SAFETY DATA SHEET

Styrene
Version 1.8 Revision Date 2019-11-20

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product information
Product Name : Styrene
Material : 1037612, 1037607, 1037608, 1037609

Company : Chevron Phillips Chemical Company LP

10001 Six Pines Drive
The Woodlands, TX 77380

Emergency telephone:

Health:
866.442.9628 (North America)
1.832.813.4984 (International)
Transport:
CHEMTREC 800.424.9300 or 703.527.3887(int'l)
Asia: CHEMWATCH (+612 9186 1132) China: 0532 8388 9090
EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax)
Mexico CHEMTREC 01-800-681-9531 (24 hours)
South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Argentina: +(54)-1159839431

Responsible Department : Product Safety and Toxicology Group

E-mail address : [email protected]
Website : www.CPChem.com

SECTION 2: Hazards identification

Classification of the substance or mixture

This product has been classified in accordance with the hazard communication standard 29 CFR
1910.1200; the SDS and labels contain all the information as required by the standard.

Classification
: Flammable liquids, Category 3
Skin irritation, Category 2
Eye irritation, Category 2A
Specific target organ toxicity - repeated exposure, Category 1,
Inhalation, Auditory organs
Aspiration hazard, Category 1

SDS Number:100000068536 1/15

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Version 1.8 Revision Date 2019-11-20
Labeling

Symbol(s) :

Signal Word : Danger

Hazard Statements : H226: Flammable liquid and vapor.

H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H372: Causes damage to organs (Auditory organs) through
prolonged or repeated exposure if inhaled.

Precautionary Statements : Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe dust/fume/gas/mist/vapor/spray.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER/doctor.
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with
water/shower.
P304 + P340 + P312 IF INHALED: Remove person to fresh
air and keep comfortable for breathing. Call a POISON
CENTER/doctor if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P314 Get medical advice/ attention if you feel unwell.
P331 Do NOT induce vomiting.
P332 + P313 If skin irritation occurs: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
P362 Take off contaminated clothing and wash before reuse.
P370 + P378 In case of fire: Use dry sand, dry chemical or
alcohol-resistant foam to extinguish.
Storage:
P403 + P233 Store in a well-ventilated place. Keep container
tightly closed.
P403 + P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

SDS Number:100000068536 2/15

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Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
Styrene 100-42-5
NTP Reasonably anticipated to be a human carcinogen
Styrene 100-42-5

SECTION 3: Composition/information on ingredients

Synonyms : Inhibited Styrene

Phenylethylene
Benzene, Ethenyl
Styrol
Cinnamene
Vinylbenzene
Styrolene
Styrene Monomer

Molecular formula : C8H8

Component CAS-No. Weight %

Styrene 100-42-5 99.9 - 100

SECTION 4: First aid measures

General advice : Move out of dangerous area. Show this material safety data
sheet to the doctor in attendance. Material may produce a
serious, potentially fatal pneumonia if swallowed or vomited.

If inhaled : If unconscious, place in recovery position and seek medical

advice. If symptoms persist, call a physician.

In case of skin contact : If skin irritation persists, call a physician. If on skin, rinse well
with water. If on clothes, remove clothes.

In case of eye contact : Immediately flush eye(s) with plenty of water. Remove contact
lenses. Protect unharmed eye. Keep eye wide open while
rinsing. If eye irritation persists, consult a specialist.

If swallowed : Keep respiratory tract clear. Never give anything by mouth to

an unconscious person. If symptoms persist, call a physician.
Take victim immediately to hospital.

SECTION 5: Firefighting measures

Flash point : 31°C (88°F)

Method: closed cup

Autoignition temperature : 490°C (914°F)

SDS Number:100000068536 3/15

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Suitable extinguishing : Alcohol-resistant foam. Carbon dioxide (CO2). Dry chemical.
media

Unsuitable extinguishing : High volume water jet.

media

Specific hazards during fire : Do not allow run-off from fire fighting to enter drains or water
fighting courses.

Special protective : Wear self-contained breathing apparatus for firefighting if

equipment for fire-fighters necessary.

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains. Fire residues and
contaminated fire extinguishing water must be disposed of in
accordance with local regulations. For safety reasons in case
of fire, cans should be stored separately in closed
containments. Use a water spray to cool fully closed
containers.

