Worksheet Amines

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INNOVATIVE SCIENCE AND COMMERCE ACADEMY(ISCA)

WORKSHEET-V (2022-23)
CLASS– XII
CHEMISTRY(043)
CHAPTER-13

1. Write the IUPAC name of the following compound:

H2N — CH2—CH2—CH = CH2.

2. Give the chemical tests to distinguish between the following pairs of compounds :
(i) Ethyl amine and Aniline
(ii) Aniline and Benzylamine

3. Identify A and B in each of the following processes

4. Describe the following giving the relevant chemical equation in each case :
(i) Carbylamine reaction
(ii) Hofmann’s bromamide reaction .

5. Give IUPAC names of the following compounds :

6. How are the following conversions carried out :


(a) Aniline to p-hydroxyazobenzene
(b) Ethanoyl chloride to Ethanenitrile.

7. How would you account for the following :


(a) Aniline is a weaker base than cyclohexyl amine.
(b) Methylamine in aqueous medium gives reddish-brown precipitate with FeCl3.

8. Illustrate the following reactions :


(a) Sandmeyer’s reaction
(b) Coupling reaction

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9. Give reasons :
(a) Aniline is a weaker base than cyclohexyl amine.
(b) It is difficult to prepare pure amines by ammonolysis of alkyl halides.

10. (i) Arrange the following compounds in an increasing order of basic strength :
C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2

(ii) Arrange the following compounds in a decreasing order of pKb values :


C2H5NH2, C6H5NHCH3, (C2H5)2NH and C6H5NH .

11. Complete the following reaction equations:

12. In the following cases rearrange the compounds as directed :

(i) In an increasing order of basic strength :


C6H5NH2, C6H5 N(CH3)2, (C2H5)2NH and CH3NH2
(ii) In a decreasing order of basic strength :
Aniline, p-nitroaniline and p-toluidine
(iii) In an increasing order of pKb values :
C2H5NH2, C6H5 NHCH3, (C2H5)2NH and C6H5NH2

13. Identify A and B in each of the following processes :

14. How would you account for the following :


(a) Electrophilic susbstitution in case of aromatic amines takes place more readily than benzene.
(b) Ethanamide is a weaker base than ethanamine.
(c) Aniline is a weaker base than cyclohexyl amine.
(d) It is difficult to prepare pure amines by ammonolysis of alkyl halides.

15. Write chemical equations for the following conversions :


(i) Nitrobenzene to benzoic acid.
(ii) Benzyl chloride to 2-phenylethanamine
(iii) Aniline to benzyl alcohol.

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