CHEMISTRY NMDCAT GOLDEN SERIES 2022

UHS TOPIC WISE TEST

TOPIC:
 Atomic Structure
Q. 1 All of the following were theorized by Bohr in his description of the atom except
A) The angular momentum of electrons in multiples of h/2?
B) Electrons revolve in discrete circular orbits
C) The energy of each electron is directly proportional to n2
D) Electrons radiate energy continuously in a given orbit
Q. 2 The letters sp d and f are used to represent which quantum numbers
A) Principal B) Azimuthal
C) Magnetic D) Spin
Q. 3 The magnetic quantum number (QN) has its values determined directly by the value of
A) Principal (QN) B) Azimuthal (QN)
C) Spin (QN) D) Both a & b
Q. 4 The atomic number of an element having the maximum number of unpaired electrons in p-
subshell is
A) 7 B) 10
C) 12 D) 16
Q. 5 The maximum number of electron in a subshell with? = 3f
A) 6 B) 10
C) 14 D) 18
Q. 6 The radius of the third shell of H-atom is
A) 5.761 A0 B) 4.761 A0
C) 6.671 A0 D) 3.716 A0
Q. 7 When an atom absorbs energy the lines in the spectrum will appear which are
A) Brighter B) Darker
C) Colourless D) Hard to locate
Q. 8 Colour of fluorescence produced by cathode rays depends upon
A) Temperature B) Pressure
C) Volume D) Composition of glass
Q. 9 Which one is not true about cathode rays?
A) 9.11×10-31 Kg B) Cast shadow
C) Heat up the platinum foil D) Cannot ionize
Q. 10 Positive rays are produced
A) By burning of gas B) By the bombardment of cathode rays on gas molecules
C) By cooling of the gas D) From anode like cathode rays produced from a cathode
Q. 11 Which one is not true about cathode rays?
A) 9.11×10-31 Kg B) Cast shadow
C) Heat up the platinum foil D) Cannot ionize
Q. 12 Rutherford’s planet-like structure was defective and unsatisfactory because
A) Continuous spectrum B) The behaviour of electron remain unexplained
C) Moving e- accelerate towards the nucleus D) All Are Correct
Q. 13 The relationship between the energy of a photon of light and its frequency is given by
A) de-Broglie duel nature of matter B) Bohrs model
C) Plancks Quantum theory D) Rutherfords atomic model
Q. 14 Splitting of spectral lines when an atom is subjected to the magnetic field is called
A) Zeemans effect B) Starks effect
C) Photo electric effect D) Compton effect
Q. 15 The velocity of the photon
A) Is independent of wavelength B) Depends upon source
C) Depends upon its frequency D) Equals to the square of the amplitude
Q. 16 Which one of the following explain the shape of orbitals
A) Principal of quantum number B) Azimuthal quantum number
C) Magnetic quantum number D) Spin quantum number

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Q. 17 Atom cannot be divided into simple unitstheorized by
A) Rutherford B) Dalton
C) Bohr D) Schrodinger
Q. 18 Pressure in gas discharge tube was kept
A) 10 torr B) 1 torr
C) 0.1 torr D) 0.01 torr
Q. 19 The number of fundamental particles in an atom of the lightest isotope carbon are
A) 6 B) 12
C) 18 D) 20
Q. 20 Angle of deflection was studied by
A) Hitorff B) Stoney
C) William Crookes D) J.Perrin
Q. 21 Increase in atomic number is observed during
A) Alpha emission B) Beta emission
C) Both A & B D) Radioactivity
Q. 22 Positive rays give flash on
A) AgNO3 plate B) AgCl plate
C) ZnO D) ZnS
Q. 23 Free neutron changes into proton with the emission of
A) Neutrino B) Electron
C) Both A & B D) Meson
Q. 24 The value of e/m ratio of electron is
A) 6.02 x 1023 C/kg B) 1.7588 x 1020 C/kg
C) 9.1095 x 10-31 C/kg D) 1.7588 x 1011 C/kg
Q. 25 The charge of an electron was measured by
A) J.J Thomson B) Millikan
C) Rutherford D) Perrin
Q. 26 Rutherford bombarded ______________ particles in discovery of nucleus
A) Gamma-rays B) Alpha-rays
C) Beta-rays D) X-rays
Q. 27 Planks theory says energy is emitted
A) In a continuous manner B) Discontinuous manner
C) Simultaneously D) In the form of heat
Q. 28 Angular momentum of an electron
A) n2h/2? B) nk2/2?