Fire and explosion : Do not spray on an open flame or any other incandescent
protection material. Take necessary action to avoid static electricity
discharge (which might cause ignition of organic vapors).
Keep away from open flames, hot surfaces and sources of
ignition.

SECTION 6: Accidental release measures

Personal precautions : Use personal protective equipment. Ensure adequate

ventilation. Remove all sources of ignition. Evacuate
personnel to safe areas. Beware of vapors accumulating to
form explosive concentrations. Vapors can accumulate in low
areas.

Environmental precautions : Prevent product from entering drains. Prevent further leakage
or spillage if safe to do so. If the product contaminates rivers
and lakes or drains inform respective authorities.

Methods for cleaning up : Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to
local / national regulations (see section 13).

SECTION 7: Handling and storage

Handling

Advice on safe handling : Avoid formation of aerosol. Do not breathe vapors/dust. Avoid
contact with skin and eyes. For personal protection see
section 8. Smoking, eating and drinking should be prohibited
in the application area. Take precautionary measures against
static discharges. Provide sufficient air exchange and/or
exhaust in work rooms. Open drum carefully as content may
be under pressure. Dispose of rinse water in accordance with
local and national regulations.

Advice on protection : Do not spray on an open flame or any other incandescent

against fire and explosion material. Take necessary action to avoid static electricity
SDS Number:100000068536 4/15
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Version 1.8 Revision Date 2019-11-20
discharge (which might cause ignition of organic vapors).
Keep away from open flames, hot surfaces and sources of
ignition.

Storage

Requirements for storage : No smoking. Keep container tightly closed in a dry and well-
areas and containers ventilated place. Containers which are opened must be
carefully resealed and kept upright to prevent leakage.
Observe label precautions. Electrical installations / working
materials must comply with the technological safety standards.

SECTION 8: Exposure controls/personal protection

Ingredients with workplace control parameters

US
Components Basis Value Control parameters Note
Styrene OSHA Z-2 TWA 100 ppm,
OSHA Z-2 CEIL 200 ppm,
OSHA Z-2 Peak 600 ppm,
OSHA Z-1-A TWA 50 ppm, 215 mg/m3
OSHA Z-1-A STEL 100 ppm, 425 mg/m3
CNS impair, URT irr,
ACGIH TWA 20 ppm, peripheral neuropathy,
BEI, A4,
CNS impair, URT irr,
ACGIH STEL 40 ppm, peripheral neuropathy,
BEI, A4,
A4 Not classifiable as a human carcinogen
BEI Substances for which there is a Biological Exposure Index or Indices (see BEI® section)
CNS impair Central Nervous System impairment
peripheral Peripheral neuropathy
neuropathy
URT irr Upper Respiratory Tract irritation

Immediately Dangerous to Life or Health Concentrations (IDLH)

Substance name CAS-No. Control parameters Update

Styrene 100-42-5 Immediately Dangerous to Life or Health 1995-03-01
Concentration Value
700 parts per million

Biological exposure indices

US

Substance name CAS-No. Control parameters Sampling time Update

Styrene 100-42-5 Mandelic acid plus phenylglyoxylic End of shift (As 2016-03-01
acid: 400 mg/g Creatinine soon as possible
(Urine) after exposure
ceases)
Styrene: 40 µg/l (Urine) End of shift (As 2016-03-01
soon as possible
after exposure
ceases)
Engineering measures
Adequate ventilation to control airborned concentrations below the exposure guidelines/limits.

SDS Number:100000068536 5/15

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Consider the potential hazards of this material (see Section 2), applicable exposure limits, job
activities, and other substances in the work place when designing engineering controls and selecting
personal protective equipment. If engineering controls or work practices are not adequate to prevent
exposure to harmful levels of this material, the personal protective equipment listed below is
recommended. The user should read and understand all instructions and limitations supplied with
the equipment since protection is usually provided for a limited time or under certain circumstances.

