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acc. to 1907/2006/EC, Article 31 (REACH), 1272/2008/EC (CLP) and 453/2010/EC

Printing date 11.04.2016 Version number 2 Revision: 06.04.2016

* SECTION 1: Identification of the substance/mixture and of the company/undertaking

. 1.1 Product identifier
. Trade name Cetamine G840
Article number: 47250
. Article number: 47250
. 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
. Application of the substance / the mixture
Water treatment
Water conditioner
. 1.3 Details of the supplier of the safety data sheet
. Manufacturer/Supplier:
Kurita Europe GmbH www.kurita.eu
Giulinistraße 2 Tel: +49 621 5709-3000
D-67065 Ludwigshafen Fax: +49 621 5709-6452
. Information: [email protected]
. 1.4 Emergency telephone number: Tel.: +49 621 / 5709-112

SECTION 2: Hazards identification

. 2.1 Classification of the substance or mixture
. Classification according to Regulation (EC) No 1272/2008
Skin Corr. 1A H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
STOT SE 3 H335 May cause respiratory irritation.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
. 2.2 Label elements
. Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
. Hazard pictograms

GHS05 GHS07 GHS08

. Signal word Danger

. Hazard-determining components of labelling:
2-diethylaminoethanol
(Z)-N-9-octadecenylpropane-1,3-diamine
2-aminoethanol
. Hazard statements
H314 Causes severe skin burns and eye damage.
H335 May cause respiratory irritation.
H373 May cause damage to organs through prolonged or repeated exposure.
H412 Harmful to aquatic life with long lasting effects.
. Precautionary statements
P260 Do not breathe mist/vapours/spray.
P273 Avoid release to the environment.
(Contd. on page 2)
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Trade name Cetamine G840

Article number: 47250

(Contd. of page 1)
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

SECTION 3: Composition/information on ingredients

. 3.2 Chemical characterisation: Mixtures
. Description: Alkanolamines in water.
. Dangerous components:
CAS: 100-37-8 2-diethylaminoethanol 10 - <25%
EINECS: 202-845-2 Flam. Liq. 3, H226; Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Corr. 1B,
Index number: 603-048-00-6 H314; Eye Dam. 1, H318; Acute Tox. 4, H302
Reg.nr.: 01-2119488937-14-xxxx
CAS: 141-43-5 2-aminoethanol 2.5-<5%
EINECS: 205-483-3 Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Acute Tox. 4,
Index number: 603-030-00-8 H332; STOT SE 3, H335; Aquatic Chronic 3, H412
Reg.nr.: 01-2119486455-28-xxxx
CAS: 7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine 1-<2.5%
EINECS: 230-528-9 STOT RE 1, H372; Skin Corr. 1B, H314; Aquatic Acute 1, H400 (M=10);
Reg.nr.: 01-2119487002-46-xxxx Aquatic Chronic 1, H410 (M=1); Acute Tox. 4, H302
CAS: 1310-73-2 sodium hydroxide 0.5-<1%
EINECS: 215-185-5 Skin Corr. 1A, H314
Index number: 011-002-00-6
Reg.nr.: 01-2119457892-27-xxxx
CAS: 61791-26-2 fatty alkylamine, ethoxylated 0.1-<1%
Acute Tox. 2, H330; Eye Dam. 1, H318; Aquatic Chronic 2, H411; Acute
Tox. 4, H302
. SVHC No
. Additional information For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

. 4.1 Description of first aid measures
. General information Instantly remove any clothing soiled by the product.
. After inhalation :
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness bring patient into stable side position for transport.
. After skin contact :
Immediately wash with soap and water and rinse thoroughly.
Call a doctor immediately.
. After eye contact :
Rinse opened eye for 15 minutes under running water.
Call a doctor immediately.
. After swallowing :
Rinse out mouth and then drink plenty of water (approx. 500 ml).
Do not induce vomiting; instantly call for medical help.
(Contd. on page 3)
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Trade name Cetamine G840

Article number: 47250

(Contd. of page 2)
. 4.2 Most important symptoms and effects, both acute and delayed
Emits highly irritating vapor. Inhalation of high concentrations may cause irritation of the nose and throat, difficulty
breathing, nausea and headaches. Risk of pulmonary edema, chemical burns of the respiratory tract. Some habituation
to the smell may occur.
Ingestion causes pain, burns, abdominal pain, possible general impact (shock).
Splashes cause strong tearing, pain, may cause permanent visual impairment.
Prolonged contact may cause dryness, redness, burns, blistering and ulceration. Can be partially absorbed by the skin.
. Danger Danger of gastric perforation.
. 4.3 Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation with added, activated carbon.
No specific antidot is known. Treatment of the symptoms.

