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FATS

They belong to class of fats and fat related compounds called lipid.
They include substances such as fats, oils, waxes and related compounds that are greasy to
the touch and insoluble in water. ------
HYDROPHOBIC
They provide a more concentrated source of energy compared to
carbohydrates.
Some fat deposits are not used and are considered structural fat. They
hold the body organs and nerves in position and protect them against
shock and injury.

CHEMICAL NATURE OF FATS


A fat molecule has the elements: carbon, hydrogen and oxygen in
glyceride linkages.
The proportion of oxygen in fats is smaller than in carbohydrates.
When a fat molecule is hydrolyzed, it yields 3 fatty acids and a molecule
of glycerol.
General Formula of Fats:
CnH2nO2 or CH3(CH2)n------COOH

CLASSIFICATION OF FATS

A.Simple lipids are called “Neutral fats”.


-The chemical name for these basic fats is triglycerides. This name
indicates their chemical structure, a glycerol base with three fatty acids
attached.
They are classified as : a. sterol and b. non-sterol esters
Triglycerides:(Fats)
Are the largest category of lipids.
In the body, fat cells stores triglycerides in adipose tissue.----major
storage form of fat in the body
In foods “ we call triglycerides as “ fats and oils”

Compound Lipids
Are various combinations of fats with other components.
Three types of compound lipids are important in human nutrition:
1. Phospholipids
2. Glycolipids
3. Lipoprotein
1.Phospholipids – are compounds of fatty acids, phosphoric acids and
nitrogenous base
About 2% of dietary lipids are phospholipids.
They are found in foods of both plant and animal origin, and the body
makes those that it needs.
Unlike other lipids, phospholipids are soluble in both fat and water.
They play a crucial role as major constituents in cell membranes, blood
and body fluids.
They are called” emulsifiers”.
Sources includes: egg yolks, liver, soy beans and peanuts.
a. Lecithin- also called "phosphatidylcholine”
-Is the most widely distributed of the phospholipids.
Are used in food industry as emulsifiers to combine 2 ingredients that don’t ordinarily mix.
Lecithins in salad dressing, chili increases dispersion and reduce fat
separation.
Also added in chewing gums.
b.Cephalin --- used in clotting agent in blood coagulation
Is needed to form thromboplastin for the blood clotting process.
c.Sphingomyelin
Is found in the brain and other nerve tissue as a component of myelin sheath.
Three substances act as an insulator around the nerve fibers.
Egg yolk and liver are good sources of these phospholipids.

2.Glycolipids

Are compounds of fatty acids combined with carbohydrates and a


nitrogenous base.
a.Cerebrocides
Are components of nerve tissue and certain cell membranes where
they play a vital role in fat transport.
Their carbohydrate component is galactose.
b.Gangliosides
are made up of certain glucose, galactose and a complex compound
containing an amino sugar.

3.Lipoproteins
Are lipids in combination with protein.
They are formed primarily in the liver and are found in cell and organelle
membranes, mitochondria and lysosomes.
They are insoluble in water and to effect their transport and activity in
aqueous medium, they are combined in protein complex.
They contain cholesterol, neutral fat and fatty acids.

C. Derived Lipids
Are simple derivatives from fat digestion or other more complex
products.
They are fat substances produced from fats and fat compounds during
digestive breakdown.
1.Fatty acids----- structural unit of fat
Are the key refined fuel forms of fat that the cell burns for energy.
They are the basic structural units of fat and may be saturated or
unsaturated in nature

Sources of Fatty Acids:


Saturated fatty acids ----- can clog arteries
Are those into which no hydrogen can be added.
They are abundant in animal fats including beef.
Examples: Palmitic and stearic acids (They are abundant in animal fats
including beef; also in chocolates

b.. Unsaturated fatty acids


The carbon chain contains one or more double bonds. Hydrogen,
oxygen or some other atom can attach easily to a double bond.
They typically have a lower melting point and are likely to be liquid at
room temp.

c. Monounsaturated fatty acid (MUFA)


The carbon chain contains one double bond.
This means that an atom can be added to each of the carbon atoms at
a double bond.
Oleic acid is the most abundant monounsaturated fatty acid e.g. olive
and peanut oils.(olive oil is a thick liquid at room temperature but may solidify under
refrigeration.)

d. Polyunsaturated fatty acid (PUFA)


Is one in which two or more double bonds are present.
Linoleic acid has two double bonds and is the most common of the polyunsaturated acids.
It is abundant in most vegetable oils.
2.Glycerol
Is a water-soluble component of triglycerides and is inconvertible with
carbohydrate.
It comes out 10% of the fat.
After it is broken off in digestion, it is available for the formation of
glucose in the diet.
A thick, smooth liquid often used in food industry.
It is considered as the “backbone” of a triglyceride.

3.Steroids
Are class of fat-related substances that contain “”sterols.”
Sterols are “ lipophilic and hydrophobic”.
The best known member is “cholesterol”.---- becomes harmful only
when it forms deposits in the arterial wall -----results to increase BP

Cholesterol:
Is a necessary, important substance in the body
It is complex fat-like compound found practically in all body tissues,
especially in the brain and nerve tissues, bile blood and the liver where
most cholesterol is synthesized.
Occurs only in foods of animal origin.
It is distributed in the body based on it’s biological roles: it is highest in
the brain, high in liver and other organ meats and moderate in muscle
tissue.
Two types: LDL and HDL

Functions of Cholesterol in our Body


It acts as a precursor of Vit. D, and 5 major classes of sterol hormones:
progestins, glucocorticoids, mineralocorticoids, androgens and estrogens.
Helps in the manufacture of bile acids, which are secreted in order to
emulsify dietary fats.
The body produces at least 1,000 mg. of cholesterol/day.

