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SAFETY DATA SHEET

ACORGA® OPT® 5540 EXTRACTION REAGENT

Revision Date 08.03.2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
- Trade name ACORGA® OPT® 5540 EXTRACTION REAGENT

1.2 Relevant identified uses of the substance or mixture and uses advised against
Uses of the Substance/Mixture
- Mining chemicals

1.3 Details of the supplier of the safety data sheet


Company
CYTEC INDUSTRIES INC.
504 CARNEGIE CENTER
PRINCETON, NJ 08540 USA
Telephone: +1-973-357-3193

E-mail address
[email protected]

1.4 Emergency telephone number


+44(0)1235 239 671 [CareChem 24]

Disclaimer
The ® indicates a Registered Trademark in the United States and the ™ indicates a trademark in the United States. The mark may
also be registered, subject of an application for registration, or a trademark in other countries.

SECTION 2: Hazards identification


2.1 Classification of the substance or mixture
GHS Classification (UN)
Flammable liquids, Category 4 H227: Combustible liquid.
Acute toxicity, Category 5 H303: May be harmful if swallowed.
Skin irritation, Category 2 H315: Causes skin irritation.
Serious eye damage/eye irritation, Category 1 H318: Causes serious eye damage.
Skin sensitization, Category 1 H317: May cause an allergic skin reaction.
Reproductive toxicity, Category 1B H360: May damage fertility or the unborn child.
Specific target organ toxicity - single exposure, H336: May cause drowsiness or dizziness. (Central nervous
Category 3 system)
Short-term (acute) aquatic hazard, Category 2 H401: Toxic to aquatic life.
Long-term (chronic) aquatic hazard, Category 1 H410: Very toxic to aquatic life with long lasting effects.

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2.2 Label elements


GHS label elements (UN)
Hazardous products which must be listed on the label
 CAS-No. 174333-80-3 5-Nonyl-2-hydroxy-benzaldoxime, branched
 CAS-No. 64742-47-8 Distillates (petroleum), hydrotreated light
 ***** Modified phenolic compound

Pictogram

Signal word
- Danger
Hazard statements
- H227 Combustible liquid.
- H303 May be harmful if swallowed.
- H315 Causes skin irritation.
- H317 May cause an allergic skin reaction.
- H318 Causes serious eye damage.
- H336 May cause drowsiness or dizziness.
- H360 May damage fertility or the unborn child.
- H401 Toxic to aquatic life.
- H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
General
- None
Prevention
- P201 Obtain special instructions before use.
- P202 Do not handle until all safety precautions have been read and understood.
- P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources.
No smoking.
- P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
- P264 Wash skin thoroughly after handling.
- P271 Use only outdoors or in a well-ventilated area.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P273 Avoid release to the environment.
- P280 Wear protective gloves/ protective clothing/ eye protection/ face protection/ hearing
protection.
Response
- P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth.
- P302 + P352 IF ON SKIN: Wash with plenty of water.
- P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a
POISON CENTER/doctor if you feel unwell.
- P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
- P312 Call a POISON CENTER/doctor if you feel unwell.
- P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.
- P370 + P378 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish.
- P391 Collect spillage.
Storage
- P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
- P405 Store locked up.
Disposal
- P501 Dispose of contents/ container to an approved waste disposal plant.

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2.3 Other hazards which do not result in classification


None known.

SECTION 3: Composition/information on ingredients


3.1 Substance
- Not applicable, this product is a mixture.
3.2 Mixture
- Chemical nature Modified aldoxime/ketoxime blend

Information on Components and Impurities


Chemical name CAS-No. GHS Classification Concentration [%]
5-Nonyl-2-hydroxy-benzaldoxime, branched CAS-No. : Acute toxicity, Category 5 ; 30 - 60
174333-80-3 H303Skin irritation, Category 2 ;
H315Serious eye damage,
Category 1 ; H318Skin
sensitization, Category 1 ;
H317Reproductive toxicity,
Category 1B ; H360FDShort-term
(acute) aquatic hazard, Category 2
; H401Long-term (chronic) aquatic
hazard, Category 1 ; H410
M-Factor(Acute) : 1
M-Factor(Chronic) : 10

Distillates (petroleum), hydrotreated light CAS-No. : Flammable liquids, Category 4 ; 10 - 30