C) nh/4? D) nh/2?
Q. 29 2nd orbit is _______ away from the nucleus of H-atom as compared to 1st orbit is
A) 2-times B) 3-times
C) 4-times D) 6 times
Q. 30 The maximum number of orbitals present in a subshell that is represented by Azimuthal
quantum number = 3 will be
A) 1 B) 3
C) 5 D) 7
Q. 31 The correct electronic configuration of Cu is
A) [Ar]4s1 B) [Ar]4s2
C) [Ar]3d104s1 D) [Ar]3d94s2
Q. 32 Pfund series are produced in the spectrum of the hydrogen atom
A) when electrons jump down to 2nd- orbit B) when electrons jump down to 3rd- orbit
C) when electrons jump down to 4th- orbit D) when electrons jump down to 5th- orbit
Q. 33 Atomic orbits having same energy are called
A) Degenerate orbitals B) Bonding molecular orbitals
C) Antibonding molecular orbitals D) Half filled orbitals
Q. 34 Sommerfeld’s modification in Bohr’s model is
A) Orbit is cylindrical B) Orbit is elliptical
C) Orbit is longitudinal D) Orbit is asymmetrical

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Q. 35 When electrons collide with heavy metals than ______ are produced.
A) Beta-rays B) Alpha-rays
C) X-rays D) Gamma-rays
Q. 36 Plancks equation is
A) E = mc2 B) mvr = nh/2
C) E = h D) = h/mv
Q. 37 An atom with higher atomic number produces X-rays of
A) Shorter wavelength B) Larger wavelength
C) X-ray not produced D) All are possible
Q. 38 The wavelength of an electron was verified by
A) Moseley B) Davisson and Germer
C) Einstein D) Roentgen
Q. 39 Space around the nucleus where finding probability of electrons is maximum is called
A) Orbital B) Orbit is elliptical
C) subshell D) Electron cloud
Q. 40 Quantum number which tells the energy of an electron is
A) n B) 1
C) m D) s
Q. 41 Electronic configuration of K is
A) [Ar]4s2 B) [Ar]4s1
1
C) [Kr]5s D) [He]2s1
Q. 42 ____________ can expel proteins from paraffins
A) Electron B) Positron
C) Neutron D) None of above has such capability
Q. 43 Millikan used __________ in his atomizer
A) Milk B) Honey
C) Oil D) Water
Q. 44 Centrifugal forces are balanced in the atom by
A) Attractive forces B) Repulsive force
C) Electrons D) Neutrons
Q. 45 Spectrum is produced due to
A) Different wavelength B) Different colours
C) Different intensities D) All have little contribution
Q. 46 When 6d orbital is complete the entering electron goes into
A) 7f B) 7s
C) 7p D) 7d
Q. 47 When electron jump into orbit 1 then series obtained is
A) Lyman B) Paschen
C) Pfund D) Brackett
Q. 48 Neutrons moving with an energy of 1.2 MeV are called
A) Fast Neutrons B) Slow Neutrons
C) Moderate neutrons D) All are possible
Q. 49 Splitting of spectral lines when atoms are subjected to strong electric filed is called
A) Zeeman effect B) Stark effect
C) Photoelectric effect D) Compton effect
Q. 50 Three quantum number has been derived from the equation of
A) De-Broglie B) Plancks
C) Schrodinger D) Heisenberg
Q. 51 The e/m values for the positive rays depends on _______enclosed in a discharge tube
A) nature of gas B) properties of gas
C) composition of gas D) all of these
Q. 52 How do the 'p' orbitals px, py, pz differ from each other
A) size B) shape
C) orientation D) capacity

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Q. 53 The wavelength of radiation that have been absorbed by an element appear as __ lines and
background is ____ in an atomic absorption spectrum
A) dark. Bright B) bright, dark
C) dark, light D) bright, light
Q. 54 sodium-11 has electronic configuration
A) [He]2s1 B) [Ne] 3s1
2
C) [Ne]3s D) [He]2s2
Q. 55 The formula for calculating electron in subshells or sub energy levels is
A) 2l+1 B) 2(l+1)
C) 2(2l+1) D) 2(2l-1)
Q. 56 If a hydrogen atom remains in its first excited level, how many times will its radius be greater
than Bohr's radius
A) twice B) four times
C) same, same D) eight times
Q. 57 When an electron jumps from n = 5 to n = 2 having wavenumber equal to 2.3 x 1 6 m-1. In which
spectral series will it fall?
