KUMYANG Co., Ltd.

SAFETY DATA SHEET

according to Regulation (EC) No 1907/2006, Annex II
th
Revision date: Dec. 06 , 2017 Replaces the version of: Jul. 21st, 1975 Page: 7
KY-QP-SDS-C-001
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING

1.1. Identification of the substance or preparation

CELLCOM – OBSH
1.2. Use of the substance/preparation
Blowing agents for plastics and rubber
1.3. Company/undertaking identification
KUM YANG CO., LTD. SEOUL OFFICE
81, NAKDONG-DAERO ROOM NO.1201, TRADE TOWER,
960BEON-GIL, SASANG-GU, WORLD TRADE CENTER ,
BUSAN, KOREA 511,YEONGDONG-DAERO,
TEL: 82-51-310-5832∼4 GANGNAM-GU, SEOUL, KOREA 135-729
FAX : 82-51-325-5887 TEL : 82-2-3454-1717
FAX : 82-2-3143-0641∼2
1.4. Emergency telephone
Advisory office in case of poisoning
Tel: : 82-51-316-5881∼6
Telephone number of the company in case of emergencies
Tel: : 82-51-316-5881∼6

2. HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]
Physical
Skin corrosion/irritation, Category 2, Serious eye damage/eye irritation, Category 2
Health
Specific target organ toxicity, single exposure; Respiratory tract irritation, Category 3
Environmental
2.2 Label elements
2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP/GHS]
Product identifier
Substances
4,4'-Oxybis(benzenesulfonyl hydrazide)
Mixtures
None
Hazard components for labelling
4,4'-Oxybis(benzenesulfonyl hydrazide)
Hazard pictograms

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 GHS07
Signal word
Danger
Hazard Statements
H315 Causes skin irritation
H319 Causes serious eye irritation
H335 May cause respiratory irritation
Prevention
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
Correspondence
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P362 Take off contaminated clothing and wash before reuse.
Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
Discard
P501 Dispose of contents/container to..…
HMIS Classification
Health hazard 2
Flammability 2
Physical hazards 2
NFPA Rating
Health hazard 2
Fire 2
Reactivity Hazard 2
Potential Health Effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Ingestion Toxic if swallowed.

3. COMPOSITION / INFORMATION ON INGREDIENTS

3.1 Substances/Mixtures
Substance 4,4'-Oxybis(benzenesulfonyl hydrazide)
Purity 96 ~ 100 %
Synonyms 4,4'-oxydi(benzenesulphonohydrazide), 4,4’-oxybis(benzenesulfonicacidhydrazide)
CAS No 80-51-3
EINECS No 201-286-1
IUPAC name 4,4'-oxydibenzenesulfonohydrazide
Formula C12H14N4O5S2
Molecular Weight 358.39g/mol

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 Classification according Regulation (EC) No 1272/2008 [CLP]
H315, H319, H335
3.2 Additional information

4. FIRST AID MEASURES

4.1 Description of first aid measures

General informations
Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.
Following inhalation
If breathed in, move person into fresh air. If not breathing give artificial respiration.
Following skin contact
Wash off with soap and plenty of water.
Following eye contact
Flush eyes with water as a precaution.
Following ingestion
Never give anything by mouth to an unconscious person. Rinse mouth with water
Special resources necessary for first aid
n.c

5. FIRE-FIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2 Special hazards arising from the substance or mixture
Hazardous combustion products: Decompose around 160 deg.℃
5.3 Special protective equipment for fire-fighters
Wear self contained breathing apparatus for fire fighting if necessary.
5.4 Additional information

6. ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Avoid dust formation. Avoid breathing vapors, mist or gas.
6.2 Environmental precautions
Do not let product enter drains.
6.3 Methods and material for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.

7. HANDLING AND STORAGE

7.1 Handling
Provide appropriate exhaust ventilation at places where dust is formed. Normal measures for preventive fire protection.
7.2 Storage
Keep container tightly closed in a dry and well-ventilated place.
Keep in a dry place.
7.3 Specific use
n.c

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 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Exposure limit values

-
8.2 Exposure controls
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95
(US) or type P1 (EN 143) dust masks. Use respirators and components tested and approved under appropriate
government standards such as NIOSH (US) or CEN (EU).
Hand protection
Handle with gloves
Eye protection
Face shield and safety glasses
Skin and body protection
Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Hygiene measures
General industrial hygiene practice.