64742-47-8 H227Aspiration hazard, Category 1
; H304

Distillates (petroleum), hydrotreated light CAS-No. : Flammable liquids, Category 4 ; 10 - 30


64742-47-8 H227Skin irritation, Category 2 ;
H315Aspiration hazard, Category 1
; H304Specific target organ toxicity
- single exposure, Category 3 ;
H336Short-term (acute) aquatic
hazard, Category 2 ; H401Long-
term (chronic) aquatic hazard,
Category 2 ; H411

1-isopropyl-2,2-dimethyltrimethylene CAS-No. : Reproductive toxicity, Category 2 ; 10 - 30


diisobutyrate 6846-50-0 H361Long-term (chronic) aquatic
hazard, Category 3 ; H412

Modified phenolic compound ***** Acute toxicity, Category 4 ; 7 - 13


H302Skin irritation, Category 2 ;
H315Eye irritation, Category 2A ;
H319Short-term (acute) aquatic
hazard, Category 1 ; H400Long-
term (chronic) aquatic hazard,
Category 1 ; H410

Nonyl salicaldehyde CAS-No. : Skin sensitization, Sub-category 1B < 0.35


Not Assigned ; H317

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Phenol, 4-nonyl-, branched CAS-No. : Acute toxicity, Category 4 ; <1


84852-15-3 H302Skin corrosion, Sub-category
1B ; H314Serious eye damage,
Category 1 ; H318Reproductive
toxicity, Category 2 ; H361fdShort-
term (acute) aquatic hazard,
Category 1 ; H400Long-term
(chronic) aquatic hazard, Category
1 ; H410
M-Factor(Acute) : 10
M-Factor(Chronic) : 10

Ditolyl methane CAS-No. : Acute toxicity, Category 5 ; < 0.1


1335-47-3 H303Acute toxicity, Category 4 ;
H332Aspiration hazard, Category 1
; H304Short-term (acute) aquatic
hazard, Category 1 ; H400Long-
term (chronic) aquatic hazard,
Category 1 ; H410

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 4: First aid measures


4.1 Description of first aid measures
In case of inhalation
- Quickly move the person away from the contaminated area. Make the affected person rest.
- Immediate medical attention is required.
- Show this sheet to the doctor.
- Be prepared to provide first aid or medical support if necessary.

In case of skin contact


- Wash off immediately with plenty of water for at least 15 minutes.
- Use appropriate protective equipment when treating a contaminated person.
- Always obtain medical attention.
- Show this sheet to the doctor.
- Be prepared to provide first aid or medical support if necessary.

In case of eye contact


- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Keep eye wide open while rinsing.
- Show this sheet to the doctor.
- Always obtain medical advice, even if there are no symptoms.
- Be prepared to provide first aid or medical support if necessary.

In case of ingestion
- Do NOT induce vomiting.
- Immediate medical attention is required.
- Show this sheet to the doctor.
- Do not give anything to drink.
- Be prepared to provide first aid or medical support if necessary.

4.2 Most important symptoms and effects, both acute and delayed
Effects
- Effects on health may appear after exposure.
- The effects will depend on target organs.
- May damage fertility or the unborn child.
- Chronic exposure may cause allergic dermatitis.
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- Exposure may cause allergic rhinitis, conjunctivitis, asthma or shock.


- If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the oesophagus and the
stomach.
- In case of inhalation, irritation/corrosion of the respiratory tract.
- Risk of respiratory disorder
- May cause irreversible skin damage.
- Chronic exposure may cause dermatitis.
- May cause irreversible eye damage.
- Loss of the eye
- Exposure may cause sleepiness, dizziness, headache, nausea, unconsciousness.

Symptoms
- Symptoms will depend on the target organs.
- Inhalation may provoke the following symptoms:
- Cough
- Breathing difficulties
- Irritation
- Redness
- Swelling of tissue
- Ingestion may provoke the following symptoms:
- Nausea
- Diarrhoea
- Abdominal pain
- Drowsiness
- Dizziness
- Headache
- Unconsciousness
- May cause respiratory tract irritation.
- allergic rhinitis
- Severe allergic skin reactions, bronchiospasm and anaphylactic shock
- Itching
- Dermatitis
- Causes skin burns.
- Lachrymation
- Conjunctivitis
- Causes eye burns.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician
- Be aware to maintain life support if necessary.
- Take victim immediately to hospital.
- Immediate medical attention is required.
- Consult with an ophthalmologist immediately in all cases.
- Burns must be treated by a physician.
- Treat symptomatically.
- Contact a poison control center.
- Keep under medical supervision for at least 48 hours.
- Contact the occupational physician in case of exposure.

