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    XII - Revision Sheet - 4 - Chemistry

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    Vipin V
    This document provides a revision paper for Class 12 Chemistry on the topic of d-block and f-block elements. It contains 9 questions across 4 sections - Section A has 5 objective type questions worth 1 mark each, Section B has 2 short answer questions worth 2 marks each, Section C has 1 short answer question worth 3 marks, and Section D has 1 long answer question worth 5 marks. The questions test a range of concepts regarding the properties, reactions, and electronic configurations of transition metals and inner transition metals.

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    XII - Revision Sheet - 4 - Chemistry

    Uploaded by

    Vipin V
    29 views2 pages
    This document provides a revision paper for Class 12 Chemistry on the topic of d-block and f-block elements. It contains 9 questions across 4 sections - Section A has 5 objective type questions worth 1 mark each, Section B has 2 short answer questions worth 2 marks each, Section C has 1 short answer question worth 3 marks, and Section D has 1 long answer question worth 5 marks. The questions test a range of concepts regarding the properties, reactions, and electronic configurations of transition metals and inner transition metals.

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    XII_Revision Sheet_4_Chemistry

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    This document provides a revision paper for Class 12 Chemistry on the topic of d-block and f-block elements. It contains 9 questions across 4 sections - Section A has 5 objective type questions worth 1 mark each, Section B has 2 short answer questions worth 2 marks each, Section C has 1 short answer question worth 3 marks, and Section D has 1 long answer question worth 5 marks. The questions test a range of concepts regarding the properties, reactions, and electronic configurations of transition metals and inner transition metals.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    29 views2 pages

    XII - Revision Sheet - 4 - Chemistry

    Uploaded by

    Vipin V
    This document provides a revision paper for Class 12 Chemistry on the topic of d-block and f-block elements. It contains 9 questions across 4 sections - Section A has 5 objective type questions worth 1 mark each, Section B has 2 short answer questions worth 2 marks each, Section C has 1 short answer question worth 3 marks, and Section D has 1 long answer question worth 5 marks. The questions test a range of concepts regarding the properties, reactions, and electronic configurations of transition metals and inner transition metals.

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    © All Rights Reserved
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    of 2

    LUCKNOW PUBPLIC SCHOOL

    TIME ALLOWED -60Min UNIT -8 (D AND F BLOCK ELEMENTS) M.M-20


    CLASS-12 (CHEMISTRY)
    REVISION PAPER
    GENERAL INSTRUCTIONS
    A) There are 9 questions in this paper. All questions are compulsory.
    B) Section A; Q No 1to 5 are objective type and carry 1marks each.
    C) Section B; Q No 6 and7 are short answer type and carry 2marks each.
    D) Section C; Q No 8 is short answer type and carry 3 marks each.
    E) Section D; Q No 9 is long answer type and carry 5 marks each.
    F) There is no overall choice. However, internal choice has been provided

    SECTION- A (OBJECTIVE TYPE)


    Q1. In basic solution pH 6, CrO3 forms the tetrahedral yellow chromate ions, CrO42-. Between pH 2 and
    6 HCrO4- and the orange red dichromate ion, Cr2O72_, are in equilibrium. At pH values below 1, the main
    species is H2CrO4 . The equilibria are
    HCrO4- ↔ CrO42- +H+ ,K=10-5.9
    H2CrO4-- ↔ HCrO4- +H+ ,K=4.1
    Cr2O72- +H2O ↔ 2 HCrO4- ,K=10-2.2
    In addition, these are base -hydrolysis equilibria
    Cr2O72- +OH ↔ HCrO4- + CrO42-
    HCrO4- +OH- ↔ CrO4- +H2O
    The pH dependent equilibria are quite labile and on addition of cations that form insoluble chromates
    (eg Ba+2, pb2+ ) the chromates and not the dichromats are precipitated

    Read the passes carefully and give the answer of the following questions (1X4)
    (i)Which of the following statement is correct?
    (a)Acidic solution of dichromate are strong oxidants (b) In alkaline solution, the chromate ion is
    strong oxidant (c) Acidic solution of dichromate are poor oxidants (d) Both a and b
    (ii) The equilibria, Cr2O72- ↔ CrO42- is shifted to right in
    (a)an acidic medium (b) a basic medium (c) a neutral medium (d) Both a and b
    (iii) In the redox reaction involving Cr2O72- and Fe2+ ions are numbers electrons absorbed per
    chromium atom is
    (a) 1 (b) 3 (c) 4 (d) 6
    OR
    Which one of the following ions is diamagnetic?
    (a) Cr2+ (b) V2+ (c) Sc3+ (d) Ti3+
    (iv)When acidified K2Cr2O7 solution is added to Sn2+ salt, then Sn2+ changes to
    (a) Sn (b) Sn3+ (c) Sn4+ (d) Sn+
    Q2. Match the column I with II and mark the appropriate choice (1)
    Column I(property) Column II( Metal)
    (A)Element with highest second ionisation enthalpy (i) Cr
    (B)Element with highest third ionisation enthalpy (ii) Cu
    (c)M in M(CO)6 is (iii) Zn
    (D) Element with highest heat of atomisation (iv) V
    A B C D
    (a) (ii) (iii) (i) (iv)
    (b) (iv) (iii) (i) (ii)
    (c) (iii) (i) (ii) (iv)
    (d) (i) (ii) (iii) (iv)
    Q3. Out of the following transition elements, the maximum number of oxidation state are shown
    by (1)
    (a) Sc (b) Cr (c) Mn (d) Fe
    OR
    Which of the following ions is colourless
    (a) Cu+ (b) Co2+ (c) Ni2+ (d) Fe3+
    Q4. There are 14 elements in actinoids series. which of the following does not belong to this
    series (1)
    (a) U (b) Np (c) Tm (d) Fm
    . Assertion and reason type question
    (a) If both assertion and reason are true and reason is true expiation of the assertion
    (b) If both assertion and reason are true, but reason is not true expiation of assertion
    (c) If assertion is true, but reason is false
    (d) If assertion is false and reason is true.
    Q5. Assertion Separation of Zr and Hf is difficult
    Reason: Because Zr and Hf lie in the same group of the periodic table
    SECTION -B
    Q6. Give reasons for the following statements (1+1)
    (i)Transition metals and most of their compounds show paramagnetic behaviour
    (ii)Zinc and Hg are soft metal
    Q7. Give reasons for the following statements (1+1)
    (i)MnO is basic while Mn2O7 is acidic
    (ii)Mn3+ is a good oxidising agent
    OR
    (i) Write the possible oxidation states of an element having atomic number 25
    (ii) What is the equivalent mass of KMnO4 in acidic medium
    SECTION-C
    Q8. Complete the following reactions (1x3)
    (i) KMnO4 on heating
    (ii) MnO4- + I- +H2O →
    (iii) MnO4- + S2O32- +H2O →
    SECTION-D
    Q9. Account for the following
    (i)Why melting point of transition metals high?
    (ii)Although F is more electronegative than O, the highest fluoride of Mn is MnF4 while the highest oxide
    is Mn2O7. (1X5)
    (iii)HCl is not used in permanganate titration.
    (iv)Atomic radii of 4d and 5d series elements are nearly same.
    (v)Transition metals form large number of complex compounds.
    OR
    (i) How would you account for the irregulatity variation of ionisation enthalpies in first series of
    transition elements
    (ii) La(OH)3 is more basic than Lu(OH)3 explain
    (iii) What are the consequences of lanthanoid contraction ?

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