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Important health, safety and environmental information

Appearance
Physical state Powder
Colour White
Odour Not available
Odour threshold Not available
Safety relevant basic data
pH(20℃) 6.0 ~ 8.0
Melting point/range (℃) Not available
Initial boiling point(℃) Not available
Decomposition temperature(℃) 158 ~ 164℃
Flash point(℃) Value not determined
Flammability Not combustible
Explosive properties Non explosive
Self-ignition temperature(℃) Not available
Oxidising properties Not available
Ignition temperature Not available
Lower explosion limit Not available
Upper explosion limit Not available
Vapour pressure (hPa) at ℃) Not available
Vapour density (air=1) Not available
Relative density (g/mL at 25℃) 1.55 g/mL
Bulk density (kg/m3) Not available
Water solubility (20℃ in g/l) Not available
Solubility Very soluble in Dimethylsulfoxide, Dimethylformamide
Partition coefficient Not available
Viscosity Not available

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 10. STABILITY AND REACTIVITY

10.1 Chemical stability

Stable under recommended storage conditions.
10.2 Conditions to avoid
Do not heat above melting point.
10.3 Materials to avoid
Strong oxidizing agents, Strong acids, Strong bases, Heavy metal salts, Plastics.
10.4 Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, nitrogen oxides (NOx)

11. TOXICOLOGICAL INFORMATION

11.1 Acute toxicity

LD50 Oral - rat > 2000 mg/kg
11.2 Skin corrosion/irritation
LD50 Oral - rat > 600 mg/kg
11.3 Serious eye damage/eye irritation
No data available
11.4 Respiratory or skin sensitization
Sensitizing
11.5 Germ cell mutagenicity
No data available
11.6 Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible
or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a known or
anticipated carcinogen by NTP.
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or
potential carcinogen by OSHA.
11.7 Reproductive toxicity
No data available
11.8 Specific target organ toxicity - single exposure (GHS)
No data available
11.9 Specific target organ toxicity - repeated exposure (GHS)
No data available
11.10 Aspiration hazard
No data available
11.11 Potential health effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Ingestion Toxic if swallowed.
11.12 Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly
investigated.

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 12. ECOLOGICAL INFORMATION

12.1 Toxicity
No data available
12.2 Persistence and degradability
No data available
12.3 Bioaccumulative potential
No data available
12.4 Mobility in soil
No data available
12.5 Results of PBT and vPvB assessment
No data available
12.6 Other adverse effects
No data available
12.7 Additional information

13. DISPOSAL CONSIDERATIONS

13.1 Product
Contact a licensed professional waste disposal service to dispose of this material.
13.2 Contaminated packaging
Dispose of as unused product.
13.3 Additional information

14. TRANSPORT INFORMATION

14.1 U.S. Department of Transportation (DOT)

UN-No: UN3226
Proper shipping name: SELF-REACTIVE SOLID TYEP D (contains 4, 4’-Oxybis(benzenesulfonyl hydrazide))
Class(es): 4.1
Packing group: PG 2
14.2 Land transport (ADR/RID/GGVSE)
UN-No: UN3226
Proper shipping name: SELF-REACTIVE SOLID TYEP D (contains 4, 4’-Oxybis(benzenesulfonyl hydrazide))
Class(es): 4.1
Classification Code: H315, H319, H335
Packing group: PG 2
Hazard label(s): N.A
Special provision(s): N.A
14.3 Sea transport (IMDG-Code/GGVSee)
UN No: UN3226
Proper shipping name: SELF-REACTIVE SOLID TYEP D (contains 4, 4’-Oxybis(benzenesulfonyl hydrazide))
Class(es): 4.1
Packing group: PG 2
Marine Pollutant: N.A
Special provision(s): N.A
14.4 Air transport (ICAO-IATA/DGR)
UN No: UN3226
Proper shipping name: SELF-REACTIVE SOLID TYEP D (contains 4, 4’-Oxybis(benzenesulfonyl hydrazide))
Class(es): 4.1

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 Packing group: PG 2
Special provision(s): N.A
14.5 Additional information

15. REGULATORY INFORMATION

15.1 OSHA Hazards

No known OSHA hazards
15.2 DSL Status
All components of this product are on the Canadian DSL list.
15.3 SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
15.4 SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed
the threshold(De Minimis) reporting levels established by SARA Title III, Section 313.
15.5 SARA 311/312 Hazards
No SARA Hazards
15.6 Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
15.7 Pennsylvania Right To Know Components
CAS-No. Revision Date
4,4'-Oxybis(benzenesulfonyl hydrazide) 80-5 1-3
15.8 New Jersey Right To Know Components
CAS-No. Revision Date
4,4'-Oxybis(benzenesulfonyl hydrazide) 80-5 1-3
15.9 California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects,
or any other reproductive harm.

16. OTHER INFORMATION

16.1 Revision Indicator

New MSDS(GHS)
16.2 Disclaimer
The information contained herein is accurate to the best of our knowledge. My Company makes no warranty of any kind,
express or implied, concerning the safe use of this material in your process or in combination with other substances.

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