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing media
- Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Unsuitable extinguishing media


- High volume water jet

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5.2 Special hazards arising from the substance or mixture


- Under fire conditions:
- Will burn
- On combustion, toxic gases are released.

5.3 Advice for firefighters


Special protective equipment for firefighters
- In the event of fire, wear self-contained breathing apparatus.
- Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing
- For further information refer to section 8 "Exposure controls/personal protection".

Specific fire fighting methods


- Cool containers/tanks with water spray.
- Do not use a solid water stream as it may scatter and spread fire.

Further information
- Standard procedure for chemical fires.
- Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
- Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
- Where exposure level is not known, wear approved, positive pressure, self-contained respirator.
- Where exposure level is known, wear approved respirator suitable for level of exposure.
- In addition to the protective clothing/equipment in Section 8, wear a two piece PVC suit with hood or PVC overalls
with hood.

6.2 Environmental precautions


- Stop the leak. Turn leaking containers leak-side up to prevent the escape of liquid.
- Contain the spilled material by bunding.
- Do not let product enter drains.
- Do not allow uncontrolled discharge of product into the environment.

6.3 Methods and materials for containment and cleaning up


- Remove all sources of ignition.
- Stop leak if safe to do so.
- Keep in properly labelled containers.
- Keep in suitable, closed containers for disposal.
- Wash non-recoverable remainder with large amounts of water.
- Soak up with inert absorbent material and dispose of as hazardous waste.
- Decontaminate tools, equipment and personal protective equipment in a segregated area.
- Dispose of in accordance with local regulations.
- Never return spills in original containers for re-use.

6.4 Reference to other sections


- 7. HANDLING AND STORAGE
- 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
- 13. DISPOSAL CONSIDERATIONS

SECTION 7: Handling and storage


7.1 Precautions for safe handling
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- Containers must be bonded and grounded when pouring or transferring material.


- This material contains a flammable or combustible liquid and vapor.
- Do not release to water.

Hygiene measures
- Handle in accordance with good industrial hygiene and safety practice.
- Wash hands before breaks and at the end of workday.
- When using do not eat, drink or smoke.
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Keep away from food and drink.

7.2 Conditions for safe storage, including any incompatibilities


Technical measures/Storage conditions
- Observe the general rules of industrial fire protection.
- Areas containing this material should have fire safe practices and electrical equipment in accordance with
applicable regulations and/or guidelines. Standards are primarily based on the material`s flashpoint, but may also
take into account properties such as miscibility with water or toxicity. All local and national regulations should be
followed. |par In the Americas, National Fire Protection Association (NFPA) 30: Flammable and Combustible
Liquids Code, is a widely used standard. NFPA 30 establishes storage conditions for the following classes of
materials: Class I Flammable Liquids, Flashpoint <37.8 °C. Class II Combustible Liquids, 37.8 °C < Flashpoint <60
°C. Class IIIa Combustible Liquids, 60 °C < Flashpoint < 93 °C. Class IIIb Combustible Liquids, Flashpoint > 93 °C.
- Keep away from sources of ignition - No smoking.

Requirements for storage rooms and vessels


Recommended storage temperature: 20 °C

- To guarantee the quality and properties of the product keep according to Storage temperature and conditions.

7.3 Specific end use(s)


- no data available

SECTION 8: Exposure controls/personal protection


8.1 Control parameters

Components with other occupational exposure limits


Components Value type Value Basis
Distillates (petroleum), hydrotreated light TWA 200 mg/m3 USA. ACGIH Threshold Limit Values (TLV)

Danger of cutaneous absorption


Expressed as :total hydrocarbon vapor

Distillates (petroleum), hydrotreated light TWA 200 mg/m3 USA. ACGIH Threshold Limit Values (TLV)

Danger of cutaneous absorption


Expressed as :total hydrocarbon vapor

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8.2 Exposure controls


Control measures
Engineering measures
- Ensure adequate ventilation.
- Apply technical measures to comply with the occupational exposure limits.