A) Layman B) Balmer
C) visible D) infrared
Q. 58 an element or its compound is first _____ to get its _________ spectrum by spectrometer
A) freezed,continuous B) freezed,line
C) volatilized, line D) volatilized,continuous
Q. 59 Which character of p-orbital determines the geometry of molecules
A) planar B) axial
C) non directional D) directional
Q. 60 According to Bohr, the orbits in which electrons revolve around the nucleus are
A) oval B) elliptical
C) cylindrical D) circular
Q. 61 The maximum probability of finding an electron is at distance of
A) 0.53mm B) 0.53nm
C) 0.153nm D) 1.53mm
Q. 62 line spectrum of sodium contains ____ colored lines separated by a definite distance
A) one yellow B) two yellow
C) two brown D) two golden
Q. 63 The equation En=-2.17x1 -18 [1/n2] J gives the energy associated with electron in nth orbit of
hydrogen atom. Its negative sign shows that electron is
A) away from nucleus B) bound by nucleus
C) closer to nucleus D) all of these
Q. 64 All the three p-orbitals have same energy in the absence of magnetic field and are called
________orbital's
A) generated B) delocalized
C) degenerated D) localized
Q. 65 Spectrum is the visual display or ________of component of white light when it is passed through
prism
A) rarefaction B) radiation
C) collection D) dispersion
Q. 66 The energy of photons related to
A) frequency B) wave length
C) wave number D) all of these
Q. 67 An orbital can accommodate at the most _electrons
A) 2 B) 14
C) 1 D) 6
Q. 68 The shapes of subshells is _if value of azimuthal quantum number 'l' is 2
A) spherical B) dumbbell
C) complicated D) all of these
Q. 69 In which direction Cathode rays deflected in the presence of magnetic field?
A) Moves upward B) Moves downward
C) Move randomly D) Moves in straight line
Q. 70 If n = 4 then what can be value of 'magnetic quantum number
A) 4,3,2,1 B) 3,2,1
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 C) infinity D) none of these
