, the classification criteria are not met, as it does not contain
substances classified as dangerous for the effects mentioned. For more information see section 3.
- Mutagenicity: Based on available data, the classification criteria are not met, as it does not contain
substances classified as dangerous for this effect. For more information see section 3.
- Reproductive toxicity: Based on available data, the classification criteria are not met, as it does not contain
substances classified as dangerous for this effect. For more information see section 3.
E- Sensitizing effects:

- Respiratory: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous with sensitising effects. For more information see section 3.
- Cutaneous: Prolonged contact with the skin can result in episodes of allergic contact dermatitis.
F- Specific target organ toxicity (STOT) - single exposure:

Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
G- Specific target organ toxicity (STOT)-repeated exposure:

- Specific target organ toxicity (STOT)-repeated exposure: Based on available data, the classification criteria
are not met, as it does not contain substances classified as dangerous for this effect. For more information see
section 3.
- Skin: Based on available data, the classification criteria are not met, as it does not contain substances
classified as dangerous for this effect. For more information see section 3.
H- Aspiration hazard:

Based on available data, the classification criteria are not met, as it does not contain substances classified as
dangerous for this effect. For more information see section 3.
Other information:

Non-applicable

Specific toxicology information on the substances:

Identification Acute toxicity Genus

Benzyl alcohol LD50 oral 500 mg/kg Rat

CAS: 100-51-6 LD50 dermal 2500 mg/kg (ATEi)
EC: 202-859-9 LC50 inhalation 11 mg/L (4 h) (ATEi)

3-aminomethyl-3,5,5-trimethylcyclohexylamine LD50 oral 1030 mg/kg Rat

CAS: 2855-13-2 LD50 dermal 1100 mg/kg
EC: 220-666-8 LC50 inhalation Non-applicable

1,3-Cyclohexanedimethanamine LD50 oral 700 mg/kg Rat

CAS: 2579-20-6 LD50 dermal 1700 mg/kg Rabbit
EC: 219-941-5 LC50 inhalation Non-applicable

SECTION 12: ECOLOGICAL INFORMATION

The experimental information related to the eco-toxicological properties of the product itself is not available
12.1 Toxicity:
Identification Acute toxicity Species Genus

3-aminomethyl-3,5,5-trimethylcyclohexylamine LC50 110 mg/L (96 h) Leuciscus idus Fish

CAS: 2855-13-2 EC50 388 mg/L (48 h) N/A Crustacean
EC: 220-666-8 EC50 Non-applicable

Benzyl alcohol LC50 646 mg/L (48 h) Leuciscus idus Fish

CAS: 100-51-6 EC50 400 mg/L (24 h) Daphnia magna Crustacean
EC: 202-859-9 EC50 79 mg/L (3 h) Scenedesmus subspicatus Algae

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FGT EPOXY HARDEBER

SPECIAL WHITE PART B 40%

SECTION 12: ECOLOGICAL INFORMATION (continued)

Identification Acute toxicity Species Genus

1,3-Cyclohexanedimethanamine LC50 130 mg/L (96 h) Leuciscus idus Fish

CAS: 2579-20-6 EC50 33 mg/L (48 h) Daphnia magna Crustacean
EC: 219-941-5 EC50 30 mg/L (72 h) Pseudokirchneriella Algae
subcapitata

12.2 Persistence and degradability:

Identification Degradability Biodegradability

3-aminomethyl-3,5,5-trimethylcyclohexylamine BOD5 Non-applicable Concentration 7 mg/L

CAS: 2855-13-2 COD Non-applicable Period 28 days
EC: 220-666-8 BOD5/COD Non-applicable % Biodegradable 8%

Benzyl alcohol BOD5 Non-applicable Concentration 100 mg/L

CAS: 100-51-6 COD Non-applicable Period 14 days
EC: 202-859-9 BOD5/COD Non-applicable % Biodegradable 94 %
1,3-Cyclohexanedimethanamine BOD5 Non-applicable Concentration 100 mg/L
CAS: 2579-20-6 COD Non-applicable Period 28 days
EC: 219-941-5 BOD5/COD Non-applicable % Biodegradable 29 %