Personal protective equipment

Respiratory protection : Wear a supplied-air NIOSH approved respirator unless

ventilation or other engineering controls are adequate to
maintain minimal oxygen content of 19.5% by volume under
normal atmospheric pressure. Wear a NIOSH approved
respirator that provides protection when working with this
material if exposure to harmful levels of airborne material may
occur, such as:. Air-Purifying Respirator for Organic Vapors.
Use a positive pressure, air-supplying respirator if there is
potential for uncontrolled release, exposure levels are not
known, or other circumstances where air-purifying respirators
may not provide adequate protection.

Hand protection : The suitability for a specific workplace should be discussed

with the producers of the protective gloves. Please observe
the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into
consideration the specific local conditions under which the
product is used, such as the danger of cuts, abrasion, and the
contact time. Gloves should be discarded and replaced if there
is any indication of degradation or chemical breakthrough.

Eye protection : Eye wash bottle with pure water. Tightly fitting safety goggles.

Skin and body protection : Choose body protection in relation to its type, to the
concentration and amount of dangerous substances, and to the
specific work-place. Wear as appropriate:. Flame retardant
antistatic protective clothing. Workers should wear antistatic
footwear.

Hygiene measures : When using do not eat or drink. When using do not smoke.
Wash hands before breaks and at the end of workday.

SECTION 9: Physical and chemical properties

Information on basic physical and chemical properties

Appearance
Physical state : Liquid
Color : Colorless
Odor : Sweet

Safety data
Flash point : 31°C (88°F)
Method: closed cup

Lower explosion limit : 0.9 %(V)

Upper explosion limit : 6.8 %(V)

SDS Number:100000068536 6/15

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Oxidizing properties : no

Autoignition temperature : 490°C (914°F)

Molecular formula : C8H8

Molecular weight : 104.16 g/mol

pH : Not applicable

Freezing point : -30.63°C (-23.13°F)

Pour point No data available

Boiling point/boiling range : 145.15°C (293.27°F)

Vapor pressure : 4.50 MMHG

at 20°C (68°F)

Relative density : 0.91

at 20 °C (68 °F)

Water solubility : 0.029 wt.% styrene in water @ 20 ºC (68ºF)

Partition coefficient: n- : log Pow: 2.96

octanol/water at 25°C (77°F)

Viscosity, dynamic : 0.763 cP

Relative vapor density : 3.6

(Air = 1.0)

Evaporation rate : No data available

Conductivity : < 50 pSm

SECTION 10: Stability and reactivity

Reactivity : Stable at normal ambient temperature and pressure.

Chemical stability : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature
and pressure.

Possibility of hazardous reactions

Hazardous reactions : Further information: No decomposition if stored and applied as

directed.

Hazardous reactions: Vapors may form explosive mixture with

SDS Number:100000068536 7/15
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Version 1.8 Revision Date 2019-11-20
air.

Conditions to avoid : Heat, flames and sparks.

Materials to avoid : No data available.

Other data : No decomposition if stored and applied as directed.

SECTION 11: Toxicological information

Acute oral toxicity

Styrene : LD50: > 5,000 mg/kg
Species: Rat
Sex: male and female

Styrene
Acute inhalation toxicity : Acute toxicity estimate: 11 mg/l
Exposure time: 4 h
Test atmosphere: vapor
Method: Calculation method

Styrene
Acute dermal toxicity : Acute toxicity estimate: 2,500 mg/kg
Method: Calculation method

Styrene
Skin irritation : May cause skin irritation in susceptible persons.

Styrene
Eye irritation : May cause irreversible eye damage.

Sensitization
Styrene : Classification: Does not cause skin sensitization.
largely based on human evidence.

Repeated dose toxicity

Styrene : Species: Mouse, Male and female
Sex: Male and female
Application Route: Oral
Dose: 0. 150, 300 mg/kg
Exposure time: 78 wk
Number of exposures: 5 d/wk
NOEL: 150 mg/kg
Lowest observable effect level: 300 mg/kg

SDS Number:100000068536 8/15

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Species: Rat, male
Sex: male
Application Route: Inhalation
Dose: 0. 500, 650, 850, 1000 ppm
Exposure time: 4 wk
Number of exposures: 6 h/d, 5 d/wk
NOEL: 500 ppm
Target Organs: Ototoxicity

Genotoxicity in vitro
Styrene : Test Type: Ames test
Result: negative

Test Type: Cytogenetic assay

Result: positive

Test Type: Reverse mutation assay

Result: negative

Test Type: Mouse lymphoma assay

Result: negative

Test Type: Sister Chromatid Exchange Assay

Result: positive

Test Type: Mammalian cell gene mutation assay

Result: negative

Genotoxicity in vivo
Styrene : Remarks: No significant adverse effects were reported

Aspiration toxicity
Styrene : May be fatal if swallowed and enters airways.