SECTION 5: Firefighting measures

. 5.1 Extinguishing media
. Suitable extinguishing agents
Use fire fighting measures that suit the environment.
CO2, extinguishing powder or water jet. Fight larger fires with foam.
. For safety reasons unsuitable extinguishing agents Water with a full water jet.
. 5.2 Special hazards arising from the substance or mixture
Fire can cause release of :
Carbon monoxide (CO)
Nitrogen oxides (NOx)
Ammonia (NH3)
. 5.3 Advice for firefighters
. Protective equipment:
Wear full protective suit.
Wear self-contained breathing apparatus.
. Additional information
Cool endangered containers with water spray jet.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

SECTION 6: Accidental release measures

. 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Use breathing protection against the effects of fumes/dust/aerosol.
. 6.2 Environmental precautions:
Do not allow concentrated solutions to enter drainage system, surface or ground water.
. 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders).
Use neutralising agent.
Dispose of contaminated material as waste according to section 13.
. 6.4 Reference to other sections
See section 7 for information on safe handling
See section 8 for information on personal protection equipment.

SECTION 7: Handling and storage

. 7.1 Precautions for safe handling
Keep containers tightly sealed.
(Contd. on page 4)
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Trade name Cetamine G840

Article number: 47250

(Contd. of page 3)
Ensure good ventilation/exhaustion at the workplace.
Do not spray / Prevent formation of aerosols.
Wear breathing protection when decanting larger quantities without extractor facilities.
. Information about protection against explosions and fires: No special measures required.
. 7.2 Conditions for safe storage, including any incompatibilities
. Storage
. Requirements to be met by storerooms and containers:
Store only in the original container.
Use polyolefine containers.
Do not use light alloy containers.
Provide floor trough without outlet.
. Information about storage in one common storage facility: Do not store together with acids.
. Further information about storage conditions:
Keep container tightly sealed.
Store container in a well ventilated position.
Product quality requires storage between 5 °C and 40 °C.
Protect from frost.
. 7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

. Additional information about design of technical systems: No further data; see section 7.
. 8.1 Control parameters
. Components with critical values that require monitoring at the workplace:
141-43-5 2-aminoethanol
WEL (Great Britain) Short-term value: 7.6 mg/m³, 3 ppm
Long-term value: 2.5 mg/m³, 1 ppm
Sk
IOELV (European Union) Short-term value: 7.6 mg/m³, 3 ppm
Long-term value: 2.5 mg/m³, 1 ppm
Skin
1310-73-2 sodium hydroxide
WEL (Great Britain) Short-term value: 2 mg/m³
. DNELs
100-37-8 2-diethylaminoethanol
Dermal Worker 1 mg/kg bw/day (long-term exposure, systemic effects) (source: ECHA)
Inhalative Worker 1.07 mg/m3 (long-term exposure, local effect) (source: ECHA)
7.34 mg/m3 (long-term exposure, systemic effects) (source: ECHA)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Dermal Worker 0.01 mg/kg bw/day (long-term exposure, systemic effects)
Inhalative Worker 0.035 mg/m3 (long-term exposure, systemic effects)
1310-73-2 sodium hydroxide
Inhalative Worker 1 mg/m3 (long-term exposure, local effect) (anhydrous (source: ECHA))
General population 1 mg/m3 (long-term exposure, local effect) (anhydrous (source: ECHA))
. PNECs
100-37-8 2-diethylaminoethanol
Water 0.044 mg/L (fresh water) (source: ECHA)
(Contd. on page 5)
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Trade name Cetamine G840

Article number: 47250

(Contd. of page 4)
0.0044 mg/L (sea water) (source: ECHA)
4.4 mg/L (intermittent release) (source: ECHA)
Sediment 0.475 mg/kg (fresh water) (source: ECHA)
0.0475 mg/kg (sea water) (source: ECHA)
Soil 0.069 mg/kg (soil) (source: ECHA)
Sewage treatment 10 mg/L (sewage-treatment plant) (source: ECHA)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Water 0.01 mg/L (fresh water)
0.001 mg/L (sea water)
0.0029 mg/L (intermittent release)
Sediment 0.22 mg/kg (fresh water)
0.022 mg/kg (sea water)
Soil 10 mg/kg (soil)
Sewage treatment 0.251 mg/L (sewage-treatment plant)
. Additional information: The lists that were valid during compilation were used as a basis.
. 8.2 Exposure controls
. Personal protective equipment
. General protective and hygienic measures
The usual precautionary measures should be adhered to in handling the chemicals.
Do not eat, drink or smoke while working.
Instantly remove any soiled and impregnated garments.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
. Breathing equipment:
Use breathing protection in case of insufficient ventilation.
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use
breathing apparatus that is independent of circulating air.
Short term filter device: ABEK-filter
Filter type K, green, for organic, basic amines.
. Protection of hands:
Protective gloves:
In case of spray contact at least protection index 2 recommended, according to more than 30 min. penetration time (EN
374).
Layer thickness of gloves at least: 0.4 mm
In case of prolonged and intensive contact protection index 6 recommended, according to more than 480 min.
penetration time (EN 374).
Layer thickness of gloves at least: 0.7 mm
. Material of gloves
Butyl rubber, BR
Nitrile rubber, NBR
Natural rubber, NR
Chloroprene rubber, CR
Neoprene gloves
. Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
. Not suitable are gloves made of the following materials: Leather gloves
. Eye protection: Tightly sealed safety glasses (DIN 58211, EN 166)
(Contd. on page 6)
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Trade name Cetamine G840