Individual protection measures


Respiratory protection
- Self-contained breathing apparatus in confined spaces/insufficient oxygen/in case of large uncontrolled emissions/in
all circumstances when the mask and cartridge do not give adequate protection.
- Use only respiratory protection that conforms to international/ national standards.
- Respirator with a vapour filter (EN 141)
- Respirator with a full face mask
- Use the indicated respiratory protection if the occupational exposure limit is exceeded.

Hand protection
- Take note of the information given by the producer concerning permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
- Impervious gloves

Suitable material
- Nitrile or fluorinated rubber gloves.

Eye protection
- Chemical resistant goggles must be worn.
- Tightly fitting safety goggles

Skin and body protection


- Impervious clothing
- Full protective suit
- Change working clothes after each workshift.
- Contaminated work clothing should not be allowed out of the workplace.

Hygiene measures
- Handle in accordance with good industrial hygiene and safety practice.
- Wash hands before breaks and at the end of workday.
- When using do not eat, drink or smoke.
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Keep away from food and drink.

Environmental exposure controls


- Dispose of rinse water in accordance with local and national regulations.

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical properties

Appearance Physical state: liquid


Colour: amber

Odour characteristic
Odour Threshold No data available
Molecular weight Mixture

pH No data available
Melting point/freezing point No data available
Initial boiling point and boiling range No data available

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Flash point 92.8 °C Pensky-Martens closed cup

Evaporation rate (Butylacetate = 1) No data available


Flammability (solid, gas) No data available
Flammability (liquids) No data available
Flammability/Explosive limit No data available
Auto-ignition temperature No data available
Vapour pressure No data available
Vapour density No data available

Density 0.93 - 0.96 g/cm3

Relative density No data available


Solubility Water solubility:
immiscible

Partition coefficient: n-octanol/water No data available


Decomposition temperature No data available

Viscosity No data available


Explosive properties No data available
Oxidizing properties Not considered as oxidizing

9.2 Other information


Corrosion of Metals Not corrosive to metals

Peroxides The substance or mixture is not classified as organic peroxide.

SECTION 10: Stability and reactivity


10.1 Reactivity
- no data available
10.2 Chemical stability
- Stable

10.3 Possibility of hazardous reactions


- no data available
10.4 Conditions to avoid
- no data available
10.5 Incompatible materials

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- Acids
- Oxygen
- Strong oxidizing agents

10.6 Hazardous decomposition products


Hazardous decomposition products
- Carbon oxides
- Nitrogen oxides (NOx)
- Ammonia

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
Acute oral toxicity The product has a low acute toxicity
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Acute inhalation toxicity Not classified as hazardous for acute inhalation toxicity according to GHS.
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Acute dermal toxicity Not classified as hazardous for acute dermal toxicity according to GHS.
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Acute toxicity (other routes of Not applicable


administration)

Skin corrosion/irritation Irritating to skin.


According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Repeated exposure may cause skin dryness or cracking.

Serious eye damage/eye irritation Risk of serious damage to eyes.


According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

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Respiratory or skin sensitisation


5-Nonyl-2-hydroxy-benzaldoxime, Local lymph node assay - Mouse
branched Stimulation Index ≥ 3
The substance or mixture is considered to be sensitizing by skin contact.
Method: OECD Test Guideline 429
Unpublished reports

Distillates (petroleum), hydrotreated Maximisation Test - Guinea pig


light Does not cause skin sensitisation.
Method: OECD Test Guideline 406

Distillates (petroleum), hydrotreated category approach


light
Buehler Test - Guinea pig
negative
The substance or mixture is not considered to be sensitizing by skin contact.
Method: OECD Test Guideline 406
Published data
Unpublished reports

category approach

Local lymph node assay - Mouse


negative
The substance or mixture is not considered to be sensitizing by skin contact.
Method: OECD Test Guideline 406
Published data
Unpublished reports

1-isopropyl-2,2-dimethyltrimethylene Humans
diisobutyrate The substance or mixture is not considered to be sensitizing by skin contact.
Unpublished reports

Phenol, 4-nonyl-, branched Maximisation Test - Guinea pig


Does not cause skin sensitisation.
Method: OECD Test Guideline 406
Unpublished reports

Ditolyl methane By analogy

Maximisation Test - Guinea pig


Not classified as sensitising by skin contact according to GHS criteria
Method: OECD Test Guideline 406
Unpublished reports

Mutagenicity
Genotoxicity in vitro Product is not considered to be genotoxic
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Genotoxicity in vivo Product is not considered to be genotoxic


According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

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Carcinogenicity The product is not considered to be carcinogenic.