CMR effects
Styrene : Carcinogenicity: This substance has been reported to cause
tumors in certain animal species.
Mutagenicity: In vitro tests showed mutagenic effects which
were not observed with in vivo test.
Teratogenicity: Did not show teratogenic effects in animal
experiments.
Reproductive toxicity: No toxicity to reproduction

Styrene
Further information : Solvents may degrease the skin.

SECTION 12: Ecological information

Toxicity to fish

Styrene : LC50: 4.02 mg/l

SDS Number:100000068536 9/15

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Exposure time: 96 h
Species: Pimephales promelas (fathead minnow)
flow-through test Test substance: yes
Toxic to fish.

Toxicity to daphnia and other aquatic invertebrates

Styrene : EC50: 4.7 mg/l

Exposure time: 48 h
Species: Daphnia magna (Water flea)
flow-through test

Toxicity to algae

Styrene : EC50: 4.9 mg/l

Exposure time: 72 h
Species: Selenastrum capricornutum (algae)

Toxicity to bacteria

Styrene : EC10: 0.28 mg/l

Exposure time: 96 h
Growth rate
Species: Skeletonema costatum (Marine Algae)
Test substance: yes

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

Styrene : NOEC: 1.01 mg/l

Exposure time: 21 d
Species: Daphnia magna (Water flea)
semi-static test
Test substance: yes
Method: OECD Test Guideline 211

Biodegradability

Styrene : According to the results of tests of biodegradability this

product is considered as being readily biodegradable.

Bioaccumulation

Styrene : Does not significantly accumulate in organisms.

Results of PBT assessment

Styrene : This substance is not considered to be very persistent and
very bioaccumulating (vPvB)., This substance is not
considered to be persistent, bioaccumulating and toxic (PBT).

Additional ecological : An environmental hazard cannot be excluded in the event of

information unprofessional handling or disposal., Toxic to aquatic life.,
Harmful to aquatic life with long lasting effects.

SDS Number:100000068536 10/15

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Ecotoxicology Assessment
Short-term (acute) aquatic : Toxic to aquatic life.
hazard
Long-term (chronic) aquatic : Harmful to aquatic life with long lasting effects.
hazard

SECTION 13: Disposal considerations

The information in this SDS pertains only to the product as shipped.

Use material for its intended purpose or recycle if possible. This material, if it must be discarded,
may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or
other State and local regulations. Measurement of certain physical properties and analysis for
regulated components may be necessary to make a correct determination. If this material is
classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste
disposal facility.

Product : The product should not be allowed to enter drains, water

courses or the soil. Do not contaminate ponds, waterways or
ditches with chemical or used container. Send to a licensed
waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product.

Do not re-use empty containers. Do not burn, or use a cutting
torch on, the empty drum.

SECTION 14: Transport information

The shipping descriptions shown here are for bulk shipments only, and may not apply to
shipments in non-bulk packages (see regulatory definition).

Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous

Goods Regulations for additional shipping description requirements (e.g., technical name or names,
etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping
description for the material. Flashpoints for the material may vary slightly between the SDS and the
bill of lading.

US DOT (UNITED STATES DEPARTMENT OF TRANSPORTATION)

UN2055, STYRENE MONOMER, STABILIZED, 3, III, RQ (STYRENE)

IMO / IMDG (INTERNATIONAL MARITIME DANGEROUS GOODS)

UN2055, STYRENE MONOMER, STABILIZED, 3, III, (31°C)

IATA (INTERNATIONAL AIR TRANSPORT ASSOCIATION)

UN2055, STYRENE MONOMER, STABILIZED, 3, III

ADR (AGREEMENT ON DANGEROUS GOODS BY ROAD (EUROPE))