Food rich in cholesterol:


Egg Yolk, organ meats, shellfish, dairy fats
Also includes butter, cream, whole milk. Whole milk cheese, ice cream.

TWO PRINCIPAL ESSENTIAL FATTY ACIDS FOR HUMANS


Linoleic Acid (An Omega 6 Fatty Acid)
Are found in vegetables and seed oils and are forms of polyunsaturated
fatty acids. When missing from the diet, the skin reddens and becomes
irritated, infections and dehydration become more likely and the liver
may develop abnormalities.
Alpha-Linolenic Acid (Omega 3 Fatty Acid)
Are found in fatty fish, walnuts, canola oil and are another form of
PUFA’s.

FUNCTIONS OF FATS
1.Concentrated Source of Energy
Normally, about 95% of the fat in food is digested and absorbed.
Fats as we all know are important sources of calories.
Under normal circumstances, dietary and stored fat supply about 6o% of the body’s resting
energy needs.

2. Sparer of Protein
Fat is said to be protein sparing because its availability reduces the
need to burn protein for energy.
Fat is the preferred fuel of muscle tissue at rest.
3.Energy Reserve
Human and some animals store excess dietary fat to tide over periods
of caloric deficits.
adipocytes – a fat cell
adipose tissue – forms body fat tissue

The body possesses complex mechanisms for freeing triglycerides and


fatty acids and delivering them when and where they are needed for
energy. Cells then break down these lipids to release energy.

4.Insulation and Protection


Fat tissue accounts for about 15 to 30% of a person’s body weight.
Visceral fat –an adipose tissue around organs that remains relatively inert until called upon
to release stored energy. Cushions body organs.
Subcutaneous fat – fat stores under the skin. Protects and insulates the body.

Sites for fat storage differ for men and women:


men – upper abdomen, buttocks.
women – breast, abdomen, neck, upper arm, buttock, hips

5.Carrier of Fat-Soluble Compounds


Dietary fats carry other fat-soluble substances through the digestive
process, improving their intestinal absorption.
e.g. lycopene – a healthful red-colored phytochemical in tomatoes;it is greatly absorb
because of the presence of fat in the diet.

6.Sensory Qualities
Fat contributes greatly to the flavor, odor and texture of food. E.g. butter
Fats have a rich satisfying feeling in the mouth.
Fats make baked goods tender and moist. E.g .chocolate cake
FOOD SOURCES
a. Visible Fats
Include lard, butter, margarine, shortenings, salad oils, visible fats of
meat.

b. Invisible Fats
Are those available in milk, cheese, eggs, nuts and meat.
Margarine and shortenings are made from relatively less expensive
vegetable oils such as cottonseed oil, soybean oil, corn oil and coconut
oils by the introduction of hydrogen into fat molecule under carefully
controlled conditions.

Margarine is then further processed by churning the cultural milk to


give the flavor of butter. It is usually fortified with vitamins A and D.

High in Saturated Fatty Acids


Whole milk, cream, ice cream, cheese made from whole milk, egg yolk
Medium fat or fatty meats; beef, lamb, pork, ham
Bacon, butter, coconut oil, lamb fat, lard, regular margarine, salt pork,
hydrogenated shortenings
Chocolate, chocolate candy, cakes, cookies, pies, rich pudding.

High in Polyunsaturated Fatty Acids


Vegetable oils, safflower, corn cotton seed, soybean, sesame,
sunflower
Salad dressings made from the above oils: mayonnaise, French
dressing and others
Special margarine: liquid oil listed first on label
Fatty fish: salmon, tuna, herring

The Essential Fatty Acids are not manufactured in the body and must be supplied in the
diet.

Linoleic Acid – primary member of the Omega 6 family. Found in


vegetable oils like corn, safflower, soybean, and cottonseed and poultry
fats. Can be made into arachidonic acid which is abundant in meats.

Linolenic Acid – primary member of the Omega 3 family.


Found in oils like flaxseed, canola, walnut, wheat germ and soy bean,
nuts and seed like butternuts, walnuts and soybean kernels and
vegetables like soybeans.

Linolenic acid can be made into Eicasopentaenoic Acid (EPA) and


Docosahexaenoic Acid (DHA) which are essential for growth and
development, prevention or treatment of heart disease, hypertension,
arthritis and cancer. It is also found in human milk, shellfish and fish.

HEALTH EFFECT OF LIPIDS

Heart Disease – elevated blood cholesterol is a major risk factor for


cardiovascular diseases.

Risks from saturated fats – lauric, myristic and palmitic acids raise
blood cholesterol levels. Stearic acid does not.

Benefits from monounsaturated fats – olive oil lowers risks of heart disease.

Benefits from Omega 3 polyunsaturated fats – lowers blood


cholesterol and prevents heart disease. EPA sources like fish, eaten
once a week, can lower blood cholesterol and risk of heart attack and
stroke.

Cancer – fat does not instigate cancer development but can promote it
once it has arisen.

Obesity – high fat diets tend to store body fat ably.

TRANS FAT
“Are artificial fats”
Made by a chemical process called partial hydrogenation
E.g. liquid vegetables oils ( Minola) converted into solid fat
Perfect fat for the food industry--- invented to withstand food production
Commercially packaged foods---french fries

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