12.3 Bioaccumulative potential:

Identification Bioaccumulation potential

Benzyl alcohol BCF 0.3

CAS: 100-51-6 Pow Log 1.1
EC: 202-859-9 Potential Low

12.4 Mobility in soil:

Identification Absorption/desorption Volatility

3-aminomethyl-3,5,5-trimethylcyclohexylamine Koc 928 Henry 4,46E-4 Pa·m³/mol

CAS: 2855-13-2 Conclusion Low Dry soil No
EC: 220-666-8 Surface tension Non-applicable Moist soil No

Benzyl alcohol Koc Non-applicable Henry Non-applicable

CAS: 100-51-6 Conclusion Non-applicable Dry soil Non-applicable
EC: 202-859-9 Surface tension 3,679E-2 N/m (25 Moist soil Non-applicable
ºC)
1,3-Cyclohexanedimethanamine Koc 30 Henry Non-applicable
CAS: 2579-20-6 Conclusion Very High Dry soil Non-applicable
EC: 219-941-5 Surface tension Non-applicable Moist soil Non-applicable

12.5 Results of PBT and vPvB assessment:

Product fails to meet PBT/vPvB criteria
12.6 Other adverse effects:
Not described

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods:

Code Description Waste class (Regulation (EU) No
1357/2014)
08 04 09* waste adhesives and sealants containing organic solvents or other hazardous substances Dangerous

Type of waste (Regulation (EU) No 1357/2014):

HP14 Ecotoxic, HP4 Irritant — skin irritation and eye damage, HP6 Acute Toxicity, HP8 Corrosive, HP13 Sensitising

Waste management (disposal and evaluation):

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FGT EPOXY HARDEBER

SPECIAL WHITE PART B 40%

SECTION 13: DISPOSAL CONSIDERATIONS (continued)

Consult the authorized waste service manager on the assessment and disposal operations in accordance with Annex
1 and Annex 2 (Directive 2008/98/EC). As under 15 01 (2014/955/EC) of the code and in case the container has
been in direct contact with the product, it will be processed the same way as the actual product. Otherwise, it will be
processed as non-dangerous residue. We do not recommended disposal down the drain. See paragraph 6.2.

Regulations related to waste management:

In accordance with Annex II of Regulation (EC) No 1907/2006 (REACH) the community or state provisions related to
waste management are stated
Community legislation: Directive 2008/98/EC, 2014/955/EU, Regulation (EU) No 1357/2014

SECTION 14: TRANSPORT INFORMATION

Transport of dangerous goods by land:

With regard to ADR 2017 and RID 2017:
14.1 UN number: UN2735
14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES,
LIQUID, CORROSIVE, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
14.3 Transport hazard 8
class(es):
Labels: 8
14.4 Packing group: II
14.5 Environmental hazards: No
14.6 Special precautions for user
Special regulations: 274
Tunnel restriction code: E
Physico-Chemical properties: see section 9
Limited quantities: 1L
14.7 Transport in bulk Non-applicable
according to Annex II of
Marpol and the IBC Code:
Transport of dangerous goods by sea:
With regard to IMDG 38-16:
14.1 UN number: UN2735
14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES,
LIQUID, CORROSIVE, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
14.3 Transport hazard 8
class(es):
Labels: 8
14.4 Packing group: II
14.5 Environmental hazards: No
14.6 Special precautions for user
Special regulations: 274
EmS Codes: F-A, S-B
Physico-Chemical properties: see section 9
Limited quantities: 1L
14.7 Transport in bulk Non-applicable
according to Annex II of
Marpol and the IBC Code:
Transport of dangerous goods by air:
With regard to IATA/ICAO 2018:

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 Safety data sheet
According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDEBER

SPECIAL WHITE PART B 40%

SECTION 14: TRANSPORT INFORMATION (continued)

14.1 UN number: UN2735

14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES,
LIQUID, CORROSIVE, N.O.S.
(3-aminomethyl-3,5,5-trimethylcyclohexylamine)
14.3 Transport hazard 8
class(es):
Labels: 8
14.4 Packing group: II
14.5 Environmental hazards: No
14.6 Special precautions for user
Physico-Chemical properties: see section 9
14.7 Transport in bulk Non-applicable
according to Annex II of
Marpol and the IBC Code:

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:
Candidate substances for authorisation under the Regulation (EC) No 1907/2006 (REACH): Non-applicable
Substances included in Annex XIV of REACH ("Authorisation List") and sunset date: Non-applicable
Regulation (EC) No 1005/2009, about substances that deplete the ozone layer: Non-applicable
Article 95, REGULATION (EU) No 528/2012: Non-applicable
REGULATION (EU) No 649/2012, in relation to the import and export of hazardous chemical products:
Non-applicable
Limitations to commercialisation and the use of certain dangerous substances and mixtures (Annex XVII
REACH, etc ….):
Shall not be used in:
—ornamental articles intended to produce light or colour effects by means of different phases, for example in
ornamental lamps and ashtrays,
—tricks and jokes,
—games for one or more participants, or any article intended to be used as such, even with ornamental aspects.
Specific provisions in terms of protecting people or the environment:
It is recommended to use the information included in this safety data sheet as a basis for conducting
workplace-specific risk assessments in order to establish the necessary risk prevention measures for the handling,
use, storage and disposal of this product.
Other legislation:
The product could be affected by sectorial legislation
15.2 Chemical safety assessment:
The supplier has not carried out evaluation of chemical safety.

SECTION 16: OTHER INFORMATION

Legislation related to safety data sheets:

This safety data sheet has been designed in accordance with ANNEX II-Guide to the compilation of safety data
sheets of Regulation (EC) No 1907/2006 (Regulation (EC) No 2015/830)
Modifications related to the previous Safety Data Sheet which concerns the ways of managing risks.:
Non-applicable
Texts of the legislative phrases mentioned in section 2:
H314: Causes severe skin burns and eye damage
H318: Causes serious eye damage
H317: May cause an allergic skin reaction
H412: Harmful to aquatic life with long lasting effects
H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled
Texts of the legislative phrases mentioned in section 3:

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According to 1907/2006/EC (REACH), 2015/830/EU

FGT EPOXY HARDEBER

SPECIAL WHITE PART B 40%

SECTION 16: OTHER INFORMATION (continued)

The phrases indicated do not refer to the product itself; they are present merely for informative purposes and refer
to the individual components which appear in section 3
CLP Regulation (EC) No 1272/2008:
Acute Tox. 4: H302+H312 - Harmful if swallowed or in contact with skin
Acute Tox. 4: H302+H332 - Harmful if swallowed or if inhaled
Aquatic Chronic 3: H412 - Harmful to aquatic life with long lasting effects
Skin Corr. 1A: H314 - Causes severe skin burns and eye damage
Skin Corr. 1B: H314 - Causes severe skin burns and eye damage
Skin Sens. 1: H317 - May cause an allergic skin reaction
Classification procedure:
Skin Corr. 1A: Calculation method
Eye Dam. 1: Calculation method
Skin Sens. 1: Calculation method
Aquatic Chronic 3: Calculation method
Acute Tox. 4: Calculation method
Advice related to training:
Minimal training is recommended in order to prevent industrial risks for staff using this product and to facilitate their
comprehension and interpretation of this safety data sheet, as well as the label on the product.
Principal bibliographical sources:
http://echa.europa.eu
http://eur-lex.europa.eu
Abbreviations and acronyms:
ADR: European agreement concerning the international carriage of dangerous goods by road
IMDG: International maritime dangerous goods code
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
COD: Chemical Oxygen Demand
BOD5: 5-day biochemical oxygen demand
BCF: Bioconcentration factor
LD50: Lethal Dose 50
LC50: Lethal Concentration 50
EC50: Effective concentration 50
Log-POW: Octanol–water partition coefficient
Koc: Partition coefficient of organic carbon

The information contained in this safety data sheet is based on sources, technical knowledge and current legislation at European and state level, without being able to
guarantee its accuracy. This information cannot be considered a guarantee of the properties of the product, it is simply a description of the security requirements. The
occupational methodology and conditions for users of this product are not within our awareness or control, and it is ultimately the responsibility of the user to take the
necessary measures to obtain the legal requirements concerning the manipulation, storage, use and disposal of chemical products. The information on this safety data
sheet only refers to this product, which should not be used for needs other than those specified.

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