UN2055, STYRENE MONOMER, STABILIZED, 3, III, (D/E)

RID (REGULATIONS CONCERNING THE INTERNATIONAL TRANSPORT OF

DANGEROUS GOODS (EUROPE))
UN2055, STYRENE MONOMER, STABILIZED, 3, III

SDS Number:100000068536 11/15

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ADN (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE

OF DANGEROUS GOODS BY INLAND WATERWAYS)
UN2055, STYRENE MONOMER, STABILIZED, 3, III

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Other information : Styrene Monomer, S.T.3, Cat. Y

SECTION 15: Regulatory information

National legislation

SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids)

Skin corrosion or irritation
Serious eye damage or eye irritation
Specific target organ toxicity (single or repeated exposure)
Aspiration hazard

CERCLA Reportable : 1000 lbs

Quantity
Styrene

SARA 302 Reportable : This material does not contain any components with a SARA
Quantity 302 RQ.

SARA 302 Threshold : This material does not contain any components with a section
Planning Quantity 302 EHS TPQ.

SARA 304 Reportable : This material does not contain any components with a section
Quantity 304 EHS RQ.

SARA 313 Components : The following components are subject to reporting levels
established by SARA Title III, Section 313:

: Styrene - 100-42-5

Clean Air Act

Ozone-Depletion : This product neither contains, nor was manufactured with a Class I or
Potential Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR
82, Subpt. A, App.A + B).
SDS Number:100000068536 12/15
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The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61):
: Styrene - 100-42-5

This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for
Accidental Release Prevention (40 CFR 68.130, Subpart F).

The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or
Final VOC's (40 CFR 60.489):
: Styrene - 100-42-5

US State Regulations

Pennsylvania Right To Know

: Styrene - 100-42-5

California Prop. 65 : WARNING: This product can expose you to chemicals including
Components [listed below], which is [are] known to the State of California to
cause cancer. For more information go to
www.P65Warnings.ca.gov/food.

Styrene 100-42-5

Notification status
Europe REACH : On the inventory, or in compliance with the inventory
United States of America (USA) : On or in compliance with the active portion of the
TSCA TSCA inventory
Canada DSL : All components of this product are on the Canadian
DSL
Australia AICS : On the inventory, or in compliance with the inventory
New Zealand NZIoC : On the inventory, or in compliance with the inventory
Japan ENCS : On the inventory, or in compliance with the inventory
Korea KECI : A substance(s) in this product was not registered,
notified to be registered, or exempted from registration
by CPChem according to K-REACH regulations.
Importation or manufacture of this product is still
permitted provided the Korean Importer of Record has
themselves notified the substance.

Philippines PICCS : On the inventory, or in compliance with the inventory

China IECSC : On the inventory, or in compliance with the inventory
Taiwan TCSI : On the inventory, or in compliance with the inventory

SDS Number:100000068536 13/15

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SECTION 16: Other information

NFPA Classification : Health Hazard: 2

Fire Hazard: 3
Reactivity Hazard: 2
3
2 2

Further information
Legacy SDS Number : CPC00089

Significant changes since the last version are highlighted in the margin. This version replaces all
previous versions.

The information in this SDS pertains only to the product as shipped.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of LD50 Lethal Dose 50%
Government Industrial Hygienists
AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect
Substances Level
DSL Canada, Domestic Substances NFPA National Fire Protection Agency
List
NDSL Canada, Non-Domestic NIOSH National Institute for Occupational
Substances List Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of
Chemicals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration
EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health
Scenario Tool Administration
EOSCA European Oilfield Specialty PEL Permissible Exposure Limit
Chemicals Association
EINECS European Inventory of Existing PICCS Philippines Inventory of
Chemical Substances Commercial Chemical Substances
MAK Germany Maximum Concentration PRNT Presumed Not Toxic
Values
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research TLV Threshold Limit Value
on Cancer
IECSC Inventory of Existing Chemical TWA Time Weighted Average
Substances in China
ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act
SDS Number:100000068536 14/15
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New Chemical Substances
KECI Korea, Existing Chemical UVCB Unknown or Variable Composition,
Inventory Complex Reaction Products, and
Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials
Information System
LC50 Lethal Concentration 50%

SDS Number:100000068536 15/15