According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Toxicity for reproduction and development


Toxicity to reproduction/Fertility
5-Nonyl-2-hydroxy-benzaldoxime, Rat, male and female, Oral
branched General Toxicity - Parent NOAEL: 100 mg/kg bw/day
Fertility LOAEL Parent: 30 mg/kg bw/day
OECD Test Guideline 421
Gavage, Clear evidence of adverse effects on sexual function and fertility, and/or
on development, based on animal experiments, Unpublished reports

Distillates (petroleum), hydrotreated category approach


light

Rat, male and female, Oral


Gavage, No toxicity to reproduction, Unpublished reports

category approach

Reproduction/developmental toxicity screening test - Rat, male and female,


Dermal
OECD Test Guideline 421
No toxicity to reproduction, Published data

1-isopropyl-2,2-dimethyltrimethylene Reproduction/developmental toxicity screening test - Rat, male and female, Oral
diisobutyrate General Toxicity - Parent NOAEL: 276 mg/kg
OECD Test Guideline 421
in feed, Animal testing did not show any effects on fertility., Unpublished reports

Phenol, 4-nonyl-, branched By analogy

Two-generation study - Rat, male and female, Gavage


Published data, Some evidence of adverse effects on sexual function and fertility,
based on animal experiments., Effects on development were observed

Ditolyl methane By analogy

Rat, male and female, Oral


OECD Test Guideline 415
No toxicity to reproduction, Gavage, Unpublished reports

By analogy

Rat, male and female, Oral


OECD Test Guideline 422
No toxicity to reproduction, Gavage, Unpublished reports

Developmental Toxicity/Teratogenicity

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5-Nonyl-2-hydroxy-benzaldoxime, Rat, male and female, Oral


branched General Toxicity Maternal NOAEL: 100 mg/kg bw/day
Developmental Toxicity NOAEL F1: 30 mg/kg bw/day
Symptoms: foetal mortality
Method: OECD Test Guideline 421
Unpublished reports

Distillates (petroleum), hydrotreated Rat, male and female, Oral


light Test period: 10 Days
General Toxicity Maternal NOAEL: 500 mg/kg/day
Teratogenicity NOAEL:1,000mg/kg/day
Method: OECD Test Guideline 414
category approach, Gavage, Published data, no embryotoxic or teratogenic
effects have been observed

Distillates (petroleum), hydrotreated category approach


light

Rat, male and female, Oral


Method: OECD Test Guideline 414
Gavage, Published data, no embryotoxic or teratogenic effects have been
observed

category approach

Rat, male and female, Oral


Method: OECD Test Guideline 414
Gavage, no embryotoxic or teratogenic effects have been observed

1-isopropyl-2,2-dimethyltrimethylene reproductive and developmental toxicity study - Rabbit, male and female, Oral
diisobutyrate General Toxicity Maternal NOAEL: 1,000 mg/kg bw/day

Teratogenicity NOAEL F1:1,000mg/kg bw/day


Developmental Toxicity NOAEL F1: 300 mg/kg bw/day

Method: OECD Test Guideline 414


Unpublished reports

Phenol, 4-nonyl-, branched By analogy

Rat, male and female, Oral


Method: OECD Test Guideline 414
Unpublished reports, The product is not considered to be teratogenic.

Ditolyl methane By analogy

Rat, female, Oral


Method: OECD Test Guideline 414
Effects on the progeny are not considered significant as they were observed only
in doses leading to maternal toxicity, Gavage, Unpublished reports

STOT
STOT - single exposure Target Organs: Central nervous system
The substance or mixture is classified as specific target organ toxicant, single
exposure, category 3 with narcotic effects according to GHS criteria.
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

STOT - repeated exposure The substance or mixture is not considered to cause damage to organs through
prolonged or repeated exposure.
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According to the available data on the components.


According to the classification criteria for mixtures.
Unpublished reports and/or published data.

The product itself has not been tested.

Neurological effects
Distillates (petroleum), hydrotreated Information given is based on data obtained from similar substances.,
light Published data, Rat, No neurotoxic effects observed.

Experience with human exposure


Experience with human exposure : Inhalation
No data is available on the product itself.

Experience with human exposure : Skin contact


No data is available on the product itself.

Experience with human exposure : Eye contact


No data is available on the product itself.

Experience with human exposure : Ingestion


No data is available on the product itself.