Q. 71 The shapes of subshells is _if value of azimuthal quantum number 'l' is 2
A) spherical B) dumbbell
C) complicated D) all of these
Q. 72 In which direction Cathode rays deflected in the presence of magnetic field?
A) Moves upward B) Moves downward
C) Move randomly D) Moves in straight line
Q. 73 If n = 4 then what can be value of 'magnetic quantum number
A) 4,3,2,1 B) 3,2,1
C) infinity D) none of these
Q. 74 When an electron remains between orbit, its momentum is
A) dequantized B) quantized
C) emitted D) changes always
Q. 75 Which of the following shows Planck's quantum theory
A) E=hcv B) E=c/v
C) E = cv D) none of these
Q. 76 It is not possible for us to measure exact position and exact momentum of electron simultaneously
is the statement of
A) de-Broglie B) Mosley
C) Heisenberg D) Neil Bohr
Q. 77 The radius of Bohr's atom depends on the following
A) 1/n B) n2
C) 1/n2 D) N
Q. 78 Greater the value of principal quantum number n', the distance of electron from nucleus will
be____
A) lower B) greater
C) higher D) moderate
Q. 79 The arrangement of sub shells or orbitals is according to _rule
A) 2(l+1) B) l+1
C) n+l D) 2(n+l)
Q. 80 The lobes of d-orbitals lie between the axis
A) first two B) first three
C) in all axis D) none of these
Q. 81 The presence of several fine lines in line spectrum shows the presence of
A) shells B) energy levels
C) sub shells D) all of these
Q. 82 According to coulomb's law ,the electrostatic forces of attraction between electron and nucleus
are _____ to its square of radius
A) directly proportional B) inversely proportional
C) equal D) none of these
Q. 83 According to________ theory, atoms were the ultimate particles that cannot be divided further.
A) Bohr's B) Rutherford's
C) Dalton's D) cannizzaro's
Q. 84 Positive rays are produced when ________strike the molecules of a gas in a discharge tube
A) low speed neutrons B) high speed neutrons
C) low speed electrons D) high speed electrons
Q. 85 What is the range of Azimuthal Quantum number(l)?
A) to n B) to s
C) to n-1 D) to s-1
Q. 86 The 'm' quantum number describes the _______of electron
A) energy level B) orbital or subshell
C) orientation of orbital D) Spin of electron
Q. 87 How many electrons can occupy in 7th energy level of an atom. Calculate by using 2n2 formula
A) 24 B) 5
C) 72 D) 98
Q. 88 The e/m value is maximum for _____gas because of _____value of "m" for positive rays obtained
from it.
A) Oxygen gas, lowest B) hydrogen gas, highest
C) hydrogen gas ,lowest D) helium gas ,highest
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Q. 89 Wave packet or quantum is often called photon in case of __________
A) energy B) brightness
C) light D) darkness
Q. 90 If uncertainty in momentum of electron is zero, the uncertainty in its position would be___?
A) Less than zero B) more then zero
C) one D) infinite
Q. 91 Quantum numbers specify the _of electron
A) shape B) energy
C) position D) all of these
Q. 92 The probability of finding an electron between s-orbital is zero. This place is called _____plane
A) nodal B) antinodal
C) non nodal D) erect
Q. 93 The region where probability of finding the electron is maximum is called as
A) Nucleus B) Atom
C) Orbital D) Nodal plane
Q. 94 The radius of an electron orbit in a hydrogen atom is of the order of
A) 1 -8 m B) 1 -1 m
C) 1 -11 m D) 1 -13 m
Q. 95 The value of Principal quantum number is _integers up to infinity
A) zero, positive B) non zero, positive
C) non zero, negative D) positive
Q. 96 Which of the following shows Planck's quantum theory
A) E=hcv B) E = cv
C) E=c/v D) none of these
Q. 97 a photon of wavelength 1 2.7 x1 5 m-1 is emitted when it jump from higher to n = 1,what will be
higher orbit
A) n = 2 B) n = 3
C) n = 4 D) n = 5
Q. 98 The region where probability of finding the electron is maximum is called as The region where
probability of finding the electron is maximum is called as
A) Nucleus B) Atom
C) Orbital D) Nodal plane
Q. 99 The region where probability of finding the electron is negligible is called as
A) Nucleus B) Atom
C) Orbital D) Nodal plane
Q. 100 According to 'n+l' rule ,the value of 6f is 9 while 7s orbital has '7' value, it shows
A) 6f filled first B) 7s placed first
C) 7s placed later D) 6f placed later
Q. 101 The order of size of 's' orbital is as follows
A) 4s<3s<2s<1s B) 4s>3s>2s>1s
C) constant D) none of these
Q. 102 According to Bohr, the orbits in which electrons revolve around the nucleus are
A) oval B) elliptical
C) cylindrical D) circular
Q. 103 When we calculate radii of Hydrogen atom by this equation r = .529A (n2) where n = 1,2,3,4,,the
distance between orbits of hydrogen atom will
A) decrease B) increase
C) remains same D) be constant
Q. 104 an element or its compound is first _____ to get its _________ spectrum by spectrometer
A) freezed,continuous B) freezed,line
C) volatilized, line D) volatilized,continuous
Q. 105 If n = 4 it will contain sub shells
A) s B) p
C) s,p,d D) s,p,d,f
Q. 106 Electrons can revolve only in those orbits having _______-angular momentum which depends on
its ______ number.