Article number: 47250

(Contd. of page 5)
. Body protection: Protective work clothing (EN 465)

SECTION 9: Physical and chemical properties

. 9.1 Information on basic physical and chemical properties
. General Information
. Appearance:
Form: Fluid
Colour: colourless - yellowish
. Smell: Characteristic
. Odour threshold: Not determined.
. pH-value at 20 °C: ca. 12.7 (100 %)
. Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: Not determined
. Flash point: > 60 °C
. Inflammability (solid, gaseous) not determined
. Ignition temperature: not determined
. Decomposition temperature: not determined
. Self-inflammability: Product is not selfigniting.
. Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is
possible.
. Critical values for explosion:
Lower: not determined
Upper: not determined
. Oxidising properties none
. Steam pressure: not determined
. Density at 20 °C ca. 1.01 g/cm3
. Evaporation rate not determined
. Solubility in / Miscibility with
Water: Fully miscible
. Partition coefficient (n-octanol/water): Not determined.
. Viscosity:
dynamic at 20 °C: < 30 mPas
. 9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

. 10.1 Reactivity No hazardous reactions when stored and handled according to instructions.
. 10.2 Chemical stability
. Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
. 10.3 Possibility of hazardous reactions
Reacts with strong acids
(Contd. on page 7)
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Trade name Cetamine G840

Article number: 47250

(Contd. of page 6)
Reacts with strong oxidizing agents
. 10.4 Conditions to avoid No further relevant information available.
. 10.5 Incompatible materials:
Oxidizers
Acids
. 10.6 Hazardous decomposition products:
Danger of toxic pyrolysis products
Nitrogen oxides (NOx)
Ammonia (NH3)

SECTION 11: Toxicological information

. 11.1 Information on toxicological effects
. Acute toxicity Based on available data, the classification criteria are not met.
. LD/LC50 values that are relevant for classification:
100-37-8 2-diethylaminoethanol
Oral LD50 1320 mg/kg (rat)
Dermal LD50 885 mg/kg (guinea pig)
1100 mg/kg (rabbit)
Inhalative LC50 (4 h) 4.6 mg/L (rat)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Oral LD50 500 mg/kg (rat)
. Components Type Value Species
Product ATEmix oral > 5000 mg/kg
Product ATEmix dermal > 5000 mg/kg
Product ATEmix inhaled > 20 mg/L, 4h
. Primary irritant effect:
. Skin corrosion/irritation
Causes severe skin burns and eye damage.
. Serious eye damage/irritation
Causes serious eye damage.
. Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
. Additional toxicological information: May cause respiratory irritation.
. Repeated dose toxicity
100-37-8 2-diethylaminoethanol
Oral NOAEL 50 - 400 mg/kg bw/day (rat) (2 years, source: ECHA)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
Oral NOAEL, systemic toxicity 0.4 mg/kg bw/day (rat) (per day, subchronic)
. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
. Germ cell mutagenicity Based on available data, the classification criteria are not met.
. Carcinogenicity Based on available data, the classification criteria are not met.
. Reproductive toxicity Based on available data, the classification criteria are not met.
. STOT-single exposure
May cause respiratory irritation.
. STOT-repeated exposure
May cause damage to organs through prolonged or repeated exposure.
. Aspiration hazard Based on available data, the classification criteria are not met.
(Contd. on page 8)
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Article number: 47250

(Contd. of page 7)