CMR effects
Mutagenicity
5-Nonyl-2-hydroxy-benzaldoxime, Tests on bacterial or mammalian cell cultures did not show mutagenic effects.
branched
Ditolyl methane Not classified as mutagen according to GHS criteria.

Teratogenicity

5-Nonyl-2-hydroxy-benzaldoxime, Classified as toxic for the reproduction in Category 1B (development) according


branched to GHS criteria

1-isopropyl-2,2-dimethyltrimethylene Classified as toxic for the reproduction in Category 2 (development) according to


diisobutyrate GHS criteria

Ditolyl methane Not classified as toxic for the reproduction (development) according to GHS
criteria

Reproductive toxicity
5-Nonyl-2-hydroxy-benzaldoxime, Classified as toxic for the reproduction in Category 1B (fertility and/or
branched development) according to GHS criteria

Phenol, 4-nonyl-, branched Classified as toxic for the reproduction in Category 2 (fertility and/or development)
according to GHS criteria

Ditolyl methane Not classified as toxic for the reproduction (fertility and/or development) according
to GHS criteria

Aspiration toxicity Not classified for aspiration toxicity according to GHS criteria

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SECTION 12: Ecological information


12.1 Toxicity

Aquatic Compartment
Acute toxicity to fish The product itself has not been tested.

Acute toxicity to daphnia and other The product itself has not been tested.
aquatic invertebrates

Toxicity to aquatic plants The product itself has not been tested.

Toxicity to microorganisms The product itself has not been tested.

Chronic toxicity to fish The product itself has not been tested.

Chronic toxicity to daphnia and The product itself has not been tested.
other aquatic invertebrates

Sediment compartment
Toxicity to benthic organisms The product itself has not been tested.

Terrestrial Compartment
Toxicity to soil dwelling organisms The product itself has not been tested.

Toxicity to terrestrial plants The product itself has not been tested.

Toxicity to above ground organisms The product itself has not been tested.

M-Factor
5-Nonyl-2-hydroxy-benzaldoxime, Acute aquatic toxicity = 1
branched Chronic aquatic toxicity = 10

Phenol, 4-nonyl-, branched Acute aquatic toxicity = 10


Chronic aquatic toxicity = 10
( according to the Globally Harmonized System (GHS) )

12.2 Persistence and degradability

Abiotic degradation
Stability in water Conclusion is not possible for a mixture as a whole.

Photodegradation Conclusion is not possible for a mixture as a whole.

Other Physico-Chemical reactions Conclusion is not possible for a mixture as a whole.

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Physical- and photo-chemical elimination


Physico-chemical removability Conclusion is not possible for a mixture as a whole.

Biodegradation

Biodegradability As (bio)degradability is not relevant for mixtures, all the components of the
mixture were assessed individually (rapid degradability assessment available
below).

Ratio BOD/COD Conclusion is not possible for a mixture as a whole.

Ratio BOD/ThOD Conclusion is not possible for a mixture as a whole.

Biochemical Oxygen Demand (BOD) Conclusion is not possible for a mixture as a whole.

Dissolved organic carbon (DOC) Conclusion is not possible for a mixture as a whole.

Chemical Oxygen Demand (COD)


Conclusion is not possible for a mixture as a whole.

Adsorbed organic bound halogens Conclusion is not possible for a mixture as a whole.
(AOX)

Degradability assessment Conclusion is not possible due to incomplete or heterogeneous data on the
components
Unpublished reports
Published data

12.3 Bioaccumulative potential

Partition coefficient: n- Conclusion is not possible for a mixture as a whole.


octanol/water

Bioconcentration factor (BCF) As bioaccumulation is not relevant for mixtures, all the components of the mixture
were assessed individually.
At least one of the components is considered to be potentially bioaccumulable.
Unpublished reports
Published data

12.4 Mobility in soil

Adsorption potential (Koc) Conclusion is not possible for a mixture as a whole.

Known distribution to Conclusion is not possible due to incomplete or heterogeneous data on the
environmental compartments components

12.5 Results of PBT and vPvB assessment According to the available data on the components
This mixture contains no substance considered to be persistent, bioaccumulating
and toxic (PBT).
This mixture contains no substance considered to be very persistent and very
bioaccumulating (vPvB).