A) variable, quantum B) fixed, principal
C) fixed, quantum D) variable, principal

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Q. 107 Each electron in an atom must have its own unique set of quantum number is a statement of ____
A) Aufbau principle B) Pauli exclusion principle
C) Hund’s rule D) none of these
Q. 108 An electron in an atom is completely described by its
A) 2 quantum numbers B) only one quantum number
C) four quantum numbers D) 3 quantum numbers
Q. 109 Which character of p-orbital determines the geometry of molecules
A) planar B) axial
C) non directional D) directional
Q. 110 Quantum numbers specify the _of electron
A) shape B) energy
C) position D) all of these
Q. 111 The presence of several fine lines in line spectrum shows the presence of
A) shells B) energy levels
C) sub shells D) all of these
Q. 112 Who discovered positive rays also called protons and when?
A) Chadwick,1895 B) Goldstein,1886
C) Rutherford,1885 D) J.Perrin,1885
Q. 113 For a sub shell l=2 and m = -2,-1, ,+1,+2,it implies that it has _________ space orientation
A) one B) two
C) three D) five
Q. 114 _____cathode is used in discharge tube experiment for discovery of protons
A) flat B) round
C) perforated D) oval
Q. 115 The maximum number of electron accommodated in a shell or energy level is calculated by
formula
A) n2 B) 2n2
C) 2n D) 3n
Q. 116 According to________ theory, atoms were the ultimate particles that cannot be divided further.
A) Bohr's B) Rutherford's
C) Dalton's D) cannizzaro's
Q. 117 The region where probability of finding the electron is maximum is called as
A) Nucleus B) Atom
C) Orbital D) Nodal plane
Q. 118 Quantum numbers are set of numerical values which give solution to the equation
A) planks B) Heisenberg
C) Schrödinger D) all of these
Q. 119 For the study of particles, discharge tube is filled with
A) gas B) air
C) vapours of a substance D) all of these
Q. 120 How many electrons can occupy in 7th energy level of an atom. Calculate by using 2n2 formula
A) 24 B) 5
C) 72 D) 98
Q. 121 Quantum numbers specify the _of electron
A) shape B) energy
C) position D) all of these
Q. 122 Canal rays are produced in the discharge tube from________?
A) Anode B) Cathode
C) Gas molecules in the tube D) None of these
Q. 123 When an electron changes its orbit from outer to inner level, energy is
A) no change B) absorbed
C) released D) remains constant
Q. 124 An orbital can accommodate at the most _electrons
A) 2 B) 14
C) 1 D) 6
Q. 125 Positive rays are produced when ________strike the molecules of a gas in a discharge tube
A) low speed neutrons B) high speed neutrons
C) low speed electrons D) high speed electrons
Q. 126 The value of Principal quantum number "n" represent

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 A) energy of electron B) location of electron
C) shells or energy levels D) all of these
Q. 127 The value of Principal quantum number "n" represent
A) energy of electron B) location of electron
C) shells or energy levels D) all of these
Q. 128 the mass of proton is _times heavier that
A) 1889,electrons B) 1886.electrons
C) 1836,protons D) 1836,electrons
Q. 129 According to________ theory, atoms were the ultimate particles that cannot be divided further.
A) Bohr's B) Rutherford's
C) Dalton's D) cannizzaro's

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