SECTION 12: Ecological information

. 12.1 Toxicity
. Aquatic toxicity:
100-37-8 2-diethylaminoethanol
LC50 (96 h) (static) 147 mg/L (golden orfey) (DIN 38412)
LC50 (48 h) 83.6 mg/L (daphnia magna) (67/548/EEC, annex V, C.2)
EC50 (72 h) 44 mg/L (desmodesmus subspicatus) (DIN 38412)
NOEC 5 mg/L (Scenedesmus subspicatus) (DIN 38412 part 9, source: ECHA)
7173-62-8 (Z)-N-9-octadecenylpropane-1,3-diamine
LC50 (96 h) 0.148 mg/L (Brachydanio rerio) (OECD 203)
EC50 25.1 mg/L (activated sludge)
EC50 (48 h) 0.013 - 0.025 mg/L (daphnia magna) (OECD 202)
EC50 (72 h) > 0.01 - 0.1 mg/L (desmodesmus subspicatus) (OECD 201)
M-factor 10 (acute)
1 (chronic)
NOEC > 0.001 - 0.01 mg/L (daphnia magna) (OECD 211, 21 d)
1310-73-2 sodium hydroxide
LC50 (48 h) 99 mg/L (Lepomis macrochirus) (source: ECHA)
EC50 (48 h) 40.4 mg/L (daphnia magna) (source: ECHA)
. 12.2 Persistence and degradability A part of the components is not easily biodegradable.
. Other information: Easy elimination possible by flocculation or adsorption by sludge.
. 12.3 Bioaccumulative potential Does not accumulate in organisms
. 12.4 Mobility in soil No further relevant information available.
. Ecotoxical effects:
. Other information: No AOX
. Additional ecological information:
. According to recipe contains the following heavy metals and compounds according to EC guideline NO. 76/464
EC:
None
. General notes:
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
. 12.5 Results of PBT and vPvB assessment
. PBT: Not applicable.
. vPvB: Not applicable.
. 12.6 Other adverse effects No further relevant information available.

* SECTION 13: Disposal considerations

. 13.1 Waste treatment methods
. Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Must be specially treated in adherence to official regulations.
. European waste catalogue
16 03 05* organic wastes containing hazardous substances
(Contd. on page 9)
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Article number: 47250

(Contd. of page 8)

. Uncleaned packaging:
. Recommendation:
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
Dispose of packaging according to regulations on the disposal of packagings.
. Recommended cleaning agent: Water, if necessary with cleaning agent.

SECTION 14: Transport information

. 14.1 UN-Number
. ADR, IMDG, IATA UN2735
. 14.2 UN proper shipping name
. ADR 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (2-
DIETHYLAMINOETHANOL, ETHANOLAMINE)
. IMDG AMINES, LIQUID, CORROSIVE, N.O.S. (2-
DIETHYLAMINOETHANOL, ETHANOLAMINE)
. IATA Amines, liquid, corrosive, n.o.s. (2-Diethylaminoethanol,
Ethanolamine)
. 14.3 Transport hazard class(es)
. ADR

. Class 8 (C7) Corrosive substances.

. Label 8
. IMDG, IATA

. Class 8 Corrosive substances.

. Label 8
. 14.4 Packing group
. ADR, IMDG, IATA II
. 14.5 Environmental hazards:
. Marine pollutant: No
. 14.6 Special precautions for user Warning: Corrosive substances.
. Kemler Number: 80
. EMS Number: F-A,S-B
. Segregation groups Alkalis
. Stowage Category A
. Segregation Code SG35 Stow "separated from" acids.
. 14.7 Transport in bulk according to Annex II of Marpol
and the IBC Code Not applicable.
. Transport/Additional information: Frost protected transport has to be guaranteed.
(Contd. on page 10)
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(Contd. of page 9)

. ADR
. Limited quantities (LQ) 1L
. Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
. Transport category 2
. Tunnel restriction code E
. IMDG
. Limited quantities (LQ) 1L
. Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
. UN "Model Regulation": UN 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (2-
DIETHYLAMINOETHANOL, ETHANOLAMINE), 8, II

SECTION 15: Regulatory information

. 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
. Directive 2012/18/EU
. Named dangerous substances - ANNEX I None of the ingredients is listed.
. National regulations
. Information about limitation of use:
Employment restrictions concerning young persons must be observed.
Employment restrictions concerning pregnant and lactating women must be observed.
. 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

SECTION 16: Other information

These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
. Relevant phrases
H226 Flammable liquid and vapour.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H330 Fatal if inhaled.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
. Department issuing data specification sheet: Product Safety and Regulatory Affairs
. Contact: [email protected]
(Contd. on page 11)
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(Contd. of page 10)

. Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International
Transport of Dangerous Goods by Rail)
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organisation
ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
SVHC: Substances of Very High Concern
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 3: Flammable liquids, Hazard Category 3
Acute Tox. 4: Acute toxicity, Hazard Category 4
Acute Tox. 3: Acute toxicity, Hazard Category 3
Acute Tox. 2: Acute toxicity, Hazard Category 2
Skin Corr. 1A: Skin corrosion/irritation, Hazard Category 1A
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3
STOT RE 1: Specific target organ toxicity - Repeated exposure, Hazard Category 1
STOT RE 2: Specific target organ toxicity - Repeated exposure, Hazard Category 2
Aquatic Acute 1: Hazardous to the aquatic environment - AcuteHazard, Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - Chronic Hazard, Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
Aquatic Chronic 3: Hazardous to the aquatic environment - Chronic Hazard, Category 3
. Sources: source ECHA: European Chemicals Agency, http://echa.europa.eu/
. * Data compared to the previous version altered.
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