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12.6 Other adverse effects

Ecotoxicity assessment
Short-term (acute) aquatic hazard Toxic to aquatic life.
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

Long-term (chronic) aquatic hazard Very toxic to aquatic life with long lasting effects.
According to the available data on the components.
According to the classification criteria for mixtures.
Unpublished reports and/or published data.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
Product Disposal
- The Company encourages the recycle, recovery and reuse of materials, where permitted. If disposal is necessary,
The Company recommends that organic materials, especially when classified as hazardous waste, be disposed of by
thermal treatment or incineration at approved facilities. All local and national regulations should be followed.

SECTION 14: Transport information


IMDG

14.1 UN number UN 3082

14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.


(Salicylaldoxime derivative, Modified phenolic compound)

14.3 Transport hazard class 9


Label(s): 9

14.4 Packing group


Packing group III

14.5 Environmental hazards YES


Marine pollutant

14.6 Special precautions for user


EmS F-A , S-F

For personal protection see section 8.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No data available

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IATA

14.1 UN number UN 3082

14.2 Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.


(Salicylaldoxime derivative, Modified phenolic compound)

14.3 Transport hazard class 9


Label(s): 9
14.4 Packing group
Packing group III

14.5 Environmental hazards YES

14.6 Special precautions for user


Packing instruction (cargo aircraft) 964
Max net qty/pkg 450.00 L
Packing instruction (passenger aircraft) 964
Max net qty/pkg 450.00 L

For personal protection see section 8.

Note: The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of
transport regulations for hazardous materials, it would be advisable to check their validity with your sales office.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Local regulations
No data available

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Notification status
Inventory Information Status
United States TSCA Inventory - All substances listed as active on the
TSCA inventory

EU. European Registration, Evaluation, Authorisation and Restriction of - When purchased from a European
Chemical (REACH) Solvay legal entity, this product is
compliant with the registration
provisions of the REACH Regulation
(EC) No. 1907/2006 as all its
components are either excluded,
exempt, and/or registered. When
purchased from a legal entity outside of
Europe, please contact your local
representative for additional information.

Canadian Domestic Substances List (DSL) - One or more components not listed on
inventory

Australia Inventory of Chemical Substances (AICS) - Listed on Inventory

Japan. CSCL - Inventory of Existing and New Chemical Substances - Listed on Inventory

Korea. Korean Existing Chemicals Inventory (KECI) - Listed on Inventory

China. Inventory of Existing Chemical Substances in China (IECSC) - Listed on Inventory

Philippines Inventory of Chemicals and Chemical Substances (PICCS) - One or more components not listed on
inventory

Taiwan Chemical Substance Inventory (TCSI) - One or more components not listed on
inventory

New Zealand. Inventory of Chemical Substances - One or more components is not listed
on the NZIOC inventory. The HSNO
status of the product has not been
assessed.

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SECTION 16: Other information


Full text of H-Statements
- H227 Combustible liquid.
- H302 Harmful if swallowed.
- H303 May be harmful if swallowed.
- H304 May be fatal if swallowed and enters airways.
- H314 Causes severe skin burns and eye damage.
- H315 Causes skin irritation.
- H317 May cause an allergic skin reaction.
- H318 Causes serious eye damage.
- H319 Causes serious eye irritation.
- H332 Harmful if inhaled.
- H336 May cause drowsiness or dizziness.
- H360 May damage fertility or the unborn child.
- H360FD May damage fertility. May damage the unborn child.
- H361 Suspected of damaging fertility or the unborn child.
- H361fd Suspected of damaging fertility. Suspected of damaging the unborn child.
- H400 Very toxic to aquatic life.
- H401 Toxic to aquatic life.
- H410 Very toxic to aquatic life with long lasting effects.
- H411 Toxic to aquatic life with long lasting effects.
- H412 Harmful to aquatic life with long lasting effects.

Key or legend to abbreviations and acronyms used in the safety data sheet
- TWA 8-hour, time-weighted average

Further information
- Distribute new edition to clients
- Update
- See section 3

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. Such information is only given as a guidance to help the user handle, use, process, store, transport,
dispose and release the product in satisfactory safety conditions and is not to be considered as a warranty or quality
specification. It should be used in conjunction with technical sheets but do not replace them. Thus, the information only
relates to the designated specific product and may not be applicable if such product is used in combination with other
materials or in any other manufacturing process, unless otherwise specifically indicated. It does not release the user from
ensuring he is in conformity with all regulations linked to its activity.

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